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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 181 records · Page 10

Chiral microwave nonreciprocity demonstrated via Rayleigh and Sezawa modes supported in an Al 0.58 ⁢Sc 0.42 ⁢N/4⁢H–Si⁢C platform

Chirality plays a crucial role in the helicity mismatch between surface acoustic waves and magnetic spin waves, leading to nonreciprocal transmission of acoustic power for coupled magnetoacoustic modes. Acoustic modes with both longitudinal and shear strain exhibit elliptical particle displacements, making them chiral, and different acoustic modes can exhibit different helicities of this elliptical particle displacement. Here, we study chiral acoustic modes with different helicities supported on the same piezoelectric platform and their interaction with magnetic spin waves. Our study demonstrates that the nonreciprocal transmission of acoustic power is driven by the helicity mismatch effect and, specifically, that the handedness of the nonreciprocity is based on whether the surface acoustic wave has retrograde (Rayleigh mode) or prograde (Sezawa mode) elliptical particle displacement with respect to the propagation direction. We found the transmission nonreciprocity to be significant, with 7.3 dB/mm for the retrograde particle displacement (Rayleigh mode at 2.358 GHz) and 3.3 dB/mm for prograde particle displacement (Sezawa mode at 3.112 GHz). Furthermore, this work highlights that piezoelectric platforms can be engineered to support acoustic modes with opposite helicities to enable frequency-selective nonreciprocal radiofrequency and microwave components, such as isolators and circulators, through coupled acoustic spin wave interactions.

42 ENGINEERING↗

Improper ferroelectricity in 134-type $AA_3'B_4\text{O}_{12}$ perovskites

The 134-type $\textit{A}$-site ordered LaMn 3 Cr 4 O 12 , that belongs to the family of $AA_3'B_4\text{O}_{12}$ perovskites, with cubic structure and magnetically driven improper polarization is puzzling because the conventional mechanisms leading to the creation of polarization in type-II multiferroics do not apply. By symmetry analysis and first-principles simulations in this work, we discover an original and previously overlooked energetic term that naturally explains the origin of improper polarization in LaMn 3 Cr 4 O 12 . In addition, we demonstrate the existence of three other energetic invariants in $AA_3'B_4\text{O}_{12}$ perovskites, for which other physical quantities (such as oxygen tiltings or shear strain) mediate the interaction between $\textit{G}$-type antiferromagnetic vectors to create and even enhance improper polarization.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Observations of twinning microstructure in iron ramp-compressed through the α – ε phase transition

Single crystal iron was ramp-compressed along the [100] axis at 4 GPa/ns through the α–ϵ phase transformation at 13 GPa. Unlike shock experiments, in these ramp compression experiments the bcc lattice is observed to be nearly isotropically relaxed before the phase transition. There was a mixed α/ϵ phase region starting at ~13 GPa which was observed for 0.75 ns until the peak stress of 18 GPa was reached. In situ x-ray diffraction measurements show the formation of new hcp orientations not reported in shock or quasistatic compression experiments. The new hcp orientations appear to be caused by {10¯11} <10¯1 ¯2> → {¯1011} <¯101¯2> sequential twins that occur during the phase transition. This twinning mechanism relieves the shear strain caused by the bcc-hcp phase transition from the isotropically relaxed bcc phase while subject to uniaxial compression. Furthermore, these results show that in iron the induced microstructure through a phase transition and the phase transition mechanism depend on the loading history.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Analysis of real-fluid thermodynamic effects on turbulent statistics in transcritical channel flows

Wall-bounded turbulence at high-pressure transcritical conditions with intense density fluctuations are encountered in many technical applications. In this study, we analyze the turbulent energy transport in transcritical channel flows specifically focusing on dissipation rate, turbulent kinetic energy budgets, heat fluxes, and momentum-fluctuation statistics; results from this analysis are used to guide the development of turbulent scaling laws. Furthermore, we find that the dissipation rate of turbulent kinetic energy is dominated by the enstrophy in the logarithmic layer, and the fluctuating viscosity results in the reduced tilting of the vortical structures and the attenuation of streamwise vorticity in the near-wall layer; the fluctuating viscosity attenuates the dissipation rate by reducing the shear strain and the enstrophy production. Local equilibrium of the turbulent kinetic energy exists in the logarithmic layer. We show that the real-fluid thermodynamic effects significantly change the turbulent heat flux correlated with the sweep and the ejection events; the density changes alter the turbulent transport and result in noticeable magnitudes of density-fluctuation-related momentum-fluctuation statistics. From these results, scaling laws for the turbulent length scales and turbulent kinetic energy budgets are proposed, thereby contributing to improvement of the wall models in large-eddy simulations and Reynolds-averaged Navier-Stokes (RANS) simulations.

42 ENGINEERING↗

Toward wide-spectrum antivirals against coronaviruses: Molecular characterization of SARS-CoV-2 NSP13 helicase inhibitors

To date, effective therapeutic treatments that confer strong attenuation against coronaviruses (CoVs) remain elusive. Among potential drug targets, the helicase of CoVs is attractive due to its sequence conservation and indispensability. We rely on atomistic molecular dynamics simulations to explore the structural coordination and dynamics associated with the SARS-CoV-2 Nsp13 apo enzyme, as well as their complexes with natural ligands. A complex communication network is revealed among the five domains of Nsp13, which is differentially activated because of the presence of the ligands, as shown by shear strain analysis, principal components analysis, dynamical cross-correlation matrix analysis, and water transport analysis. The binding free energy and the corresponding mechanism of action are presented for three small molecules that were shown to be efficient inhibitors of the previous SARS-CoV Nsp13 enzyme. Together, our findings provide critical fresh insights for rational design of broad-spectrum antivirals against CoVs.

59 BASIC BIOLOGICAL SCIENCES↗

Large-Volume Stimulation of Rock for Greatly Enhanced Fluids Recovery using Targeted Seismic-Assisted Hydraulic Fracturing (Final Technical Report)

This project has developed and demonstrated a new technology for large-volume and targeted comminution of rock in low permeability formations to enhance recovery from unconventional oil and gas (UOG) resources. The technology is based on a strategically designed interaction of multiple induced seismic pulses that assist the hydraulic fracturing process to enhance shear and multi-planar crack formation. This greatly increased rock stimulation, through bulk comminution, is expected to cause significant increase in permeability leading to enhancement of recovery factors for sub- surface fluids. The proposed technology is especially applicable for enhanced recovery in emerging UOG plays, such as ductile shales that are resistant to opening-mode fracturing by conventional hydraulic fracturing processes. The project combines an integrated experimental and computation approach to develop and demonstrate a modular technology that can be easily implement in the field to augment current practices. The effort integrates a fundamental scientific understanding of dynamic material response under constraint and damage-induced permeability and porosity enhancements at multiple length scales, along with models of comminution due to the local release of kinetic energy associated with high shear strain rate of dynamic deformation. The results will be validated through small-scale experiments and then implemented in a lab-scale field test to demonstrate the developed technology. The project involves collaboration between a solid mechanician, a materials scientist, and a petroleum engineering geo-mechanician. It builds on a successful history of success and collaboration that includes both fundamental scientific exploration and technology development.

04 OIL SHALES AND TAR SANDS↗

Density and stress distribution in the moon.

A model is presented for the lateral variations of density within the moon. The model gives rise to a gravitational potential which is equal to the observed potential at the lunar surface; moreover, it minimizes the total shear-strain energy of the moon. The model exhibits lateral variations of about plus or minus 0.25 g/cc within 50 km depth. The variations, however, reduce to plus or minus 0.06 and plus or minus 0.008 g/cc within layers at 50 to 135 and 135 to 235 km respectively, and they become negligible below this region. The associated stress differences are found to be about 50 bar within 600 km depth, having their maximum values of about 90 bars at a depth of about 250 km. On the basis of these stress differences a strength of about 100 bar is concluded for the upper 400 km of the lunar interior for the last 3.3 b.y.

Arkani-Hamed, J.↗

Lateral density variations in elastic Earth models from an extended minimum energy approach

Kaula's minimum energy approach was extended to include the nonhydrostatic gravitational potential energy and the density perturbation field was obtained to degree and order eight. The depth profiles for the density perturbation show a stratification with density excesses and deficiencies alternating with depth. The addition of the gravitational potential energy in the minimization process does not change significantly the conclusions based on results for the minimum shear strain energy case, concerning the inability of the mantle to withstand the lateral loading elastically.

Sanchez, B. V.↗

Gravitational potential energy of the earth - A spherical harmonic approach

A spherical harmonic equation for the gravitational potential energy of the earth is derived for an arbitrary density distribution by conceptually bringing in mass-elements from infinity and building up the earth shell upon spherical shell. The zeroth degree term in the spherical harmonic expansion agrees with the usual expression for the energy of a radial density distribution. The second degree terms give a maximum nonhydrostatic energy in the crust and mantle of -2.77 x 10 to the 29th ergs, an order of magnitude below McKenzie's (1966) estimate. McKenzie's result stems from mathematical error. Our figure is almost identical with Kaula's (1963) estimate of the minimum shear strain energy in the mantle, a not unexpected result on the basis of the virial theorem. If the earth is assumed to be a homogeneous viscous oblate spheroid relaxing to an equilibrium shape, then a lower limit to the mantle viscosity of 1.3 x 10 to the 20th P is found by assuming that the total geothermal flux is due to viscous dissipation of energy. This number is almost six orders of magnitude below MacDonald's (1966) estimate of the viscosity and removes his objection to convection. If the nonequilibrium figure is dynamically maintained by the earth acting as a heat engine at 1% efficiency, then the viscosity is 10 to the 22nd P, a number preferred by Cathles (1975) and Peltier and Andrew (1976) as the viscosity of the mantle.

Rubincam, D. P.↗

A mixed formulation finite element for linear thin shell analysis

An eight node curved thin shell slement was tested. The element is based on the degenerate solid concept and the mixed formulation with the independent inplane and transverse shear strains. The number of unknown parameters in the assumed strains is chosen to alleviate the spurious constaining or locking effect. It is indicated that for a pinched cylindrical shell with diaphragmed ends and fixed ends the present element shows good performance.

Lee, S. W.↗

Imide modified epoxy matrix resins

Results of a program designed to develop tough imide modified epoxy (IME) resins cured by bisimide amine (BIA) hardeners are presented. State of the art epoxy resin, MY720, was used. Three aromatic bisimide amines and one aromatic aliphatic BIA were evaluated. BIA's derived from 6F anhydride (3,3 prime 4,4 prime-(hexafluoro isopropyl idene) bis (phthalic anhydride) and diamines, 3,3 prime-diam nodiphenyl sulfone (3,3 prime-DDS), 4,4 prime-diamino diphenyl sulfone (4,4 prime-DDS), 1.12-dodecane diamine (1,12-DDA) were used. BIA's were abbreviated 6F-3,3 prime-DDS, 6F-4,4 prime-DDS, 6F-3,3 prime-DDS-4,4 prime DDS, and 6F-3,3 prime-DDS-1,12-DDA corresponding to 6F anhydride and diamines mentioned. Epoxy resin and BIA's (MY720/6F-3,3 prime-DDS, MY720/6F-3,3 prime-DDS-4,4 prime-DDS, MY720/6F-3,3 prime-DDS-1,12-DDA and a 50:50 mixture of a BIA and parent diamine, MY720/6F-3,3 prime-DDS/3,3 prime-DDS, MY720/6F-3,3 prime-DDS-4,4 prime-DDS/3,3 prime-DDS, MY720/6F-3,3 prime-DDS-1,12-DDA/3,3 prime-DDS were studied to determine effect of structure and composition. Effect of the addition of two commercial epoxies, glyamine 200 and glyamine 100 on the properties of several formulations was evaluated. Bisimide amine cured epoxies were designated IME's (imide modified epoxy). Physical, thermal and mechanical properties of these resins were determined. Moisture absorption in boiling water exhibited by several of the IME's was considerably lower than the state of the art epoxies (from 3.2% for the control and state of the art to 2.0 wt% moisture absorption). Char yields are increased from 20% for control and state of the art epoxies to 40% for IME resins. Relative toughness characteristics of IME resins were measured by 10 deg off axis tensile tests of Celion 6000/IME composites. Results show that IME's containing 6F-3,3 prime-DDS or 6F-3,3 prime-DDS-1,12-DDA improved the "toughness" characteristics of composites by about 35% (tensile strength), about 35% (intralaminar shear strength), and about 78% (shear strain to failure) relative to the control composite.

Scola, D. A.↗

Synthesis and characterization of bisimide amines and bisimide amine-cured epoxy resins

An attempt is made to develop tough, moisture resistant, high char yield epoxy resins by means of novel bisimide amine (BIA) hardener curing agents and a state-of-the-art epoxy resin system. The BIAs are isolated as mixtures containing monomer, oligomer, and polymeric species, and then characterized by elemental analysis and high pressure liquid chromatography. The bisimide amine-cured epoxies (IMEs) were characterized with respect to moisture absorption, thermal properties, and physical and mechanical properties, as well as in the role of matrices in Celion 6000/IME composites. The relative toughness characteristics of each IME formulation was measured by the 10 deg off-axis tensile test, measuring the uniaxial tensile strength, shear strength, and shear-strain-to-failure of the composite systems.

Scola, D. A.↗

A triangular finite element for thin plates and shells

A finite element modeling technique which utilizes a triangular element called TSHEL with 45 degrees of freedom and seven point integration was tested for analysis of thin plate and shell structures. The element formulation is based on the degenerate solid shell concept and the mixed formulation with assumed independent inplane and transverse shear strains. The effectiveness of the present modeling technique which features combined use of elements with kinematic modes and those without kinematic modes to eliminate both locking and spurious kinematic modes at the global structural levels are shown.

Lee, S. W.↗

A higher-order shear deformation theory of laminated elastic shells

A higher-order shear deformation theory of elastic shells is developed for shells laminated of orthotropic layers. The theory is a modification of the Sanders' theory and accounts for parabolic distribution of the transverse shear strains through thickness of the shell and tangential stress-free boundary conditions on the boundary surfaces of the shell. The Navier-type exact solutions for bending and natural vibration are presented for cylindrical and spherical shells under simply supported boundary conditions.

Reddy, J. N.↗

A simplified computer solution for the flexibility matrix of contacting teeth for spiral bevel gears

A computer code, FLEXM, was developed to calculate the flexibility matrices of contacting teeth for spiral bevel gears using a simplified analysis based on the elementary beam theory for the deformation of gear and shaft. The simplified theory requires a computer time at least one order of magnitude less than that needed for the complete finite element method analysis reported earlier by H. Chao, and it is much easier to apply for different gear and shaft geometries. Results were obtained for a set of spiral bevel gears. The teeth deflections due to torsion, bending moment, shearing strain and axial force were found to be in the order 10(-5), 10(-6), 10(-7), and 10(-8) respectively. Thus, the torsional deformation was the most predominant factor. In the analysis of dynamic load, response frequencies were found to be larger when the mass or moment of inertia was smaller or the stiffness was larger. The change in damping coefficient had little influence on the resonance frequency, but has a marked influence on the dynamic load at the resonant frequencies.

Hsu, C. Y.↗