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NASA NTRS2019

Laboratory Investigations of Cloud Particle Formation and Sublimation on Titan, Mars, and Earth

Microphysical modeling of cloud formation and growth relies on fundamental measurements of the properties of condensable gases which form cloud particles. NASA's Ames Chemistry Laboratory has the capability to measure vapor pressures and heterogeneous nucleation conditions for a variety of gases found in the atmospheres of solar system bodies. Highlights from work for Earth, Mars, and Titan demonstrate the range of conditions and atmospheres studied to date.

Iraci, Laura T.↗
NASA NTRSDate not supplied

Observations on Fluidization, Particle Entrainment, Sublimation, and Evaporation During Tests Using Hydrated Regolith Simulants .

The presence of water ice in permanently shadowed regions on the lunar surface may enable a sustained human presence on the Moon with minimal need for consumables. In order to successfully extract water from lunar regolith, there are a few physical behaviors that should be accounted for when designing systems to handle icy regolith samples. Many of these behaviors have been observed and recorded in the process of testing ISRU technologies.

A. Paz↗
NASA NTRS2010

Trade Study for 9 kW Water Membrane Evaporator

Sublimators have been proposed and used in spacecraft for heat rejection. Sublimators are desirable heat rejection devices for short duration use because they can transfer large amounts of heat using little mass and are self-regulating devices. Sublimators reject heat into space by freezing water inside a porous substrate, allowing it to sublimate into vapor, and finally venting it into space. The state of the art thermal control system in orbiting spacecraft is a two loop, two fluid system. The external coolant loop typically uses a toxic single phase fluid that acquires heat from the spacecraft and rejects most of it via a radiator. The sublimator functions as a transient topper for orbiting spacecraft during day pass periods when radiator efficiency decreases. The sublimator interfaces with the internal loop through a built in heat exchanger. The internal loop fluid is non-toxic and is typically a propylene glycol and water solution with inhibitors to prevent corrosion with aluminum fins of the heat exchangers. Feedwater is supplied from a separate line to the sublimator to maintain temperature control of the cabin and vehicle hardware. Water membrane evaporators have been developed for spacecraft and spacesuits. They function similar to a sublimator but require a backpressure valve which could be actuated for this application with a simple fully open or fully closed modes. This technology would be applied to orbital thermal control (lunar or planetary). This paper details a trade study showing that evaporators would greatly reduce the consumable that is used, effectively wasted, by sublimators during start up and shut down during the topping phases of each orbit. State of the art for 9 kW sublimators reject about 870 W per kilogram of mass and 1150 W per liter of volume. If water with corrosion inhibitors is used the evaporators would be about 80% of the mass and volume of the equivalent system. The size and mass increases to about 110% if the internal fluid is 50% propylene glycol/50% water. The true benefit comes from the backpressure valve, that prevents the cyclical shutdown/startup loss of the sublimator and amounts to as much as 0.85 kg per orbit.

Bue, Grant C.↗
NASA NTRSDate not supplied

Comparative Analysis for EMU Fleet Latent Loading Characterization in Support of US EVA 80 Failure

During United States Extravehicular Activity 80 (US EVA 80), water was observed in the helmet of an Extravehicular Mobility Unit (EMU) during cabin repressurization. One of the primary mechanisms that can cause water in the helmet of an EMU is integrated performance induced sublimator carryover. The sublimator is a heat exchanger that removes heat and humidity from the ventilation loop. Water vapor is condensed from the gas and removed by slurper holes in the sublimator. Sublimator carryover is caused by the inability of the EMU sublimator to remove all of the condensed water vapor, resulting in liquid water entering the helmet. To determine if sublimator carryover was a likely cause of the US EVA 80 failure, a comparative analysis of numerous historical EVAs was conducted to calculate the total latent load (total water vapor generated by the crewmember) for numerous historical EVAs and ground tests using the Systems Improved Numerical Differencing Analyzer EMU (SINDA EMU) model. The analysis showed that US EVA 80 was associated with a comparatively high latent load when compared to other EVAs that did not present water in the helmet. Further, this analysis showed that other historical EVAs which had visible water in the helmet were also associated with higher latent loads. This analysis provides evidence that the likely cause of the US EVA 80 water in the helmet event was not the failure of an individual component, but rather sublimator carryover caused by excessive production of water vapor by the crewmember. The evidence from this analysis agrees with results from the Test, Teardown, and Evaluation (TT&E) of the EMU which did not show any failure of individual components of the EMU that would lead to water in the helmet.

Noah Andersen↗
NASA NTRS1977

The lifetime of ice particles in the solar system

The behavior of spherical water-ice particles in interplanetary space is investigated theoretically using an equation which gives the sublimation rate as a function of the solar energy distribution at 1 AU, solar distance, the temperature of the ice-particle surface, the temperature of the surrounding background, particle absorption efficiency, particle radius, and the complex refractive index of ice. The variation of sublimation rate with particle size is examined, and it is shown that the sublimation rate depends critically on the absorptivity of ice in the near-IR spectral region. Two different spectral-absorption curves are plotted on the basis of two different choices for the complex refractive index of ice, and an attempt is made to decide experimentally which energy distribution is more appropriate. Results of direct laboratory measurements of the sublimation rate of smooth spherical ice particles are compared with the theoretical results obtained from the cited sublimation-rate equation. Agreement between theory and experiment is found to be excellent when the complex refractive indices given by Bertie et al., (1969) are employed. Sublimation rates and particle lifetimes are then computed as a function of particle radius for heliocentric distances of 0.5, 0.75, and 1.0 AU.

Patashnick, H.↗
NASA NTRS1993

Equatorial ground ice on Mars: Steady-state stability

Current Martian equatorial surface temperatures are too warm for water ice to exist at the surface for any appreciable length of time before subliming into the atmosphere. Subsurface temperatures are generally warmer still and, despite the presence of a diffusive barrier of porous regolith material, it has been shown by Smoluchowski, Clifford and Hillel, and Fanale et al. that buried ground ice will also sublime and be lost to the atmosphere in a relatively short time. We investigate the behavior of this subliming subsurface ice and show that it is possible for ice to maintain at a steady-state depth, where sublimation and diffusive loss to the atmosphere is balanced by resupply from beneath by diffusion and recondensation of either a deeper buried ice deposits or ground water. We examine the behavior of equatorial ground ice with a numercial time-marching molecular diffusion model. In our model we allow for diffusion of water vapor through a porous regolith, variations in diffusivity and porosity with ice content, and recondensation of sublimed water vapor. A regolith containing considerable amounts of ice can still be very porous, allowing water vapor to diffuse up from deeper within the ice layer where temperatures are warmer due to the geothermal gradient. This vapor can then recondense nearer to the surface where ice had previously sublimed and been lost to the atmosphere. As a result we find that ice deposits migrate to find a steady-state depth, which represents a balance between diffusive loss to the atmosphere through the overlying porous regolith and diffusive resupply through a porous icy regolith below. This depth depends primarily on the long-term mean surface temperature and the nature of the geothermal gradient, and is independent of the ice-free porosity and the regolith diffusivity. Only the rate of loss of ground ice depends on diffusive properties.

Mellon, Michael T.↗
NASA NTRS2003

Survival of Amino Acids in Micrometeorites During Atmospheric Entry

The delivery of amino acids by micrometeorites to the early Earth during the period of heavy bombardment could have been a significant source of the Earth's prebiotic amino acid inventory provided that these organic compounds survived atmospheric entry heating. To investigate the sublimation of amino acids from a micrometeorite analog at elevated temperature, grains from the CM-type carbonaceous chondrite Murchison were heated to 550 C inside a glass sublimation apparatus (SA) under reduced pressure. The sublimed residue that had collected on the cold finger of the SA after heating was analyzed for amino acids by HPLC. We found that when the temperature of the meteorite reached approx. 150 C, a large fraction of the amino acid glycine had vaporized from the meteorite, recondensed onto the end of the SA cold finger, and survived as the rest of the grains heated to 550 C. alpha-Aminoisobutryic acid and isovaline, which are two of the most abundant non-protein amino acids in Murchison, did not sublime from the meteorite and were completely destroyed during the heating experiment. Our experimental results suggest that sublimation of glycine present in micrometeorite grains may provide a way for this amino acid to survive atmospheric entry heating at temperatures less than 550 C; all other amino acids apparently are destroyed. Key Words: Amino acids-Exogenous delivery-Micrometeorites-Sublimation.

Glavin, Daniel P.↗
NASA NTRS2011

Life Testing of Yb14MnSb11 for High Performance Thermoelectric Couples

The goal of this study is to verify the long term stability of Yb14MnSb11 for high performance thermoelectric (TE) couples. Three main requirements need to be satisfied to ensure the long term stability of thermoelectric couples: 1) stable thermoelectric properties, 2) stable bonding interfaces, and 3) adequate sublimation suppression. The efficiency of the couple is primarily based on the thermoelectric properties of the materials selected for the couple. Therefore, these TE properties should exhibit minimal degradation during the operating period of the thermoelectric couples. The stability of the bonding is quantified by low contact resistances of the couple interfaces. In order to ensure high efficiency, the contact resistances of the bonding interfaces should be negligible. Sublimation suppression is important because the majority of thermoelectric materials used for power generation have peak figures of merit at temperatures where sublimation rates are high. Controlling sublimation is also essential to preserve the efficiency of the couple. During the course of this research, three different life tests were performed with Yb14MnSb11 coupons. TE properties of Yb14MnSb11 exhibited no degradation after 6 months of aging at 1273K, and the electrical contact resistance between a thin metallization layer and the Yb14MnSb11 remained negligible after 1500hr aging at 1273K. A sublimation suppression layer for Yb14MnSb11 was developed and demonstrated for more than 18 months with coupon testing at 1273K. These life test data indicate that thermoelectric elements based on Yb14MnSb11 are a promising technology for use in future high performance thermoelectric power generating couples.

thermoelectric couples↗
NASA NTRS1973

Long life performance predictions of SiGe MHW-RTG.

Recent experimental investigations at JPL, Resalab and GGA are incorporated into an analytical model which predicts generator performance over long time periods. The important aging mechanisms considered are degradation in foil insulation conductivity due to reactions with Si sublimed from the hot shoe and SiO2 from the astroquartz layers; changes in hot shoe dimensions due to Si sublimation; changes in leg dimensions due to SiGe sublimation; baffling factors which are applied to the legs to correct the free sublimation model for various effects such as geometry, reactions with the astroquartz wrapping, and hot shoe Si generation; new bulk property changes due to dopant precipitation; and changes in radiation heat exchange due to gap streaming as leg material sublimes.

Caputo, R. S.↗
NASA NTRS1996

Mass Wasting and Ground Collapse in Terrains of Volatile-Rich Deposits as a Solar System-Wide Geological Process: The Pre-Galileo View

The polar terrains of Mars are covered in many places with irregular pits and retreating scarps, as are some of the surfaces of the outer-planet satellites. These features are interpreted by us as diagnostic of exogenic degradation due to the loss of a volatile rock-forming matrix or cement. In this study we propose that sublimation degradation is a plausible Solar Systemwide geological process. Candidate examples have been identified on Mars, Io, and Triton, and possibly Europa and Ganymede. We envision this process as having two end-member expressions (pits and scarps), for which we hypothesize two end-member mechanisms (massive localized lenses and areally extensive basal layers). In this study we focus on the role this process may play on the surfaces of the galilean satellites. Our principle modeling results are that for these satellites, H2S, CO2, and NH3 are the only viable candidate volatiles for sublimation degradation of landforms, in light of galilean satellite cosmochemistry. For Io's polar regions only H2S, and then only from slopes that face the Sun and have thin lags, is volatile enough to cause the observed sublimation-induced erosion at those latitudes. SO2 is not a viable candidate as an agent of erosion, especially for these polar landforms. In the case of Europa, only CO2 and H2S are viable candidates (given surface age constraints). Both species could be efficient eroders in nonpolar regions. H2S could generate erosion within the polar regions if the deposition and erosion conditions were essentially identical as those we invoked for Io's polar regions. For Ganymede (and Callisto) NH3 might be an agent of erosion in equatorial terrains of great age. The sublimation of CO2 and H2S is much more robust than NH3. The much slower rate of sublimation degradation from NH3 might be detectable by Galileo and used as a compositional indicator.

Moore, Jeffrey M.↗
NASA NTRS2006

Aerogel/Particle Composites for Thermoelectric Devices

Optimizing solution chemistry and the addition of titania and fumed silica powder reduces shrinkage. These materials would serve to increase thermal efficiency by providing thermal insulation to suppress lateral heat leaks. They would also serve to prolong operational lifetime by suppressing sublimation of certain constituents of thermoelectric materials (e.g., sublimation of Sb from CoSb3) at typical high operating temperatures. [The use of pure silica aerogels as cast-in-place thermal-insulation and sublimation-suppression materials was described in "Aerogels for Thermal Insulation of Thermoelectric Devices" (NPO-40630), NASA Tech Briefs, Vol. 30, No. 7 (July 2006), page 50.] A silica aerogel is synthesized in a solgel process that includes preparation of a silica sol, gelation of the sol, and drying of the gel in a solvent at a supercritical temperature and pressure. The utility of pure silica aerogel is diminished by a tendency to shrink (and, therefore, also to crack) during the gelation and supercritical-drying stages. Moreover, to increase suppression of sublimation, it is advantageous to make an aerogel having greater density, but shrinkage and cracking tend to increase with density. A composite material of the type under investigation consists mostly of titania oxide powder particles and a small addition of fumed silica powder, which are mixed into the sol along with other ingredients prior to the gelation stage of processing. The silica aerogel and fumed silica act as a binder, gluing the titania particles together. It is believed that the addition of fumed silica stiffens the aerogel network and reduces shrinkage during the supercritical-drying stage. Minimization of shrinkage enables establishment of intimate contact between thermoelectric legs and the composite material, thereby maximizing the effectiveness of the material for thermal insulation and suppression of sublimation. To some extent, the properties of the composite can be tailored via the proportions of titania and other ingredients. In particular (see figure), the addition of a suitably large proportion of titania (e.g., 0.6 g/cu cm) along with a 10-percent increase in the amount of tetraethylorthosilicate [TEOS (an ingredient of the sol)] to an aerogel component having a density 40 mg/cm3makes it possible to cast a high-average-density (>0.1 g/cm3) aerogel/particle composite having low shrinkage (2.3 percent).

Paik, Jong-Ah↗
NASA NTRS2011

Management of the Post-Shuttle Extravehicular Mobility Unit (EMU) Water Circuits

The EMU incorporates two separate water circuits for the rejection of metabolic heat from the astronaut and the cooling of electrical components. The first (the Transport Water Loop) circulates in a semi-closed-loop manner and absorbs heat into a Liquid Coolant and Ventilation Garment (LCVG) warn by the astronaut. The second (the Feed Water Loop) provides water to a cooling device (Sublimator) with a porous plate, and that water subsequently sublimates to space vacuum. The cooling effect from the sublimation of this water translates to a cooling of the LCVG water that circulates through the Sublimator. Efforts are underway to streamline the use of a water processing kit (ALCLR) that is being used to periodically clean and disinfect the Transport Loop Water. Those efforts include a fine tuning of the duty cycle based on a review of prior performance data as well as an assessment of a fixed installation of this kit into the EMU backpack or within on-orbit EMU interface hardware. Furthermore, testing is being conducted to ensure compatibility between the International Space Station (ISS) Water Processor Assembly (WPA) effluent and the EMU Sublimator as a prelude to using the WPA effluent as influent to the EMU Feed Water loop. This work is undertaken to reduce the crew-time and logistics burdens for the EMU, while ensuring the long-term health of the EMU water circuits for a post-Shuttle 6-year service life.

Steele, John W.↗
NASA NTRS2012

Management of the Post-Shuttle Extravehicular Mobility Unit (EMU) Water Circuits

The EMU incorporates two separate water circuits for the rejection of metabolic heat from the astronaut and the cooling of electrical components. The first (the Transport Water Loop) circulates in a semi-closed-loop manner and absorbs heat into a Liquid Coolant and Ventilation Garment (LCVG) worn by the astronaut. The second (the Feed-water Loop) provides water to a cooling device (Sublimator) with a porous plate, and that water subsequently sublimates to space vacuum. The cooling effect from the sublimation of this water translates to a cooling of the LCVG water that circulates through the Sublimator. Efforts are underway to streamline the use of a water processing kit (ALCLR) that is being used to periodically clean and disinfect the Transport Loop Water. Those efforts include a fine tuning of the duty cycle based on a review of prior performance data as well as an assessment of a fixed installation of this kit into the EMU backpack, within on-orbit EMU interface hardware or as a stand-alone unit. Furthermore, testing is being conducted to ensure compatibility between the International Space Station (ISS) Water Processor Assembly (WPA) effluent and the EMU Sublimator as a prelude to using the WPA effluent as influent to the EMU Feed Water loop. This work is undertaken to reduce the crewtime and logistics burdens for the EMU, while ensuring the long-term health of the EMU water circuits for a 6-year service life.

Steele, John W.↗
NASA NTRS2013

The Pinnacles of Callisto

Many regions of Callisto feature an unusual landscape consisting of rolling dark plains with interspersed bright knobs (pinnacles) and ridges. In earlier work we interpreted the dark plains as dusty, mass-wasted residue from sublimation from volatile-rich bedrock and the bright knobs (often crater rims) as water ice accumulations at locations sheltered from thermal reradiation from the dusty residue. We simulated evolution of Callisto's craters as a combination of bedrock volatile sublimation, mass wasting of the dark, non-coherent residue, and redeposition of ice, and concluded that the ice pinnacles and ridges might be underlain by tens to hundreds of meters of ice. Here we report the initial work of a new study of pinnacles addressing additional questions: 1) Is there an evolutionary sequence starting, e.g., from a cratered initial surface through growth and formation of a dust mantle and pinnacles, to eventual loss of ice to sublimation resulting in just a dark, dusty surface? 2) What determines the areal density and spatial scale of pinnacles - volatile content of bedrock, crater density, surface age, broad-scale topographic setting? 3) Are pinnacles still forming? Several observations address these questions. In a few places scattered high-albedo blocks approx. 25-60 m in diameter occur in the vicinity of large icy pinnacles. We interpret these blocks to be remnants from the collapse of tall pinnacles that were undermined by mass wasting. Some high-relief icy knobs have developed a skeletonized planform due to mass wasting by avalanching, or perhaps to seeding of new sites of ice deposition on mass-wasted ice blocks. Some areas nearly lack fresh craters with well-defined ejecta and ice-free rims. This may imply rapid transformation of fresh craters by sublimation, mass wasting, and ice reprecipitation. In other areas small sharp-rimmed craters occur which lack ice pinnacles, but the craters nonetheless lack visible ejecta sheets. Our preliminary interpretation is that mass wasting is very efficient on Callisto, or alternatively the dust cover is very thick and lacks competent coarse materials.

bedrock volatile sublimation↗
NASA NTRS1972

Silicon-germanium technology program of the Jet Propulsion Laboratory.

The outer planetary exploration missions studied by the Jet Propulsion Laboratory require silicon-germanium radioisotope thermoelectric generators (RTGs) in which the factors of safety are as low as is compatible with the reliable satisfaction of the power needs. Work on silicon germanium sublimation performed at the Jet Propulsion Laboratory is presented. Analytical modeling work on the solid-diffusion process involved in the steady-state (free) sublimation of silicon germanium is described. Analytical predictions are made of the sublimation suppression which can be achieved by using a cover gas. A series of accelerated (high-temperature) tests which were performed on simulated hardware (using four SiGe couples) to study long-term sublimation and reaction mechanisms are also discussed.

De Winter, F.↗
NASA NTRS1986

A New Method for Laminar Boundary Layer Transition Visualization in Flight: Color Changes in Liquid Crystal Coatings

The visualization of laminar to turbulent boundary layer transition plays an important role in flight and wind tunnel aerodynamic testing of aircraft wing and body surfaces. Visualization can help provide a more complete understanding of both transition location as well as transition modes; without visualization, the transition process can be very difficult to understand. In the past, the most valuable transition visualization methods for fight applications included sublimating chemicals and oil flows. Each method has advantages and limitations. In particular, sublimating chemicals are impractical to use in subsonic applications much above 20,000 feet because of the greatly reduced rates of sublimation at lower temperatures (less than -4 degrees Fahrenheit). Both oil flow and sublimating chemicals have the disadvantage of providing only one good data point per flight. Thus, for many important flight conditions, transition visualization has not been readily available. This paper discusses a new method for visualizing transition in fight by the use of liquid crystals. The new method overcomes the limitations of past techniques, and provides transition visualization capability throughout almost the entire altitude and speed ranges of virtually all subsonic aircraft flight envelopes. The method also has wide applicability for supersonic transition visualization in flight and for general use in wind tunnel research over wide subsonic and supersonic speed ranges.

Holmes, Bruce J.↗
NASA NTRS1986

Boundary layer flow visualization for flight testing

Flow visualization is used extensively in flight testing to determine aerodynamic characteristics such as surface flow direction and boundary layer state. Several visualization techniques are available to the aerodynamicist. Two of the most popular are oil flows and sublimating chemicals. Oil is used to visualize boundary layer transition, shock wave location, regions of separated flow, and surface flow direction. Boundary layer transition can also be visualized with sublimating chemicals. A summary of these two techniques is discussed, and the use of sublimating chemicals is examined in some detail. The different modes of boundary layer transition are characterized by different patterns in the sublimating chemical coating. The discussion includes interpretation of these chemical patterns and the temperature and velocity operating limitations of the chemical substances. Information for selection of appropriate chemicals for a desired set of flight conditions is provided.

Obara, Clifford J.↗