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At least 181 records · Page 10

Atomic Oxygen Removes Varnish And Lacquer From Old Paintings

Dry and relatively nondestructive plasma process found effective in removing protective coats from old paintings. Process generates monatomic oxygen, which reacts with varnish, lacquer, polyurethane, acrylic, and other organic coating materials; reactions produce mostly carbon monoxide and water vapor, then simply pumped away by vacuum system in which plasma generated. Does not attack oxide-based pigments in underlying paint layers, and brush-stroke marks remain undisturbed.

Rutledge, Sharon K.↗

Assessment of Localized Deformations in Sand Using X-Ray Computed Tomography

The internal fabric and localized deformation patterns of triaxial sand specimens were investigated using Computed Tomography (CT). Three displacement-controlled, conventional, drained axisymmetric (triaxial) experiments were conducted on dry Ottawa sand specimens at very low effective confining stresses (0.05, 0.52, and 1.30 kPa) in a microgravity environment aboard the Space Shuttle during the NASA STS-79 mission. CT scanning was p'erformed on these flight specimens, as well as on an uncompressed specimen and a specimen tested in a terrestrial laboratory at 1.30 kPa effective confining stress. CT demonstrated high accuracy in detecting specimen inhomogeneity and localization patterns. Formation of deformation patterns is dependent on the effective confining stress and gravity. Multiple symmetrical radial shear bands were observed in the specimens tested in a microgravity environment. In the axial direction, two major conical surfaces were developed. Nonsymmetrical spatial deformation was observed in the 1-G specimen. Analysis tools were developed to quantify the spatial density change. Void ratio variation within and outside the shear bands was calculated and discussed.

Alshibli, Khalid A↗

Quantifying Void Ratio Variation in Sand using Computed Tomography

A series of displacement-controlled, conventional, drained axisymmetric (triaxial) experiments were conducted on dry Ottawa sand specimens at very low effective confining stresses in a microgravity environment aboard the Space Shuttle during the NASA STS-89 mission. Post-flight analysis included studying the internal fabric and failure patterns of these specimens using Computed Tomography (CT). The CT scans of three specimens subjected to different compression levels (uncompressed specimen, a specimen compressed to 3.3% nominal axial strain (epsilon(sub a)), and a specimen compressed to 25% epsilon(sub a)) are presented to investigate the evolution of instability patterns and to quantify void ratio variation. The progress of failure is described and discussed. Also, specimens' densities were calibrated using standard ASTM procedures and void ratio spatial variation was calculated and represented by contour maps and histograms. The CT technique demonstrated good ability to detect specimen inhomogeneities, localization patterns, and quantifying void ratio variation within sand specimens.

Alshibli, Khalid A.↗

Fabrication and Characterization of High Temperature Resin/Carbon Nanofiber Composites

As part of ongoing efforts to develop multifunctional advanced composites, blends of PETI-330 and carbon nanofibers (CNF) were prepared and characterized. Dry mixing techniques were employed and the effect of CNF loading level on melt viscosity was determined. The resulting powders were characterized for degree of mixing, thermal and rheological properties. Based on the characterization results, samples containing 30 and 40 wt% CNF were scaled up to approx.300 g and used to fabricate moldings 10.2 cm x 15.2 cm x 0.32 cm thick. The moldings were fabricated by injecting the mixtures at 260-280 C into a stainless steel tool followed by curing for 1 h at 371 C. The tool was designed to impart high shear during the injection process in an attempt to achieve some alignment of CNFs in the flow direction. Moldings were obtained that were subsequently characterized for thermal, mechanical and electrical properties. The degree of dispersion and alignment of CNFs were investigated using high-resolution scanning electron microscopy. The preparation and preliminary characterization of PETI-330/CNF composites will be discussed.

Ghose, Sayata↗

Biases in Total Precipitable Water Vapor Climatologies from Atmospheric Infrared Sounder and Advanced Microwave Scanning Radiometer

We examine differences in total precipitable water vapor (PWV) from the Atmospheric Infrared Sounder (AIRS) and the Advanced Microwave Scanning Radiometer (AMSR-E) experiments sharing the Aqua spacecraft platform. Both systems provide estimates of PWV over water surfaces. We compare AIRS and AMSR-E PWV to constrain AIRS retrieval uncertainties as functions of AIRS retrieved infrared cloud fraction. PWV differences between the two instruments vary only weakly with infrared cloud fraction up to about 70%. Maps of AIRS-AMSR-E PWV differences vary with location and season. Observational biases, when both instruments observe identical scenes, are generally less than 5%. Exceptions are in cold air outbreaks where AIRS is biased moist by 10-20% or 10-60% (depending on retrieval processing) and at high latitudes in winter where AIRS is dry by 5-10%. Sampling biases, from different sampling characteristics of AIRS and AMSR-E, vary in sign and magnitude. AIRS sampling is dry by up to 30% in most high-latitude regions but moist by 5-15% in subtropical stratus cloud belts. Over the northwest Pacific, AIRS samples conditions more moist than AMSR-E by a much as 60%. We hypothesize that both wet and dry sampling biases are due to the effects of clouds on the AIRS retrieval methodology. The sign and magnitude of these biases depend upon the types of cloud present and on the relationship between clouds and PWV. These results for PWV imply that climatologies of height-resolved water vapor from AIRS must take into consideration local meteorological processes affecting AIRS sampling.

Atmospheric Infrared Sounder (AIRS)↗

Fabrication and Characterization of High Temperature Resin/Carbon Nanofiber Composites

Multifunctional composites present a route to structural weight reduction. Nanoparticles such as carbon nanofibers (CNF) provide a compromise as a lower cost nanosize reinforcement that yields a desirable combination of properties. Blends of PETI-330 and CNFs were prepared and characterized to investigate the potential of CNF composites as a high performance structural medium. Dry mixing techniques were employed and the effect of CNF loading level on melt viscosity was determined. The resulting powders were characterized for degree of mixing, thermal and rheological properties. Based on the characterization results, samples containing 30 and 40 wt% CNF were scaled up to approx.300 g and used to fabricate moldings 10.2 cm x 15.2 cm x 0.32 cm thick. The moldings were fabricated by injecting the mixtures at 260-280 C into a stainless steel tool followed by curing for 1 h at 371 C. The tool was designed to impart high shear during the process in an attempt to achieve some alignment of CNFs in the flow direction. Moldings were obtained that were subsequently characterized for thermal, mechanical and electrical properties. The degree of dispersion and alignment of CNFs were investigated using high-resolution scanning electron microscopy. The preparation and preliminary characterization of PETI-330/CNF composites are discussed. Keywords: resins, carbon nanofibers, scanning electron microscopy, electrical properties, thermal conductivity,injection

Ghose, Sayata↗

New Padded Harness for Self-Acquisition of Resting 12-Lead ECGs

We have developed a dry-electrode harness that permits easy, rapid, and unsupervised self-acquisition of resting 12-lead ECGs without the use of any disposables. Various other advantageous features of the harness include: 1) padded or inflatable cushions at the lateral sides of the torso that function to press the left arm (LA) and right arm (RA) dry electrodes mounted on cushions against sideward (as shown in the Figure below) or downward-rested arms of the subject; 2) sufficient distal placement of the arm electrodes with good abutment and without the need for adhesives, straps, bands, bracelets, or gloves on the arms; 3) padding over the sternum to avoid "tenting" in the V1 through V3 (and V3R, when present) electrode positions; 4) easy-to-don, one-piece design with an adjustable single point of connection and an adjustable shoulder strap; and 5) Lund or "modified Lund" placement of the dry electrodes, the results of which more effectively reproduce results from "standard" 12-lead ECG placements than do results from Mason-Likar lead placements.

Schlegel, T. T.↗

Wireless Self-Acquistion of 12-Lead ECG via Android Smart Phone

Researchers at NASA s Johnson Space Center and at Orbital Research, Inc. (a NASA SBIR grant recipient) have recently developed a dry-electrode harness that allows for self-acquisition of resting 12-lead ECGs by minimally trained laypersons. When used in conjunction with commercial wireless (e.g., Bluetooth(TM) or 802.11-enabled) 12-lead ECG devices and custom smart phone-based software, the collected 12-lead ECG data can also immediately be forwarded from any geographic location within cellular range to the user s physician(s) of choice. The system can also be used to immediately forward to central receiving stations 12-lead ECG data collected during space flight or during activities in any remote terrestrial location supported by an internet or cellular phone infrastructure. The main novel aspects of the system are first, the dry-electrode 12-lead ECG harness itself, and second, an accompanying Android(TM) smart phone-based wireless 12-lead ECG capability. The ECG harness nominally employs dry electrodes manufactured by Orbital Research, Inc, recently cleared through the Food and Drug Administration (FDA). However, other dry electrodes that are not yet FDA cleared, for example those recently developed by Nanosonic, Inc as part of another NASA SBIR grant, can also be used. The various advantageous features of the harness include: 1) laypersons can be quickly instructed on its correct use, remotely if necessary; 2) all tangled "leadwire spaghetti" is eliminated, as is the common clinical problem of "leadwire reversal"; 3) all adhesives and disposables are also eliminated, the harness being fully reusable; if multiple individuals intend to use use the same harness, then standard antimicrobial wipes can be employed to sterilize the dry electrodes (and harness surface if needed) between users; 5) padded cushions at the lateral sides of the torso function to press the left arm (LA) and right arm (RA) dry electrodes mounted on the cushions against sideward or downward-rested arms of the subject; 6) sufficient distal placement of the arm electrodes achieves good electrode abutment to the arms without the need for adhesives, straps, bands, bracelets, or gloves; 7) padding over the sternum avoids "tenting" in the V1 through V3 (and, when present, the V3R) electrode positions; 8) easy-to-don, one-piece design with an adjustable, front-side single point of connection and an adjustable shoulder strap; and 9) Lund or "modified Lund" placement of the dry electrodes, the results of which more effectively reproduce results from "standard" 12-lead ECG placements than do results from Mason-Likar placements. The main limitation of the harness is that "one size does not fit all", meaning that an appropriately sized harness (small, medium, large, etc) must be chosen on the basis of an individual's size. To facilitate the use of the harness with inexpensive, commodity-grade cell phones and tablet devices, 12-lead ECG software is also being developed to accompany the harness for wireless use with Android. For this part of the project, NASA has teamed with TopCoder, Inc and the Harvard-affiliated NASA Tournament Lab in sponsoring java-based software programming contests through TopCoder. While ECG signals from the harness can already be wirelessly received and thoroughly processed (locally or remotely) by commercial-grade conventional (as well as advanced) 12-lead ECG software running on Microsoft Windows(TM), the Android-based software, once completed, will "cast a wider net" by allowing for a greater percentage of cell phone owners to participate in inexpensive, store-and-forward recordings of 12-lead ECGs worldwide, including for example Android cell phone users in many remote, third-world locations. At the time of writing, the Android 12-lead ECG software platform consists of a basic but expanding graphical user interface and accompanying software that: 1) wirelessly receives the 12-lead ECG data stream from a Bluetooth-based, FDA-cleared 12-leaCG device attached to the harness; 2) locally stores the same data in binary format to the SD card on the Android cell phone; and 3) makes the data stream in available in real time, for now to TopCoder's java programming contestants.

Schlegel, Todd T.↗

Apatite-Melt Partitioning at 1 Bar: An Assessment of Apatite-Melt Exchange Equilibria Resulting from Non-Ideal Mixing of F and Cl in Apatite

The mineral apatite [Ca5(PO4)3(F,Cl,OH)] is present in a wide range of planetary materials. Due to the presence of volatiles within its crystal structure (X-site), many recent studies have attempted to use apatite to constrain the volatile contents of planetary magmas and mantle sources. In order to use the volatile contents of apatite to precisely determine the abundances of volatiles in coexisting silicate melt or fluids, thermodynamic models for the apatite solid solution and for the apatite components in multi-component silicate melts and fluids are required. Although some thermodynamic models for apatite have been developed, they are incomplete. Furthermore, no mixing model is available for all of the apatite components in silicate melts or fluids, especially for F and Cl components. Several experimental studies have investigated the apatite-melt and apatite-fluid partitioning behavior of F, Cl, and OH in terrestrial and planetary systems, which have determined that apatite-melt partitioning of volatiles are best described as exchange equilibria similar to Fe-Mg partitioning between olivine and silicate melt. However, McCubbin et al. recently reported that the exchange coefficients may vary in portions of apatite compositional space where F, Cl, and OH do not mix ideally in apatite. In particular, solution calorimetry data of apatite compositions along the F-Cl join exhibit substantial excess enthalpies of mixing. In the present study, we conducted apatite-melt partitioning experiments in evacuated, sealed silica-glass tubes at approximately 1 bar and 950-1050 degrees Centigrade on a synthetic Martian basalt composition equivalent to the basaltic shergottite Queen Alexandria Range (QUE) 94201. These experiments were conducted dry, at low pressure, to assess the effects of temperature and apatite composition on the partitioning behavior of F and Cl between apatite and basaltic melt along the F-Cl apatite binary join, where there is non-ideal mixing of F and Cl in apatite.

McCubbin, F. M.↗

Studies of warm-rain development

The development of rain in warm (over 0 C) clouds due to the combined effects of condensation and coalescence following collisions is discussed. The detailed shape of the size distribution produced by condensation has a controlling influence on the rate of coalescence, and this shape is affected by entrainment of dry air, mixing of various cloud parcels, and radiative effects. Aspects of these processes in cloud types where rain formed through warm-rain processes are reviewed. Results suggest that diffusional growth may be enhanced in highly mixed regions of maritime cumulus in a manner similar to that in wave clouds, but that this effect is minor in updraft cores or in the stratocumulus layers examined.

Cooper, William A.↗

On the dynamic and thermodynamic structures of marine stratocumulus

Latent heating effects on stratocumulus circulations were studied successfully with a nine-coefficient spectral model of two-dimensional shallow Boussinesq convection (Laufersweiler and Shirer, 1989). Further, more realistic investigations are being performed currently with a larger, 18-coefficient spectral model, in which the effects of cloud top radiational cooling and in-cloud radiational heating are also being represented. Because assuming a rigid lid at the inversion base may have affected previous results significantly, the domain top was raised to include the lower portion of the capping inversion. As in the previous model, a uniform cloud base is assumed and latent heating effects are included implicitly such that the motions in the sub- and above-cloud regions are dry adiabatic and the motions in the cloud region are moist adiabatic. The effects of forcing by radiational heating profiles that are tied to the cloud layer, such as the one used by Nicholls will be investigated, as will profiles measured during the FIRE experiment. One concern of using truncated spectral models is that the phenomena are so poorly represented that they can change dramatically as the number of spectral coefficients is increased. The efficacy of the nine-coefficient model results is checked by examining the steady state solutions of the 18-coefficient model for parameter values used by Laufersweiler and Shirer (1989), which corresponds to the case of a moderately deep cloud and no capping inversion. The horizontally asymmetric circulation patterns that have narrow downdraft areas and broad updraft areas are virtually the same as those found in the smaller spectral model. Also captured in the case of weaker heating is an elevated circulation centered at cloud base. Thus, the results of the smaller model are substantiated. Since one of the goals of studying the new model is to represent a more realistic domain, the second test of the model is to investigate whether the steady solutions are suppressed in the case of an inversion with no cloud.

Laufersweiler, Mark J.↗

Evaluating Rock Pool Hydroperiod Fluctuation using Climate Variables to Inform Habitat Monitoring and Protection in the Western Sonoran Desert

As warming and drying trends continue to impact the greater American Southwest, effective ecosystem management increasingly relies upon understanding the relationships between climate and water resources. Ephemeral freshwater rock pools, known as tinajas, have great ecological and cultural importance as some of the only sources of surface water in the western Sonoran Desert (WSD). Tinaja flooding and drying cycles, known as hydroperiods, vary based on meteorologic and climatologic conditions; however, a lack of extensive research relating climatic impacts to tinajas puts these critical ecosystems further at risk. Tinajas throughout the WSD are monitored by the National Park Service (NPS) using resource intensive strategies including in situ trail camera observation and direct measurement. To aid NPS monitoring efforts, this research used remotely sensed climate data to analyze spatiotemporal climate trends and relationships between climate variables and tinaja hydroperiods in the WSD between 1979–2022. Using Aqua and Terra Moderate Resolution Imaging Spectroradiometers (MODIS), University of Idaho Gridded Surface Meteorological Dataset (gridMET), and OpenET data, the project analyzed land surface temperature, evapotranspiration, precipitation, wind velocity, and solar radiation. The team generated climate anomaly time series and climate normal maps for the WSD, identifying statistically significant spatial and temporal trends. These data were then compared to daily, qualitative in situ hydroperiod observations taken between 2019–2022. This work will be used by the NPS to inform the monitoring and protection of tinajas in the WSD. Findings contribute to a limited body of research concerning climate and tinajas, which are often overlooked despite their disproportionate ecological importance.

Annie Britton↗

Origin of moisture effects on crack propagation in composites

A study has been made of the origin of unexpected moisture effects on crack extension in fiberglass laminates. Water immersion has been found to greatly reduce the rate of crack growth under constant loading, while increasing the rate under cyclic loading, the latter effect being the expected one. Observations were made of the extension of the stable damage zone at the tip of precut notches in wet and dry environments. The damage zone size is postulated as a critical element in the relaxation of high stress concentrations in composites, such as those at notch or crack tips. Under constant load, moisture is shown to greatly expand the interply delamination region in the damage zone, thus reducing the local fiber stresses and increasing crack resistance. Under cyclic loading moisture has little effect on the delamination region, which is large even for dry environments, and the only effect is weakening of the material and acceleration of cracks. Severe hygrothermal conditions can so weaken the material that the crack resistance is reduced under constant loading as well.

Mandell, J. F.↗

Modeling of membrane processes for air revitalization and water recovery

Gas-separation and reverse-osmosis membrane models are being developed in conjunction with membrane testing at NASA JSC. The completed gas-separation membrane model extracts effective component permeabilities from multicomponent test data, and predicts the effects of flow configuration, operating conditions, and membrane dimensions on module performance. Variable feed- and permeate-side pressures are considered. The model has been applied to test data for hollow-fiber membrane modules with simulated cabin-air feeds. Results are presented for a membrane designed for air drying applications. Extracted permeabilities are used to predict the effect of operating conditions on water enrichment in the permeate. A first-order reverse-osmosis model has been applied to test data for spiral wound membrane modules with a simulated hygiene water feed. The model estimates an effective local component rejection coefficient under pseudosteady-state conditions. Results are used to define requirements for a detailed reverse-osmosis model.

Lange, Kevin E.↗

Ozone budget over the Amazon - Regional effects from biomass-burning emissions

Data from the NASA dry-season Amazon boundary layer experiment (ABLE2A) is used with a 1D tropospheric photochemical model to analyze the atmospheric chemistry in the region and determine the impact of the long-range transport of biomass-burning emissions. Inputs of surface sources and the deposition of various species measured during ABLE2A are employed to simulate the background atmosphere, and haze characteristics are introduced for a 12-hr simulation. The in situ ozone production rate doubles during the period of haze when hydrocarbons are present. The model predicts that the production of ozone is enhanced during the dry season, and that increased ozone during the southern tropical burning season is related to the regional transport of haze.

Richardson, Jennifer L.↗

Ion-Implanted Diamond Films and Their Tribological Properties

This paper reports the physical characterization and tribological evaluation of ion-implanted diamond films. Diamond films were produced by microwave plasma, chemical vapor deposition technique. Diamond films with various grain sizes (0.3 and 3 microns) and roughness (9.1 and 92.1 nm r.m.s. respectively) were implanted with C(+) (m/e = 12) at an ion energy of 160 eV and a fluence of 6.72 x 10(exp 17) ions/sq cm. Unidirectional sliding friction experiments were conducted in ultrahigh vacuum (6.6 x 10(exp -7)Pa), dry nitrogen and humid air (40% RH) environments. The effects of C(+) ion bombardment on fine and coarse-grained diamond films are as follows: the surface morphology of the diamond films did not change; the surface roughness increased (16.3 and 135.3 nm r.m.s.); the diamond structures were damaged and formed a thin layer of amorphous non-diamond carbon; the friction coefficients dramatically decreased in the ultrahigh vacuum (0.1 and 0.4); the friction coefficients decreased slightly in the dry nitrogen and humid air environments.

Wu, Richard L. C.↗