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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 181 records · Page 10

Negative thermal expansion and the role of hybridization in perovskite-type PbTiO 3 -Bi(Cu 0.5 Ti 0.5) O 3

PbTiO 3 -BiMeO 3 ferroelectrics have attracted much attention due to not only their extremely large polarization and piezoelectricity but also their controllable thermal expansion. In this study, we present a new binary system of (1 - x)PbTiO 3 -xBi(Cu 0.5 Ti 0.5 )O 3 possessing large tetragonality and enhanced spontaneous polarization. Interestingly, a combination of near zero thermal expansion and negative thermal expansion over a temperature range of RT to T C (~550 °C) has been observed in tetragonal 0.85PbTiO 3 -0.15Bi(Cu 0.5 Ti 0.5 )O 3 . The comprehensive structure analysis addressed that the abnormal thermal expansion is coupled to the spontaneous volume ferroelectrostriction. Moreover, the chemical bonding investigation by a maximum entropy method further attests that the covalent hybridization of Pb/Bi–O bonds plays a vital role in the improved ferroelectricity and interacts with thermal vibration to dominate the crossover from positive to negative thermal expansion. fINALLY, The present studies would give direct evidence to verify the theoretical calculations and could be extended to reveal the nature of thermal expansion in ferroelectrics.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Near-field radiative heat transfer between irregularly shaped dielectric particles modeled with the discrete system Green's function method

Near-field radiative heat transfer (NFRHT) between irregularly shaped dielectric particles made of SiO 2 and morphology characterized by Gaussian random spheres is studied. Particles are modeled using the discrete system Green's function (DSGF) approach, which is a volume integral numerical method based on fluctuational electrodynamics. This method is applicable to finite, three-dimensional objects, and all system interactions are defined independent of thermal excitation by a generalized system Green's function. The DSGF method is deemed suitable to model NFRHT between irregularly shaped particles after verification against the analytical solution for chains of two and three SiO 2 spheres. The NFRHT results reveal that geometric irregularity in particles leads to a reduction of the total conductance from that of comparable perfect spheres at vacuum separation distances smaller than the particle size, a regime in which NFRHT is a surface phenomenon. At vacuum separation distances larger than the particle size, NFRHT becomes a volumetric process, and the total conductance between irregularly shaped particles converges to that of comparable perfect spheres. Spectral analysis reveals, however, that particle irregularity leads to damping and broadening of resonances at all separation distances, thereby highlighting the importance of the DSGF method for spectral engineering in the near field. The reduced spectral coherence when particle size is larger than the vacuum separation distance is attributed to coupling of surface phonon-polaritons within the randomly generated, distorted particle features. For particle size smaller than the vacuum separation distance, resonance broadening and damping are linked with the multiple localized surface phonon modes supported by the composite spherical harmonic morphologies of the Gaussian random spheres. In conclusion, this paper has direct implications for thermal management of packed particle systems, with applications in radiative property control, electronics, energy conversion, and nanomanufacturing.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Test Article and Test Plan for Heat-Pipe Gap-Conductance Testing

The SPHERE Facility at INL is established to test phenomena related to heat pipes in nuclear applications. The current capability of the SPHERE testbed is operation of liquid alkali-metal-cooled heat pipes in a variety of atmospheres. The controlled atmosphere can be used to prevent oxidation of system parts and also to affect the thermal conductivity of gases for any interfacial gaps within the heat-pipe assembly. Currently available modes are vacuum, air, nitrogen, helium, and argon. Controlled mixtures of helium and argon are available to vary the thermal conductivity of the gas. The primary test article will be based on the existing 7-hole block design used for shakedown testing of the SPHERE Facility. The SPHERE test stand will be used with test articles to establish the conductivity between fuel elements as well as between the heat pipe and other layers of the fuel-rod assembly. Existing and new test blocks will be used and modified with additional instrumentation to establish the thermal conductivity between the gap of the block wall and the heat pipes.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Prediction of Breakdown in Air and Solid Dielectrics: A Complete Plasma Model from Discharge Initiation to Flashover (Final Technical Report)

A major challenge for most of the technologies of today, and the technologies of the future, is the compact and reliable design of electrical insulation systems for their electrical components. Although controlled low-temperature plasmas (LTPs) or non-thermal plasmas in air at atmospheric pressure are of interest for a wide range of technologies, the appearance of such discharges is considered highly undesirable in insulation systems because they are precursors of a breakdown or flashover, where complete insulation failure takes place. For non-thermal plasmas, often only one mechanism, or the transition from one discharge mechanism to another, has typically been studied to date. On the other hand, in the case of thermal plasma applications, the conditions following the occurrence of an electric arc or flashover have always been considered. Here, there is a big technical gap: there is no paper describing a complete plasma model simulating all discharge mechanisms and their transitions from discharge initiation to electrical arc and flashover. To address this gap, a complete plasma model for both thermal and non-thermal plasmas should be developed using a hydrodynamic approach. The project aimed to build the model. The work has the potential to address industrial applications and is of great importance to higher voltage systems.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

History and State of the Art in Advanced Thermal Protection Systems

This report documents the current state of the art of thermal protection systems (TPS) relevant to missile application materials and MTCR control language. The information is intended to provide data on current TPS for determining the current state of development and identifying potential research directions. Various vehicle configurations and types of TPS are described, including the evolution of materials and systems. Vehicle configurations such as high drag rocket and capsule systems and low-drag air-breathers are discussed. TPS are complex, transitioning from often very low temperatures to temperatures exceeding 3000°C and heat fluxes of up to 30,000 W/cm 2 . They can take the form of blankets, sheets, tiles and fabricated rigid structures, and can be made from high temperature capable alloys, refractory metals, ceramics, ceramic matrix composites, ultra-high temperature ceramics, carbon-carbon composites or ablative carbonaceous materials. Current state of the art in TPS is based on materials any systems developed for the initial space program. TPS was upgraded to the point of the Space Shuttle development and has stagnated since them.

36 MATERIALS SCIENCE↗

Re-establishment of Sandia National Labs super-critical carbon dioxide testing autoclave capability for exposure of metal alloys and polymers (Level 4 Milestone Report)

The sCO 2 system located in 916/160A, Sandia National Laboratories, CA, was constructed in 2014, for testing of materials in the presence of supercritical carbon dioxide (sCO 2 ) at high pressures (up to 3500 psi) and temperatures (up to 650°C). The basic design of the system consists of a thermally insulated IN625 autoclave, a high-pressure supercritical CO 2 compressor, autoclave heaters, temperature controllers, gas manifold, and temperature and pressure diagnostics. This system was modified in 2016 (sCO 2 compressor was removed) to enable corrosion studies with metal alloys in gaseous CO 2 at lower pressure (up to 300 psi) at 500°C. The capability was not used much afterwards until 2020, when preliminary tests using this capability (again without the supercritical CO 2 compressor) involved the exposure of fatigue and tensile specimens of HN 230 and 800H alloys to CO 2 gas for 168 hours in gaseous CO 2 . Using this capability, we finished experiments with low pressure (450 psi/ 3 MPa), high temperature (650°C) exposure of fatigue and tensile specimens of HN 230 and 800H alloys to CO 2 gas for 168 hours. The data from these experiments will be compared to that gathered from experiments performed in 2020 using the tube furnace and presented in a future report. It is to be noted that the tube furnace experiments ran 500-1500 hours, unlike the 168 hours of exposure in the recent experiment. This can help validate the use of the sCO 2 autoclave for both CO 2 and sCO 2 experiments.

36 MATERIALS SCIENCE↗

Fuel Flow Modeling under Thermal Fluidics Considerations within Operational Domains of Molten Salt Reactors

Molten Salt Reactors (MSRs) offer significant versatility supported by their design flexibility and safety advantages due to high temperatures, design customization capabilities, strong negative reactivity feedback effects, and salt chemistry characteristics. Different control schedules and different mass flow rates in the MSR primary systems impact neutronics and thermal hydraulics coupling. The result is two-fold. First, it leads to adaptability in various applications when the customization of a MSR unit is desired. Second, it calls for the quantification of dynamics and safety characteristics to assess the operational domain and make sure reactor stability and inherent safety characteristics are maintained. This paper provides an in-depth transient analysis of the operational implications of MSRs having heat-generating fuel and heat-transporting salt mixed forming liquid fuel salts contained within primary systems. A coupling model was developed to simulate fuel flow in molten salt reactors. A zero-dimensional reactor kinetics model was used with a one-dimensional heat transfer model in the reactor core. The temperature reactivity feedbacks of the fuel salt resulting from the thermal-hydraulics model were used in the reactor kinetics model to complete the coupled code. The model was applied to simulate the Molten Salt Breeder Reactor (MSBR) response at steady state and transients. The developed model was shown to be a suitable tool for the dynamic analysis of molten salt reactors.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Lens alignment system and method

A lens alignment system and method is disclosed. The disclosed system/method integrates one or more lens retaining members/tubes (LRM/LRT) and focal length spacers (FLS) each comprising a metallic material product (MMP) specifically manufactured to have a thermal expansion coefficient (TEC) in a predetermined range via selection of the individual MMP materials and an associated MMP manufacturing process providing for controlled TEC. This controlled LRM/LRT TEC enables a plurality of optical lenses (POL) fixed along a common optical axis (COA) by the LRM/LRT to maintain precise interspatial alignment characteristics that ensure consistent and/or controlled series focal length (SFL) within the POL to generate a thermally neutral optical system (TNOS). Integration of the POL using this LRM/LRT/FLS lens alignment system reduces the overall TNOS implementation cost, reduces the overall TNOS mass, reduces TNOS parts component count, and increases the reliability of the overall optical system.

Monroe, James Alan↗

Co-Simulation of Electric Power Distribution Systems and Buildings including Ultra-Fast HVAC Models and Optimal DER Control

Smart homes and virtual power plant (VPP) controls are growing fields of research with potential for improved electric power grid operation. A novel testbed for the co-simulation of electric power distribution systems and distributed energy resources (DERs) is employed to evaluate VPP scenarios and propose an optimization procedure. DERs of specific interest include behind-the-meter (BTM) solar photovoltaic (PV) systems as well as heating, ventilation, and air-conditioning (HVAC) systems. The simulation of HVAC systems is enabled by a machine learning procedure that produces ultra-fast models for electric power and indoor temperature of associated buildings that are up to 133 times faster than typical white-box implementations. Hundreds of these models, each with different properties, are randomly populated into a modified IEEE 123-bus test system to represent a typical U.S. community. Advanced VPP controls are developed based on the Consumer Technology Association (CTA) 2045 standard to leverage HVAC systems as generalized energy storage (GES) such that BTM solar PV is better utilized locally and occurrences of distribution system power peaks are reduced, while also maintaining occupant thermal comfort. An optimization is performed to determine the best control settings for targeted peak power and total daily energy increase minimization with example peak load reductions of 25+%.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Python-EPICS RF Conditioning Automatic Control System at the Spallation Neutron Source

The RF Test Facility (RFTF) at the Spallation Neutron Source (SNS) is used for the conditioning of RF compo-nents such as ceramic vacuum windows and power cou-plers prior to their installation in the H- ion linear accel-erator. This process exposes components to high-power RF fields and thermal cycling to improve performance and remove surface impurities. To automate and optimize this process, a Python-based EPICS control system was developed alongside targeted hardware upgrades. The system enables real-time monitoring and control of RF power levels, temperature, and vacuum pressure. A user-friendly graphical interface was implemented using CS-Studio (Phoebus), allowing operators to adjust parameters and collect data efficiently. The system integrates a High-Power Protection Module (HPM) for interlocks based on vacuum and arc detection, ensuring safe operation. These upgrades have significantly improved the efficiency, accuracy, and safety of RF conditioning at the SNS RFTF. This paper describes the updated RF conditioning sys-tem, highlighting the software and hardware develop-ments and their application in support of the Proton Pow-er Upgrade (PPU) project.

Lee, Sung-Woo [ORNL] (ORCID:000000030915835X)↗

Transactive HVAC Agent - Design and Performance Evaluation

Transactive energy systems are playing an increasingly important role in the efficient and reliable marketbased operation of the power grid. Since a significant portion of the residential building energy consumption is from heating ventilation and air conditioning (HVAC) systems, HVAC is one of the most promising resources to provide load flexibility. However, utilizing HVAC flexibility to provide various grid services while simultaneously maintaining consumer comfort and cost-reductions is challenging. This paper presents a design of a transactive HVAC agent (T-HVAC) to be used as a supervisory control for the HVAC system that can simultaneously ensure comfort and cost-reduction. In particular, the T-HVAC a) estimates HVAC thermal dynamics, b) ensures optimal operations of the HVAC system, and c) participates into markets, and d) implements a market-based control via controlling the thermostat temperature set-point. The T-HVAC performance is demonstrated through multiple scenarios and illustrations.

Demand flexibility, distribution system, HVAC, Tra↗

Development and Demonstration of a Reduced-Order PWR Power Dispatch Simulator

This report describes the development, modeling, and results of a reduced-order thermal power dispatch pressurized water reactor (RO-TPD-PWR) power plant simulator that incorporates coupled electrical and thermal power dispatch to an industrial process. The simulator is built on models that have been developed in previous work, including a Rancor Microworld model previously developed by INL and the University of Idaho [Ref] and reactor core and secondary system models that have been published previously [Ref]. The simulator also includes a scalable model of a high temperature electrolysis (HTE) system that has been developed at INL. A particular benefit of the Rancor Microworld model is that it is compatible with a human-system interface (HMI) that has already been developed by the Human System Simulation Laboratory (HSSL) at INL that can emulate the control room of a PWR for realistic human-in-the-loop studies with mock nuclear power plant operating procedures. The results of these human-in-the-loop tests will be compared with similar tests using a commercial full-scope generic PWR (GPWR) simulator that has been modified to include thermal power dispatch, referred to as the TPD-GPWR [ , ]. The simplicity of the RO-TPD-PWR helps to better understand and verify the results of the TPD-GPWR, which employs >1,000 variables and has much greater complexity. A second key purpose of the RO-TPD-PWR simulator is that its relative simplicity allows it scale between lab-size equipment (~100 kW) and full-scale nuclear power plants (~1 GW) by adjusting only a few parameters in the models, such as fluid masses and heat exchanger areas. The RO-TPD-PWR simulator will be used to guide the controls of lab tests, so that equipment in those tests, such as the Thermal Energy Distribution System (TEDS) and pilot-scale high temperature electrolysis (HTE) units at scales of 50-250 kW, may operate in a manner that is relevant to full-scale PWR operations.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Frequency Control and Dynamics (Part 1) [Slides]

This presentation provides an introductory overview of system dynamics and frequency control in electric power systems, with a focus on concepts relevant to small and interconnected grids such as those in Malawi. It explains foundational principles of AC system frequency, the relationship between generation-demand balance and frequency deviations, and the operational limits of generators and end-use equipment. The deck discusses frequency stability within broader system stability classifications and illustrates how inertia and turbine-governor dynamics shape system response to disturbances. It then outlines the tiered approach to frequency control - primary, secondary, and tertiary - detailing the roles, characteristics, timescales, and response mechanisms of each. Special emphasis is placed on hydro and thermal unit behavior, area control error (ACE), automatic generation control (AGC), and the operational implications of interconnecting small systems with larger grids. The material was developed to support Malawi's electricity sector and the establishment of the Southern Africa Battery Energy Storage Center of Excellence (SABESS CoE).

24 POWER TRANSMISSION AND DISTRIBUTION↗

Frequency Control and Dynamics (Part 2) [Slides]

This presentation provides an introductory overview of system dynamics and frequency control in electric power systems, with a focus on concepts relevant to small and interconnected grids such as those in Malawi. It explains foundational principles of AC system frequency, the relationship between generation-demand balance and frequency deviations, and the operational limits of generators and end-use equipment. The deck discusses frequency stability within broader system stability classifications and illustrates how inertia and turbine-governor dynamics shape system response to disturbances. It then outlines the tiered approach to frequency control - primary, secondary, and tertiary - detailing the roles, characteristics, timescales, and response mechanisms of each. Special emphasis is placed on hydro and thermal unit behavior, area control error (ACE), automatic generation control (AGC), and the operational implications of interconnecting small systems with larger grids. The material was developed to support Malawi's electricity sector and the establishment of the Southern Africa Battery Energy Storage Center of Excellence (SABESS CoE).

24 POWER TRANSMISSION AND DISTRIBUTION↗

Residential Building Energy Efficiency Field Studies: Low-Rise Multifamily

In recent years, the U.S. Department of Energy (DOE) has conducted a series of research studies to validate energy efficient building technologies in the field. Much of the work has focused on single-family construction, and some has also addressed commercial energy codes. The work detailed in this DOE-funded study (EE0007616) focuses on low-rise multifamily buildings (three stories or fewer above grade) in various regions of the United States, and reports on how state-level building codes are being implemented, both in terms of observed characteristics and also in terms of estimated energy impacts. Nearly 100 buildings across four states—Illinois, Minnesota, Oregon, and Washington—were sampled, which represent a range of climate types from mild temperature to very cold continental. Both common entry and outdoor entry buildings were included, and a parallel research project evaluated envelope air tightness and current still-evolving air tightness testing methods. Finally, a set of structured interviews of building designers and other relevant professionals was carried to out to gain more insight into this market. To the greatest extent possible, the methodology developed under the project for low-rise multifamily buildings mirrored the approach established by Pacific Northwest National Laboratory (PNNL) for single-family residential buildings (https://www.energy.gov/eere/buildings/downloads/residential-building-energy-code-field-study). This included the general approach to sampling, recruitment, and data collection, as well as data analysis and presentation. The range of permitting dates for the sites encompassed two energy code cycles in most regions. All states in the study had adopted a variation of the International Energy Conservation Code (IECC) for the structure of their state code. The low-rise multifamily occupancy presents a hybrid building type: most of the building’s conditioned floor area was covered by the residential chapter of the code while portions of the building (such as corridors and common spaces) fell under the commercial code chapter. The key items assessed in this work were: Building Shell—exterior wall insulation, ceiling insulation, foundation insulation, windows. Common Areas—HVAC and lighting. Living Units—lighting, ventilation. A few items were not assessed in detail, given their relative paucity in this occupancy type; these included duct leakage, pipe insulation, and hot water circulation controls. Building characteristics were collected via a combination of architectural, mechanical, electrical, and plumbing plan reviews and field inspections, and entered into a spreadsheet-based tool that was later queried to build a database. Data went through quality control both upon arrival and via a later semi-automated review and assurance process. Most of the data are presented graphically so that the reader can quickly assess compliance with the applicable energy codes (both by state and by code year). As a final step, EnergyPlus™ simulations were created for all buildings in the study to estimate both the as-found energy use intensity (EUI) and the energy and CO 2 that could be saved if features that were found to not meet code minimums were brought up to code. The savings estimates were tabulated for each of the four states in the study. The research team found that the single-family approach was largely applicable to low-rise multifamily buildings. This applies to both the data collection and the prototype EUI analysis. Most of the occupied space is living units and falls under residential energy codes, and many characteristics use similar envelope construction and relatively straightforward mechanical systems and lighting. One of the most challenging aspects of this work was to build an effective spreadsheet-based data collection instrument that could allow efficient collection of both building plan and field data. The research team is of the view that other methods could be equally effective if the work is done carefully with diligent quality control. The primary findings for the work center around the thermal envelope and mechanical systems and lighting at the sites: For thermal envelope components, the majority of buildings met or were better than the prescriptive code.This suggests that building designers and builders are aware of code requirements. In some cases, surveyed buildings were designed to qualify for energy efficiency certification programs. These buildings made up at least 20% of sampled buildings in each state. Almost all buildings met mechanical system efficiency requirements (for both living units and common areas). In some cases, sites employed systems that were considerably more efficient than required by the applicable energy code. Dwelling units had a majority of high-efficacy lighting, often in excess of the state’s residential code requirements. While high-efficacy fixtures were also typical in common areas (corridors and stairwells), lighting power densities (LPDs) in these areas were sometimes higher than levels dictated by the applicable part of the state commercial energy code. The simulation models run on a series of low-rise multifamily prototypes, informed by a composite of the field data collected, calculated annual EUIs of between 20 and 50 kBtu/ft2-yr, with the range representing the effects of both building characteristics and building location (climate zone). A detailed process (based on simulations of prototype buildings) was used to estimate the amount of avoided energy use that would occur if 100% adherence to energy codes were attained. The results indicated modest savings are attainable for items such as window thermal performance and common area lighting. The result is overall only a modest potential for additional energy savings, averaging about 10% of EUI.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Thermal energy storage apparatus, controllers and thermal energy storage control methods

Thermal energy storage apparatus, controllers and thermal energy storage control methods are described. According to one aspect, a thermal energy storage apparatus controller includes processing circuitry configured to access first information which is indicative of surpluses and deficiencies of electrical energy upon an electrical power system at a plurality of moments in time, access second information which is indicative of temperature of a thermal energy storage medium at a plurality of moments in time, and use the first and second information to control an amount of electrical energy which is utilized by a heating element to heat the thermal energy storage medium at a plurality of moments in time.

Hammerstrom, Donald J.↗

Hot, Cold, or Just Right? Using a Wide-View Infrared Biometric Sensor to Improve Occupant Comfort and Reduce Overcooling in Buildings via Closed-loop Control (CRADA Final Report)

This research adds to the understanding of building energy management by fundamentally challenging the long-standing paradigm of controlling an environmental parameter—air temperature—and assuming occupant comfort will follow. The project developed and demonstrated a novel approach that directly senses physiological indicators of human comfort to enable closedloop, human-centric control of heating, ventilation, and air conditioning (HVAC) systems. This work shifts the focus from open-loop environmental control to a closed-loop system that prioritizes the occupants' actual thermal state. The primary benefit to the public is the potential for a simultaneous improvement in the quality of indoor environments, where people spend most of their time, and a significant reduction in national energy consumption. Overcooling, or the overuse of cooling energy in a way that discomforts occupants, wastes approximately 0.5 Quads of primary energy annually in U.S. commercial buildings and creates unproductive indoor environments.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗