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At least 181 records · Page 10

Room-temperature Broadening and Pressure-shift Coefficients in the nu(exp 2) Band of CH3D-O2: Measurements and Semi-classical Calculations

We report measured Lorentz O2-broadening and O2-induced pressure-shift coefficients of CH3D in the nu(exp 2) fundamental band. Using a multispectrum fitting technique we have analyzed 11 laboratory absorption spectra recorded at 0.011 cm(exp 1) resolution using the McMath-Pierce Fourier transform spectrometer, Kitt Peak, Arizona. Two absorption cells with path lengths of 10.2 and 25 cm were used to record the spectra. The total sample pressures ranged from 0.98 to 339.85 Torr with CH3D volume mixing ratios of 0.012 in oxygen. We report measurements for O2 pressure-broadening coefficients of 320 nu(exp 2) transitions with quantum numbers as high as J0(sup w) = 17 and K = 14, where K(sup w) = K' is equivalent to K (for a parallel band). The measured O2-broadening coefficients range from 0.0153 to 0.0645 cm(exp -1) atm(exp -1) at 296 K. All the measured pressure-shifts are negative. The reported O2-induced pressure-shift coefficients vary from about -0.0017 to -0.0068 cm(exp -1) atm(exp -1). We have examined the dependence of the measured broadening and shift parameters on the J(sup W), and K quantum numbers and also developed empirical expressions to describe the broadening coefficients in terms of m (m = -J(sup W), J(sup W), and J(sup w) + 1 in the QP-, QQ-, and QR-branch, respectively) and K. On average, the empirical expressions reproduce the measured broadening coefficients to within 4.4%. The O2-broadening and pressure shift coefficients were calculated on the basis of a semiclassical model of interacting linear molecules performed by considering in addition to the electrostatic contributions the atom-atom Lennard-Jones potential. The theoretical results of the broadening coefficients are generally larger than the experimental data. Using for the trajectory model an isotropic Lennard-Jones potential derived from molecular parameters instead of the spherical average of the atom-atom model, a better agreement is obtained with these data, especially for |m| <= 12 values (11.3% for the first calculation and 8.1% for the second calculation). The O2-pressure shifts whose vibrational contribution are either derived from parameters fitted in the QQ-branch of selfinduced shifts of CH3D or those obtained from pressure shifts induced by Xe in the nu(sup 3) band of CH3D are in reasonable agreement with the scattered experimental data (17.0% for the first calculation and 18.7% for the second calculation).

Predoi-Cross, Adriana↗

Simulation and non-linear stage of the electrostatic waves observed during the AMPTE lithium release in the solar wind

During the AMPTE lithium releases in the solar wind intense electrostatic waves with frequencies between a few tens of Hz to several kHz were observed outside the diamagnetic cavity. The results of linear Vlasov theory have suggested that these waves may be generated through two types of instabilities. One is the ion-ion instability associated with the relative drift between the lithium ions and the solar wind protons, and the other is the ion-acoustic instability due to the relative drift between the electrons and the ions. In order to look at the non-linear behavior of the wave-particle interactions, and discern the effect of waves on the particles, full particle electrostatic simulations have been performed, and the results are presented here. It is shown that the ion-ion instability whose phase velocity is oblique to the solar wind velocity can cause considerable anisotropic 'heating' of both the lithium ions and the solar wind protons.

Omidi, N.↗

Lack of Evidence for Prenucleation Aggregate Formation in Lysozyme Crystal Growth Solutions

There have been numerous claims of large concentrations of prenucleation aggregates in supersaturated as well as undersaturated lysozyme solutions at high salt concentrations. The presence of these aggregates was derived from measurements of the light or neutron scattering intensity, ultracentrifugation and dialysis behavior, as well as over-simplified crystal growth kinetics considerations. In all these interpretations it has been assumed that lysozyme solutions are either ideal or that protein interactions are independent of salt concentration. Contrary to these presumptions, our static and dynamic light scattering experiments provide evidence that lysozyme forms highly non-ideal, strongly interacting solutions. At low salt concentrations, the scattering intensities fall well below the values expected for an ideal, monomeric solution at the same protein concentration, while diffusivities increase with increasing protein concentration. Upon increase in salt concentration, these trends are eventually reversed. This enhancement in scattering intensity and decrease in diffusivity was widely interpreted as sign of aggregate formation. Yet, a quantitative interpretation of the scattering behavior over the whole salt concentration range can only be given in terms of a transition from net repulsion to net attraction between lysozyme monomers. Increased salt screening of the electrostatic repulsion among the protein macro-ions, together with attractive protein interactions, such as van der Waals, hydrophobic and hydration forces, provide an unambiguous mechanism for the observed transition and a more physical interpretation of the various observations.

Muschol, Martin↗

Origin of hot ions observed in a modified Penning discharge

Ions with a Maxwellian energy distriubtion and kinetic temperatures ranging from below 100 eV to several keV are observed in a steady state modified Penning discharge. Observations in the plasma, with capacitive probes at several azimuthal locations, are consistent with the existence of two distinct spokes rotating with different velocities in the sheath between the plasma and the anode ring. The faster (0.5 to 10 MHz) spoke consists of electrons rotating with the E/B drift velocity. The slow (0.1 to 1.0 MHz) spoke consists of ions whose measured thermal velocity is directly proportional to the spoke velocity. The interaction of the two spokes is apparently responsible for the observed electrostatic turbulence and ion thermalization. The anode sheath thickness is smaller than the ion gyrodiameter in this plasma. Thus the ions are in the electric field of the sheath for only a fraction of their orbit, and their E/B drift (spoke) velocity is smaller than that of the electrons.

Roth, J. R.↗

Origin of hot ions observed in a modified Penning discharge.

Ions with a Maxwellian energy distribution and kinetic temperatures ranging from below 100 eV to several keV have been observed in a steady-state modified Penning discharge. Observations in the plasma, with capacitive probes at several azimuthal locations, are consistent with the existence of two distinct spokes rotating with different velocities in the sheath between the plasma and the anode ring. The faster (0.5-10 MHz) spoke consists of electrons rotating with the E/B drift velocity. The slow (0.1-1.0 MHz) spoke consists of ions, the measured thermal velocity of which is directly proportional to the spoke velocity. The interaction of the two spokes is apparently responsible for the observed electrostatic ?turbulence' and ion thermalization. The anode sheath thickness is smaller than the ion gyrodiameter in this plasma. Thus the ions are in the electric field of the sheath for only a fraction of their orbit, and their E/B drift (spoke) velocity is smaller than that of the electrons.

Roth, J. R.↗

Origin of hot ions observed in a modified Penning discharge.

Ions with a Maxwellian energy distribution and kinetic temperatures ranging from below 100 eV to several keV have been observed in a steady-state modified Penning discharge. Observations in the plasma, with capacitive probes at several azimuthal locations, are consistent with the existence of two distinct spokes rotating with different velocities in the sheath between the plasma and the anode ring. The faster (0.3-10 MHz) spoke consists of electrons rotating with the E/B drift velocity. The slow (0.06-0.8 MHz) spoke consists of ions, the measured thermal velocity of which is directly proportional to the spoke velocity. The interaction of the two spokes is apparently responsible for the observed electrostatic turbulence and ion thermalization.

Roth, J. R.↗

Interaction of upgoing auroral H(+) and O(+) beams

Data from the S3-3 and DE 1 satellites are analyzed to study the interaction between H(+) and O(+) ions in upgoing auroral beams. Every data set analyzed showed some evidence of an interaction. The measured plasma was found to be unstable to a low-frequency electrostatic wave that propagates at an oblique angle to vector-B(0). A second wave, which can propagate parallel to vector-B(0), is weakly damped in the plasma studied in most detail. It is likely that the upgoing ion beams generate this parallel wave at lower altitudes. The resulting wave-particle interactions qualitatively can explain most of the features observed in ion distribution functions.

Kaufmann, R. L.↗

Equivalent Circuit Modeling for Carbon Nanotube Schottky Barrier Modulation in Polarized Gases

We study the carbon nanotube Schottky barrier at the metallic electrode interface in polarized gases using an equivalent circuit model. The gas-nanotube interaction is often weak and very little charge transfer is expected [l]. This is the case with'oxygen, but the gas-electrode interaction is appreciable and makes the oxygen molecules negatively charged. In the closed circuit condition, screening positive charges appear in the nanotube as well as in the electrode, and the Schottky barrier is modulated due to the resultant electrostatic effects [2]. In the case of ammonia, both the gas-nanotube and gas-electrode interactions are weak, but the Schottky barrier can still be modulated since the molecules are polarized and align in the preferred orientation within the gap between the electrode and nanotube in the open circuit condition (dipole layer formation). In the closed circuit condition, an electric field appears in the gap and strengthens or weakens the preferred dipole alignment reflecting the nanotube Fermi level. The modulation is visible when the nanotube depletion mode is involved, and the required dipole density is as low as 2 x 10(exp 13) dipoles/sq cm, which is quite feasible experimentally,

Yamada, Toshishige↗

Refocusing of the spent axisymmetric beam in klystron tubes

Analytic methods were developed and employed to optimize the magnetic field transition region between the output interaction gap of a klystron and a multi-stage depressed potential electrostatic beam collector, in order to enhance the power conversion efficiency of satellite-borne broadcast transmitters. Permanent magnet structures were designed to provide the magnetic field distributions required to expand and recollimate the spent electron beam of the power amplifier klystron for proper entry into the beam collector. These design criteria for magnetic field distributions for expanding and recollimating spent-beam electrons for optimal entry into a multi-stage depressed potential collector are generally applicable to traveling-wave tubes as well as klystrons.

Branch, G. M.↗

Microscale instabilities in stream interaction regions

The microstructure of solar wind stream interaction regions is considered theoretically with emphasis on the role of several electrostatic kinetic instabilities which may be important within the stream interface and the compression region. Inside of 1 AU, the interface is likely to be stable against the electrostatic streaming instabilities considered. Between 1 and 2 AU, the interface will excite the magnetized ion-ion instability. The compression region is also found to be unstable beyond 1 AU where the modified two-stream instability, beam-cyclotron instability, and ion-acoustic instability are important in determining the structure of the compressive pulses as they evolve into forward and reverse shocks. It is concluded that the modified two-stream instability and beam-cyclotron instability predominately play a role in heating the electrons to the threshold for the ion-acoustic instability. Various electrostatic plasma waves, ranging in frequency from the lower-hybrid to harmonics of the electron cyclotron frequency, would be produced by these instabilities. Their signature should also be seen by high time resolution measurements of the temperature of the various plasma species.

Eviatar, A.↗

Linear instabilities in multicomponent plasmas and their consequences for the auroral zone

Ion conics are commonly observed along auroral-zone field lines and involve all major terrestrial ion species, including H, He, and O. It is believed that low-frequency plasma waves, driven unstable by field-aligned currents, transversely heat the ion distributions via wave-particles interactions, creating the ion conics. Considered here are low-frequency oblique electrostatic instabilities found in a mixed plasma that includes an electron beam streaming through a background of electrons, H and O. The addition of O not only modifies the lower hybird frequency, but allows the existence of an ion-ion (Buchsbaum) hybrid mode with a frequency between the H and O gyrofrequencies. Because of its low frequency, the ion-ion hybrid instability can be effective in transversely heating heavy ions. When the electron beam drift speed is greater than 3 times the background electron thermal velocity and the electron gyrofrequency to plasma frequency ratio is less than 10, the lower hybrid instability dominates. However, for ratios greater than 20, which is a condition commonly found in the auroral-zone nightside region, the ion-ion instability has the largest growth rates; in these regions, heavy ion transverse heating can occur. When the ratio is between 10 and 20, the H to O density ratio determines which instability dominates.

Schriver, David↗

Data analysis and interpretation related to space system/environment interactions at LEO altitude

Several studies made on the interaction of active systems with the LEO space environment experienced from orbital or suborbital platforms are covered. The issue of high voltage space interaction is covered by theoretical modeling studies of the interaction of charged solar cell arrays with the ionospheric plasma. The theoretical studies were complemented by experimental measurements made in a vacuum chamber. The other active system studied was the emission of effluent from a space platform. In one study the emission of plasma into the LEO environment was studied by using initially a 2-D model, and then extending this model to 3-D to correctly take account of plasma motion parallel to the geomagnetic field. The other effluent studies related to the releases of neutral gas from an orbiting platform. One model which was extended and used determined the density, velocity, and energy of both an effluent gas and the ambient upper atmospheric gases over a large volume around the platform. This model was adapted to study both ambient and contaminant distributions around smaller objects in the orbital frame of reference with scale sizes of 1 m. The other effluent studies related to the interaction of the released neutral gas with the ambient ionospheric plasma. An electrostatic model was used to help understand anomalously high plasma densities measured at times in the vicinity of the space shuttle orbiter.

Raitt, W. John↗

The Micromechanics of the Moving Contact Line

The proposed research is divided into three components concerned with molecular structure, molecular orientation, and continuum averages of discrete systems. In the experimental program, we propose exploring how changes in interfacial molecular structure generate contact line motion. Rather than rely on the electrostatic and electrokinetic fields arising from the molecules themselves, we augment their interactions by an imposed field at the solid/liquid interface. By controling the field, we can manipulate the molecular structure at the solid/liquid interface. In response to controlled changes in molecular structure, we observe the resultant contact line motion. In the analytical portion of the proposed research we seek to formulate a system of equations governing fluid motion which accounts for the orientation of fluid molecules. In preliminary work, we have focused on describing how molecular orientation affects the forces generated at the moving contact line. Ideally, as assumed above, the discrete behavior of molecules can be averaged into a continuum theory. In the numerical portion of the proposed research, we inquire whether the contact line region is, in fact, large enough to possess a well-defined average. Additionally, we ask what types of behavior distinguish discrete systems from continuum systems. Might the smallness of the contact line region, in itself, lead to behavior different from that in the bulk? Taken together, our proposed research seeks to identify and accurately account for some of the molecular dynamics of the moving contact line, and attempts to formulate a description from which one can compute the forces at the moving contact line.

Han, Minsub↗

THEMIS Observations of the Magnetopause Electron Diffusion Region: Large Amplitude Waves and Heated Electrons

We present the first observations of large amplitude waves in a well-defined electron diffusion region based on the criteria described by Scudder et al at the subsolar magnetopause using data from one Time History of Events and Macroscale Interactions during Substorms (THEMIS) satellite. These waves identified as whistler mode waves, electrostatic solitary waves, lower hybrid waves, and electrostatic electron cyclotron waves, are observed in the same 12 s waveform capture and in association with signatures of active magnetic reconnection. The large amplitude waves in the electron diffusion region are coincident with abrupt increases in electron parallel temperature suggesting strong wave heating. The whistler mode waves, which are at the electron scale and which enable us to probe electron dynamics in the diffusion region were analyzed in detail. The energetic electrons (approx. 30 keV) within the electron diffusion region have anisotropic distributions with T(sub e(right angle))/T(sub e(parallel)) > 1 that may provide the free energy for the whistler mode waves. The energetic anisotropic electrons may be produced during the reconnection process. The whistler mode waves propagate away from the center of the "X-line" along magnetic field lines, suggesting that the electron diffusion region is a possible source region of the whistler mode waves.

magnetopause and boundary layers↗

Implementation of Charged Particle Behavior in Discrete Element Method (DEM) Simulations

To understand the behavior of charged lunar regolith when perturbed by lunar landers, it is important to couple the grain dynamics with mechanical and electrical particle interactions. To accomplish this, improvements have been made to a discrete element method (DEM) software package to include both short- and long-range interactions between spherical particles. Short-range interactions rely on contact between the particles, such as electrical conduction and triboelectric charge transfer driven by work functions. Long-range interactions act at a distance between every pairing of particles, such as electrostatic forces and gravitational forces. Results from simulations between a few particles are compared with theory to verify these added behaviors prior to scaling up to more complex scenarios. The radii, initial charges, electrical conductivities, work functions, and separation of the particles are varied and the resultant charges as well as the time required to reach the final state are determined.

Electrostatics↗

Sideband growth in nonlinear Landau wave-particle interaction.

The distortion of the electron velocity distribution caused by a large amplitude Landau wave is determined analytically for the initial-value problem. The resulting stability of electrostatic perturbations impressed on the evolving plasma is studied. Narrow sidebands of the applied frequency experience consecutive growths of large magnitude during the early stages of the nonlinear wave-particle interaction. The significance of the derived results to both wave propagation experiments and triggered VLF emissions in the magnetosphere is discussed.

Brinca, A. L.↗

SPARCLE: Electrostatic Dust Control Tool Proof of Concept

Successful exploration of most planetary surfaces, with their impact-generated dusty regoliths, will depend on the capabilities to keep surfaces free of the performance-compromising dust. Once in contact with surfaces, whether set in motion by natural or mechanical means, regolith fines, or dust, behave like abrasive Velcro, coating surfaces, clogging mechanisms, making movement progressively more difticult, and being almost impossible to remove by mechanical mcans (brushing). The successful dust removal strategy will deal with dust dynamics resulting from interaction between Van der Waals and Coulombic forces. Here, proof of concept for an electrostatically-based concept for dust control tool is described and demonstrated. A low power focused electron beam is used in the presence of a small electrical field to increase the negative charge to mass ratio of a dusty surface until dust repulsion and attraction to a lower potential surface, acting as a dust collector, occurred. Our goal is a compact device of less than 5 kg mass and using less than 5 watts of power to be operational in less than 5 years with heritage from ionic sweepers for active spacecraft potential control (e.g ., on POLAR). Rovers could be fitted with devices that could hamess the removal of dust for sampling as part of the extended exploration process on Mercury, Mars, asteroids or outer solar system satellites, as well as the Moon.

Clark, P. E.↗