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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 181 records · Page 10

Effect of thermal exposure, forming, and welding on high-temperature, dispersion-strengthened aluminum alloy: Al-8Fe-1V-2Si

The feasibility of applying conventional hot forming and welding methods to high temperature aluminum alloy, Al-8Fe-1V-2Si (FVS812), for structural applications and the effect of thermal exposure on mechanical properties were determined. FVS812 (AA8009) sheet exhibited good hot forming and resistance welding characteristics. It was brake formed to 90 deg bends (0.5T bend radius) at temperatures greater than or equal to 390 C (730 F), indicating the feasibility of fabricating basic shapes, such as angles and zees. Hot forming of simple contoured-flanged parts was demonstrated. Resistance spot welds with good static and fatigue strength at room and elevated temperatures were readily produced. Extended vacuum degassing during billet fabrication reduced porosity in fusion and resistance welds. However, electron beam welding was not possible because of extreme degassing during welding, and gas-tungsten-arc welds were not acceptable because of severely degraded mechanical properties. The FVS812 alloy exhibited excellent high temperature strength stability after thermal exposures up to 315 C (600 F) for 1000 h. Extended billet degassing appeared to generally improve tensile ductility, fatigue strength, and notch toughness. But the effects of billet degassing and thermal exposure on properties need to be further clarified. The manufacture of zee-stiffened, riveted, and resistance-spot-welded compression panels was demonstrated.

Kennedy, J. R.↗

Carbon nanotubes decorated with Pt as a viable electrocatalyst system using electrochemical atomic layer deposition

Surface limited redox replacement (SLRR) is an electrochemical deposition method designed to deposit metal thin films, typically onto other metals, that are mere monolayers in thickness, where such low dimensions allows catalyst-support interactions to affect catalyst efficiency. Here we explore the growth of Pt, using iterative Cu-mediated SLRR cycles, directly onto carbon nanotubes (CNTs) which are potentially good candidates as electrocatalyst supports due to their electrical conductivity and chemical resistance. Here scanning electron microscope images showed that Pt grew as nanoparticles, and hydrogen underpotential deposition from cyclic voltammetry showed that the active surface area approached an asymptotic value around eight iterations. Catalytic activity, measured using the oxygen reduction reaction, reached a maximum at ten iterations. Both are shown to be influenced by the growth mode, but electrochemical modeling indicates that the trend in activity is also due to a change in activation energy, possibly due to changes in Pt electronic structure due to interactions with the CNTs. Durability cycling showed a greater than 85% retention of surface area for the first 10,000 cycles of accelerated stress testing but decayed steadily to about 50% after 30,000 cycles. This performance may be related to the phenomenon that limits surface area growth.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Influence of oxygen on the optical and electrical properties of magnetron-sputtered indium tin oxide thin films at ambient temperature

Indium Tin Oxide (ITO) thin films are commonly used as transparent conductive layers in the production of solar cells. ITO films are typically heat-treated at temperatures exceeding 200 °C after magnetron sputtering to optimize the physical, optical, and electrical characteristics for photovoltaic devices. Here, this high temperature heating procedure greatly limits the use of potential substrates, particularly those comprised of low-temperature-rated polymers. Herein, we examine the physical, optical, and electrical transport effects of oxygen:argon plasmas during radio frequency magnetron sputtering of ITO on glass and flexible polymer surfaces without subsequent heat treatment. ITO thin films were characterized via sheet resistance testing, UV-Vis spectroscopy, X-ray diffraction, and scanning electron microscopy imaging. Sheet resistance measurements revealed an increase in surface resistance with increasing oxygen concentration during sputtering. UV-Vis optical transmittance measurements demonstrated an improvement in optical transmittance with an increase in oxygen concentration reaching a maximum transmittance at an oxygen concentration of 1-2 %. Most importantly, it was discovered that producing bilayers of ITO with pure argon sputtered plasmas followed by oxygen:argon plasmas produced ITO thin films with suitable resistance and transmittance without the need for high temperature post annealing. These results highlight a methodology for the deposition of ITO thin films on temperature sensitive substrates for flexible photovoltaics and low-cost module production.

36 MATERIALS SCIENCE↗

Crystallization of the Transdimensional Electron Liquid

Wigner crystallization of free electrons at room temperature has been explored theoretically for a new class of metallic ultrathin (transdimensional) materials whose properties can be controlled by their thickness. Our calculations of the melting surface, critical electron density and temperature explain consistently the experimental data reported previously. We show that by reducing the material thickness one can Wigner-crystallize free electrons at room temperature to get them pinned onto a two-dimensional triangular lattice of a supersolid inside of the crystalline material. Such a solid melts and freezes reversibly with increase and decrease of electron doping or temperature, whereby its resistivity behaves opposite to the free electron gas model predictions.

Wigner crystal↗

Topological behavior and Zeeman splitting in trigonal PtBi2-x single crystals

Abstract Transition-metal dipnictide PtBi 2 exhibits rich structural and physical properties with topological semimetallic behavior and extremely large magnetoresistance (XMR) at low temperatures. We have investigated the electrical and magnetic properties of trigonal-phase PtBi 2 -x single crystals with x ~ 0.4. Profound de Haas–van Alphen (dHvA) and Shubnikov-de Haas (SdH) oscillations are observed. Through fast Fourier transformation (FFT) analyses, four oscillation frequencies are extracted, which result from α, β, γ, and δ bands. By constructing the Landau fan diagram for each band, the Berry phase is extracted demonstrating the non-trivial nature of the α, β, and δ bands. Despite Bi deficiency, we observe the Zeeman splitting in dHvA and SdH oscillations under moderate magnetic field and the moderate Landé g factor (4.97–6.48) for the α band. Quantitative analysis of the non-monotonic field dependence including the sign change of the Hall resistivity suggests that electrons and holes in our system are not perfectly compensated thus not responsible for the XMR effect.

36 MATERIALS SCIENCE↗

Systematic over-estimation of lattice thermal conductivity in materials with electrically-resistive grain boundaries

Reducing the thermal conductivity κ of a material via nano-structuring to create small grain sizes is one of the most common strategies to improve thermoelectric materials. In such polycrystalline materials heat carrying phonons are scattered at the grain boundaries, which directly improves the thermoelectric quality factor and ultimately the figure-of-merit zT. In some cases, however, such as in Mg 3 Sb 2 , SnSe, and Mg 2 Si an opposite trend is found where higher lattice thermal conductivity reported in small grain polycrystalline material than in large grain or single crystal materials. This unphysical result indicates a problem with the conventional use of the Wiedemann–Franz law. Here, we trace this problematic finding to the electrical resistance at the grain boundaries, which leads to an overestimation of the phonon or lattice contribution of the thermal conductivity κ L . In materials with significant grain boundary electrical resistance, the estimated electronic contribution to the thermal conductivity LσT is low because the measured electrical conductivity σ is low. However within the grain electrons may still be transporting more heat than the total conductivity suggests, leading to an overestimation of κ L if the conventional κ L = κ – LσT is used with the measured values of κ and σ. Here, the overestimation of κL in small-grain samples is shown to be pervasive across a broad range of thermoelectric materials, including Mg 3 Sb 2 , Mg 2 Si, PbTe, PbSe, SnSe, (Hf,Zr)CoSb, CoSb 3 , and Bi 2 Te 3 alloys, and a correction is necessary to properly understand and predict their charge and heat transport.

36 MATERIALS SCIENCE↗

Advances in the Co-Simulation of Detailed Electrical and Whole-Building Energy Performance

This article describes recent co-simulation advances for the simultaneous modeling of detailed building electrical distribution systems and whole-building energy performance. The co-simulation architecture combines the EnergyPlus® engine for whole-building energy modeling with a new Modelica library for building an electrical distribution system model that is based on harmonic power flow. This new library allows for a higher-fidelity modeling of electrical power flows and losses within buildings than is available with current building electrical modeling software. We demonstrate the feasibility of the architecture by modeling a simple, two-zone thermal chamber with internal power electronics converters and resistive loads, and we validate the model using experimental data. The proposed co-simulation capability significantly expands the capabilities of building electrical distribution system models in the context of whole-building energy modeling, thus enabling more complex analyses than would have been possible with individual building performance simulation tools that are used to date.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Superconductivity in sputtered CuMO6S8

Samples were prepared by melting the metals, followed by annealing to various temperatures. The result was a structurally weak material. Sputtered films on sapphire substrates were prepared and studied. The substrates give the films mechanical strength and permit easy attachment of electrical leads. Materials were characterized by X-ray diffraction, electron microscopy, electrical resistance vs. temperature, and critical current measurements. Some of the results on CuMo6S8 are presented.

Alterovitz, S.↗

Surface acoustic wave/silicon monolithic sensor/processor

A new technique for sputter deposition of piezoelectric zinc oxide (ZnO) is described. An argon-ion milling system was converted to sputter zinc oxide films in an oxygen atmosphere using a pure zinc oxide target. Piezoelectric films were grown on silicon dioxide and silicon dioxide overlayed with gold. The sputtered films were evaluated using surface acoustic wave measurements, X-ray diffraction, scanning electron microscopy, Auger electron spectroscopy, and resistivity measurements. The effect of the sputtering conditions on the film quality and the result of post-deposition annealing are discussed. The application of these films to the generation of surface acoustic waves is also discussed.

Kowel, S. T.↗

Attaching an Electrical Ground to an Aluminum Structure

Method for creating low-resistance groundpath from electronic equipment to aluminum supporting structure requires no drilling or other penetration of structure. Method does not require costly silver-filled adhesive used previously. Ground connection is light weight, requires few parts, and not subject to galvanic corrosion. Placed at any convenient location on structure so interference with adjacent parts avoided.

Billington, K. L.↗

Planar techniques for fabricating X-ray diffraction gratings and zone plates

The state of current planar techniques in the fabrication of Fresnel zone plates and diffraction gratings is reviewed. Among the fabrication techniques described are multilayer resist techniques; scanning electron beam lithography; and holographic lithography. Consideration is also given to: X-ray lithography; ion beam lithography; and electroplating. SEM photographs of the undercut profiles obtained in a type AZ 135OB photoresistor by holographic lithography are provided.

Smith, H. I.↗

Microwave emission above steady and moving sunspots

Two-dimensional maps of radio brightness temperature and polarization, computed assuming thermal emission with free-free and gyroresonance absorption, are compared with observations of active region 2502, performed at Westerbork at lambda = 6.16 cm during a period of 3 days in June 1980. The computation is done assuming a homogeneous model in the whole field of view and a force-free extrapolation of the photospheric magnetic field observed at MSFC with a resolution of 2.34 arcsec. The mean results are the following: (1) a very good agreement is found above the large leading sunspot of the group, assuming a potential extrapolation of the magnetic field and a constant conductive flux in the transition region ranging from .2 x 10 to the 6th to 10 to the 7th erg/sq cm 5; (2) a strong radio source, associated with a new-born moving sunspot, cannot be ascribed to thermal emission. It is suggested that this source may be due to synchrotron radiation by mildly relativistic electrons accelerated by resistive instabilities occurring in the evolving magnetic configuration. An order-of-magnitude computation of the expected number of accelerated particles seems to confirm this hypothesis.

Drago, F. Chiuderi↗

Microwave emission from steady and moving sunspots

Force-free extrapolations of photospheric magnetic field observations from Marshall Space Flight Center have been used to compute the total intensity and circular polarizaton of sunspot associated emission from active region 2502 in the period June 13 to 15, 1980. The computed maps were compared to high resolution observations of the same active region obtained with the Westerbork Synthesis Radio Telescope. The most interesting aspect of the active region was the development of a new spot between the preceding and the following spots on June 14, which subsequently merged with the preceding with the preceding spot. The new spot was associated with enhanced microwave emission with a peak brightness temperature in excess of 4 x 10 to the 6th K. It is shown that unrealistic values of the conductive flux are required for the interpretation of the emission of the new sunspot in terms of thermal processes. It is suggested that this source is due to gyrosynchrotron radiation from mildly relativistic electrons accelerated by resistive instabilities in the evolving magnetic field.

Alissandrakis, C. E.↗

Plasma waves at Venus

Many significant wave phenomena have been discovered at Venus with the plasma wave instrument on the Pioneer Venus Orbiter. It has been shown that whistler-mode waves in the magnetosheath of the planet may be an important source of energy for the topside ionosphere. Plasma waves are also associated with thickening of the ionopause current layer. Current-generated waves in plasma clouds may also provide anomalous resistance resulting in electron acceleration, possibly producing aurora. Ion-acoustic waves are observed in the bow shock, and appear to be a feature of the magnetotail boundary. Lastly, plasma waves have been cited as evidence for lightning on Venus.

Strangeway, R. J.↗