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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 181 records · Page 10

Origin of Intrinsically Low Thermal Conductivity in a Garnet-Type Solid Electrolyte: Linking Lattice and Ionic Dynamics with Thermal Transport

Understanding thermal transport in solid electrolytes is essential for improving the performance, reliability, and safety of all-solid-state batteries. Garnet-type lithium-ion conductors are promising candidates for solid electrolytes, yet their thermal-transport mechanisms remain poorly understood. Here, we connect the lattice and ion dynamics of single-crystal garnet-type Li 6.5 La 3 Zr 1.5 Ta 0.5 O 12 to its intrinsically low thermal conductivity. Our study reveals that the single crystals grown by the floating-zone method exhibit remarkably low glasslike thermal conductivity. Using first-principles calculations and inelastic-neutron-scattering measurements, we identify both the acoustic and numerous optical phonon modes, which stem from the complex crystal structure of the material. Notably, a low-energy optical branch exhibits an avoided crossing with acoustic phonons near 7 meV. These optical modes can enhance the scattering of heat-carrying acoustic phonons and reduce thermal conductivity. Furthermore, the calculated Grüneisen parameters are large, especially for the vibrational modes around 6 meV, indicating strong anharmonicity, with a noticeable contribution from lithium-ion vibrations. A two-channel thermal-transport model is employed to describe the weak temperature dependence of the thermal conductivity, which can be attributed to the substantial contribution of diffuson transport facilitated by the abundance of optical phonons and intrinsic anharmonicity. These results offer valuable insights into the thermal transport in a broad class of ionic conductors of interest for energy conversion and storage applications.

Ab initio calculations↗

Acoustic Reflection and Transmission of 2-Dimensional Rotors and Stators, Including Mode and Frequency Scattering Effects

A reduced order modeling scheme has been developed for the unsteady acoustic and vortical coupling between blade rows of a turbomachine. The essential behavior of the system is governed by modal scattering coefficients (i.e., reflection and transmission coefficients) of the rotor, stator, inlet and nozzle, which are calculated as if they were connected to non-reflecting ducts. The objective of this report is to identify fundamental behavior of these scattering coefficients for a better understanding of the role of blade row reflection and transmission in noise generation. A 2D flat plate unsteady cascade model is used for the analysis with the expectation that the general behavior presented herein will carry over to models that include more realistic flow and geometry. It is shown that stators scatter input waves into many modes at the same frequency whereas rotors scatter on frequency, or harmonic order. Important cases are shown here the rotor reflection coefficient is greater than unity; a mode at blade passing frequency (BPF) traveling from the stator with unit sound power is reflected by the rotor with more than unit power at 2xBPF and 3xBPE Analysis is presented to explain this unexpected phenomenon. Scattering curves are presented in a format chosen for design use and for physical interpretation. To aid in interpretation of the curves, formulas are derived for special condition where waveforms are parallel to perpendicular to the rotor.

Hanson, Donald B.↗

Microscopic Mechanisms of Glasslike Lattice Thermal Transport in Cubic Cu 12 Sb 4 S 13 Tetrahedrites

Materials based on cubic tetrahedrites (Cu 12 Sb 4 S 13 ) are useful thermoelectrics with unusual thermal and electrical transport properties, such as very low and nearly temperature-independent lattice thermal conductivity (κ L ). We explain the microscopic origin of the glasslike κ L in Cu 12 Sb 4 S 13 by explicitly treating anharmonicity up to quartic terms for both phonon energies and phonon scattering rates. We show that the strongly unstable phonon modes associated with trigonally coordinated Cu atoms are anharmonically stabilized above approximately 100 K and continue hardening with increasing temperature in accord with experimental data. This temperature-induced hardening effect reduces scattering of heat carrying acoustic modes by reducing the available phase space for three-phonon processes, thereby balancing the conventional ∝ T increase in scattering due to phonon population and yielding nearly temperature independent κ L . Furthermore, we find that very strong phonon broadening leads to a qualitative breakdown of the conventional phonon-gas model and modify the dominant heat transport mechanism from the particlelike phonon wave packet propagation to incoherent contributions described by the off-diagonal terms in the heat-flux operator, which are typically prevailing in glasses and disordered crystals. Furthermore, our work paves the way to a deeper understanding of glasslike thermal conductivity in complex crystals with strong anharmonicity.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Free-field correction factor for spherical acoustic waves impinging on cylinders

The scattering and diffraction of spherical waves by an infinite rigid cylinder is analytically studied for monopole and dipole acoustic sources. A correction factor at the cylinder surface for the change in the free-field radiation levels due to the presence of the cylinder is calculated. The results indicate that the correction factor is sensitive to source frequency and location. Regions of negative correction factor, due to shadowing and creeping wave behavior are identified.

Fuller, C. R.↗

High-pressure elasticity and equation of state of the fluoroelastomer Viton® A-500

Viton® A is a semi-crystalline copolymer of polyvinylidene fluoride and hexafluoropropylene used in various engineering applications due to its mechanical properties and chemical inertness. In situ ultrasonic spectroscopy and x-ray radiography measurements were performed in a Paris–Edinburgh press to measure the pressure dependence of the transverse and longitudinal acoustic velocity of the fluoroelastomer A-500 from 2.7 to 5.7 GPa at 296 K. In addition, we performed high-pressure Brillouin scattering measurements to obtain acoustic velocities from ambient pressure to 5.7 GPa to supplement the ultrasonic measurements, especially at low pressures. The acoustic velocities were then used to calculate a pressure–volume (P–V) equation of state, the bulk and shear moduli, and the Poisson's ratio. These quantities are compared with the reported pressure-dependent properties of related polymers over this range of pressures.

Acoustical properties↗

Acoustic phonon dispersion of α – RuCl 3

Acoustic phonons have recently been posited as playing an integral role in explaining the halfquantized thermal Hall effect in α-RuCl 3 . Therefore, we present much needed inelastic x-ray scattering measurements of its acoustic phonon dispersion, along with calculations using the frozen-phonon method. We also discuss a temperature study which conclusively shows a first-order structural transition to a non-C2/m space group at low temperature. Together these results are an important backbone for future theoretical and experimental studies of α-RuCl 3 .

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

The plasma mechanism for preferential acceleration of heavy ions

The induced scattering of ion-acoustic waves on ions is considered for preferential preacceleration of heavy elements. The reconsidered diffusion coefficient in velocity space is used. If the threshold velocity for the main acceleration is linear in charge-to-mass ratio, the induced scattering can account for the observed heavy element abundances in solar cosmic rays.

Kocharov, L. G.↗

Noise Scattering Study for a NACA 0012 Airfoil with a Shielding Flap

Noise scattering measurements for a NACA 0012 airfoil with a flap were conducted. The effects of the flap relative placement and geometry on noise shielding are examined. This scattering test supports the development of a noise reduction concept (referred as the Shielding Flap) applicable to a NATO MULDICON vehicle. Together with the NASA PAASc scattering prediction method, the experimental study presented here was used for the initial exploration and development of the Shielding Flap concept.

acoustic↗

Acoustic plasmons and conducting carriers in hole-doped cuprate superconductors

The layered crystal structures of cuprates enable collective charge excitations fundamentally different from those of three-dimensional metals. Acoustic plasmons have been observed in electron-doped cuprates by resonant inelastic X-ray scattering (RIXS); in contrast, whether acoustic plasmons exist in hole-doped cuprates is under debate, despite extensive measurements. This contrast led us to investigate the charge excitations of hole-doped cuprate La 2-x Sr x CuO 4 . Here we present incidentenergy-dependent RIXS measurements and calculations of collective charge response via the loss function to reconcile the aforementioned issues. Our results provide evidence for the acoustic plasmons of Zhang-Rice singlet (ZRS), which has a character of the Cu 3d x 2 -y 2 strongly hybridised with the O 2p orbitals; the metallic behaviour is implied to result from the movement of ZRS rather than the simple hopping of O 2p holes.

36 MATERIALS SCIENCE↗

Coexistence of Soft Modes and Dynamic Ti Disorder in Cubic BaTiO 3 Studied by Inelastic Neutron Scattering

The phonon dispersion relations in cubic BaTiO 3 have been measured along the [100], [110], and [111] directions at T = 453 K using inelastic neutron scattering. The isotropic transverse acoustic (TA) branches indicate that the interatomic force constant between Ba and O atoms in BaTiO 3 is large compared with that between Pb and O atoms in PbTiO 3 . The transverse optical (TO) branches along the [100] and [111] directions soften toward the Brillouin zone center. The TO branch along the [110] direction with [001] polarization is relatively low and flat, indicating the weak interatomic force constant between Ti and O atoms along the Ti–O chain. The intensity of inelastic diffuse scattering along the [100] and [110] directions increases with decreasing temperature down to 453 K. In conclusion, the present results suggest that the soft modes coexist with the dynamic Ti disorder in the Ti–O chain near the phase transition in the cubic phase.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

The Radiated Field Generated by a Monopole Source in a Short, Rigid, Rectangular Duct

This thesis develops a method to model the acoustic field generated by a monopole source placed in a moving rectangular duct. The walls of the duct are assumed to be infinitesimally thin and the source is placed at the center of the duct. The total acoustic pressure is written in terms of the free-space pressure, or incident pressure, and the scattered pressure. The scattered pressure is the augmentation to the incident pressure due to the presence of the duct. It satisfies a homogeneous wave equation and is discontinuous across the duct walls. Utilizing an integral representation of the scattered pressure, a set of singular boundary integral equations governing the unknown jump in scattered pressure is derived. This equation is solved by the method of collocation after representing the jump in pressure as a double series of shape functions. The solution obtained is then substituted back into the integral representation to determine the scattered pressure, and the total acoustic pressure at any point in the field. A few examples are included to illustrate the influence of various geometric and kinematic parameters on the radiated sound field.

Lakota, Barbara Anne↗

The Application of a Boundary Integral Equation Method to the Prediction of Ducted Fan Engine Noise

The prediction of ducted fan engine noise using a boundary integral equation method (BIEM) is considered. Governing equations for the BIEM are based on linearized acoustics and describe the scattering of incident sound by a thin, finite-length cylindrical duct in the presence of a uniform axial inflow. A classical boundary value problem (BVP) is derived that includes an axisymmetric, locally reacting liner on the duct interior. Using potential theory, the BVP is recast as a system of hypersingular boundary integral equations with subsidiary conditions. We describe the integral equation derivation and solution procedure in detail. The development of the computationally efficient ducted fan noise prediction program TBIEM3D, which implements the BIEM, and its utility in conducting parametric noise reduction studies are discussed. Unlike prediction methods based on spinning mode eigenfunction expansions, the BIEM does not require the decomposition of the interior acoustic field into its radial and axial components which, for the liner case, avoids the solution of a difficult complex eigenvalue problem. Numerical spectral studies are presented to illustrate the nexus between the eigenfunction expansion representation and BIEM results. We demonstrate BIEM liner capability by examining radiation patterns for several cases of practical interest.

Dunn, M. H.↗

Resonances, radiation pressure and optical scattering phenomena of drops and bubbles

Acoustic levitation and the response of fluid spheres to spherical harmonic projections of the radiation pressure are described. Simplified discussions of the projections are given. A relationship between the tangential radiation stress and the Konstantinov effect is introduced and fundamental streaming patterns for drops are predicted. Experiments on the forced shape oscillation of drops are described and photographs of drop fission are displayed. Photographs of critical angle and glory scattering by bubbles and rainbow scattering by drops are displayed.

Marston, P. L.↗

Cross-beam energy transfer in conditions relevant to direct-drive implosions on OMEGA

In cross-beam energy transfer (CBET), the interference of two laser beams ponderomotively drives an ion-acoustic wave that coherently scatters light from one beam into the other. This redirection of laser beam energy can severely inhibit the performance of direct-drive inertial confinement fusion (ICF) implosions. To assess the role of nonlinear and kinetic processes in direct-drive-relevant CBET, the energy transfer between two laser beams in the plasma conditions of an ICF implosion at the OMEGA laser facility was modeled using particle-in-cell simulations. For typical laser beam intensities, the simulations are in excellent agreement with linear kinetic theory, indicating that nonlinear processes do not play a role in direct-drive implosions. At higher intensities, CBET can be modified by pump depletion, backward stimulated Raman scattering, or ion trapping, depending on the plasma density.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Distributed fiber sensor and machine learning data analytics for pipeline protection against extrinsic intrusions and intrinsic corrosions

This paper presents an integrated technical framework to protect pipelines against both malicious intrusions and piping degradation using a distributed fiber sensing technology and artificial intelligence. A distributed acoustic sensing (DAS) system based on phase-sensitive optical time-domain reflectometry (φ-OTDR) was used to detect acoustic wave propagation and scattering along pipeline structures consisting of straight piping and sharp bend elbow. Signal to noise ratio of the DAS system was enhanced by femtosecond induced artificial Rayleigh scattering centers. Data harnessed by the DAS system were analyzed by neural network-based machine learning algorithms. The system identified with over 85% accuracy in various external impact events, and over 94% accuracy for defect identification through supervised learning and 71% accuracy through unsupervised learning.

Peng, Zhaoqiang↗

Acoustical properties of a model rotor in nonaxial flight

Wind tunnel measurements on model rotor blade loads and acoustical noise were correlated to a theoretical formulation of the rotational noise of a rotor in non-axial flight. Good correlation between theory and data was achieved using actual measured rotor blade pressure harmonic decay levels and lift, drag and radial force magnitudes. Both pressure and acoustic data exhibited considerable scatter in hover and low speed forward flight which resulted in a fairly wide latitude in the noise level prediction at higher harmonics.

Hinterkeuser, E. G.↗