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At least 181 records · Page 10

Visualization of Secondary Flow Development in High Aspect Ratio Channels with Curvature

The results of an experimental project to visually examine the secondary flow structure that develops in curved, high aspect-ratio rectangular channels are presented. The results provide insight into the fluid dynamics within high aspect ratio channels. A water flow test rig constructed out of plexiglass, with an adjustable aspect ratio, was used for these experiments. Results were obtained for a channel geometry with a hydraulic diameter of 10.6 mm (0.417 in.), an aspect ratio of 5.0, and a hydraulic radius to curvature radius ratio of 0.0417. Flow conditions were varied to achieve Reynolds numbers up to 5,100. A new particle imaging velocimetry technique was developed which could resolve velocity information from particles entering and leaving the field of view. Time averaged secondary flow velocity vectors, obtained using this velocimetry technique, are presented for 30 degrees, 60 degrees, and 90 degrees into a 180 degrees bend and at a Reynolds number of 5,100. The secondary flow results suggest the coexistence of both the classical curvature induced vortex pair flow structure and the eddies seen in straight turbulent channel flow.

Meyer, Michael L.↗

Extrapolation of Earth-based solar irradiance measurements to exoatmospheric levels for broad-band and selected absorption-band observations

Techniques for extrapolating Earth-based spectral band measurements of directly transmitted solar irradiance to equivalent exoatmospheric signal levels were used to aid in determining system gain settings of the Halogen Occultation Experiment (HALOE) sunsensor system being developed for the NASA Upper Atmosphere Research Satellite and for the Stratospheric Aerosol and Gas (SAGE) 2 instrument on the Earth Radiation Budget Satellite. A band transmittance approach was employed for the HALOE sunsensor which has a broad-band channel determined by the spectral responsivity of a silicon detector. A modified Langley plot approach, assuming a square-root law behavior for the water vapor transmittance, was used for the SAGE-2 940 nm water vapor channel.

Reagan, J. A.↗

Extrapolation of earth-based solar irradiance measurements to exoatmospheric levels for broad-band and selected absorption-band observations

Techniques for extrapolating earth-based spectral band measurements of directly transmitted solar irradiance to equivalent exoatmospheric signal levels were used to aid in determining system gain settings of the Halogen Occultation Experiment (HALOE) sunsensor being developed for the NASA Upper Atmosphere Research Satellite and for the Stratospheric Aerosol and Gas (SAGE) 2 instrument on the Earth Radiation Budget Satellite. A band transmittance approach was employed for the HALOE sunsensor which has a broad-band channel determined by the spectral responsivity of a silicon detector. A modified Langley plot approach, assuming a square-root law behavior for the water vapor transmittance, was used for the SAGE-2 940 nm water vapor channel.

Reagan, John A.↗

Investigation of water vapor motion winds from geostationary satellites

Water vapor imagery from geostationary satellites has been available for over a decade. These data are used extensively by operational analysts and forecasters, mainly in a qualitative mode (Weldon and Holmes 1991). In addition to qualitative applications, motions deduced in animated water vapor imagery can be used to infer wind fields in cloudless regimes, thereby augmenting the information provided by cloud-drift wind vectors. Early attempts at quantifying the data by tracking features in water vapor imagery met with modest success (Stewart et al. 1985; Hayden and Stewart 1987). More recently, automated techniques have been developed and refined, and have resulted in upper-level wind observations comparable in quality to current operational cloud-tracked winds (Laurent 1993). In a recent study by Velden et al. (1993) it was demonstrated that wind sets derived from Meteosat-3 (M-3) water vapor imagery can provide important environmental wind information in data void areas surrounding tropical cyclones, and can positively impact objective track forecasts. M-3 was repositioned to 75W by the European Space Agency in 1992 in order to provide complete coverage of the Atlantic Ocean. Data from this satellite are being transmitted to the U.S. for operational use. Compared with the current GOES-7 (G-7) satellite (positioned near 112W), the M-3 water vapor channel contains a superior horizontal resolution (5 km vs. 16 km ). In this paper, we examine wind sets derived using automated procedures from both GOES-7 and Meteosat-3 full disk water vapor imagery in order to assess this data as a potentially important source of large-scale wind information. As part of a product demonstration wind sets were produced twice a day at CIMSS during a six-week period in March and April (1994). These data sets are assessed in terms of geographic coverage, statistical accuracy, and meteorological impact through preliminary results of numerical model forecast studies.

Velden, Christopher S.↗

Evaluation of Vertically Resolved Water Winds from AIRS using Hurricane Katrina

The knowledge of wind velocity as a function of altitude is key to weather forecast improvements. The ability of hyperspectral sounders in principle to measure vertically resolved water winds, which has long been recognized, has been tested with Atmospheric Infrared Sounder (AIRS) data. AIRS retrievals of total column water above 300 mb have been correlated with the radiosonde upper-tropospheric wind velocity and moisture data. The excellent correlation is illustrated with results obtained from hurricane Katrina and from the western United States. AIRS is a hyperspectral infrared sounder in low Earth orbit. It was launched in May 2002. We illustrate the use of AIRS data for the measurement of upper tropospheric water by using the 2387/cm CO2 R-branch channel and the 1551/cm water vapor channel. The 2387/cm channel measures the temperature at 300 mb totally independent of water vapor. The weighting function of the 1551/cm channel peaks at 300 mb only under moist conditions; the peak shifts downward (higher temperature) for less water and upward (lower temperature) for more water. The difference between the brightness temperatures bt2387 and bt1551 cancels the local several degree weather related variability of the temperature and measures the component due to the water vapor at 300 mb.

Atmospheric Infrared Sounder (AIRS)↗

Analysis of tropical synoptic disturbances using satellite-derived soundings and radiance data from selected channels

Some of the results of comparing and combining conventional meteorological data with data retrieved from satellite radiance measurements in determining the atmospheric structure associated with a portion of the life cycle of an eastern Pacific moisture burst are presented. The satellite-derived data, consisting of microwave and water vapor channel brightness temperature fields and cloud-tracked winds, detect synoptic scale patterns of temperature, moisture, and wind. The microwave channel temperatures provide 'all weather' coverage but require special interpretation in rain areas. The need for further investigations to improve the accuracy of inferring structure from satellite-derived information is emphasized.

Thompson, A. H.↗

One-Dimensional Glassy Behavior of Ultraconfined Water Strings

Water is renowned for its anomalous behaviors, which can be linked to a distributed H-bond network in bulk water. Ultraconfinement of the water molecule can remove H-bonding, leaving only molecular water. In natural cordierite crystals, water is trapped in an orthorhombic channel with an average diameter of 5.7 Å, running through the center of the unit cell parallel to the c-axis. Calorimetric measurements reveal the existence of a one-dimensional (1D) glass linked to this water. In these channels, water molecules in truncated, sparse 1D strings interact only via dipole–dipole correlations. Here, a physical 1D glass is formed from these strings. This unusual state can be explained by a modified Ising model. This model predicts a dependence of the glass transition temperature, Tg, on the size of these domains. This is confirmed experimentally.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Integrated cooling (i-Cool) textile of heat conduction and sweat transportation for personal perspiration management

Perspiration evaporation plays an indispensable role in human body heat dissipation. However, conventional textiles tend to focus on sweat removal and pay little attention to the basic thermoregulation function of sweat, showing limited evaporation ability and cooling efficiency in moderate/profuse perspiration scenarios. Here, we propose an integrated cooling (i-Cool) textile with unique functional structure design for personal perspiration management. By integrating heat conductive pathways and water transport channels decently, i-Cool exhibits enhanced evaporation ability and high sweat evaporative cooling efficiency, not merely liquid sweat wicking function. In the steady-state evaporation test, compared to cotton, up to over 100% reduction in water mass gain ratio, and 3 times higher skin power density increment for every unit of sweat evaporation are demonstrated. Besides, i-Cool shows about 3 °C cooling effect with greatly reduced sweat consumption than cotton in the artificial sweating skin test. The practical application feasibility of i-Cool design principles is well validated based on commercial fabrics. Owing to its exceptional personal perspiration management performance, we expect the i-Cool concept can provide promising design guidelines for next-generation perspiration management textiles.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Remote Sensing of Suspended Sediments and Shallow Coastal Waters

Ocean color sensors were designed mainly for remote sensing of chlorophyll concentrations over the clear open oceanic areas (case 1 water) using channels between 0.4 and 0.86 micrometers. The Moderate Resolution Imaging Spectroradiometer (MODIS) launched on the NASA Terra and Aqua Spacecrafts is equipped with narrow channels located within a wider wavelength range between 0.4 and 2.5 micrometers for a variety of remote sensing applications. The wide spectral range can provide improved capabilities for remote sensing of the more complex and turbid coastal waters (case 2 water) and for improved atmospheric corrections for Ocean scenes. In this article, we describe an empirical algorithm that uses this wide spectral range to identifying areas with suspended sediments in turbid waters and shallow waters with bottom reflections. The algorithm takes advantage of the strong water absorption at wavelengths longer than 1 micrometer that does not allow illumination of sediments in the water or a shallow ocean floor. MODIS data acquired over the east coast of China, west coast of Africa, Arabian Sea, Mississippi Delta, and west coast of Florida are used in this study.

Li, Rong-Rong↗

The Effects of Morphology and Hydration on Anion Transport in Self-Assembled Nanoporous Membranes

Ordered nanoporous polymer membranes offer opportunities for systematically probing the mechanisms of ion transport under confinement and for realizing useful materials for electrochemical devices. Here, we examine the impact of morphology and ion hydration on the transport of hydroxide and bromide anions in nanostructured polymer membranes with 1 nm scale pores. We use aqueous lyotropic self-assembly of an amphiphilic monomer, with a polymerizable surfactant to create direct hexagonal (H I ) and gyroid mesophases. UV-induced cross-linking leads to the formation of nanoporous polymers with water continuous channels. The membranes are mechanically robust and chemically durable, resisting degradation during extended exposure to 1 M NaOH solutions. We use a combination of electrochemical impedance spectroscopy, pulsed-field gradient NMR spectroscopy, and molecular simulations to elucidate anion and water transport. The as-prepared hexagonal systems display higher conductivity and lower activation energies for both anions relative to the gyroid system. When compared at equivalent hydration, however, gyroid and hexagonal membranes show similar activation energies, with nearly identical conductivities at ambient temperatures. Both ionic conductivity and water diffusivity increase with increasing hydration. Here, the water uptake as a function of relative humidity for the hexagonal and gyroid mesophases ultimately dictates the water diffusion and magnitude of the ionic conductivity, with the hexagonal system showing overall higher capacity for hydration and thus faster ion transport. The durability of these materials under aggressive alkaline conditions and their relatively high hydroxide ion conductivity suggest that these nanostructured polymers could be of interest as membranes for alkaline fuel cells.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Early Mars: A regional assessment of denudation chronology

Within the oldest highland units on Mars, the record of crater degradation indicates that fluvial resurfacing was responsible for modifying the Noachian through middle-Hesperian crater population. Based on crater frequency in the Noachian cratered terrain, age/elevation relations suggest that the highest exposures of Noachian dissected and plateau units became stabilized first, followed by successively lower units. In addition, studies of drainage networks indicate that the frequency of Noachian channels is greatest at high elevations. Together, these observations provide strong evidence of atmospheric involvement in volatile recycling. The long time period of crater modification also suggests that dendritic highland drainage was not simply the result of sapping by release of juvenile water, because the varied geologic units as well as the elevation dependence of stability ages makes it unlikely that subsurface recycling could provide a continuous supply of water for channel formation by sapping. While such geomorphic constraints on volatile history have been established by crater counts and stratigraphic relations using the 1:2M photomosaic series, photogeologic age relationships at the detailed level are needed to establish a specific chronology of erosion and sedimentation. Age relations for discrete erosional slopes and depositional basins will help refine ages of fluvial degradation, assess effectiveness of aeolian processes, and provide a regional chronology of fluvial events.

Maxwell, T. A.↗

A MHD channel study for the ETF conceptual design

The procedures and computations used to identify an MHD channel for a 540 mW(I) EFT-scale plant are presented. Under the assumed constraints of maximum E(x), E(y), J(y) and Beta; results show the best plant performance is obtained for active length, L is approximately 12 M, whereas in the initial ETF studies, L is approximately 16 M. As MHD channel length is reduced from 16 M, the channel enthalpy extraction falls off, slowly. This tends to reduce the MHD power output; however, the shorter channels result in lower heat losses to the MHD channel cooling water which allows for the incorporation of more low pressure boiler feedwater heaters into the system and an increase in steam plant efficiency. The net result of these changes is a net increase in the over all MHD/steam plant efficiency. In addition to the sensitivity of various channel parameters, the trade-offs between the level of oxygen enrichment and the electrical stress on the channel are also discussed.

Wang, S. Y.↗

Zr‐Porphyrin Metal–Organic Framework as nanoreactor for boosting the formation of hydrogen clathrates

Abstract We report the first experimental evidence for rapid formation of hydrogen clathrates under mild pressure and temperature conditions within the cavities of a zirconium‐metalloporphyrin framework, specifically PCN‐222. PCN‐222 has been selected for its 1D mesoporous channels, high water‐stability, and proper hydrophilic behavior. Firstly, we optimize a microwave (MW)‐assisted method for the synthesis of nanosized PCN‐222 particles with precise structure control (exceptional homogeneity in morphology and crystalline phase purity), taking advantage of MW in terms of rapid/homogeneous heating, time and energy savings, as well as potential scalability of the synthetic method. Second, we explore the relevance of the large mesoporous 1D open channels within the PCN‐222 to promote the nucleation and growth of confined hydrogen clathrates. Experimental results show that PCN‐222 drives the nucleation process at a lower pressure than the bulk system (1.35 kbar vs 2 kbar), with fast kinetics (minutes), using pure water, and with a nearly complete water‐to‐hydrate conversion. Unfortunately, PCN‐222 cannot withstand these high pressures, which lead to a significant alteration of the mesoporous structure while the microporous network remains mainly unchanged.

Carrillo‐Carrión, Carolina↗

Zr‐Porphyrin Metal–Organic Framework as nanoreactor for boosting the formation of hydrogen clathrates

Abstract We report the first experimental evidence for rapid formation of hydrogen clathrates under mild pressure and temperature conditions within the cavities of a zirconium‐metalloporphyrin framework, specifically PCN‐222. PCN‐222 has been selected for its 1D mesoporous channels, high water‐stability, and proper hydrophilic behavior. Firstly, we optimize a microwave (MW)‐assisted method for the synthesis of nanosized PCN‐222 particles with precise structure control (exceptional homogeneity in morphology and crystalline phase purity), taking advantage of MW in terms of rapid/homogeneous heating, time and energy savings, as well as potential scalability of the synthetic method. Second, we explore the relevance of the large mesoporous 1D open channels within the PCN‐222 to promote the nucleation and growth of confined hydrogen clathrates. Experimental results show that PCN‐222 drives the nucleation process at a lower pressure than the bulk system (1.35 kbar vs 2 kbar), with fast kinetics (minutes), using pure water, and with a nearly complete water‐to‐hydrate conversion. Unfortunately, PCN‐222 cannot withstand these high pressures, which lead to a significant alteration of the mesoporous structure while the microporous network remains mainly unchanged.

Carrillo‐Carrión, Carolina↗

Distinct Chemistries Explain Decoupling of Slip and Wettability in Atomically Smooth Aqueous Interfaces

Despite essentially identical crystallography and equilibrium structuring of water, nanoscopic channels composed of hexagonal boron nitride and graphite exhibit an order-of-magnitude difference in fluid slip. We investigate this difference using molecular dynamics simulations, demonstrating that its origin is in the distinct chemistries of the two materials. In particular, the presence of polar bonds in hexagonal boron nitride, absent in graphite, leads to Coulombic interactions between the polar water molecules and the wall. We demonstrate that this interaction is manifested in a large typical lateral force experienced by a layer of oriented hydrogen atoms in the vicinity of the wall, leading to the enhanced friction in hexagonal boron nitride. The fluid adhesion to the wall is dominated by dispersive forces in both materials, leading to similar wettabilities. Finally, our results rationalize recent observations that the difference in frictional characteristics of graphite and hexagonal boron nitride cannot be explained on the basis of the minor differences in their wettabilities.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Comparisons of Upper Tropospheric Humidity Retrievals from TOVS and METEOSAT

Two different methods for retrieving Upper Tropospheric Humidities (UTH) from the TOVS (TIROS Operational Vertical Sounder) instruments aboard NOAA polar orbiting satellites are presented and compared. The first one, from the Environmental Technology Laboratory, computed by J. Bates and D. Jackson (hereafter BJ method), estimates UTH from a simplified radiative transfer analysis of the upper tropospheric infrared water vapor channel at wavelength measured by HIRS (6.3 micrometer). The second one results from a neural network analysis of the TOVS (HIRS and MSU) data developed at, the Laboratoire de Meteorologie Dynamique (hereafter the 3I (Improved Initialization Inversion) method). Although the two methods give very similar retrievals in temperate regions (30-60 N and S), an absolute bias up to 16% appears in the convective zone of the tropics. The two datasets have also been compared with UTH retrievals from infrared radiance measurements in the 6.3 micrometer channel from the geostationary satellite METEOSAT (hereafter MET method). The METEOSAT retrievals are systematically drier than the TOVS-based results by an absolute bias between 5 and 25%. Despite the biases, the spatial and temporal correlations are very good. The purpose of this study is to explain the deviations observed between the three datasets. The sensitivity of UTH to air temperature and humidity profiles is analysed as are the clouds effects. Overall, the comparison of the three retrievals gives an assessment of the current uncertainties in water vapor amounts in the upper troposphere as determined from NOAA and METEOSAT satellites.

Escoffier, C.↗

Water facilities in retrospect and prospect: An illuminating tool for vehicle design

Water facilities play a fundamental role in the design of air, ground, and marine vehicles by providing a qualitative, and sometimes quantitative, description of complex flow phenomena. Water tunnels, channels, and tow tanks used as flow-diagnostic tools have experienced a renaissance in recent years in response to the increased complexity of designs suitable for advanced technology vehicles. These vehicles are frequently characterized by large regions of steady and unsteady 3-D flow separation and ensuing vortical flows. The visualization and interpretation of the complicated fluid motions about isolated vehicle components and complete configurations in a time and cost effective manner in hydrodynamic test facilities is a key element in the development of flow control concepts, and, hence, improved vehicle designs. A historical perspective of the role of water facilities in the vehicle design process is presented. The application of water facilities to specific aerodynamic and hydrodynamic flow problems is discussed, and the strengths and limitations of these important experimental tools are emphasized.

Erickson, Gary E.↗