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At least 181 records · Page 10

Processing technology for high efficiency silicon solar cells

Recent advances in silicon solar cell processing have led to attainment of conversion efficiency approaching 20%. The basic cell design is investigated and features of greatest importance to achievement of 20% efficiency are indicated. Experiments to separately optimize high efficiency design features in test structures are discussed. The integration of these features in a high efficiency cell is examined. Ion implantation has been used to achieve optimal concentrations of emitter dopant and junction depth. The optimization reflects the trade-off between high sheet conductivity, necessary for high fill factor, and heavy doping effects, which must be minimized for high open circuit voltage. A second important aspect of the design experiments is the development of a passivation process to minimize front surface recombination velocity. The manner in which a thin SiO2 layer may be used for this purpose is indicated without increasing reflection losses, if the antireflection coating is properly designed. Details are presented of processing intended to reduce recombination at the contact/Si interface. Data on cell performance (including CZ and ribbon) and analysis of loss mechanisms are also presented.

Spitzer, M. B.↗

High-efficiency module and array research

An outline is presented giving module high efficiency research activities and module technologies contributing to high efficiency. Some factors given on high efficiency are high cell packing factors, low optical losses, low electrical mismatch losses and low operating temperatures. Factors given which are associated with reliability of modules are high efficiency cells, narrow module borders, antisoiling coatings, and antireflection coatings on glass-air interfaces.

Ross, R. G., Jr.↗

Important loss mechanisms in high-efficiency solar cells

A study was conducted to identify loss mechanisms in high efficiency silicon solar cells. The following were considered: (1) recombination loss mechanisms; (2) high efficiency cells; (3) very high efficiency cells; and (4) ultra high efficiency cells.

Sah, C. T.↗

Towards a 20 percent efficient silicon solar cell

A project is underway at the University of New South Wales aimed at producing a 20 percent efficient silicon solar cell. A prerequisite for obtaining such a significant increase in cell efficiency is the improvement of the open circuit voltage of these cells. Two techniques are described which have produced experimental devices with open circuit voltages of 690 mV or higher. These high voltage techniques have been combined with other high efficiency design features to produce silicon cells with independently measured energy conversion efficiencies in excess of 19 percent under standard terrestrial test conditions (direct beam AM1.5 spectrum, 100 mW/sq cm, 28 C).

Green, M. A.↗

The relative fluorescent efficiency of sodium salicylate between 90 and 800 eV

The relative fluorescent quantum efficiency of sodium salicylate was measured between 90 and 800 eV (138 -15 A) by the use of synchrotron radiation. A general increase in efficiency was observed in this spectral range except for abrupt decreases in efficiency at the carbon and oxygen K-edges. Beyond the oxygen K-edge (532 eV) the efficiency increased linearly with the incident photon energy to the limit of the present observations.

Angel, G. C.↗

Overview of processing activities aimed at higher efficiencies and economical production

An overview of processing activities aimed at higher efficiencies and economical production were presented. Present focus is on low-cost process technology for higher-efficiency cells of up to 18% or higher. Process development concerns center on the use of less than optimum silicon sheet, the control of production yields, and making uniformly efficient large-area cells. High-efficiency cell factors that require process development are bulk material perfection, very shallow junction formation, front-surface passivation, and finely detailed metallization. Better bulk properties of the silicon sheet and the keeping of those qualities throughout large areas during cell processing are required so that minority carrier lifetimes are maintained and cell performance is not degraded by high doping levels. When very shallow junctions are formed, the process must be sensitive to metallizatin punch-through, series resisitance in the cell, and control of dopant leaching during surface passivation. There is a need to determine the sensitivity to processing by mathematical modeling and experimental activities.

Bickler, D. B.↗

Development of high-efficiency solar cells on silicon web

High-efficiency dendritic cells were discussed. The influence of twin planes and heat treatment on the location and effect of trace impurities was of particular interest. Proper heat treatment often increases efficiency by causing impurities to pile up at twin planes. Oxide passivation had a beneficial effect on efficiency. A very efficient antireflective (AR) coating of zinc selenide and magnesium fluoride was designed and fabricated. An aluminum back-surface reflector was also effective.

Rohatgi, A.↗

Power conversion efficiency of semiconductor injection lasers and laser arrays in CW operation

The problem of optimizing power conversion efficiency of semiconductor lasers and laser arrays and minimizing efficiency degradation due to temperature effects is treated. A method for calculating this efficiency is described and some calculated results are presented and discussed. Under some conditions, a small increase in the thermal resistance of the device can result in a large reduction of its efficiency. Temperature effects are important in high-power semiconductor laser, and in particular in laser arrays, where low thermal resistance heat sinking may be crucial to the device operation.

Katz, J.↗

Basic concepts for the design of high-efficiency single-junction and multibandgap solar cells

Concepts for obtaining practical solar-cell modules with one-sun efficiencies up to 30 percent at air mass 1 are now well understood. Such high-efficiency modules utilize multibandgap structures. To achieve module efficiencies significantly above 30 percent, it is necessary to employ different concepts such as spectral compression and broad-band detection. A detailed description of concepts for the design of high-efficiency multibandgap solar cells is given.

Fan, J. C. C.↗

Kinetic efficiencies of stellar wind bubbles

The theoretical fraction of a stellar wind's energy converted into the kinetic energy of an expanding swept-up shell is 20 percent in the classical theory of stellar wind bubbles. Observational estimates of this conversion factor based on the amount of ionized material in wind-swept shells about Wolf-Rayet stars generally yield results of 1 percent. If there is a substantial amount of neutral material in the shell, it will not be counted and the kinetic efficiency will be underestimated. Presented here is a dynamical estimate which accounts for this neutral material in deducing the kinetic efficiencies of stellar wind bubbles. Bubbles classified as wind-blown shells have kinetic efficiencies in line with theoretical expectations for energy-conserving evolution in a homogeneous medium. Ringlike nebulae have significantly lower efficiencies, probably because they have been 'poisoned' by the photoevaporation of clouds engulfed during evolution into a cloudy substrate.

Van Buren, D.↗

High efficiency crystalline silicon solar cells

A review of the entire research program since its inception ten years ago is given. The initial effort focused on the effects of impurities on the efficiency of silicon solar cells to provide figures of maximum allowable impurity density for efficiencies up to about 16 to 17%. Highly accurate experimental techniques were extended to characterize the recombination properties of the residual imputities in the silicon solar cell. A numerical simulator of the solar cell was also developed, using the Circuit Technique for Semiconductor Analysis. Recent effort focused on the delineation of the material and device parameters which limited the silicon efficiency to below 20% and on an investigation of cell designs to break the 20% barrier. Designs of the cell device structure and geometry can further reduce recombination losses as well as the sensitivity and criticalness of the fabrication technology required to exceed 20%. Further research is needed on the fundamental characterization of the carrier recombination properties at the chemical impurity and physical defect centers. It is shown that only single crystalline silicon cell technology can be successful in attaining efficiencies greater than 20%.

Sah, C. Tang↗

Development of high-efficiency solar cells on silicon web

Work was performed to improve web base material with a goal of obtaining solar cell efficiencies in excess of 18% (AM1). Efforts in this program are directed toward identifying carrier loss mechanisms in web silicon, eliminating or reducing these mechanisms, designing a high efficiency cell structure with the aid of numerical models, and fabricating high efficiency web solar cells. Fabrication techniques must preserve or enhance carrier lifetime in the bulk of the cell and minimize recombination of carriers at the external surfaces. Three completed cells were viewed by cross-sectional transmission electron microscopy (TEM) in order to investigate further the relation between structural defects and electrical performance of web cells. Consistent with past TEM examinations, the cell with the highest efficiency (15.0%) had no dislocations but did have 11 twin planes.

Meier, D. L.↗

Relative fluorescent efficiency of sodium salicylate between 90 and 800 eV

The relative fluorescent quantum efficiency of sodium salicylate was measured between 90 and 800 eV (138-15 A) by the use of synchrotron radiation. A general increase in efficiency was observed in this spectral range except for abrupt decreases in efficiency at the carbon and oxygen K-edges. Beyond the oxygen K-edge (532 eV) the efficiency increased linearly with the incident photon energy to the limit of the present observations.

Angel, G. C.↗

Simulation analysis of a novel high efficiency silicon solar cell

It is recognized that crystalline silicon photovoltaic module efficiency of 15 percent or more is required for cost-effective photovoltaic energy utilization. This level of module efficiency requires large-area encapsulated production cell efficiencies in the range of 18 to 20 percent. Though the theoretical maximum of silicon solar cell efficiency for an idealized case is estimated to be around 30 percent, practical performance of cells to-date are considerably below this limit. This is understood to be largely a consequence of minority carrier losses in the bulk as well as at all surfaces including those under the metal contacts. In this paper a novel device design with special features to reduce bulk and surface recombination losses is evaluated using numerical analysis technique. Details of the numerical model, cell design, and analysis results are presented.

Mokashi, Anant R.↗

Identification of some key parameters limiting the performance of high-efficiency silicon solar cells

This paper presents, for the first time, a detailed sensitivity analysis of key cell parameters on silicon-cell efficiency by incorporating advanced solar cell physics in a sophisticated numerical simulation program. It delineates the true physical barriers to obtaining a high-efficiency silicon solar cell. Specific parameters presently limiting cell efficiency are identified to be the minority carrier lifetime and the recombination velocities at the front and back surfaces. Practical cell efficiencies in the vicinity of 22 percent are estimated to be attainable by using good quality silicon crystal and substantially reducing surface recombination velocities.

Mokashi, Anant R.↗

An efficient sparse matrix multiplication scheme for the CYBER 205 computer

This paper describes the development of an efficient algorithm for computing the product of a matrix and vector on a CYBER 205 vector computer. The desire to provide software which allows the user to choose between the often conflicting goals of minimizing central processing unit (CPU) time or storage requirements has led to a diagonal-based algorithm in which one of four types of storage is selected for each diagonal. The candidate storage types employed were chosen to be efficient on the CYBER 205 for diagonals which have nonzero structure which is dense, moderately sparse, very sparse and short, or very sparse and long; however, for many densities, no diagonal type is most efficient with respect to both resource requirements, and a trade-off must be made. For each diagonal, an initialization subroutine estimates the CPU time and storage required for each storage type based on results from previously performed numerical experimentation. These requirements are adjusted by weights provided by the user which reflect the relative importance the user places on the two resources. The adjusted resource requirements are then compared to select the most efficient storage and computational scheme.

Lambiotte, Jules J., Jr.↗

DSS 14 64-meter antenna S- and X-band efficiency and system noise temperature calibrations, September 1987

The efficiency and noise temperature characteristics of the DSN 64 m antenna network prior to its upgrading to 70 m configuration are documented. The DSS 14 (Goldstone, California) is the last of the three large antennas to be upgraded, and the test results presented document its performance just prior to its downtime during the end of 1987. Antenna area efficiency was found to be somewhat higher at DSS 14 than at DSS 43 (Australia) and DSS 63 (Spain). The peak X-band efficiency was determined to be 49.8 percent (without atmosphere), compared with 45.4 and 45.1 percent for DSS 43 and DSS 63, respectively. The X-band zenith system noise temperature was found to be 1 to 3 Kelvins higher than at the other two stations, depending on which maser was chosen for the measurements. Ascribing efficiency differences to small-scale antenna surface roughness, DSS 14 may be regarded as having a 1.5 to 1.6 mm rms surface as compared to the other two antennas with 1.7 to 1.8 mm rms surfaces.

Slobin, S. D.↗

Heating efficiencies in the thermosphere of Venus reconsidered

Heating efficiencies less than 10 percent are required by recent models of the low neutral temperatures in the daytime thermosphere of Venus. It is considered here whether such values are justifiable from a molecular point of view. The primary uncertainty in a calculation of the heating efficiency is the fraction of energy, f sub v, that appears as vibrational excitation of product molecules in quenching, photodissociation, and exothermic chemical reactions. The current state of knowledge of energy partitioning in chemical reactions is discussed and a range of likely values for f sub v is deduced. The calculated heating efficiencies fall in the range 16-25 percent over the altitude range from 115 to 200 km. It is suggested that the heating efficiency should not be taken as a free parameter and that the cold Venus thermosphere has not yet been satisfactorily explained.

Fox, J. L.↗