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At least 181 records · Page 10

Asymmetric photolysis of /RS/-leucine with circularly polarized ultraviolet light

(RS)-leucine in 0.1 M HCl solution has been subjected to photolysis with 212.8-nm right (R-) and left circularly polarized light (LCPL) obtained from a laser source. RCPL preferentially photolyzed the (R)-leucine component and LCPL the (S)-leucine component of the RS substrate. The enantiomeric excess produced were 1.98% for the 59% conversion with RCPL and 2.50% for the 75% conversion with LCPL. These 'equal and opposite' effects represent the second highest enantiomeric enrichments yet reported for an asymmetric photolysis and the first ever reported for a prebiotically important substrate - an amino acid. Implications regarding the origin of optical activity are briefly discussed.

Flores, J. J.↗

Low speed test of a high-bypass-ratio propulsion system with an asymmetric inlet designed for a tilt-nacelle V/STOL airplane

A large scale model of a lift/cruise fan inlet designed for a tilt nacelle V/STOL airplane was tested with a high bypass ratio turbofan. Testing was conducted at low freestream velocities with inlet angles of attack ranging from 0 deg to 120 deg. The operating limits for the nacelle were found to be related to inlet boundary layer separation. Small separations originating in the inlet diffuser cause little or no performance degradation. However, at sufficiently severe freestream conditions the separation changes abruptly to a lip separation. This change is associated with a significant reduction in nacelle net thrust as well as a sharp increase in fan blade vibratory stresses. Consequently, the onset of lip separation is regarded as the nacelle operating limit. The test verified that the asymmetric inlet design will provide high performance and stable operation at the design forward speed and angle of attack conditions. At some of these, however, operation near the lower end of the design inlet airflow range is not feasible due to the occurrence of lip separation.

Syberg, J.↗

Three dimensional steady and unsteady asymmetric flow past wings of arbitrary planforms

The nonlinear discrete vortex method is extended to treat the problem of asymmetric flows past a wing with leading edge separation, including steady and unsteady flows. The problem is formulated in terms of a body fixed frame of reference and the nonlinear-discrete vortex method is modified accordingly. Although the method is general, only examples of flows past delta wings are presented due to the availability of experimental data as well as approximate theories. Comparison of results with experimental results for a delta wing undergoing a steady rolling motion at zero angle of attack demonstrate the superiority of the present method over existing approximate theories in obtaining highly accurate loads. Numerical results for yawed wings at large angles of attack are also presented. In all cases, total load coefficients, pressure distributions, and shapes of the free vortex sheets are shown.

Kandil, O. A.↗

Symmetrical and Asymmetrical separations about a yawed cone

Three-dimensional flow separations about a 5 degree (semiapex angle, theta sub C), 1.4 m long, circular cone up to moderately high relative incidence, alpha/theta sub C approximately 5, were studied in the Mach number range 0.3 M sub infinity 1.8. The cone was tested in the Ames 1.8 by 1.8 m wind tunnel at Reynolds numbers, R sub L infinity, based on the cone length, L, from 4.5 times 10 to the 6th power to 13.5 times 10 to the 6th power, under nominally zero heat transfer conditions. Overall forces and mean surface pressures were compared with earlier measurements. Supportive three-dimensional laser velocimeter measurements of mean and fluctuating velocity in a slightly asymmetric vortex wake about a slender tangent ogive cylinder at incidence having respective nose and overall body fineness ratios of 3.5 and 12, are included.

Peake, D. J.↗

The stability of an asymmetric rotor in damped supports

A general-purpose method of evaluating the stability of an asymmetric flexible rotor, mounted in symmetric damped bearings, is defined. This method evaluates the complex eigenvalues of the rotor system by solving the equations of motion in a rotating coordinate frame. The application of this method to a rotor mounted in tilting-pad bearings is demonstrated. The observed behavior of a number of different rotor configurations is compared with corresponding predictions of stability. For the configurations predicted to be unstable, a distinct and unnegotiable threshold of instability is encountered. The sharpness of this threshold is emphasized by careful balancing at speeds fractionally below the threshold. In a final configuration predicted to be marginally stable, lightly damped resonant behavior, negotiable by balancing, is encountered in the region of the first critical speed.

Smalley, A. J.↗

Thermal stress analysis of symmetric shells subjected to asymmetric thermal loads

The performance of the NASTRAN level 16.0 axisymmetric solid elements when subjected to both symmetric and asymmetric thermal loading was investigated. A ceramic radome was modeled using both the CTRAPRG and the CTRAPAX elements. The thermal loading applied contained severe gradients through the thickness of the shell. Both elements were found to be more sensitive to the effect of the thermal gradient than to the aspect ratio of the elements. Analysis using the CTRAPAX element predicted much higher thermal stresses than the analysis using the CTRAPRG element, prompting studies of models for which theoretical solutions could be calculated. It was found that the CTRAPRG element solutions were satisfactory, but that the CTRAPAX element was very geometry dependent. This element produced erroneous results if the geometry was allowed to vary from a rectangular cross-section. The most satisfactory solution found for this type of problem was to model a small segment of a symmetric structure with isoparametric solid elements and apply the cyclic symmetry option in NASTRAN.

Negaard, G. R.↗

New class of asymmetric shapes of rotating liquid drops

Shapes and stability of surface-tension-endowed drops rotating rigidly at fixed angular momentum are calculated by finite-element analysis. A new family of asymmetric two-lobed drop shapes is discovered that branches from, and rejoins, the Pik-Pichak family of symmetric two-lobed shapes. The computations are verified for axisymmetric and symmetric two-lobed drop shape by comparison with previous approximations.

Brown, R. A.↗

Asymmetric trailing-edge flows at high Reynolds number

Results from an experimental investigation of asymmetric trailing-edge flows at high Reynolds numbers and subsonic Mach numbers are presented. Measurements include skin friction; surface and flow-field pressures; and mean-velocity, turbulent shear-stress, and turbulent kinetic-energy profiles in the trailing-edge region. Comparisons are made with computed solutions using Reynolds averaged Navier-Stokes and boundary-layer equations; two different turbulence models are used. Two attached flow are considered, one having a moderate adverse pressure gradient and the other a more severe gradient. From the comparisons, an evaluation is made of the predictions for these two pressure-gradient cases. Although the comparisons demonstrate reasonable agreement for the moderate pressure-gradient case, some differences are noted for the severe pressure-gradient case.

Cleary, J. W.↗

A three-dimensional body-fitted coordinate system for flow field calculations on asymmetric nosetips

A three dimensional body-fitted coordinate system developed for use in the calculation of inviscid flows over ablated, asymmetric reentry vehicle nosetips is described. Because of the potential geometric asymmetries, no standard coordinate system (e.g., spherical, axisymmetric reference surface-normal) is capable of being closely aligned with the nosetip surface. To generate a 3-D, body-fitted coordinate system an analytic mapping procedure is applied that is conformal within each meridional plane of the nosetip; these transformations are then coupled circumferentially to yield a three dimensional coordinate system. The mappings used are defined in terms of hinge points, which are points selected to approximate the body contours in each meridional plane. The selection of appropriate hinge points was automated to facilitate the use of the resulting nosetip flow field code.

Hall, D. W.↗

A valid Margules formulation for an asymmetric ternary solution - Revision of the olivine-ilmenite thermometer, with applications

A derivation of a valid asymmetric ternary Margules expression for the excess free energy is presented, and the olivine-ilmenite thermometer is revised accordingly. Although the effect on the thermometer is relatively small, the revision results in improved precision. Estimated temperatures of equilibration are presented for olivine and ilmenite from lunar and terrestrial rocks.

Andersen, D. J.↗

Calculation of a mirror asymmetric effect in electron scattering from chiral targets

A dynamical calculation is presented of the helicity induced in an initially unpolarized electron beam after elastic scattering from an optically active medium, a process analogous to the circular polarization induced in unpolarized light following Rayleigh scattering from chiral targets. The calculation is based on the bound helical electron model of a chiral molecule, according to which the major contribution to the helicity is provided by the perturbation of the electron bound state by the spin-orbit interaction of the bound electrons moving in the electric field of the molecular core. The net helicity acquired is found to depend directly on a molecular asymmetry factor and the square of the atomic number of the heaviest atom in an asymmetric environment. For the case of carbon, the induced helicity is on the order of 0.00001, which would account for its lack of observation in a recent experiment. Results may have implications for the origin of optical activity in biological molecules by the differential ionization of D and L isomers by beta-decay electrons.

Rich, A.↗

Gravity perception and asymmetric growth in plants - A model derived from the grass pulvinus

It is pointed out that gravitropic responses in plants involve asymmetric growth. On the basis of the geometry of growth response in grass leaf sheath pulvinus, a general model is proposed for gravitropism in multicellular plant organs. The negative gravitropic response of a pulvinus is a result of cell elongation involving all but the uppermost region of a horizontally placed organ. Whereas the uppermost region does not grow, the lowermost region elongates maximally. The regions between elongate to intermediate extents. An expression is given relating the angle of curvature of the organ to the diameter and initial and final lengths of the organ. It is shown that the response of the individual cells can be expressed as inherent sensitivity to gravitational stimulus according to a particular equation.

Dayanandan, P.↗

On the interaction of surface heating anomalies with zonally symmetric and asymmetric atmospheric flows

Models of intermediate complexity have been used to study some aspects of the climatic effects of anomalous heating, but many aspects of the problem have yet to be explored thoroughly. The present study represents a preliminary investigated of the gaps in scientific understanding of the interaction of heating and atmospheric dynamics. The principle research tool is a model of intermediate complexity, including a time-dependent, nonlinear-two-layer quasi-geostrophic model of relatively high horizontal resolution which incorporates simple heating parameterizations. The model is used to examine systematically the interaction of heating arising from anomalies in surface temperature with zonally symmetric and zonally asymmetric flows characterized by different values of static stability and mean vertical wind shear.

Phillips, T. J.↗

The effect of asymmetric attack on trim angle of attack

Ballistic range tests were conducted to determine the effect of an asymmetrically ablated heat shield on the trim angle of attack of an entry vehicle. The tests, which were in support of Project Galileo, were conducted in atmospheric air at Mach numbers from 0.7 to 2.0. For the results for the configuration that was tested, the deduced trim angle varied between 13 deg and 21 deg.

Kruse, R. L.↗

Asymmetric emission-line regions with out-flowing mass in QSOs and the z/ab/ at least equal to z/em/ systems

A heuristic asymmetrical model for a quasar emission-line region, with material streaming out, is described. The physical parameters are essentially the same as those of static models; the geometry turns out to be the dominant factor in determining the emission line profiles. Calculations are carried out for a variety of parameterized flow models and for the Blumenthal and Mathews (1975) theoretical model of a radiatively driven flow. The emission-line profiles are insensitive to the details of the acceleration, the filling factor, and the ionization profile. Absorption is assumed to take place in stationary matter in the QSO's galaxy or associated group or cluster, so that z(ab) is identified with the cosmological redshift. Due to the flow, the emission-lines are shifted with respect to the absorption-lines; in cases of a flow directed towards the observer systems with z(ab) at least equal to z(em) result. The distribution of absorption redshifts is symmetric about z(em).

Goldman, I.↗

Dynamics and spectroscopy of asymmetrically heated coronal loops

Numerical models of steady flows along coronal magnetic flux tubes of varying cross sectional areas are investigated. The flows are induced by altering the spatial symmetry of the heating. In two cases the flux tube geometry is symmetric about the top of the loop, but the spatial dependence of the heating rate is changed from a symmetric deposition which supports a stationary equilibrium to a time-independent asymmetric deposition. In a third case the volumetric heating rate is uniform, but one half of the loop is larger in volume than the other. The resulting velocity structure varies significantly with changes in the flux tube geometry. Calculations of the ionization balance and line emission for a number of ionization stages of oxygen suggest that heating induced flows may be responsible for the redshifts seen in spectral lines formed in the network at transition region temperatures.

Mariska, J. T.↗

Control of the forebody vortex orientation by asymmetric air injection. Part A: Application to enhance departure/spin recovery of fighter aircraft and Part B: Details of the flow structure

A concept developed to provide powerful directional control effectiveness for a fighter aircraft at high angles of attack is described. The concept utilizes the energy concentrated in the strong forebody vortices (which form on slender bodies of high relative incidence) by controlling the lateral orientation of the vortices with respect to the body. The objective was to utilize the side force associated with asymmetric vortices, in a controlled manner, to enhance the ability of the fighter to recover from a departure from controlled flight. The results from water tunnel and wind tunnel experiments show that a small amount of tangential blowing along the forebody near the apex can effectively alter the forebody vortex system and generate large restoring yawing moments. Six degree of freedom digital simulation results show that this concept can substantially enhance recovery characteristics of fighter aircraft with long, slender forebodies. Also, the results of experiments which were conducted on a cone model are discussed where the principal test objective was to develop an understanding of the fluid mechanics involved in the process of vortex control. Knowledge gained in these more generic tests should allow the concept to be applied to a wider range of configurations.

Skow, A. M.↗