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At least 181 records · Page 10

Evolution of the Electrode–Electrolyte Interface of LiNi 0.8 Co 0.15 Al 0.05 O 2 Electrodes Due to Electrochemical and Thermal Stress

For layered oxide cathodes, impedance growth and capacity fade related to reactions at the cathode–electrolyte interface (CEI) are particularly prevalent at high voltage and high temperatures. At a minimum, the CEI layer consists of Li 2 CO 3 , LiF, reduced (relative to the bulk) metal-ion species, and salt decomposition species, but conflicting reports exist regarding their progression during (dis)charging. Utilizing transport measurements in combination with X-ray and nuclear magnetic resonance spectroscopy techniques in our work, we study the evolution of these CEI species as a function of electrochemical and thermal stress for LiNi 0.8 Co 0.15 Al 0.05 O 2 (NCA) particle electrodes using a LiPF 6 ethylene carbonate:dimethyl carbonate (1:1 volume ratio) electrolyte. Although initial surface metal reduction does correlate with surface Li 2 CO 3 and LiF, these species are found to decompose upon charging and are absent above 4.25 V. While there is trace LiPF 6 breakdown at room temperature above 4.25 V, thermal aggravation is found to strongly promote salt breakdown and contributes to surface degradation even at lower voltages (4.1 V). An interesting finding of our work was the partial reformation of LiF upon discharge, which warrants further consideration for understanding CEI stability during cycling.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Micromechanics thermal stress analysis of composites for space structure applications

This paper presents results from a finite element micromechanics analysis of thermally induced stresses in composites at cryogenic temperatures typical of spacecraft operating environments. The influence of microstructural geometry, constituent and interphase properties, and laminate orientation were investigated. Stress field results indicated that significant matrix stresses occur in composites exposed to typical spacecraft thermal excursions; these stresses varied with laminate orientation and circumferential position around the fiber. The major difference in the predicted response of unidirectional and multidirectional laminates was the presence of tensile radial stresses, at the fiber/matrix interface, in multidirectional laminates with off-axis ply angles greater than 15 deg. The predicted damage initiation temperatures and modes were in good agreement with experimental data for both low (207 GPa) and high (517 GPa) modulus carbon fiber/epoxy composites.

Bowles, David E.↗

Structural dynamic and thermal stress analysis of nuclear reactor vessel support system

A nuclear reactor vessel is supported by a Z-ring and a box ring girder. The two proposed structural configurations to transmit the loads from the Z-ring and the box ring girder to the foundation are shown. The cantilever concrete ledge transmitting the load from the Z-ring and the box girder via the cavity wall to the foundation is shown, along with the loads being transmitted through one of the six steel columns. Both of these two supporting systems were analyzed by using rigid format 9 of NASTRAN for dynamic loads, and the thermal stresses were analyzed by AXISOL. The six column configuration was modeled by a combination of plate and bar elements, and the concrete cantilever ledge configuration was modeled by plate elements. Both configurations were found structurally satisfactory; however, nonstructural considerations favored the concrete cantilever ledge.

Chi-Diango, J.↗

The effect of water on thermal stresses in polymer composites

The fundamentals of the thermodynamic theory of mixtures and continuum thermochemistry are reviewed for a mixture of condensed water and polymer. A specific mixture which is mechanically elastic with temperature and water concentration gradients present is considered. An expression for the partial pressure of water in the mixture is obtained based on certain assumptions regarding the thermodynamic state of the water in the mixture. Along with a simple diffusion equation, this partial pressure expression may be used to simulate the thermostructural behavior of polymer composite materials due to water in the free volumes of the polymer. These equations are applied to a specific polymer composite material during isothermal heating conditions. The thermal stresses obtained by the application of the theory are compared to measured results to verify the accuracy of the approach.

Sullivan, Roy M.↗

Thermal stresses in composite tubes

This paper summarizes work to determine the thermally-induced stresses and deformations in specially-constructed angle-ply composite tubes subjected to a uniform temperature change relative to their stress-free cure state. The tubes are designed for application to space structures and have high axial stiffness. Four angle-ply designs are examined in an effort to determine which design might have the most favorable thermally-induced response. A planar elasticity solution is used, the solution being valid away from the ends of the tube. Of the four designs considered, none has any particular advantage as far as stress levels are concerned. However, despite the fact that the tube wall is a balanced laminate, one design exhibits a significant amount of thermally-induced twist.

Hyer, M. W.↗

A comparison of experimental and calculated thin-shell leading-edge buckling due to thermal stresses

High-temperature thin-shell leading-edge buckling test data are analyzed using NASA structural analysis (NASTRAN) as a finite element tool for predicting thermal buckling characteristics. Buckling points are predicted for several combinations of edge boundary conditions. The problem of relating the appropriate plate area to the edge stress distribution and the stress gradient is addressed in terms of analysis assumptions. Local plasticity was found to occur on the specimen analyzed, and this tended to simplify the basic problem since it effectively equalized the stress gradient from loaded edge to loaded edge. The initial loading was found to be difficult to select for the buckling analysis because of the transient nature of thermal stress. Multiple initial model loadings are likely required for complicated thermal stress time histories before a pertinent finite element buckling analysis can be achieved. The basic mode shapes determined from experimentation were correctly identified from computation.

Jenkins, Jerald M.↗

Thermal expansion and thermal stress in the moon and terrestrial planets - Clues to early thermal history

The paper discusses how features of the surface geology of the moon and also Mars and Mercury impose constraints on the volumetric expansion or contraction of a planet and consequently provide a test of thermal history models. The moon has changed very little in volume over the last 3.8 b.y. Thermal models satisfying this constraint involve early heating and perhaps melting of the outer 200 km of the moon and an initially cold interior. Mercury has contracted by about 2 km in radius since emplacement of its present surface, so core formation must predate that surface. A hot initial temperature distribution is implied.

Solomon, S. C.↗

Thermal stresses in composite tubes using complementary virtual work

This paper addresses the computation of thermally induced stresses in layered, fiber-reinforced composite tubes subjected to a circumferential gradient. The paper focuses on using the principle of complementary virtual work, in conjunction with a Ritz approximation to the stress field, to study the influence on the predicted stresses of including temperature-dependent material properties. Results indicate that the computed values of stress are sensitive to the temperature dependence of the matrix-direction compliance and matrix-direction thermal expansion in the plane of the lamina. There is less sensitivity to the temperature dependence of the other material properties.

Hyer, M. W.↗

Micromechanics analysis of space simulated thermal stresses in composites. I - Theory and unidirectional laminates. II - Multidirectional laminates and failure predictions

A micromechanics analysis is used to study the effects of constituent properties on thermally induced stresses in continuous fiber reinforced composites. A finite element formulation is described, and results are presented for unidirectional carbon/epoxy laminates. It is shown that significant stresses develop in composites exposed to thermal excursions typical of spacecraft operating environments and that the fiber thermoelastic properties have a minimal effect on the magnitude of these stresses. The finite element micromechanics analysis is then extended to the study of multidirectional laminates using a simple global/local formulation. Damage initiation predictions are compared with experimental data, and factors controlling the initiation of damage are identified. Ways of improving the durability of composites are discussed.

Bowles, David E.↗

Thermal stress cycling of GaAs solar cells

A thermal cycling experiment was performed on GaAs solar cells to establish the electrical and structural integrity of these cells under the temperature conditions of a simulated low-Earth orbit of 3-year duration. Thirty single junction GaAs cells were obtained and tests were performed to establish the beginning-of-life characteristics of these cells. The tests consisted of cell I-V power output curves, from which were obtained short-circuit current, open circuit voltage, fill factor, and cell efficiency, and optical micrographs, spectral response, and ion microprobe mass analysis (IMMA) depth profiles on both the front surfaces and the front metallic contacts of the cells. Following 5,000 thermal cycles, the performance of the cells was reexamined in addition to any factors which might contribute to performance degradation. It is established that, after 5,000 thermal cycles, the cells retain their power output with no loss of structural integrity or change in physical appearance.

Janousek, B. K.↗

Thermal Stress Weathering of Boulders on Airless Bodies

Rock boulders are considerably typical of airless rocky bodies throughout the inner solar system, so their environments prove useful to understanding the rates of surface-modification processes and “survival times” of these boulders. On the Moon, there are meter-sized boulders on the rims of small lunar carters of some known age, so modeling the rock destruction is applied. Interior and exterior stresses must be considered, including thermal day-night cycling of the regolith and sub-regolith, and solar wind.

Caitlin Ahrens↗

Prognostics Approach for Power MOSFET Under Thermal-Stress

The prognostic technique for a power MOSFET presented in this paper is based on accelerated aging of MOSFET IRF520Npbf in a TO-220 package. The methodology utilizes thermal and power cycling to accelerate the life of the devices. The major failure mechanism for the stress conditions is dieattachment degradation, typical for discrete devices with leadfree solder die attachment. It has been determined that dieattach degradation results in an increase in ON-state resistance due to its dependence on junction temperature. Increasing resistance, thus, can be used as a precursor of failure for the die-attach failure mechanism under thermal stress. A feature based on normalized ON-resistance is computed from in-situ measurements of the electro-thermal response. An Extended Kalman filter is used as a model-based prognostics techniques based on the Bayesian tracking framework. The proposed prognostics technique reports on preliminary work that serves as a case study on the prediction of remaining life of power MOSFETs and builds upon the work presented in [1]. The algorithm considered in this study had been used as prognostics algorithm in different applications and is regarded as suitable candidate for component level prognostics. This work attempts to further the validation of such algorithm by presenting it with real degradation data including measurements from real sensors, which include all the complications (noise, bias, etc.) that are regularly not captured on simulated degradation data. The algorithm is developed and tested on the accelerated aging test timescale. In real world operation, the timescale of the degradation process and therefore the RUL predictions will be considerable larger. It is hypothesized that even though the timescale will be larger, it remains constant through the degradation process and the algorithm and model would still apply under the slower degradation process. By using accelerated aging data with actual device measurements and real sensors (no simulated behavior), we are attempting to assess how such algorithm behaves under realistic conditions.

Power MOSFET PHM↗

Thermal stress analysis of reusable surface insulation for shuttle

An iterative procedure for accurately determining tile stresses associated with static mechanical and thermally induced internal loads is presented. The necessary conditions for convergence of the method are derived. An user-oriented computer program based upon the present method of analysis was developed. The program is capable of analyzing multi-tiled panels and determining the associated stresses. Typical numerical results from this computer program are presented.

Ojalvo, I. U.↗

Thermal stresses in thick laminated composite shells

The paper provides an analytical formulation to investigate the thermomechanical behavior of thick composite shells subjected to a temperature distribution which varies arbitrarily in the radial direction. For illustrative purposes, shells under uniform temperature change are presented. It is found that thermal twist would occur even for symmetric laminated shells. Under uniform temperature rise, results for off-axis graphite/epoxy shells show that extensional-shear coupling can cause tensile radial stress throughout the shell and tensile hoop stress in the inner region. Laminated graphite/epoxy shells can exhibit negative effective thermal expansion coefficients in the longitudinal and transverse directions. Finally, the stacking sequence has a strong influence on the thermal stress distributions.

Yuan, F. G.↗

Thermal stress reduces carbonate production of benthic foraminifera and changes the material properties of their shells

Abstract In shallow marine environments, benthic foraminifera are important foundation species and carbonate producers. Understanding their response to future climate is often drawn from their acclimation potential in short laboratory experiments, thereby limiting our understanding of migration, species replacement, and adaptive potential. To overcome this challenge, we examine two species of benthic foraminifera from a thermally polluted field site mimicking future warming. This site and a control station cover 13–36°C causing both warm and cold stress to the local species. Computer Tomography reveals that under heat stress, even with acclimation, Lachlanella significantly reduced its shell volume. In contrast, Pararotalia calcariformata did not reduce its shell volume but reduced the relative amount of calcite with respect to shell volume and changed its reproduction cycle from twice to once per year. Raman spectroscopy indicates that thermal conditions alter the chemical composition of the calcite shells of both species. Calcification during thermal stress creates alterations in the crystal structure that are unexpectedly more prominent under cold stress than warm stress indicating warming might positively affect the shell's protective function. Supported by previous laboratory experiments and observations from the geological record, our results provide new perspective to the effect of warming on benthic foraminifera.

Titelboim, Danna↗

Application of numerical methods to heat transfer and thermal stress analysis of aerospace vehicles

The paper describes a thermal-structural design analysis study of a fuel-injection strut for a hydrogen-cooled scramjet engine for a supersonic transport, utilizing finite-element methodology. Applications of finite-element and finite-difference codes to the thermal-structural design-analysis of space transports and structures are discussed. The interaction between the thermal and structural analyses has led to development of finite-element thermal methodology to improve the integration between these two disciplines. The integrated thermal-structural analysis capability developed within the framework of a computer code is outlined.

Wieting, A. R.↗