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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 181 records · Page 10
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

Discrimination of phosgene from cyanogen chloride in recovered chemical munitions using tagged neutron interrogation with high-resolution gamma-ray spectroscopy

The Associated Particle technique has recently been utilized with a germanium-based high-resolution $\gamma$-ray spectrometer and assessed for its capability to improve field identification of recovered chemical warfare (CW) materiel through prompt gamma-ray neutron activation analysis (PGNAA) measurements. An accurate chemical identification is necessary for the safe handling, destruction, and disposal of such hazardous items. A particularly challenging pair of CW agents commonly found in recovered munitions are phosgene (CG) and cyanogen chloride (CK), which have two of three elements in common, i.e. chlorine and carbon, but differ in the third being either oxygen or nitrogen. The detection of both latter elements is complicated by high oxygen concentration in the field environment which interferes with the small signal produced from the chemical agents. The matter is further complicated by the precautionary field practice of overpacking recovered munitions with vermiculite in larger steel multiple round containers (MRCs), which places additional oxygen-rich material around the munition while further attenuating an already weak signal emitted from the munition center. Here, this work reports quantitative results from realistic field measurements of CG and CK simulants in mock 4.2-inch mortar rounds overpacked with vermiculite in a large MRC. Results obtained with the AP technique are compared to those obtained with the traditional PGNAA approach for both overpacked- and bare-munition measurements. The AP technique is shown to provide a much more confident discrimination between the two chemicals, particularly for the more challenging field-relevant overpacked measurements, where a significant gain in sensitivity to all the key elements chlorine, carbon, nitrogen and oxygen is achieved.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2024

Intramolecular Polarization Contributions to the pKa’s of Carboxylic Acids Through the Chain Length Dependence of Vibrational Tag-Shifts in Cryogenically Cooled Pyridinium-(CH2)n-COOH (n = 1-7) Cations

The pKa’s of acids are known to depend on the ionic strength of an electrolyte solution, an effect that qualitatively results from electrostatic interactions of the acid and conjugate base with proximal ions. Here we explore an intramolecular variation on this theme in which a carboxylic acid group is tethered to a pyridinium cationic charge center with increasingly long alkyl linkages in the series Py+-(CH2)n-COOH, with n = 1-7. The effective acidities of the carboxylic acid group in the isolated cations are determined by recording the red-shifts in the frequencies of the acid OH stretches upon attachment to D2 and N2 molecules, measured by using cryogenic ion spectroscopy. The short chains indeed lead to substantial increases in acidity, with the effect falling off in the range of n = 4-5. The response of the CO stretch on the acid head group is surprisingly strong and, in contrast to the expected red shift of the OH, displays a blue shift as the chain length is reduced. Electronic structure calculations recover these trends and indicate that the proximal cationic charge center acts to draw electron density away from the acid C=O bond. This acts to blue shift the CO stretch while weakening the C-C bond that attaches the head group to the chain.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2024

The ones that got away: chemical tagging of globular cluster-origin stars with Gaia BP/RP spectra

ABSTRACT Globular clusters (GCs) are sites of extremely efficient star formation, and recent studies suggest they significantly contributed to the early Milky Way’s stellar mass build-up. Although their role has since diminished, GCs’ impact on the Galaxy’s initial evolution can be traced today by identifying their most chemically unique stars – those with anomalous nitrogen and aluminum overabundances and oxygen depletion. While they are a perfect tracer of clusters, be it intact or fully dissolved, these high-[N/O], high-[Al/Fe] GC-origin stars are extremely rare within the current Galaxy. To address the scarcity of these unusual, precious former GC members, we train a neural network (NN) to identify high-[N/O], high-[Al/Fe] stars using low-resolution Gaia Blue Photometer/Red Photometer spectra. Our NN achieves a classification accuracy of approximately $\approx 99~{{\ \rm per\ cent}}$ and a false positive rate of around $\approx 7~{{\ \rm per\ cent}}$, identifying 878 new candidates in the Galactic field. We validate our results with several physically motivated sanity checks, showing, for example, that the incidence of selected stars in Galactic GCs is significantly higher than in the field. Moreover, we find that most of our GC-origin candidates reside in the inner Galaxy, having likely formed in the proto-Milky Way, consistent with previous research. The fraction of GC candidates in the field drops at a metallicity of [Fe/H]$\approx -1$, approximately coinciding with the completion of spin-up, i.e. the formation of the Galactic stellar disc.

Kane, Sarah G. (ORCID:0000000184111012)↗
DOE OSTI2025

Measurement of the time-integrated 𝐶⁢𝑃 asymmetry in 𝐷 0 → 𝐾$^{0}_{S}$𝐾$^{0}_{S}$ decays using opposite-side flavor tagging at Belle and Belle II

We measure the time-integrated 𝐶⁢𝑃 asymmetry in 𝐷 0 → 𝐾$^{0}_{S}$𝐾$^{0}_{S}$ decays reconstructed in 𝑒 + ⁢𝑒 − → $c\bar{c}$ events collected by the Belle and Belle II experiments. The corresponding data samples have integrated luminosities of 980 and 428 fb −1 , respectively. To infer the flavor of the 𝐷 0 meson, we exploit the correlation between the flavor of the reconstructed decay and the electric charges of particles reconstructed in the rest of the 𝑒 + ⁢𝑒 − → $c\bar{c}$ event. This results in a sample which is independent from any other previously used at Belle or Belle II. The result, 𝐴 𝐶⁢𝑃 ⁡(𝐷 0 → 𝐾$^{0}_{S}$𝐾$^{0}_{S}$)=(1.3±2.0±0.2)%, where the first uncertainty is statistical and the second systematic, is consistent with previous determinations and with 𝐶⁢𝑃 symmetry.

CP violation↗
DOE OSTI2025

Test of lepton flavor universality with measurements of 𝑅⁡(𝐷 + ) and 𝑅⁡(𝐷* + ) using semileptonic 𝐵 tagging at the Belle II experiment

We report measurements of the ratios of branching fractions ℛ⁡(𝐷 (*)+ ) = ℬ⁡($\bar{𝐵}$ 0 → 𝐷 (*)+ ⁢𝜏 −⁢ $\bar{𝜈}$ 𝜏 )/ℬ⁡($\bar{𝐵}$ 0 → 𝐷 (*)+ ⁢ℓ − $\bar{𝜈}$ ℓ ), where ℓ denotes either an electron or a muon. These ratios test the universality of the charged-current weak interaction. The results are based on a 365 fb −1 data sample collected with the Belle II detector at the SuperKEKB 𝑒 + ⁢𝑒 − collider, which operates at a center-of-mass energy corresponding to the ϒ⁡(4⁢𝑆) resonance, just above the threshold for $𝐵\bar{𝐵}$ production. Signal candidates are reconstructed by selecting events in which the companion 𝐵 meson from the ϒ⁡(4⁢𝑆) → $𝐵\bar{𝐵}$ decay is identified in semileptonic modes. The 𝜏 lepton is reconstructed via its leptonic decays. We obtain ℛ⁡(𝐷 + ) = 0.418$^{+0.075}_{−0.073}$⁢(stat)$^{+0.049}_{−0.056}$⁢(syst) and ℛ⁡(𝐷 *+ ) = 0.306$^{+0.035}_{−0.033}$⁢(stat)$^{+0.016}_{−0.018⁢}$(syst), which are consistent with world average values. Accounting for the correlation between them, these values differ from the Standard Model expectation by a collective significance of 1.7 standard deviations.

bottom quark↗