Search NASA⌕ Search

SEARCH · Search NASA

Results for “Transmission spectroscopy”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 181 records · Page 10
All sourcesNASA NTRSDOE OSTI
NASA NTRS1990

Ballistic-hole spectroscopy of interfaces

A new technique allows direct control and measurement of ballistic-hole transport through interfaces. This spectroscopy has been applied to determine the detailed properties of hole transmission through metal-semiconductor interfaces and probe the valence-band structure of subsurface semiconductor heterostructures. The ballistic-hole probe is created by electron-tunneling-microscopy methods and provides high-spatial-resolution capabilities.

Hecht, M. H.↗
NASA NTRS1996

Crystallography of the NiHfSi Phase in a NiAl (0.5 Hf) Single-Crystal Alloy

Small additions of Hf to conventionally processed NiAl single crystals result in the precipitation of a high density of cuboidal G-phase along with a newly identified silicide phase. Both of these phases form in the presence of Si which is not an intentional alloying addition but is a contaminant resulting from contact with the ceramic shell molds during directional solidification of the single-crystal ingots. The morphology, crystal structure and Orientation Relationship (OR) of the silicide phase in a NiAl (0.5 at.%Hf) single-crystal alloy have been determined using transmission electron microscopy, electron microdiffraction and energy dispersive X-ray spectroscopy. Qualitative elemental analysis and indexing of the electron microdiffraction patterns from the new phase indicate that it is an orthorhombic NiHfSi phase with unit cell parameters, a = 0.639 nm, b = 0.389 nm and c = 0.72 nm, and space group Pnma. The NiHfSi phase forms as thin rectangular plates on NiAl/111/ planes with an OR that is given by NiHfSi(100))(parallel) NiAl(111) and NiHfSi zone axes(010) (parallel) NiAl zone axes (101). Twelve variants of the NiHfSi phase were observed in the alloy and the number of variants and rectangular morphology of NiHfSi plates are consistent with symmetry requirements. Quenching experiments indicate that nucleation of the NiHfSi phase in NiAI(Hf) alloys is aided by the formation of NiAl group of zone axes (111) vacancy loops that form on the NiAl /111/ planes.

Garg, A.↗
NASA NTRS1997

A Chemical and Structural Study of the A1N-Si Interface

Samples of A1N grown on silicon [111] subtrates were examined using electron enery loss spectroscopy (EELS) and selected area diffraction (SAD) with high-resolution transmission electron microscopy (TEM) to determine the source of out-of-place tilts and in-plane rotations of the A1N crystallites at the Si interface.

silicon out-of-plane tilts in-plane rotations sili↗
NASA NTRS2011

Correlated Microanalysis of Cometary Organic Grains Returned by Stardust

Preliminary examination (PE) of samples returned from Comet 81P/Wild 2 by the NASA Stardust mission revealed a wide variety of carbonaceous samples [e.g. 1]. Carbonaceous matter is present as inclusions, rinds, and films in polyminerallic terminal particles [2-4], as carbon-rich particles along track walls [2, 5, 6], and as organic matter in aerogel around tracks [7, 8]. The organic chemistry of these samples ranges from purely aliphatic hydrocarbons to highly-aromatic material, often modified by various organic functional groups [2, 4, 5, 9-11]. Difficulty arises when interpreting the genesis of these carbonaceous samples, since contaminants could be introduced from the spacecraft [12], aerogel [1, 8], or during sample preparation. In addition, hypervelocity capture into aerogel may have heated cometary material in excess of 1000 C, which could have significantly altered the structure and chemistry of carbonaceous matter. Fortunately, much of this contamination or alteration can be identified through correlated microanalysis with transmission electron microscopy (TEM), scanning-transmission X-ray microscopy (STXM), and nanoscale secondary ion mass spectroscopy (SIMS).

DeGregorio, B. T.↗
NASA NTRS1984

Advanced smoke meter development survey and analysis

Ideal smoke meter characteristics are determined to provide a basis for evaluation of candidate systems. Five promising techniques are analyzed in detail to evaluate compilance with the practical smoke meter requirements. Four of the smoke measurement concepts are optical methods: Modulated Transmission (MODTRAN), Cross Beam Absorption Counter (CBAC), Laser Induced Incandescence (LIN), and Photoacoustic Spectroscopy (PAS). A rapid response filter instrument called a Taper Element Oscillating Microbalance (TEOM) is also evaluated. For each technique, the theoretical principles are described, the expected performance is determined, and the advantages and disadvantages are discussed The expected performance is evaluated against each of the smoke meter specifications, and the key questions for further study are given. The most promising smoke meter technique analyzed was MODTRAN, which is a variation on a direct transmission measurement. The soot-laden gas is passed through a transmission cell, and the gas pressure is modulated by a speaker.

Pitz, R. W.↗
NASA NTRS2014

X-Ray Absorption near Edge Structure Spectroscopic Study of Hayabusa Category 3 Carbonaceous Particles

Analyses with a scanning transmission x-ray microscope (STXM) using x-ray absorption near edge structure (XANES) spectroscopy were applied for the molecular characterization of two kinds of carbonaceous particles of unknown origin, termed category 3, which were collected from the Hayabusa spacecraft sample catcher. Carbon-XANES spectra of the category 3 particles displayed typical spectral patterns of heterogeneous organic macromolecules; peaks corresponding to aromatic/olefinic carbon, heterocyclic nitrogen and/or nitrile, and carboxyl carbon were all detected. Nitrogen-XANES spectra of the particles showed the presence of N-functional groups such as imine, nitrile, aromatic nitrogen, amide, pyrrole, and amine. An oxygen-XANES spectrum of one of the particles showed a ketone group. Differences in carbon- and nitrogen-XANES spectra of the category 3 particles before and after transmission electron microscopic (TEM) observations were observed, which demonstrates that the carbonaceous materials are electron beam sensitive. Calcium-XANES spectroscopy and elemental contrast mapping identified a calcium carbonate grain from one of the category 3 particles. No fluorine-containing molecular species were detected in fluorine-XANES spectra of the particles. The organic macromolecular features of the category 3 particles were distinct from commercial and/or biological ‘fresh (non-degraded)’ polymers, but the category 3 molecular features could possibly reflect degradation of contaminant polymer materials or polymer materials used on the Hayabusa spacecraft. However, an extraterrestrial origin for these materials cannot currently be ruled out.

Asteroides↗
NASA NTRS1993

Pigmenting agents in Martian soils: inferences from spectral, Mossbauer, and magnetic properties of nanophase and other iron oxides in Hawaiian palagonitic soil PN-9

We have examined a Hawaiian palagonitic tephra sample (PN-9) that has spectroscopic similarities to Martian bright regions using a number of analytical techniques, including Mossbauer and reflectance spectroscopy, X-ray diffraction, instrumental neutron activation analysis, electron probe microanalysis, transmission electron microscopy, and dithionite-citrate-bicarbonate extraction. Chemically, PN-9 has a Hawaiitic composition with alkali (and presumably silica) loss resulting from leaching by meteoric water during palagonitization; no Ce anomaly is present in the REE pattern. Mineralogically, our results show that nanophase ferric oxide (np-Ox) particles (either nanophase hematite (np-Hm) or a mixture of ferrihydrite and np-Hm) are responsible for the distinctive ferric doublet and visible-wavelength ferric absorption edge observed in Mossbauer and reflectivity spectra, respectively, for this and other spectrally similar palagonitic samples. The np-Ox particles appear to be imbedded in a hydrated aluminosilicate matrix material; no evidence was found for phyllosilicates. Other iron-bearing phases observed are titanomagnetite, which accounts for the magnetic nature of the sample; olivine; pyroxene; and glass. By analogy, np-Ox is likely the primary pigmenting agent of the bright soils and dust of Mars.

Minerals/analysis↗
NASA NTRS2000

High-Resolution X-Ray Spectroscopy of the Seyfert 2 Galaxy Circinus with Chandra

Results from a 60 ks Chandra High Energy Transmission Grating Spectrometer (HETGS) observation of the nearby Seyfert 2 Circinus are presented. The spectrum shows a wealth of emission lines at both soft and hard X-rays, including lines of Ne, Mg, Si, S, Ar, Ca, and Fe, and a prominent Fe K(alpha) line at 6.4 keV. We identify several of the He-like components and measure several of the Lyman lines of the N-like ions. The lines' profiles are unresolved at the limited signal-to-noise ratio of the data. Our analysis of the zeroth-order image in a companion paper constrains the size of the emission region to be 20-60 pc, suggesting that emission within this volume is almost entirely due to the reprocessing of the obscured central source. Here we show that a model containing two distinct components can reproduce almost all the observed properties of this gas. The ionized component can explain the observed intensities of the ionized species, assuming twice-solar composition and an N is proportional r(exp -1.5) density distribution. The neutral component is highly concentrated, well within the 0.8" point source, and is responsible for almost all of the observed K(alpha) (6.4 keV) emission. Circinus seems to be different than Mkn 3 in terms of its gas distribution.

Sambruna, Rita M.↗
NASA NTRS1984

Coaxial carbon plasma gun deposition of amorphous carbon films

A unique plasma gun employing coaxial carbon electrodes was used in an attempt to deposit thin films of amorphous diamond-like carbon. A number of different structural, compositional, and electrical characterization techniques were used to characterize these films. These included scanning electron microscopy, scanning transmission electron microscopy, X ray diffraction and absorption, spectrographic analysis, energy dispersive spectroscopy, and selected area electron diffraction. Optical absorption and electrical resistivity measurements were also performed. The films were determined to be primarily amorphous, with poor adhesion to fused silica substrates. Many inclusions of particulates were found to be present as well. Analysis of these particulates revealed the presence of trace impurities, such as Fe and Cu, which were also found in the graphite electrode material. The electrodes were the source of these impurities. No evidence of diamond-like crystallite structure was found in any of the film samples. Details of the apparatus, experimental procedure, and film characteristics are presented.

Sater, D. M.↗
NASA NTRS1992

Analysis of surfaces from the LDEF A0114, phase 2

Analysis of surfaces from the Long Duration Exposure Facility (LDEF) continued during the reporting period. Work has continued on profilometry measurements of eroded and corroded sample surfaces, optical transmission measurements, analysis of the pinhole camera, and x-ray photoelectron spectroscopy (XPS) analysis of some samples. Papers that have appeared or have been accepted for publications are listed. Several of these papers and an abstact are included.

Gregory, John C.↗
NASA NTRS1993

Analysis of surfaces from the LDEF A0114, phase 2

During the reporting period, work continued on profilometry measurements of eroded and corroded sample surfaces, optical transmission measurements, analysis of the pinhole camera, and x-ray photoelectron spectroscopy (XPS) analysis of some samples. Among metal samples, copper showed some interesting new results. There were two forms of copper samples: a thin film sputter-coated on fused silica and a solid piece of OFHC copper. They were characterized by x-ray and Auger electron spectroscopies, x-ray diffraction, and high resolution profilometry. Cu 2p core level spectra were used to demonstrate the presence of Cu2O and CuO and to determine the oxidation states.

Gregory, John C.↗
NASA NTRS2000

Discovery of Spatial and Spectral Structure in the X-Ray Emission from the Crab Nebula

The Chandra X-ray Observatory observed the Crab Nebula and Pulsar During orbital calibration. Zeroth-order images with the High-Energy Transmission Grating (HETG) read-out by the Advanced CCD Imaging Spectrometer spectroscopy array (ACIS-S) show a striking richness of X-ray structure, at a resolution comparable to that of the best ground-based visible-light observations. The HETG-ACIS-S images reveal, for the first time, an X-ray knots along the inner ring and (perhaps) along the inward extension of the X-ray jet. Although complicated by instrumental effects and the brightness of the Crab Nebula, the spectrometric analysis shows systematic variations of the X-ray spectrum throughout the Nebula.

Weisskopf, M.↗
NASA NTRS2022

CLEAR: Boosted Lyα Transmission of the Intergalactic Medium in UV-bright Galaxies

Reionization is an inhomogeneous process, thought to begin in small ionized bubbles of the intergalactic medium (IGM) around overdense regions of galaxies. Recent Lyα studies during the epoch of reionization show evidence that ionized bubbles formed earlier around brighter galaxies, suggesting higher IGM transmission of Lyα from these galaxies. We investigate this problem using IR slitless spectroscopy from the Hubble Space Telescope (HST) Wide-Field Camera 3 (WFC3) G102 grism observations of 148 galaxies selected via photometric redshifts at 6.0 < z < 8.2. These galaxies have spectra extracted from the CANDELS Lyα Emission at Reionization (CLEAR) survey. We combine the CLEAR data for 275 galaxies with the Keck Deep Imaging Multi-Object Spectrograph and MOSFIRE data set from the Texas Spectroscopic Search for Lyα Emission at the End of Reionization Survey. We constrain the Lyα equivalent width (EW) distribution at 6.0 < z < 8.2, which is described by an exponential form, dN / dEW ∝ exp(-EW) W(sub 0), with the characteristic e-folding scale width (W(sub 0)). We confirm a significant drop in the Lyα strength (i.e., W(sub 0)) at z > 6. Furthermore, we compare the redshift evolution of W(sub 0) between galaxies at different UV luminosities. UV-bright (M(sub UV) < −21 [i.e., L(sub UV) > L*]) galaxies show weaker evolution with a decrease of 0.4 ( ± 0.2) dex in W(sub 0) at z > 6, while UV-faint (M(sub UV) > −21 [LUV < L*]) galaxies exhibit a significant drop of 0.7–0.8 (±0.2) dex in W(sub 0) from z < 6 to z > 6. If the change in W(sub 0) is proportional to the change in the IGM transmission for Lyα photons, then this is evidence that the transmission is “boosted” around UV-brighter galaxies, suggesting that reionization proceeds faster in regions around such galaxies.

Reionization↗
NASA NTRS2020

Swift Spectroscopy of the Accretion Disk Wind in the Black Hole GRO J1655–40

Chandra obtained two High Energy Transmission Grating spectra of the stellar-mass black hole GRO J1655−40 during its 2005 outburst, revealing a rich and complex disk wind. Soon after its launch, the Neil Gehrels Swift Observatory began monitoring the same outburst. Some X-ray Telescope (XRT) observations were obtained in a mode that makes it impossible to remove strong Mn calibration lines, so the Fe Kα line region in the spectra was previously neglected. However, these lines enable a precise calibration of the energy scale, facilitating studies of the absorption-dominated disk wind and its velocity shifts. Here we present fits to 15 Swift/XRT spectra, revealing variability and evolution in the outflow. The data strongly point to a magnetically driven disk wind: both the higher-velocity (e.g., v~-104 km s-1) and lower-velocity (e.g., v~-103 km s-1) wind components are typically much faster than is possible for thermally driven outflows (v </ 200 km s-1), and photoionization modeling yields absorption radii that are two orders of magnitude below the Compton radius that defines the typical inner extent of thermal winds. Moreover, correlations between key wind parameters yield an average absorption measure distribution that is consistent with magnetohydrodynamic wind models. We discuss our results in terms of recent observational and theoretical studies of black hole accretion disks and outflows, as well as future prospects.

Black hole↗
NASA NTRS1976

DSN research and technology support

Continuing remote controlled pulsar observations are noted, along with routine observations of 22 pulsars. Preliminary installation of equipment for planned unattended operation of the Venus Station is reported, along with extensive measurements and performance evaluation of the 26-m antenna. Support of the X-band radar at the Mars Station (DSS 14), and stability and reliability testing of the DSS 13 receiving system is reported. Klystron testing and other DSN support activities of the DSN High-Power Transmitter Maintenance Facility are noted, along with energy conservation modifications to two buildings at DSS 13. Radio Science experiment support included Planetary Radio Astronomy, Pulsar Rotation Constancy, Interstellar Microwave Spectroscopy, and Very Long Baseline Interferometry observations. An increased schedule of clock synchronization transmissions, planned on five-day centers, is noted, as 39 transmissions were made to Australia, DSS 43, and Spain, DSS 63.

Jackson, E. B.↗
NASA NTRS1982

Progress in airborne infrared and submillimetre spectroscopy

The role of spectral resolution and of instrumental sensitivity in astronomical spectroscopy conducted from aircraft is discussed. One cause of difficulty in changing atmospheric transmission is the variations in water vapor content above the aircraft. A main source of uncertainty in measurements is the modulation of the observed signal.

Harwit, M.↗
NASA NTRS1987

High resolution infrared spectroscopy from space: A preliminary report on the results of the Atmospheric Trace Molecule Spectroscopy (ATMOS) experiment on Spacelab 3

The ATMOS (Atmospheric Trace Molecule Spectroscopy) experiment has the broad purpose of investigating the physical structure, chemistry, and dynamics of the upper atmosphere through the study of the distributions of the neutral minor and trace constituents and their seasonal and long-term variations. The technique used is high-resolution infrared absorption spectroscopy using the Sun as the radiation source, observing the changes in the transmission of the atmosphere as the line-of-sight from the Sun to the spacecraft penetrates the atmosphere close to the Earth's limb at sunrise and sunset. During these periods, interferograms are generated at the rate of one each second which yield, when transformed, high resolution spectra covering the 2.2 to 16 micron region of the infrared. Twenty such occultations were recorded during the Spacelab 3 flight, which have produced concentration profiles for a large number of minor and trace upper atmospheric species in both the Northern and Southern Hemispheres. Several of these species have not previously been observed in spectroscopic data. The data reduction and analysis procedures used following the flight are discussed; a number of examples of the spectra obtained are shown, and a bar graph of the species detected thus far in the analysis is given which shows the altitude ranges for which concentration profiles were retrieved.

Farmer, Crofton B.↗
NASA NTRS2000

Discovery of Spatial and Spectral Structure in the X-Ray Emission from the Crab Nebula

The Chandra X-Ray Observatory observed the Crab Nebula and pulsar during orbital calibration. Zeroth-order images with the High-Energy Transmission Grating (HETG) readout by the Advanced Charge Coupled Devices (CCD) Imaging Spectrometer spectroscopy array (ACIS-S) show a striking richness of X-ray structure at a resolution comparable to that of the best ground-based visible-light observations. The HETG-ACIS-S images reveal, for the first time, an X-ray inner ring within the X-ray torus, the suggestion of a hollow-tube structure for the torus, and X-ray knots along the inner ring and (perhaps) along the inward extension of the X-ray jet. Although complicated by instrumental effects and the brightness of the Crab Nebula, the spectrometric analysis shows systematic variations of the X-ray spectrum throughout the nebula.

Weisskopf, Martin C.↗