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NASA NTRSDate not supplied

TPSAS-NF1676L-11931-DND

Researchers at NASA Langley Research Center have developed an efficient, high repetition rate, pulsed, 2-µm coherent DIAL/IPDA transmitter for CO2 measurements. This transmitter will be employed to measure atmospheric CO2 profiles (by DIAL) initially from a ground platform, and then measure both the atmospheric CO2 profiles (by DIAL) and column densities (by IPDA) from an airborne platform with the potential for measuring CO2 column density from a space-borne platform. The transmitter consists of a pulsed Q-switched ring-cavity Ho:YLF laser operating at 2.05 micron, being pumped by a Tm:fiber laser. The repetition rate can be adjusted from a few hundred Hz to 10 kHz with corresponding energy of 25 to 1 mJ, respectively. This transmitter can be used for direct or coherent detection of CO2 from ground, air or space-borne platform, as it is capable of providing required energy/repetition rate even from space platform. This presentation will describe the details of the injection-seeded highrepetition rate 2-micron transmitter and demonstrate its flexibility for direct or coherent detection of CO2.

Upendra N Singh↗

NASA NTRS1991

The biogeochemistry of microbial mats, stromatolites and the ancient biosphere

Stromatolites offer an unparalleled geologic record of early life, because they constitute the oldest and most abundant recognizable remains of microbial ecosystems. Microbial mats are living homologs of stromatolites; thus, the physiology of the microbiota as well as the processes which create those features of mats (e.g., biomarker organic compounds, elemental and stable isotopic compositions) which are preserved in the ancient record. Observations of the carbon isotopic composition (delta C-13) of stromatolites and microbial mats were made and are consistent with the hypothesis that atmospheric CO2 concentrations have declined by at least one to two orders of magnitude during the past 2.5 Ga. Whereas delta C-13 values of carbonate carbon average about 0 permil during both the early and mid-Proterozoic, the delta C-13 values of stromatolitic organic matter increase from an average of -35 between 2.0 and 2.6 Ga ago to an average of about -28 about 1.0 Ga ago. Modern microbial mats in hypersaline environments have delta C-13 values typically in the range of -5 to -9, relative to an inorganic bicarbonate source at 0 permil. Both microbial mats and pur cultures of cyanobacteria grown in waters in near equilibrium with current atmospheric CO2 levels exhibit minimal discrimination against C-13. In contrast, hot spring cyanobacterial mats or cyanobacterial cultures grown under higher CO2 levels exhibit substantially greater discrimination. If care is taken to compare modern mats with stromatolites from comparable environments, it might be possible to estimate ancient levels of atmospheric CO2. In modern microbial mats, a tight coupling exists between photosynthetic organic carbon production and subsequent carbon oxidation, mostly by sulfate reduction. The rate of one process fuels a high rate of the other, with much of the sulfate reduction occurring within the same depth interval as oxygenic photosynthesis. Other aspects of this study are presented.

Desmarais, D. J.↗

DOE OSTI2025

Short-Term Energy and Meteorological Impacts on Thanksgiving CO2 in Salt Lake City

Abstract Long-term, high-frequency atmospheric CO2 measurements at multiple sites in the Salt Lake City (SLC), Utah, reveal that annual and monthly CO2 variability aligns with a priori estimates of emissions from anthropogenic and biological sources. In this study, we investigate whether short-term fluctuations in anthropogenic emissions, as captured in the Vulcan3 dataset for the United States, can be detected in atmospheric CO2 observations. Specifically, we focus on Thanksgiving holidays, when traffic and energy usage patterns differ from the rest of November. Onroad CO2 emissions exhibit a double peak during weekday morning and evening rush hours but remain relatively low on weekends and Thanksgiving. Interestingly, CO2 mole fractions during Thanksgiving were higher than the rest of November at all SLC monitoring sites, particularly from 2008 to 2013. This increase is partially attributed to elevated energy-related emissions — especially residential sources — and meteorological factors such as weak wind speeds, cold temperature, and a low planetary boundary layer height (PBLH). While CO₂ emissions and mole fraction patterns align over time, notable spatial differences exist. For instance, the near-highway site in Murray shows the highest CO₂ mole fractions despite low local emissions, suggesting pollution transport via highways and wind advection. Random Forest model-based SHapley Additive exPlanations (SHAP) analysis reveals that onroad emissions dominate CO2 contributions on weekdays and weekends, while energy-related emissions play a larger role during Thanksgiving, alongside meteorological drivers such as wind speed and PBLH. Across six urban cities, CO2 emissions display a consistent pattern: residential and commercial (onroad) emissions peak during Thanksgiving (weekday) with substantial (minimal) year-to-year variability. These findings highlight that urban CO₂ variability is driven by the combined influence of emissions and meteorology, underscoring the need for integrated mitigation strategies. Additionally, multi-site measurements are essential for accurate source attribution and the development of effective policy interventions. 

Ryoo, Ju-Mee (ORCID:0000000234256296)↗

NASA NTRS1994

North African savanna fires and atmospheric carbon dioxide

The effect of north African savanna fires on atmospheric CO2 is investigated using a tracer transport model. The model uses winds from operational numerical weather prediction analyses and provides CO2 concentrations as a function of space and time. After a spin-up period of several years, biomass-burning sources are added, and model experiments are run for an additional year, utilizing various estimates of CO2 sources. The various model experiments show that biomass burning in the north African savannas significantly affects CO2 concentrations in South America. The effect is more pronounced during the period from January through March, when biomass burning in South America is almost nonexistent. During this period, atmospheric CO2 concentrations in parts of South America typically may increase by 0.5 to 0.75 ppm at 970 mbar, the average pressure of the lowest model layer. These figures are above the probable uncertainty level, as model runs with biomass-burning sources estimated from independent studies using distinct data sets and techniques indicate. From May through September, when severe biomass burning occurs in South America, the effect of north African savanna fires over South America has become generally small at 970 mbar, but north of the equator it may be of the same magnitude or larger than the effect of South American fires. The CO2 concentration increase in the extreme northern and southern portions of South America, however, is mostly due to southern African fires, whose effect may be 2-3 times larger than the effect of South American fires at 970 mbar. Even in the central part of the continent, where local biomass-burning emissions are maximum, southern African fires contribute to at least 15% of the CO2 concentration increase at 970 mbar. At higher levels in the atmosphere, less CO2 emitted by north African savanna fires reaches South America, and at 100 mbar no significant amount of CO2 is transported across the Atlantic Ocean. The vertical structure of the CO2 concentration increase due to biomass burning differs substantially, depending on whether sources are local or remote. A prominent maximum of CO2 concentration increase in the lower layers characterizes the effect of local sources, whereas a more homogeneous profile of CO2 concentration increase characterizes the effect of remote sources. The results demonstrate the strong remote effects of African biomoass burning which, owing to the general circulation of the atmosphere, are felt as far away as South America.

Iacobellis, Sam F.↗

NASA NTRS2024

Additional Aviation Sustainability Strategies

Emissions from the aviation sector are expected to grow significantly in the next few decades due to growing demand for aviation. The U.S. fleet size has increased significantly in the past 20 years, growing from 2,132 aircraft to 5,485 aircraft. Similarly from 1990 to 2019, aviation emissions more than doubled, growing faster than any other transportation mode. These emissions include carbon dioxide (CO2), as well as non-CO2 sources including nitrogen oxides (NOx), sulfur dioxide (SO2), water (H2O), and particulate matter (soot). However, this report focuses specifically on CO2 emissions because the impacts from CO2 are well-understood and long-lived. There are also many climate goals tied to CO2 emissions, including the US Aviation Climate Action Plan which is pushing for net-zero in 2050. CO2 is a greenhouse, or heat-trapping, gas that comes from the extraction and burning of fossil fuels, from wildfires, and natural processes like volcanoes. Greenhouse gases absorb heat radiating from the Earth’s surface and release it in all directions, including back toward Earth’s surface. By adding more CO2 to the atmosphere, humans amplify the natural greenhouse effect, causing global temperature to rise. Since the onset of industrial times in 1750, human activities have raised atmospheric CO2 by 50%. Considering this challenge, the United States has set a climate goal to achieve net-zero CO2 emissions in the U.S. aviation sector by 2050 to reduce the environmental impact of aviation. Net-zero emissions refers to the amount of greenhouse gases (GHGs), such as CO2, methane or SO2, that are removed from the atmosphere being equal to those emitted by human activity. This contrasts with carbon-neutrality, which refers to no net release of carbon dioxide to the atmosphere, especially through offsetting emissions, that could be accomplished through a series of actions. As of 2022, the goal of net-zero has been adopted by much of the aviation industry including multiple airlines and countries. To reach net-zero by 2050, sustainable aviation fuels (SAFs) are identified as the technology that could provide the greatest impact within this timeframe. However, certain challenges may limit the production and/or adoption of SAFs in the marketplace, such as competition for feedstocks, production capacity, and high cost. In this case, SAFs would be insufficient to meet the net-zero CO2 emission goals. Therefore, in addition to SAFs, other strategies will be needed to close the gap on emissions produced as a result of SAF shortfalls or to enhance the impact of SAFs on reducing emissions. NASA’s Aeronautics Research Mission Directorate (ARMD) aims to examine these additional pathways to explore how its research may best contribute to the realization of net-zero emissions by 2050. Specifically, this effort considers strategies that can reduce emissions in the aviation sector in combination with the use of SAFs and carbon offsets while still meeting projected passenger demand. The strategies considered are not only feasible but also could be operationally scalable by 2050. The goal of this report is to investigate additional strategies such as alternative flight and ground operations, providing insight into the CO2 emission reduction potential and feasibility of strategy implementation by 2050.

Carbon Emissions↗

NASA NTRS2006

The Orbiting Carbon Observatory (OCO) Mission

Science objectives include: Collect the first space-based measurements of atmospheric CO2 with the precision, resolution, and coverage needed to characterize its sources and sinks on regional scales and quantify their variability over the seasonal cycle. Use independent data validation approaches to ensure high accuracy (1-2 ppm, 0.3% - 0.5%). Reliable climate predictions require an improved understanding of CO2 sinks. What human and natural processes are controlling atmospheric CO2? What are the relative roles of the oceans and land ecosystems in absorbing CO2?

carbon dioxide↗

NASA NTRSDate not supplied

TPSAS-NF1676L-23459-DND

This talk covers the needs for carbon science, laser absorption lidar approach for atmospheric CO2 measurements, recent campaign findings, and future work on atmospheric CO2 observations.

Bing Lin↗

NASA NTRS2016

Carbon Monoxide and the Potential for Prebiotic Chemistry on Habitable Planets Around Main Sequence M Stars

Lifeless planets with CO2 atmospheres produce CO by CO2 photolysis. On planets around M dwarfs, CO is a long-lived atmospheric compound, as long as UV emission due to the stars chromospheric activity lasts, and the sink of CO and O2 in seawater is small compared to its atmospheric production. Atmospheres containing reduced compounds, like CO, may undergo further energetic and chemical processing to give rise to organic compounds of potential importance for the origin of life. We calculated the yield of organic compounds from CO2-rich atmospheres of planets orbiting M dwarf stars, which were previously simulated by Domagal- Goldman et al. (2014) and Harman et al. (2015), by cosmic rays and lightning using results of experiments by Miyakawaet al. (2002) and Schlesinger and Miller (1983a, 1983b). Stellar protons from active stars may be important energy sources for abiotic synthesis and increase production rates of biological compounds by at least 2 orders of magnitude compared to cosmic rays. Simple compounds such as HCN and H2CO are more readily synthesized than more complex ones, such as amino acids and uracil (considered here as an example), resulting in higher yields for the former and lower yields for the latter. Electric discharges are most efficient when a reducing atmosphere is present. Nonetheless, atmospheres with high quantities of CO2 are capable of producing higher amounts of prebiotic compounds, given that CO is constantly produced in the atmosphere. Our results further support planetary systems around M dwarf stars as candidates for supporting life or its origin.

M stars↗

NASA NTRS2012

High Energy 2-Micron Solid-State Laser Transmitter for NASA's Airborne CO2 Measurements

A 2-micron pulsed, Integrated Path Differential Absorption (IPDA) lidar instrument for ground and airborne atmospheric CO2 concentration measurements via direct detection method is being developed at NASA Langley Research Center. This instrument will provide an alternate approach to measure atmospheric CO2 concentrations with significant advantages. A high energy pulsed approach provides high-precision measurement capability by having high signal-to-noise level and unambiguously eliminates the contamination from aerosols and clouds that can bias the IPDA measurement.

Singh, Upendra N.↗

NASA NTRS1993

Possible solutions to the problem of channel formation on early Mars

A warm climate on early Mars would provide a natural, although not unique, explanation for the presence of fluvial networks on the ancient, heavily cratered terrains. Explaining how the climate could have been kept warm, however, is not easy. The idea that the global average surface temperature, T(sub s), could have been kept warm by a dense, CO2 atmosphere supplied by volcanism or impacts is no longer viable. It was shown that CO2 cloud formation should have kept T(sub s) well below freezing until approximately 2 b.y. ago, when the Sun had brightened to at least 86 percent of its present value. Warm equatorial regions on an otherwise cold planet seem unlikely because atmospheric CO2 would probably condense out at the poles. Warming by impact-produced dust in the atmosphere seems unlikely because the amount of warming expected for silicate dust particles is relatively small. Greenhouse warming by high altitude CO2 ice clouds seems unlikely because such are poor absorbers of infrared radiation at most wavelengths. Warming by atmospheric NH3 seems unlikely because NH3 is readily photodissociated and because N may have been in short supply as consequence of impact erosion and the high solubility of NH3. A brighter, mass-losing young Sun seems unlikely because stellar winds of the required strength were not observed on other solar-type stars. In short, most of the explanations for a warm Martian paleoclimate that were proposed in the past seem unlikely. One possibility that seems feasible from radiative/photochemical standpoint is that CH4 and associated hydrocarbon gases and particles contributed substantially to the greenhouse effect on early Mars. Methane is photochemically more stable than NH3 and the gases and particles that can be formed from it are all good absorbers of infrared radiation. The idea of a CH4-rich Martian paleoatmosphere was suggested a long time ago but has fallen out of favor because of perceived difficulties in maintaining a CH4-rich atmosphere. In particular, it is not obvious where the CH4 might come from, since volcanic gases (on Earth, at least) contain very little CH4. This difficulty could be largely overcome if early Mars was inhabited by microorganisms. Then, methanogenic bacteria living in sediments could presumably have supplied CH4 to the atmosphere in copious quantities.

Kasting, J. F.↗

NASA NTRS2022

Compressed CO2 Hard Rock Drill for Mars

We have developed a down-the-hole (DTH) rotary-percussive drill prototype that could operate on compressed Mars atmospheric CO2 gas with a wireline drilling approach. This technology addresses a need for more aggressive sampling and drilling techniques, for both scientific purposes and to obtain In-Situ Resource Utilization (ISRU) resources for future NASA missions and human crew support. Using a spool of lightweight, high-pressure capillary, a DTH drill assembly would be moved in and out of the hole that could be a kilometer or more in depth. The CO2 drill is designed so that Mars atmospheric CO2 could be collected, compressed, and supplied down the hole and routed through microducts, valves, and reservoirs for the purpose of controlling miniature mechanical actuation in the assembly. By using compressed CO2, the drill system avoids the need for heavy electrical cabling and actuator systems or a liquid media for carrying away particulates as is typically used in terrestrial drilling systems. Instead, the liquid CO2 that powers the drill expands to a gas and could be channeled around the drill housing to carry cuttings to be collected in a bailing bucket. Where terrestrial systems often use drill depth vs time as a metric, a Mars drilling system would need to be extremely low mass, but would have no need to perform under tight schedules. In this paper, we will document our trade studies, progression for the design of microduct logic verified through multiple generations of prototypes, and provide predictive performance data on energy consumption, hole depth, and drill time.

Wilcox, Brian↗

NASA NTRS2022

Compressed CO2 Hard Rock Drill for Mars

Wilcox, Brian↗

DOE OSTI2023

Life Cycle Assessment of Innovative Carbon Dioxide Selective Membranes from Low Carbon Emission Sources: A Comparative Study

Carbon capture has been an important topic of the twenty-first century because of the elevating carbon dioxide (CO2) levels in the atmosphere. CO2 in the atmosphere is above 420 parts per million (ppm) as of 2022, 70 ppm higher than 50 years ago. Carbon capture research and development has mostly been centered around higher concentration flue gas streams. For example, flue gas streams from steel and cement industries have been largely ignored due to lower associated CO2 concentrations and higher capture and processing costs. Capture technologies such as solvent-based, adsorption-based, cryogenic distillation, and pressure-swing adsorption are under research, but many suffer from higher costs and life cycle impacts. Membrane-based capture processes are considered cost-effective and environmentally friendly alternatives. Over the past three decades, our research group at Idaho National Laboratory has led the development of several polyphosphazene polymer chemistries and has demonstrated their selectivity for CO2 over nitrogen (N2). Poly[bis((2-methoxyethoxy)ethoxy)phosphazene] (MEEP) has shown the highest selectivity. A comprehensive life cycle assessment (LCA) was performed to determine the life cycle feasibility of the MEEP polymer material compared to other CO2-selective membranes and separation processes. The MEEP-based membrane processes emit at least 42% less equivalent CO2 than Pebax-based membrane processes. Similarly, MEEP-based membrane processes produce 34–72% less CO2 than conventional separation processes. In all studied categories, MEEP-based membranes report lower emissions than Pebax-based membranes and conventional separation processes.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

NASA NTRS2007

Laser Sounder for Global Measurement of CO2 Concentrations in the Troposphere from Space

Measurements of tropospheric CO2 abundance with global-coverage, a few hundred km spatial and monthly temporal resolution are needed to quantify processes that regulate CO2 storage by the land and oceans. The Orbiting Carbon Observatory (OCO) is the first space mission focused on atmospheric CO2 for measuring total column CO, and O2 by detecting the spectral absorption in reflected sunlight. The OCO mission is an essential step, and will yield important new information about atmospheric CO2 distributions. However there are unavoidable limitations imposed by its measurement approach. These include best accuracy only during daytime at moderate to high sun angles, interference by cloud and aerosol scattering, and limited signal from CO2 variability in the lower tropospheric CO2 column. We have been developing a new laser-based technique for the remote measurement of the tropospheric CO2 concentrations from orbit. Our initial goal is to demonstrate a lidar technique and instrument technology that will permit measurements of the CO2 column abundance in the lower troposphere from aircraft. Our final goal is to develop a space instrument and mission approach for active measurements of the CO2 mixing ratio at the 1-2 ppmv level. Our technique is much less sensitive to cloud and atmospheric scattering conditions and would allow continuous measurements of CO2 mixing ratio in the lower troposphere from orbit over land and ocean surfaces during day and night. Our approach is to use the 1570nm CO2 band and a 3-channel laser absorption spectrometer (i.e. lidar used an altimeter mode), which continuously measures at nadir from a near polar circular orbit. The approach directs the narrow co-aligned laser beams from the instrument's lasers toward nadir, and measures the energy of the laser echoes reflected from land and water surfaces. It uses several tunable fiber laser transmitters which allowing measurement of the extinction from a single selected CO2 absorption line in the 1570 nm band. This band is free from interference from other gases and has temperature insensitive absorption lines. During the measurement the lasers are tuned on- and off- a selected CO2 line near 1572 nm and a selected O2 line near 768 nm in the Oxygen A band at kHz rates. The lasers use tunable diode seed lasers followed by fiber amplifiers, and have spectral widths much narrower than the gas absorption lines. The receiver uses a 1-m diameter telescope and photon counting detectors and measures the background light and energies of the laser echoes from the surface. The extinction and column densities for the CO2 and O2 gases are estimated from the ratio of the on and offline surface echo via the differential optical absorption technique. Our technique rapidly alternates between several on-line wavelengths set to the sides of the selected gas absorption lines. It exploits the atmospheric pressure broadening of the lines to weight the measurement sensitivity to the atmospheric column below 5 km. This maximizes sensitivity to CO2 in the boundary layer, where variations caused by surface sources and sinks are largest. Simultaneous measurements of O2 column will use an identical approach with an O2 line. Thee laser frequencies are tunable and have narrow (MHz) line widths. In combination with sensitive photon counting detectors these enables much higher spectral resolution and precision than is possible with passive spectrometer. 1aser backscatter profiles are also measured, which permits identifying measurements made to cloud tops and through aerosol layers. The measurement approach using lasers in common-nadir-zenith path allows retrieving CO2 column mixing ratios in the lower troposphere irrespective of sun angle. Pulsed laser signals, time gated receiver and a narrow receiver field-of-view are used to isolate the surface laser echo signals and to exclude photons scattered from clouds and aerosols. Nonetheless, the optical absorption change due to a change of a few ppO2 is small, <1 % which makes achieving the needed measurement sensitivities and stabilities quite challenging. Measurement SNRs and stabilities of >600:1 are needed to estimate CO2 mixing ratio at the 1-2 ppm level. We have calculated characteristics of the technique and have demonstrated aspects of the laser, detector and receiver approaches in th e laboratory We have also measured O2 in an absorption cell, and made C02 measurements over a 400 m long (one way) horizontal path using a sensor breadboard. We will describe these and more details of our approach in the paper.

Abshire, James B.↗

NASA NTRSDate not supplied

A Qualitative Systematic Review Evaluating the Impact of Elevated Ambient Co2 in Atmosphere on Pharmaceutical Stability

Pharmaceuticals are an essential component of the medical system for crewed missions. Current research has identified decreased stability in space-flown pharmaceuticals compared to ground controls, and this presents a significant risk for future exploration-class missions where resupply will be limited. While the cause is not known, the elevated ambient carbon dioxide (CO2) in the spacecraft atmosphere has been postulated as a potential cause.

A Yuen↗

DOE OSTI2024

Innovations in Direct Air Capture: Unveiling a Simple and Robust Synthesized Fibrous Amine-functionalized Matrix (FAM) Sorbent for Commercial Scale-up

The escalating challenge of climate change necessitates innovative solutions in the realm of carbon management, particularly in mitigating the impact of fossil fuel emissions. Direct Air Capture (DAC) technology emerged as a critical component within the spectrum of Carbon Capture and Sequestration (CCS) solutions, offering the distinct advantage of directly removing CO2 from the atmosphere irrespective of the source. This attribute grants DAC systems unparalleled flexibility in deployment locations and the potential to make substantial contributions to lowing atmospheric CO2 levels. The success of DAC technologies significantly depends on the development of an efficient, economical sorbent capable of selective and durable CO2 capture from ambient air. Recent advancements in material science have led to the exploration of amine-functionalized sorbents, hollow fiber sorbents and membranes, and other novel materials designed to meet these criteria. This study explores a novel Fibrous Amine-functionalized Matrix (FAM) sorbent. The FAM sorbent distinguished itself through its mechanical robustness, a streamlined synthesis process, and the capability for low-temperature regeneration (is 90 oC really low temperature?). FAM’s exceptional adsorption-desorption kinetics enable swift CO2 capture and release, crucial for the viability of DAC on a commercial scale. The synthesis process involves a simple dip-coating technique, allowing crosslinked amines to coat glass substrates.

Wang, Qiuming↗

DOE OSTI2024

Advancements in Direct Air Capture: Unveiling a Simple and Robust Synthesized Fibrous Amine-functionalized Matrix (FAM) Sorbent for Commercial Scale-up

The escalating challenge of climate change necessitates innovative solutions in the realm of carbon management, particularly in mitigating the impact of fossil fuel emissions. Direct Air Capture (DAC) technology emerges as a critical component within the spectrum of Carbon Capture and Sequestration (CCS) solutions, offering the distinct advantage of directly removing CO2 from the atmosphere irrespective of the source. This attribute grants DAC systems unparalleled flexibility in deployment location sand the potential to make substantial contributions to lowing atmospheric CO2 levels. The success of DAC technologies significantly depends on the development of efficient, economical sorbent capable of selective and durable CO2 capture from ambient air. Recent advancements in material science have led to the exploration of amine-functionalized sorbents, hollow fiber sorbents and membranes, and other novel materials designed to meet these criteria. This study introduces a significant advancement in DAC technology with the development of a Fibrous Amine-functionalized Matrix (FAM) sorbent. The FAM sorbent distinguished itself through its mechanical robustness, a streamlined synthesis process, and the capability for low-temperature regeneration. Its exceptional adsorption-desorption kinetics enable swift CO2 capture and release, crucial for the viability of DAC on a commercial scale.

Wang, Qiuming↗

DOE OSTI2024

CO2 Capture Using Amines Bound to Silica

One of the main culprits of global warming is the increased amount of carbon dioxide, or CO2, in the atmosphere. NASA's global climate reports a 13% increase in atmospheric CO2 from 2000 to present. Adsorptive CO2 capture by nitrogen groups of amine-containing solvents is one of the most mature technologies deployed in petrochemical and natural gas processing plants to purify industrial gases. However, key challenges in widespread application include solvent induced reactor corrosion, amine degradation, and high regeneration energy for repeated cycling. An alternative approach is to immobilize amines on solid supports. Key performance metrics of solid amine-based CO2 adsorbents include the CO2 adsorption capacity and stability to degradation over hundreds of thousands of regeneration cycles. Our research aims to develop descriptors for CO2 capture capacity and stability against oxygen-induced degradation for amines bound to porous silica supports using experimental and computational techniques. We experimentally measure the change in CO2-uptake using solid amine adsorbents with varying chemical compositions and exposure to varying gas streams and use high-performance computers to simulate the nature and strength of CO2-adsorption and oxidative degradation reaction mechanisms. Insights from our work can facilitate the development of stable solid amine adsorbents for large-scale CO2 capture processes.

amines↗