NASA NTRS1976
The amounts of volatiles incorporated in the Martian regolith by photostimulated oxidation weathering of Fe(2+)-bearing minerals are estimated. The process of photostimulated oxidation weathering is described, and it is noted that all the necessary constituents for this process are present on Mars. The rates at which oxygen and hydrogen are irreversibly removed from the Martian atmosphere by the present process are determined, irreversible and reversible water losses are considered, and the loss of CO2 by carbonate formation is shown to be irreversible. The results suggest that photostimulated oxidation weathering has irreversibly consumed 100 to 100,000 g/sq cm of H2O and 10 to 10,000 g/sq cm of CO2, assuming a uniform rate over geologic time. It is concluded that if the amounts of H2O and CO2 actually removed by photostimulated oxidation are close to the upper limits of the present estimates, then that process may have had a major effect in limiting the amount of H2O and CO2 trapped in the regolith and polar caps.