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The effects of target characteristics on fresh crater morphology - Preliminary results for the moon and Mercury

The results are reported of an analysis of the characteristics of fresh crater samples occurring on the two major geologic units on the moon (maria and highlands) and on Mercury (smooth plains and cratered terrain). In particular, the onset diameters and abundances of central peaks and terraces are examined and compared for both geologic units on each planet in order to detect any variations that might be due to geologic unit characteristics. The analysis of lunar crater characteristics is based on information provided in the LPL Catalog of Lunar Craters of Wood and Andersson (1977). The Mercurian data set utilized is related to a program involving the cataloguing of Mercurian craters visible in Mariner 10 photography. It is concluded that the characteristics of the substrate have exerted a measurable influence on the occurrence of central peaks, terraces, and scallops in flash crater samples. Therefore, in order to compare the morphologic characteristics of fresh crater populations between planets, an analysis of possible substrate-related differences must first be undertaken for each planet under consideration. It is suggested that large variations in gravity do not produce major variations in crater wall failure.

Cintala, M. J.↗

Lunar and Planetary Science XXXV: Venus

The session "Venus" included the following reports:Is It Possible to Detect Magnetic Materials on Venus with Bistatic Radar Probing?; Airfall Crater Deposits on the Surface of Venus: Do We See Them in the Venera Panoramas?; Rift System Architecture on Venus; Constraints on Deformation Belt Evolution on Venus; An Admittance Survey of Large Volcanoes on Venus: Implications for Volcano Growth; Crustal Thickening Above a Convecting Mantle with Application to Venus and Mars; Geological Mapping of Venus: Interpretation of Geologic History and Assessment of; Directional and Non-Directional Models; Ages of Venusian Ridge Belts Relative to Regional Plains; and Plumes as a Mechanism for Equilibrium Resurfacing of Venus.

Source record↗

Initial Observations by the Mars Exploration Rover Opportunity at Cape York, Meridiani Planum

Since the beginning of its mission, the MER rover Opportunity has visited a sequence of progressively larger impact craters in order to characterize rocks that represent an ever broader stratigraphic range. Endeavour Crater is by far the largest crater that this rover has visited, therefore the crater rim provides materials from strata that are much deeper and older than any materials yet sampled. Indeed, the Mars Reconnaissance Orbiter CRISM instrument detected spectral signatures of hydrated phyllosilicates in several rim segments, consistent with a Noachian provenance. In addition, the crater rim might have recorded the effects of the original impact as well as the thermal processes that occurred in its aftermath. This report summarizes initial observations of geologic structures and the fabrics, chemistry and mineralogy of rocks. Cape York is an N/NE - S/SW-trending segment of crater rim that is bounded by rim segments that are more deeply eroded, forming embayments. Opportunity drove onto the southwest margin of Cape York and has traversed across the Cape to a ridge near its northern end. The rim of Endeavour Crater was severely degraded and then on lapped by Meridiani sulfate-rich deposits, indicating that Cape York deposits experienced extensive erosion prior to the deposition of Meridiani Planum sulfate-rich sediments. Cape York consists of impact-uplifted rocks that are surrounded by a younger bedrock bench that might represent sediments shed from Cape York. The uplifted rock "Tisdale-2," located near the southern end of Cape York, is a polymict lithic breccia. Its elemental composition resembles a mixture of basalt plus bedrock encountered previously at Meridiani Planum, and it is relatively enriched in Ni, Zn, P, characteristic of hydrothermal fluids. "Chester Lake" and "Greeley Haven" are bedrock surfaces located near the southern and northern ends of Cape York, respectively, and they exhibit fabrics reminiscent of suevites. The rocks that were analyzed so far are quite different from any rocks previously encountered by Opportunity and Spirit. Several light-toned vein deposits (approx 1 cm) were discovered in the bench that borders the western flanks of Cape York. The vein "Homestake" is rich in Ca and S, and it exhibits a spectral feature near 1000 run caused by hydration, indicating that "Homestake" consists substantially of gypsum. The relationship(s) between these veins and the sulfate-rich layered deposits at Meridiani Planum remains uncertain. The veins might have been deposited by sulfate-rich fluids perhaps either in the immediate aftermath of the impact that formed Endeavour Crater or at some later time. Current uncertainties notwithstanding, the novel lithologies at Cape York are significantly older than the sulfate-rich sedimentary rocks at Meridiani Planum, and these lithologies have recorded episodes of aqueous activity from earlier epochs, perhaps during the Noachian. The author acknowledges the contributions of the Athena Science Team, the MER engineering team, JPL and NASA.

Marais, David J.↗

Radar Probing of Planetary Regoliths: An Example from the Northern Rim of Imbrium Basin

Imaging radar measurements at long wavelengths (e.g., >30 cm) allow deep (up to tens of meters) probing of the physical structure and dielectric properties of planetary regoliths. We illustrate a potential application for a Mars orbital synthetic aperture radar (SAR) using new Earth-based 70-cm wavelength radar data for the Moon. The terrae on the northern margin of Mare Imbrium, the Montes Jura region, have diffuse radar backscatter echoes that are 2-4 times weaker at 3.8-cm, 70-cm, and 7.5-m wavelengths than most other lunar nearside terrae. Possible geologic explanations are (1) a pyroclastic deposit associated with sinuous rilles in this region, (2) buried mare basalt or a zone of mixed highland/basaltic debris (cryptomaria), or (3) layers of ejecta associated with the Iridum and Plato impacts that have fewer meter-sized rocks than typical highlands regolith. While radar data at 3.8-cm to 7.5-m wavelengths suggest significant differences between the Montes Jura region and typical highlands, the surface geochemistry and rock abundance inferred from Clementine UV-VIS data and eclipse thermal images are consistent with other lunar terrae. There is no evidence for enhanced iron abundance, expected for basaltic pyroclastic deposits, near the source vents of the sinuous rilles radial to Plato. The regions of low 70-cm radar return are consistent with overlapping concentric ''haloes'' about Iridum and Plato and do not occur referentially in topographically low areas, as is observed for radar-mapped cryptomaria. Thus we suggest that the extensive radar-dark area associated with the Montes Jura region is due to overlapping, rock-poor ejecta deposits from Iridum and Plato craters. Comparison of the radial extent of low-radar-return crater haloes with a model for ejecta thickness shows that these rock-poor layers are detected by 70-cm radar where they are on the order of 10 m and thicker. A SAR in orbit about Mars could use similar deep probing to reveal the nature of crater - and basin-related deposits.

Iridum crater↗

The Seismic Signatures of Recently Formed Impact Craters on Mars

We investigated the seismic signatures of recent impact crater clusters on Mars that would be recorded by the Interior Exploration using Seismic Investigations, Geodesy and Heat Transport (InSight)seismometers. We used a database of 77 measured and dated impact sites, with craters with diameters between 2.1 and 33.8 m, along with inferred impact angle, bolide trajectory, and varying target material properties to empirically scale for the momentum, expected seismic source function, and radiation pattern of impacts. The impact source is simulated in a local 3‐Dfinite difference wave propagation code and coupled to teleseismic distances by scaling the spectra of 1‐D global synthetic seismograms. We use the InSight seismometer noise floors to estimate detectability of impact(s) across azimuth and distance. Our experiments reveal that impact clusters have a higher peak corner frequency resulting from energy contributed by smaller craters to the power spectrum. We also find that the time separation between individual impacts in a cluster is small (<10–15 ms) and requires a seismometer closely situated to the source (<10 km) and a high sampling rate (>100 Hz) to resolve individual impacts within the cluster. Two of the clusters in our database(>20‐m effective diameter) would have been detectable by InSight, with the assumptions that the Martian background noise and seismic attenuation are both low. Joint detection of surface changes from newly formed crater(s) in images and by InSight will provide precise source locations that are crucial for constraining the internal structure of Mars

N. C. Schmerra↗

VIPER’s Mass Spectrometer observing lunar operations (MSolo)

The Volatiles Investigating Polar Exploration Rover (VIPER) is a lunar volatiles detection and measurement mission that will land on Mons Mouton near Nobile crater, close to the Moon’s south pole. One of the analytical instruments embedded within the rover is the Mass Spectrometer observing lunar operations (MSolo) instrument. VIPER’s data will ultimately be used to create lunar water resource maps that may enable a sustained presence on the lunar surface. As VIPER navigates several kilometers of terrain, its onboard analytical instrumentation will characterize the presence of volatiles along the traverse path and identify candidate locations for drilling. Upon selection of a drilling site, the rover will position itself and deploy an auguring, percussive drill down to a meter depth. Upon extraction, regolith cuttings captured by the auger are deposited on the surface; an activity that will initiate the release of any volatile gases that are subsequently detected and quantified by MSolo. MSolo is designed to identify low-molecular-weight volatiles (between m/z 1-100) with unit mass resolution. Volatiles of interest include D/H and O18/O16 bearing species, including possible water contained within the lunar regolith. MSolo is a modified, commercial off-the-shelf (COTS) system, meaning the instrument is based on a commercially available unit that has been ruggedized for space applications.

MSolo↗

Plasma produced by impacts of fast dust particles on a thin film

The thin-film impact plasma detector was pioneered by Berg for detecting small cosmic dust particles and measuring their approximate velocities in a time-of-flight configuration. While Berg's device was highly successful in establishing the flux of interplanetary dust, the accuracy of measuring the velocities of individual particles was a moderate 18 percent in magnitude and 27 degrees in angle. A much greater accuracy of less than or equal to 1 percent in determining the velocity components appears desirable in order to associate a particle with its parent body. In order to meet that need, research was initiated to determine if a thin-film detector can be designed to provide such accurate velocity measurements. Previous laboratory investigations of the impact plasma uncovered two difficulties: (1) solid or liquid spray is ejected from a primary impact crater and strikes neighboring walls where it produces secondary impact craters and plasma clouds; as a result, both quantity and time of detection of the plasma can vary significantly with the experiment configuration. Particles from an accelerator rarely have speeds v greater than or equal to 10-15 km/s, while cosmic dust particles typically impact at v = 10-72 km/s. The purpose of the tests discussed in this paper was to resolve the two difficulties mentioned. That is, the experiment configuration was designed to reduce the contribution of plasma from secondary impacts. In addition, most particles with v less than or equal to 25 km/s and all particles with v less than or equal to 10 km/s were eliminated from the beam.

Auer, Siegfried↗

Sources of lunar magnetic anomalies and their bulk directions of magnetization - Additional evidence from Apollo orbital data

A relatively high-amplitude magnetic anomaly directly detected with the Apollo 15 subsatellite magnetometer and centered near the crater Gerasimovich on the southeastern lunar far side is found to correlate with the location of a conspicuous Reiner Gamma-type swirl marking visible on a Zond 8 photograph. Examinations of available direct and indirect orbital magnetics measurements demonstrate that most strong anomalies occur in areas where morphologically similar markings are concentrated. Even though photogeologic studies indicate an impact-related origin for the swirls, both the swirls and their associated strong anomalies tend to exist preferentially in or near areas that have been seismically modified. Modeling of improved vector magnetic anomaly maps is used to infer 28 independent bulk directions of magnetization for relatively strong and isolated lunar magnetic anomaly sources.

Hood, L. L.↗

Comet 81p/Wild 2: The Updated Stardust Coma Dust Fluence Measurement for Smaller (Sub 10-Micrometre) Particles

Micrometre and smaller scale dust within cometary comae can be observed by telescopic remote sensing spectroscopy [1] and the particle size and abundance can be measured by in situ spacecraft impact detectors [2]. Initial interpretation of the samples returned from comet 81P/Wild 2 by the Stardust spacecraft [3] appears to show that very fine dust contributes not only a small fraction of the solid mass, but is also relatively sparse [4], with a low negative power function describing grain size distribution, contrasting with an apparent abundance indicated by the on-board Dust Flux Monitor Instrument (DFMI) [5] operational during the encounter. For particles above 10 m diameter there is good correspondence between results from the DFMI and the particle size inferred from experimental calibration [6] of measured aerogel track and aluminium foil crater dimensions (as seen in Figure 4 of [4]). However, divergence between data-sets becomes apparent at smaller sizes, especially submicrometre, where the returned sample data are based upon location and measurement of tiny craters found by electron microscopy of Al foils. Here effects of detection efficiency tail-off at each search magnification can be seen in the down-scale flattening of each scale component, but are reliably compensated by sensible extrapolation between segments. There is also no evidence of malfunction in the operation of DFMI during passage through the coma (S. Green, personal comm.), so can the two data sets be reconciled?

Price, M. C.↗

Lunar Flashlight: Mapping Lunar Surface Volatiles Using a Cubesat

Lunar Flashlight is an exciting new mission concept in preformulation studies for NASA's Advanced Exploration Systems (AES) by a team from the Jet Propulsion Laboratory, UCLA, and Marshall Space Flight Center. This innovative, low-cost concept will map the lunar south pole for volatiles and demonstrate several technological firsts, including being the first CubeSat to reach the Moon, the first mission to use an 80 m2 solar sail, and the first mission to use a solar sail as a reflector for science observations. The Lunar Flashlight mission spacecraft maneuvers to its lunar polar orbit and uses its solar sail as a mirror to reflect 50 kW of sunlight down into shaded polar regions, while the on-board spectrometer measures surface reflection and composition. The Lunar Flashlight 6U spacecraft has heritage elements from multiple cubesat systems. The deployable solar sail/reflector is based on previous solar sail experiments, scaled up for this mission. The mission will demonstrate a path where 6U CubeSats could, at dramatically lower cost than previously thought possible, explore, locate and estimate size and composition of ice deposits on the Moon. Locating ice deposits in the Moon's permanently shadowed craters addresses one of NASA's Strategic Knowledge Gaps (SKGs) to detect composition, quantity, distribution, form of water/H species and other volatiles associated with lunar cold traps. Polar volatile data collected by Lunar Flashlight could then ensure that targets for more expensive lander- and rover-borne measurements would include volatiles in sufficient quantity and near enough to the surface to be operationally useful.

Cohen, Barbara A.↗

Elemental Analyses of Hypervelocity Microparticle Impact Sites on Interplanetary Dust Experiment Sensor Surfaces

The Interplanetary Dust Experiment (IDE) had over 450 electrically active ultra-high purity metal-oxide-silicon impact detectors located on the six primary sides of the Long Duration Exposure Facility (LDEF). Hypervelocity microparticles (approximately 0.2 to approximately 100 micron diameter) that struck the active sensors with enough energy to breakdown the 0.4 or 1.0 micron thick SiO2 insulator layer separating the silicon base (the negative electrode), and the 1000 A thick surface layer of aluminum (the positive electrode) caused electrical discharges that were recorded for the first year of orbit. The high purity Al-SiO2-Si substrates allowed detection of trace (ppm) amounts of hypervelocity impactor residues. After sputtering through a layer of surface contamination, secondary ion mass spectrometry (SIMS) was used to create two-dimensional elemental ion intensity maps of microparticle sites on the IDE sensors. The element intensities in the central craters of the impacts were corrected for relative ion yields and instrumental conditions and then normalized to silicon. The results classification resulted from the particles' origins as 'manmade', 'natural', or 'indeterminate'. The last classification resulted from the presence of too little impactor residue, analytical interference from high background contamination, the lack of information on silicon and aluminum residues, or a combination of these circumstances. Several analytical 'blank' discharges were induced on flight sensors by pressing down on the sensor surface with a pure silicon shard. Analyses of these blank discharges showed that the discharge energy blasts away the layer of surface contamination. Only Si and Al were detected inside the discharge zones, including the central craters, of these features. Thus far, a total of 79 randomly selected microparticle impact sites from the six primary sides of the LDEF were analyzed: 36 from tray C-9 (Leading (ram), or east, side), 18 from tray C-3 (Trailing (wake), or west, side), 12 from tray B-12 (north side), 4 from tray D-6 (south side), 3 from tray H-11 (space end), and 6 from tray G-10 (earth end). Residue from manmade debris was identified in craters on all trays (aluminum oxide particle residues were not detectable on the Al/Si substrates). These results were consistent with the IDE impact record which showed highly variable long term microparticle impact flux rates on the west, space, and Earth sides of the LDEF which could not be ascribed to astronomical variability of micrometeorite density. The IDE record also showed episodic bursts of microparticle impacts on the east, north, and south sides of the satellite, denoting passage through orbital debris clouds or rings.

Simon, C. G.↗

Organic Matter Preserved in 3-Billion-Year-Old Mudstones at Gale Crater, Mars

Establishing the presence and state of organic matter, including its possible biosignatures, in martian materials has been an elusive quest, despite limited reports of the existence of organic matter on Mars. We report the in situ detection of organic matter preserved in lacustrine mudstones at the base of the ~3.5-billion-year-old Murray formation at Pahrump Hills, Gale crater, by the Sample Analysis at Mars instrument suite onboard the Curiosity rover. Diverse pyrolysis products, including thiophenic, aromatic, and aliphatic compounds released at high temperatures (500° to 820°C), were directly detected by evolved gas analysis. Thiophenes were also observed by gas chromatography–mass spectrometry. Their presence suggests that sulfurization aided organic matter preservation. At least 50 nanomoles of organic carbon persists, probably as macromolecules containing 5% carbon as organic sulfur molecules.

Eigenbrode, Jennifer L.↗

Elemental analyses of hypervelocity microparticle impact sites on Interplanetary Dust Experiment sensor surfaces

The Interplanetary Dust Experiment (IDE) had over 450 electrically active ultra-high purity metal-oxide-silicon impact detectors located on the six primary sides of the Long Duration Exposure Facility (LDEF). Hypervelocity microparticles (approximately 0.2 to approximately 100 micron diameter) that struck the active sensors with enough energy to break down the 0.4 or 1.0 micron thick SIO2 insulator layer separating the silicon base (the negative electrode), and the 1000 A thick surface layer of aluminum (the positive electrode) caused electrical discharges that were recorded for the first year of orbit. The high purity Al-SiO2-Si substrates allowed detection of trace (ppm) amounts of hypervelocity impactor residues. After sputtering through a layer of surface contamination, secondary ion mass spectrometry (SIMS) was used to create two-dimensional elemental ion intensity maps of microparticle impact sites on the IDE sensors. The element intensities in the central craters of the impacts were corrected for relative ion yields and instrumental conditions and then normalized to silicon. The results were used to classify the particles' origins as 'manmade,' 'natural,' or 'indeterminate.' The last classification resulted from the presence of too little impactor residue, analytical interference from high background contamination, the lack of information on silicon and aluminum residues, or a combination of these circumstances. Several analytical 'blank' discharges were induced on flight sensors by pressing down on the sensor surface with a pure silicon shard. Analyses of these blank discharges showed that the discharge energy blasts away the layer of surface contamination. Only Si and Al were detected inside the discharge zones, including the central craters of these features. Thus far a total of 79 randomly selected microparticle impact sites from the six primary sides of the LDEF have been analyzed: 36 from tray C-9 (Leading (ram), or East, side), 18 from tray C-3 (Trailing (wake), or West, side), 12 from tray B-12 (North side), 4 from tray D-6 (South side), 3 from tray H-11 (Space end), and 6 from tray G-10 (Earth end). Residue from manmade debris was identified in craters on all trays. (Aluminum oxide particle residues were not detectable on the Al/Si substrates.) These results were consistent with the IDE impact record which showed highly variable long term microparticle impact flux rates on the West, Space and Earth sides of the LDEF which could not be ascribed to astronomical variability of micrometeorite density. The IDE record also showed episodic bursts of microparticle impacts on the East, North, and South sides of the satellite, denoting passage through orbital debris clouds or rings.

Simon, Charles G.↗

Nanophase Carbonates on Mars: Implications for Carbonate Formation and Habitability

Despite having an atmosphere composed primarily of CO2 and evidence for abundant water in the past, carbonate minerals have only been discovered in small amounts in martian dust [1], in outcrops of very limited extent [2, 3], in soils in the Northern Plains (the landing site of the 2007 Phoenix Mars Scout Mission) [4] and may have recently been detected in aeolian material and drilled and powdered sedimentary rock in Gale Crater (the Mars Science Laboratory [MSL] landing site) [5]. Thermal analysis of martian soils by instruments on Phoenix and MSL has demonstrated a release of CO2 at temperatures as low as 250-300 degC, much lower than the traditional decomposition temperatures of calcium or magnesium carbonates. Thermal decomposition temperature can depend on a number of factors such as instrument pressure and ramp rate, and sample particle size [6]. However, if the CO2 released at low temperatures is from carbonates, small particle size is the only effect that could have such a large impact on decomposition temperature, implying the presence of extremely fine-grained (i.e., "nanophase" or clay-sized) carbonates. We hypothesize that this lower temperature release is the signature of small particle-sized (clay-sized) carbonates formed by the weathering of primary minerals in dust or soils through interactions with atmospheric water and carbon dioxide and that this process may persist under current martian conditions. Preliminary work has shown that clay-sized carbonate grains can decompose at much lower temperatures than previously thought. The first work took carbonate, decomposed it to CaO, then flowed CO2 over these samples held at temperatures >100 degC to reform carbonates. Thermal analysis confirmed that carbonates were indeed formed and transmission electron microsopy was used to determine crystal sized were on the order of 10 nm. The next step used minerals such as diopside and wollastonite that were sealed in a glass tube with a CO2 and H2O source. After reacting these materials for a number of hours, thermal analysis demonstrated the formations of carbonates that decomposed at temperatures as low as 500 degC [7]. Further work is underway to carry out the weathering process under more Mars-like conditions (low pressure and low temperature) to determine if the carbonate decomposition temperature can be shifted to even lower temperatures, consistent with what has been detected by thermal analysis instruments on Mars.

Archer, P. Douglas, Jr.↗

Oxychlorine Species on Mars: The Gale Crater Story

Comparing data from the Alpha- Particle X-Ray Spectrometer (APXS) and the Sample Analysis at Mars (SAM) instruments on MSL reveals a strong linear correlation between chlorine and oxygen, further demonstrating the presence of oxychlorine species in Gale Crater and, very likely, globally on Mars. Perchlorate was first discovered on Mars by the Microscopy, Electrochemistry, and Conductivity Analyzer (MECA) instrument on the Phoenix lander in 2008. Current hypotheses suggest that the formation of oxychlorine species such as perchlorate or chlorate is a global process and that these species should be globally distributed on Mars [e.g. 2-4]. To date, the SAM and Chemistry and Mineralogy (CheMin) instruments on MSL have analyzed one scooped sample of aeolian material (Rocknest [RN]), and four drilled samples (John Klein [JK], Cumberland [CB], Windjana [WJ], and Confidence Hills [CH]). The APXS instrument has also investigated the same or very similar samples. Although not definitively identified, oxychlorine species have been proposed to explain releases of O2, HCl, and chlorinated hydrocarbon species detected by evolved gas analysis (EGA) with the SAM instrument. We report a strong linear correlation between wt. % Cl detected by APXS and moles O2 detected by SAM during pyrolysis, indicating the presence of oxychlorine species in Gale Crater.

Archer, P. D., Jr.↗

Abundances of Volatile - Bearing Species from Evolved Gas Analysis of Samples from the Rocknest Aeolian Bedform in Gale Crater

The Sample Analysis at Mars (SAM) instrument suite on board the Mars Science Laboratory (MSL) recently ran four samples from an aeolian bedform named Rocknest. SAM detected the evolution of H2O, CO2, O2, and SO2, indicative of the presence of multiple volatile bearing species (Fig 1). The Rocknest bedform is a windblown deposit selected as representative of both the windblown material in Gale crater as well as the globally-distributed martian dust. Four samples of Rocknest material were analyzed by SAM, all from the fifth scoop taken at this location. The material delivered to SAM passed through a 150 m sieve and is assumed to have been well mixed during the sample acquisition/preparation/handoff process. SAM heated the Rocknest samples to approx.835 C at a ramp rate of 35 C/min with a He carrier gas flow rate of apprx.1.5 standard cubic centimeters per minute and at an oven pressure of ~30 mbar [1]. Evolved gases were detected by a quadrupole mass spectrometer (QMS). This abstract presents the molar abundances of H2O, CO2, O2, and SO2 as well as their concentration in rocknest samples using an estimated sample mass.

Archer, P. D., Jr.↗

Metallic Fe phases in Apollo 16 fines - Their origin and characteristics as revealed by electron spin resonance studies

The intense electron spin resonance (ESR) signals detected in the Apollo 16 fines from three sites (61141,4, Station 1; 64501,22, South Ray Crater; 67601,20, North Ray Crater) are found to be essentially similar in g-value, in lineshape asymmetry and in temperature dependence to those previously observed for the Apollo 11-15 fines. On the basis of these similarities, it is concluded that these ESR signals like those detected in the Apollo 11-15 fines are principally ferromagnetic in nature arising from metallic Fe phases having the body-centered cubic structure, and not from hematite, magnetite, or any other ferric oxides. It is shown that a quantitative correlation exists between the ESR linewidth observed for the Apollo 11-16 fines and their average Ni contents in the metallic Fe phases as determined by other means. A common source of meteoritic origin is indicated for the metallic Fe phases of these samples.

Tsay, F.-D.↗

Mapping Organic-Mineral Associations in Jezero crater

The search for potential signs of life on Mars, a primary aim of the Mars 2020 mission, is greatly informed by the detection of organic matter1. The presence of organic matter also provides key information about the habitability and biological potential of the planet throughout its history. The Perseverance rover was designed for in situ science with the ability to collect a suite of promising samples for eventual return to Earth. One of its instruments, Scanning Habitable Environments with Raman and Luminescence for Organics and Chemicals (SHERLOC), is a deep ultraviolet (DUV) Raman and fluorescence spectrometer designed to map the distribution of organic molecules and minerals on rock surfaces at a resolution of 100 μm2. With its unique spectral mapping capabilities, SHERLOC enables a novel understanding of organic-mineral relationships on Mars to better determine their formation, deposition, and preservation mechanisms. The rover’s landing site within Jezero crater combines a high potential for past habitability as the site of an ancient lake basin with a diverse set of minerals, including carbonates and clays, that may preserve organic materials and potential biosignatures. The Jezero crater floor includes three formations (fm); two of these, Máaz and Séítah, were explored as part of the mission’s first campaign. Here, we report the detection of multiple species of aromatic organic molecules using Raman and fluorescence spectroscopy across ten targets in the two formations. This is the first evidence of organic molecules in Martian materials obtained using Raman spectroscopy, and among the first using fluorescence spectroscopy, beyond Earth3. We report specific spatial patterns and classes of organic molecules in these compositionally distinct formations, potentially indicating different fates of carbon in these environments. Our findings indicate that there is a diversity of aromatic molecules prevalent on the Martian surface and these materials persist despite exposure to surface conditions. These organic molecules are largely found within minerals linked to aqueous processes, suggesting that these processes may have had a key role in organic synthesis, transport from their point of origin, or preservation.

Sunanda Sharma↗