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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 181 records · Page 10

Monitoring Immune System Function and Reactivation of Latent Viruses in the Artificial Gravity Pilot Study

Numerous studies have indicated that dysregulation of the immune system occurs during or after spaceflight. Using 21 day -6 degrees head-down tilt bed rest as a spaceflight analog, this study describes the effects of artificial gravity (AG) as a daily countermeasure on immunity, stress and reactivation of clinically important latent herpes viruses. The specific aims were to evaluate psychological and physiological stress, to determine the status of the immune system, and to quantify reactivation of latent herpes viruses. Blood, saliva, and urine samples were collected from each participating subject at different times throughout the study. An immune assessment was performed on all treatment and control subjects that consisted of a comprehensive peripheral immunophenotype analysis, intracellular cytokine profiles and a measurement of T cell function. The treatment group displayed no differences throughout the course of the study with regards to peripheral leukocyte distribution, cytokine production or T cell function. Shedding of Epstein barr virus (EBV), Cytomegalovirus (CMV), and Varicella zoster virus (VZV) was quantified by real time PCR in saliva and urine samples, respectively. There was no significant difference in CMV DNA in the treatment group as compared to the control group. EBV and VZV on the other hand showed a mild reactivation during the study. There were no significant differences in cortisol between the control and treatment groups. In addition, no significant differences between antiviral antibody titers (EBV-VCA, -EA, -EBNA, CMV) or tetramer-positive (EBV, CMV) were found between the two groups. EBV DNA copies in blood were typically undetectable but never exceeded 1,500 copies per 106 PBMCs. Overall, these data indicate that the artificial gravity countermeasure and the 21 day head-down tilt bed rest regimen had no observable adverse effect on immune function.

Mehta, Satish K.↗

NACA Zero Power Reactor Facility Hazards Summary

The Lewis Flight Propulsion Laboratory of the National Advisory Committee for Aeronautics proposes to build a zero power research reactor facility which will be located in the laboratory grounds near Clevelaurd, Ohio. The purpose of this report is to inform the Advisory Commit tee on Reactor Safeguards of the U. S. Atomic Energy Commission in re gard to the design of the reactor facility, the cha,acteristics of th e site, and the hazards of operation at this location, The purpose o f this reactor is to perform critical experiments, to measure reactiv ity effects, to serve as a neutron source, and to serve as a training tool. The reactor facility is described. This is followed by a discu ssion of the nuclear characteristics and the control system. Site cha racteristics are then discussed followed by a discussion of the exper iments which may be conducted in the facility. The potential hazards of the facility are then considered, particularly, the maximum credib le accident. Finally, the administrative procedure is discussed.

Source record↗

Dynamic Modeling of a Fast Spectrum Molten Salt Reactor Integrated Energy System

Liquid-fueled molten salt fast reactors and nuclear-powered integrated energy systems (IESs) have the potential to play a pivotal role in the green energy transition. However, these systems have little to no operating experience. There is therefore increased interest and value in modeling and simulating these systems. The IES dynamic model developed in this work utilizes a lumped-parameter control volume methodology to investigate the behavior of the IES in a variety of accident scenarios. The results provide initial evidence for the potential inherent safety of the advanced reactor because of temperature-dependent reactivity feedback and the efficiency of hydrogen and electricity production at the high temperatures provided by the advanced reactor.

MCFR↗

In situ measurement of reactive neutral constituents in the thermosphere by atomic and molecular resonance fluorescence

The Tethered Satellite System in combination with in situ atomic and molecular resonance fluorescence techniques can treat the problem of simultaneously determining the absolute density of atomic and molecular species known to control the photochemical structure of the upper atmosphere. Two familities of reactants which can be treated by these techniques are the nitrogen oxygen family and the hydrogen oxygen family.

Anderson, J. G.↗

REACCH - Reactive Electro-Adhesive Capture ClotH Mechanism to Enable Safe Grapple of Cooperative/Non-Cooperative Space Debris

USC’s Space Engineering Research Center (SERC) and the Jet Propulsion Laboratory (JPL) have created a unique “octopus” tentacle end effector for robotic systems that uses formable electro-adhesion (EA) and Gecko adhesion capture cloth material. REACCH, or Reactive Electro-Adhesive Capture ClotH, supports soft capture of objects of any size, shape, surface finish or material on-orbit. To-date SERC/JPL have developed initial tentacles and backing spines that can control the EA/G material. Prototypes with two tentacles have been demonstrated and tested on a 3-DOF air bearing device in 1g in one plane of grip. The results show promise to further develop this new type of grappling mechanism able to make first soft contact with an object, with a technology that merges compliance and control elements for future on-orbit servicing and assembly missions. This paper presents the initial design and test results on this type of system.

Narayanan, Sriram↗

An unwanted guest in the electrochemical oxidation of high-voltage Li-ion battery electrolytes: the life of highly reactive protons

Lithium-ion batteries (LIBs) are central to the urgent societal need to decarbonize both transportation and energy storage on the grid. Unfortunately, despite their attractive energy/power density, as well as high coulombic and energy efficiencies, further improvement of this technology – especially their durability – is desperately needed. To support these efforts, our study focuses on fundamental understanding of the decomposition pathways for LIB electrolytes at the cathode–electrolyte interface (CEI), as the nature of these reactions directly controls the extent to which cell capacity and voltage decays in these systems. In this study, we employ electrochemical methods, coupled with product analysis using NMR spectroscopy and mass spectrometry, to determine the decomposition mechanisms in both model and technologically relevant electrolytes. Remarkably, we discovered the electrochemical formation of protons with high chemical activity, comparable to known superacids, at potentials relevant to practical Li-ion batteries. Their reactivity toward every individual component of the CEI provides a unified thermochemical origin for a myriad of side reactions that are commonly associated with the electrochemical reaction. In particular, electrochemically generated protons react with intact EC molecules to form CO 2 and other short and long chain ethers. They also undergo an acid–base reaction with LiPF 6 , to form the weaker acid HF, and with the cathode active material, leaching transition metals into the electrolyte. Collectively, the results of this study all point to the urgent need to either mitigate this proton formation or introduce benign harvesting additives via new electrolyte design strategies.

Ilic, Stefan [Argonne National Laboratory (ANL), A↗

CyRRL (Cyber Resilient Reinforcement Learning for grid voltage control) [SWR-24-115]

This codebase contains a multi-agent, actor-critic reinforcement learning implementation for cyber-resilient grid voltage control. It uses a 123-bus OpenDSS system as the environment, with three-phase power flow translating nodal power injections into solved nodal voltages. The reward function penalizes deviations from nominal voltage as well as reactive power dispatch, while encouraging agents to take actions that result in fast convergence to nominal conditions. The codebase models false data injection attacks and includes functionality for training, testing, hyper-parameter tuning, and visualization.

Murphy, Sinnott [National Renewable Energy Laborat↗

Introduction to Grid Forming Inverters: A Key to Transforming our Power Grid [Slides]

A grid-forming (GFM) inverter-based resource (IBR) controls maintain an internal voltage phasor that is constant or nearly constant in the sub-transient to transient time frame. This definition means that the GFM IBR will nearly immediately respond to changes in the external system and attempt to maintain IBR control during challenging network conditions to maintain grid stability. In GFM IBR, the voltage phasor is controlled to maintain synchronism with other devices in the grid while regulating the active and reactive power appropriately to support the grid. This contrasts with conventional GFL IBR controls wherein immediately after a disturbance (0-5 cycles), within the normal operating range of voltage, the output current phasor magnitude and angle remain unchanged, and the current phasor begins changing only within the transient time frame (tens of cycles) to strictly control the active and reactive power being injected into the network. This presentation gives an introduction to GFM IBR and presents the current state of the art in this area.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Three axis attitude control system

A three-axis attitude control system for an orbiting body comprised of a motor driven flywheel supported by a torque producing active magnetic bearing is described. Free rotation of the flywheel is provided about its central axis and together with limited angular torsional deflections of the flywheel about two orthogonal axes which are perpendicular to the central axis. The motor comprises an electronically commutated DC motor, while the magnetic bearing comprises a radially servoed permanent magnet biased magnetic bearing capable of producing cross-axis torques on the flywheel. Three body attitude sensors for pitch, yaw and roll generate respective command signals along three mutually orthogonal axes (x, y, z) which are coupled to circuit means for energizing a set of control coils for producing torques about two of the axes (x and y) and speed control of the flywheel about the third (z) axis. An energy recovery system, which is operative during motor deceleration, is also included which permits the use of a high-speed motor to perform effectively as a reactive wheel suspended in the magnetic bearing.

Studer, Philip A.↗

Comparing Control Performance Between Simulation and Experiment using the Microreactor Automated Control System Testbed

In the advanced reactor domain, a flexible and scalable software/hardware infrastructure is crucial for integrating and validating various control technologies. This study used the Microreactor Automated Control System (MACS) hardware platform as a testbed. MACS was originally designed to mirror Idaho National Laboratory (INL)'s Microreactor Applications Research Validation and Evaluation (MARVEL), a 85-kW thermal fission microreactor. It features control drums for simulated reactivity control; lights that function as a surrogate reactor core, with the brightness being proportional to the reactor power; and light sensors that emulate neutron detectors. To transform MACS into a physical twin of MARVEL for evaluating control methods, the Control and Optimization Modular Modeling Application for Nuclear Deployment (COMMAND) software was employed. This software integrated the hardware with two models of the MARVEL core, based on Reactor Excursion and Leak Analysis Program (RELAP5-3D) and Monte Carlo N-Particle (MCNP) models. The study aimed to demonstrate the gap between control theory and actual practice—a gap that often necessitates empirical adjustments such as control gain retuning, filters, time discretization, and integrator anti-windup measures. Controllers were developed based on increasingly complex simulations without hardware, starting from the base MARVEL model and then introducing actuator saturation constraints and sensor noise. The final control strategy was then tested using MACS, and a comparative performance analysis was conducted.

46 - INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AN↗

Sources, Sinks, and the Distribution of OH in the Lower Stratosphere

Extensive measurement campaigns by the NASA ER-2 research aircraft have obtained a nearly pole-to-pole database of the species that control HOx (OH + HO2) chemistry. The wide dynamic range of these in situ measurements provides an opportunity to demonstrate empirically the mechanisms that control the HOx system. Measurements in the lower stratosphere show a remarkably tight correlation of OH concentration with the solar zenith angle (SZA). This correlation is nearly invariant over latitudes ranging from 70 S to 90 N and all seasons. An analysis of the production and loss of HOx in terms of the rate determining steps of reaction sequences developed by Johnston and Podolske and Johnston and Kinnison is used to clarify the behavior of the system and to directly test our understanding of the system with observations. Calculations using in situ measurements show that the production rate of HOx is proportional to O3 and ultraviolet radiation flux. The loss rate is proportional to the concentration and the partitioning of NOy (reactive nitrogen) and the concentration of HO2. In the absence of heterogeneous reactions, the partitioning of NOy is controlled by O3 and NOx and the concentration of HO2 is controlled by NOy and O3, so that the removal rate of OH is buffered against changes in the correlation of O3 and NOy. The heterogeneous conversion of NO2 to HNO3 is not an important net source of HO, because production and removal sequences are nearly balanced. Changes in NOy partitioning resulting from heterogeneous chemistry have a large effect on the loss rates of HOx, but little or no impact on the measured abundance of OH. The enhanced loss rates at high NO2/HNO3 are offset in the data set examined here by enhanced production rates resulting from increased photolysis rates resulting from the decreased O3 column above the ER-2.

Hanisco, T. F.↗

Description of a 20 Kilohertz power distribution system

A single phase, 440 VRMS, 20 kHz power distribution system with a regulated sinusoidal wave form is discussed. A single phase power system minimizes the wiring, sensing, and control complexities required in a multi-sourced redundantly distributed power system. The single phase addresses only the distribution link; mulitphase lower frequency inputs and outputs accommodation techniques are described. While the 440 V operating potential was initially selected for aircraft operating below 50,000 ft, this potential also appears suitable for space power systems. This voltage choice recognizes a reasonable upper limit for semiconductor ratings, yet will direct synthesis of 220 V, 3 power. A 20 kHz operating frequency was selected to be above the range of audibility, minimize the weight of reactive components, yet allow the construction of single power stages of 25 to 30 kW. The regulated sinusoidal distribution system has several advantages. With a regulated voltage, most ac/dc conversions involve rather simple transformer rectifier applications. A sinusoidal distribution system, when used in conjunction with zero crossing switching, represents a minimal source of EMI. The present state of 20 kHz power technology includes computer controls of voltage and/or frequency, low inductance cable, current limiting circuit protection, bi-directional power flow, and motor/generator operating using standard induction machines. A status update and description of each of these items and their significance is presented.

Hansen, I. G.↗

Description of a 20 kilohertz power distribution system

A single phase, 440 VRMS, 20 kHz power distribution system with a regulated sinusoidal wave form is discussed. A single phase power system minimizes the wiring, sensing, and control complexities required in a multi-sourced redundantly distributed power system. The single phase addresses only the distribution links multiphase lower frequency inputs and outputs accommodation techniques are described. While the 440 V operating potential was initially selected for aircraft operating below 50,000 ft, this potential also appears suitable for space power systems. This voltage choice recognizes a reasonable upper limit for semiconductor ratings, yet will direct synthesis of 220 V, 3 power. A 20 kHz operating frequency was selected to be above the range of audibility, minimize the weight of reactive components, yet allow the construction of single power stages of 25 to 30 kW. The regulated sinusoidal distribution system has several advantages. With a regulated voltage, most ac/dc conversions involve rather simple transformer rectifier applications. A sinusoidal distribution system, when used in conjunction with zero crossing switching, represents a minimal source of EMI. The present state of 20 kHz power technology includes computer controls of voltage and/or frequency, low inductance cable, current limiting circuit protection, bi-directional power flow, and motor/generator operating using standard induction machines. A status update and description of each of these items and their significance is presented.

Hansen, I. G.↗

Multiscale Dynamics of Reactive Fronts in the Subsurface

Understanding and predicting flow and reactive transport in rocks (i.e. geologic porous media) is critical to many technologies at the heart of the energy transition, including CO 2 sequestration and H2 storage. However, accurate modeling and prediction of these systems is very complex because physico-chemical processes that occur at very small spatial scales, i.e. in the pores of the rocks, can dramatically control the system performance at the field scale (km). For example, precipitation reactions at the pore-scale can lead to large permeability changes at the field scale and dramatically alter the migration of stored gases. Properly accounting for multi-scale coupling effects is critical to achieve predictivity and confidence in model outputs, which then can guide design and optimization at the system-scale. This can be achieved through the development of rigorous mathematical models that can appropriately account for fine-scale effects at the large scale. The final report of the Early Career award DE-SC0019075 “Multiscale dynamics of reactive fronts in the subsurface” summarizes the mathematical, numerical and experimental advancements to study and predict reactive transport in geologic porous media across scales.

58 GEOSCIENCES↗

Calcium-Magnesium-Alumino-Silicates (CMAS) Reaction Mechanisms and Resistance of Advanced Turbine Environmental Barrier Coatings for SiC/SiC Ceramic Matrix Composites

Environmental barrier coatings (EBCs) and SiC/SiC ceramic matrix composites (CMCs) systems will play a crucial role in future turbine engines for hot-section component applications because of their ability to significantly increase engine operating temperatures, reduce engine weight and cooling requirements. The development of prime-reliant environmental barrier coatings is an essential requirement to enable the applications of the 2700-3000 F EBC - CMC systems. This presentation primarily focuses on the reaction mechanisms of advanced NASA environmental barrier coating systems, when in contact with Calcium-Magnesium Alumino-Silicates (CMAS) at high temperatures. Advanced oxide-silicate defect cluster environmental barrier coatings are being designed for ultimate balanced controls of the EBC temperature capability and CMAS reactivity, thus improving the CMAS resistance. Further CMAS mitigation strategies are also discussed.

Environmental barrier coatings (EBCs)↗

Smart Droplets Stabilized by Designer Surfactants: From Biomimicry to Active Motion to Materials Healing

The science and technologies of emulsion droplets have been a long‐term focus of extensive research endeavors for their practical utility across a breadth of industries, including pharmaceutical products, oil recovery processes, and the food sciences. However, with advances in materials chemistry and characterization tools, new emerging areas are arising with a focus on “smart droplets”. The versatility of emulsion droplets across is based on their ability to partition and create isolated systems with properties defined by the liquid–liquid interface, while preparative routes allow manipulation of droplet size, stability, and encapsulated contents. As described in this article, significant efforts are being devoted to creating new types of droplets by “activating” this interface through the incorporation of reactive structures that trigger droplet response to applied or environmental stimuli (e.g., pH, temperature, salt, or external fields). Moreover, parallels between droplets and live cells inspire efforts to conceive systems that resemble biological motifs or that can produce cellular behaviors that imitate biology (e.g., swarming, communication, or motion). Here, the authors highlight recent advances in smart droplets, with emphasis on organic, polymer, and/or particle surfactants that give rise to inter‐droplet communication (via aggregation, fusion, division, or mass transfer), droplet vehicles for controlled delivery, autonomous droplet motion, and tunable emulsion inversion. Especially emphasized is the macromolecular design to produce reactive and functional surfactants, which are crucial to responsive droplet behavior and their underlying mechanisms. More generally, the exquisite interplay between materials science and biology inspires the review of this research area that provides unique opportunities for insight and inspiration into the capabilities of new droplet designs.

36 MATERIALS SCIENCE↗

Automatic Processing of Reactive Polymers

A series of process modeling computer codes were examined. The codes use finite element techniques to determine the time-dependent process parameters operative during nonisothermal reactive flows such as can occur in reaction injection molding or composites fabrication. The use of these analytical codes to perform experimental control functions is examined; since the models can determine the state of all variables everywhere in the system, they can be used in a manner similar to currently available experimental probes. A small but well instrumented reaction vessel in which fiber-reinforced plaques are cured using computer control and data acquisition was used. The finite element codes were also extended to treat this particular process.

Roylance, D.↗

Rationalizing Burned Carbon with Carbon Monoxide Exported from South America

We present several estimates cross-checking the fluxes of carbon to the atmosphere from burning, comparing models that are based on simple land-surface parameterizations and atmospheric transport dynamics. Both estimates made by NASA Ames and USP modeling techniques are quite high compared to some detailed satellite/land-use studies of emissions. The flux of carbon liberated to the atmosphere via biomass burning is important for several reasons. This flux is a fundamental statistic for the parameterization of the large-scale flux of gases controlling the reactive greenhouse gases methane and ozone. Similarly, it is central to the estimation of the translocation of nitrogen and pyrodenitrification in the tropics. Thirdly, CO2 emitted from rainforest clearing contributes directly to carbon lost from the rainforest system as it contributes to greenhouse gas forcing. While CO2 from pasturage, agriculture, etc, is considered to be reabsorbed seasonally, and so "off budget" for the carbon cycle, it must also be accounted. CO2 anomalies related to daily weather and interannual climatic variation are strong enough to perturb our scientific perception of long-term carbon storage trends. We compare fluxes deduced from land-use statistics (originally, W.M. Hao) and from satellite hot pixels (A. Setzer) with atmospheric fluxes determined by the mesoscale/continental scale models RAMS and MM5, and point to some new work with highly resolved global models (the NASA Data Assimilation Office's GEOS4). Our simulations are tied to events, so that measured tracers like CO tie the models directly to the burning and meteorology of a specific period. We point out a particular sensitivity in estimates based on CO, and indicate how analysis of CO2 along with other biomass-burning tracers may lead to an improved multi-species estimator of carbon burned.

Chatfield, R.↗