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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 181 records · Page 10
All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

Origin of deactivation of aqueous Na–CO 2 battery and mitigation for long-duration energy storage

Here, the development of long-duration energy storage technology is crucial to facilitate the efficient utilization of renewable energy sources while mitigating carbon dioxide production. In this study, we investigate the deactivation and reactivation mechanisms of the aqueous Na–CO 2 battery during extended cycling. We have designed the cathode to include non-precious intermetallic catalysts. As the cell undergoes repeated cycles, the voltage polarization during discharge progressively rises, eventually leading to the cell's deactivation and formation of decomposition products clogging the electrode surface. Results obtained from comprehensive characterization techniques, including conductive atomic force microscopy (cAFM), Raman spectroscopy, X-ray photoelectron spectroscopy, X-ray diffraction, and inductively coupled plasma-mass spectrometry provide insight into the decomposition products. We also showcase an electrochemical approach for regeneration of these aqueous cells. Our findings, along with the insights we have gained, provide a path toward creating long-duration systems with self-healing properties.

25 ENERGY STORAGE↗
DOE OSTI2024

Technical and economic evaluation of heat transfer fluids for a TES system integrated to an advanced nuclear reactor

The utilization of thermal energy storage technology has emerged as a potential enhancement for nuclear power plants. Although nuclear energy systems possess the ability to adjust their energy output, prolonged variations in production can impact the plant's overall efficiency and economic viability. However, the nuclear industry can capitalize on thermal energy storage to bolster the power plant's economics by leveraging ancillary services and market hedging strategies. Here this research aims to advance the development of thermal energy storage for advanced nuclear reactors by assessing the thermophysical properties of various heat transfer fluids, including FLiNaK, KCl-MgCl 2 , LiCl-KCl, (LiNaK) 2 CO 3 , NaF-ZrF 4 , and KF-ZrF 4 , at temperatures ranging from 500 to 900oC. The assessment is conducted based on thermophysical correlations established in previous studies and employs figures of merit as a metric to evaluate the heat transfer performance of different salt candidates. Additionally, a cost analysis is conducted to provide an idea of the potential cost associated with each salt candidate.

25 ENERGY STORAGE↗
DOE OSTI2025

A Novel Approach for Microencapsulating Salt Hydrate-Based Phase Change Materials

Energy storage technologies, particularly those utilizing phase change materials (PCMs), have gained attention for their high energy density and efficient thermal management. PCMs, which store energy through solid-liquid phase transitions, can efficiently capture and release thermal energy, but face the challenge of leakage during the phase change process. Inorganic PCMs, such as salt hydrates, offer high energy storage capacity, but are difficult to encapsulate due to their corrosive nature. Conventional encapsulation techniques for inorganic PCMs are limited, particularly for scalable applications. In this work, we present an innovative method for the encapsulation of salt hydrate-based inorganic PCMs (CaCl 2 ·6H 2 O) using co-axial electrospinning. The process involves the creation of co-axial fibers, with salt hydrate as the core and polymer (e.g., PVP) as the outer shell, effectively preventing leakage and improving the stability of the PCM. This approach demonstrates the potential for scalable microencapsulation of inorganic PCMs, marking the first report of using co-axial electrospinning for this purpose. This novel technique could contribute to enhancing the performance and applicability of PCMs in thermal energy storage systems and other energy efficiency applications.

36 MATERIALS SCIENCE↗
DOE OSTI2022

Dynamic Earth Energy Storage: Terawatt-year, Grid-scale Energy Storage Using Planet Earth as a Thermal Battery (GeoTES): Phase I Project (Final Report)

Grid-scale energy storage has been identified by the U.S. Department of Energy’s (DOE) Energy Storage Grand Challenge as a necessary technology to support the continued build-out of intermittent renewable energy resources required to attain a carbon-free energy future. To meet this goal, the 2018 Department of Energy Research and Innovation Act mandated the creation of a comprehensive program to accelerate the development and commercialization of next-generation energy storage technologies. One of numerous energy storage technology options is the storage of excess energy as heated geothermal brine in suitable geologic formations. This concept, known as reservoir thermal energy storage (RTES), geologic thermal energy storage (GeoTES), aquifer thermal energy storage (ATES), etc., relies on the storage of thermal energy in geologic formations for recovery and use in large-scale direct use geothermal (e.g., district heating, industrial processes, etc.) and electrical power generation applications. This thermal energy is derived from excess or waste heat from any high-temperature heat source, such as concentrated solar or from conventional thermal/nuclear generation. As such, RTES can potentially play a significant role in meeting the energy storage shortfall in the coming decades. RTES can provide energy arbitrage through both the storage and production of thermal energy stored in geologic formations for direct use applications and can serve as a source of hot fluids that can be used to generate electricity to support peak demand ramping, thus easing stress on transmission and distribution. This energy storage option has geographic benefits in that energy can be stored locally or regionally depending on the various needs/loads. RTES can also be located across an enormous geographic area, without the need for a traditional hydrothermal resource but where thermal gradients and hydrogeology allow economic exploitation of subsurface heat. The work conducted for this project includes (1) a review of lessons learned from past high-temperature RTES international projects; (2) geochemical experimental investigation and numerical simulations of potential domestic sedimentary reservoirs and (3) development of a thermo-hydrological-mechanical (THM) numerical simulation tool for optimizing formation properties and design parameters to maximize thermal energy storage performance.

15 GEOTHERMAL ENERGY↗
DOE OSTI2020

A Comprehensive Review on the Development of Solid–State Metal–Air Batteries Operated on Oxide–Ion Chemistry

The recently developed solid oxide metal–air redox battery (SOMARB) operating on oxide-ion chemistry represents an emerging and promising energy storage technology, which is well suited for managing grid stability and efficiently harvesting renewable energy. Compared to widely reported metal–air batteries operating on liquid-phase alkali-ion or alkaline chemistries, the SOMARB uniquely features a direct reduction of the high concentration of O 2 molecules in the gas phase without invoking the detrimental formation of a diffusion-blocking oxide phase on the surface of the oxygen electrode. A typical SOMARB is composed of a reversible solid oxide cell (RSOC) and an energy storage unit (ESU), which is capable of storing a high capacity of energy at high power without safety concerns. In this article, the SOMARB concept birth and development are reviewed and discussed with the fundamental differences separating it from other types of metal–air batteries, along with the challenges and opportunities around commercialization. Particular focus is placed on the functional materials tailored for ESU and RSOC applications, including recent experimental and computational efforts to boost the redox activity of Fe-based ESU materials and the performance of intermediate temperature RSOCs. Lastly, candid opinions are offered on the challenges and opportunities facing the future development of SOMARBs toward large-scale energy storage applications.

08 HYDROGEN↗
DOE OSTI2023

Composite Membrane for Sodium Polysulfide Hybrid Redox Flow Batteries

Non-aqueous redox flow batteries (NARFBs) using earth-abundant materials, such as sodium and sulfur, are promising long-duration energy storage technologies. NARFBs utilize organic solvents, which enable higher operating voltages and potentially higher energy densities compared with their aqueous counterparts. Despite exciting progress throughout the past decade, the lack of low-cost membranes with adequate ionic conductivity and selectivity remains as one of the major bottlenecks of NARFBs. Here, we developed a composite membrane composed of a thin (<25 µm) Na+-Nafion coating on a porous polypropylene scaffold. The composite membrane significantly improves the electrochemical stability of Na + -Nafion against sodium metal, exhibiting stable Na symmetric cell performance for over 2300 h, while Na + -Nafion shorted by 445 h. Additionally, the composite membrane demonstrates a higher room temperature storage modulus than the porous polypropylene scaffold and Na + -Nafion separately while maintaining high Na + conductivity (0.24 mS/cm at 20 °C). Our method shows that a composite membrane utilizing Na + -Nafion is a promising approach for sodium-based hybrid redox flow batteries.

25 ENERGY STORAGE↗
DOE OSTI2021

Electrical Energy Storage Data Submission Guidelines, Version 2

Energy storage technologies are positioned to play a substantial role in power delivery systems. They have the potential to serve as an effective new resource to maintain reliability and allow for increased penetration of renewable energy. However, because of their relative infancy, there is a lack of knowledge about how these resources truly operate over time. A data analysis can help ascertain the operational and performance characteristics of these emerging technologies. Rigorous testing and a data analysis are important for all stakeholders to ensure a safe, reliable system that performs predictably on a macro level. Standardizing testing and analysis approaches to verify the performance of energy storage devices, equipment, and systems when integrating them into the grid will improve the understanding and benefit of energy storage over time from technical and economic vantage points. Demonstrating the life-cycle value and capabilities of energy storage systems begins with the data that the provider supplies for the analysis. After a review of energy storage data received from several providers, some of these data have clearly shown to be inconsistent and incomplete, raising the question of their efficacy for a robust analysis. This report reviews and proposes general guidelines, such as sampling rates and data points, that providers must supply for a robust data analysis to take place. Consistent guidelines are the basis of a proper protocol and ensuing standards to (1) reduce the time that it takes for data to reach those who are providing the analysis; (2) allow them to better understand the energy storage installations; and (3) enable them to provide a high-quality analysis of the installations. The report is intended to serve as a starting point for what data points should be provided when monitoring. Readers are encouraged to use the guidance in the report to develop specifications for new systems, as well as enhance current efforts to ensure optimal storage performance. As battery technologies continue to advance and the industry expands, the report will be updated to remain current.

25 ENERGY STORAGE↗
DOE OSTI2023

Low‐cost, Long Duration Electrical Energy Storage Using a CO 2 ‐based Pumped Thermal Energy Storage

The increasing deployment of non‐dispatchable, intermittent renewable energy generation sources to address climate change is placing pressure upon electrical grids’ ability to match supply with demand. The need to deploy large quantities of long duration energy storage assets is rapidly approaching, and innovative methods of energy storage that are low cost, efficient, safe and environmentally benign are needed urgently. CO 2 ‐based Pumped Thermal Energy Storage (PTES) is a low cost, efficient and environmentally safe energy storage technology. PTES uses an electrically‐driven CO 2 heat pump to charge thermal reservoirs that are later used as resources to generate electricity using a CO 2 heat engine. In this program, Echogen and collaborators refined the design of a utility‐scale CO 2 PTES system and demonstrated key technologies that will be required for successful commercial development in a laboratory‐scale system. Component and system‐level performance was evaluated over multiple charge/discharge cycles, with favorable results. Echogen is continuing to develop and commercialize this technology at utility scale.

25 ENERGY STORAGE↗
DOE OSTI2022

Energy-efficient building technologies

Buildings consume one-third of the total final energy produced on the globe and are responsible for almost 40 percent of total carbon dioxide generation annually. The latest carbon dioxide burden of buildings approached 10 Gigatons in the year 2019. Energy-efficient building technologies are necessary to address the climate change induced by greenhouse gases and fulfill the growth in demand and continuously depleting energy reserves. To meet the net-zero carbon footprint goals, sustainable, renewable energy resources, efficient building technologies, and demand management strategies are needed. Achieving zero emissions will require buildings to be equipped with energy-efficient technologies while completely avoiding on-site fossil fuel consumption and being only powered by renewable energy. In this context, this chapter provides an overview of various building technologies, including envelopes, materials, equipment, appliances, and integration concepts, which will play a significant role in lowering the overall energy consumption in both existing building stock and new buildings. Specifically, the following areas are discussed in detail: emerging building envelope designs, thermal comfort and refrigeration equipment, bridging technologies for improved energy efficiency in the ongoing energy transition, hybrid renewable (photovoltaic) configurations, energy storage technologies, miscellaneous appliances, refrigerants, and renewable fuels. The influence of key design and operating characteristics on annual carbon footprint is presented.

Cheekatamarla, Praveen↗
DOE OSTI2022

Simulink Modeling and Dynamic Study of Fixed-Speed, Variable-Speed, and Ternary Pumped Storage Hydropower

Pumped Storage Hydropower (PSH) is one of the most popular energy storage technologies in the world. It uses an upper reservoir to store water which can be later used during high-demand. In the United States, most of the energy storage capability actually corresponds to PSH. Moreover, PSH also brings multiple benefits to grid operation. This report presents the Simulink models of three common PSH technologies: Fixed-Speed (FS), Variable-Speed (VS), and Ternary (T)-PSH. These models are available to the general public on this GitHub repository, which contains the MATLAB model initialization files, the Simulink model files, and supplementary MATLAB code used to obtain the figures in this work. For each PSH model, an introductory description of the model components and other relevant functionalities are provided. For further information regarding the models and the initialization parameters, the reader is referred to the shared files in the repository. This report also presents the dynamic behavior of each model. The response of such models to a load event is analyzed and matched with each model's features. A custom IEEE 39 bus case is employed for the FS and T-PSH simulations, while the VS-PSH is simulated on a simplified three-bus test system due to the computational complexity of the model. For the T-PSH, the steady-state and the switching between several operating modes are also studied in this work.

13 HYDRO ENERGY↗
DOE OSTI2026

Project Phase 1 Report: Reducing Data Center Peak Cooling Demand and Energy Costs With Cold Underground Thermal Energy Storage (Cold UTES)

Cold Underground Thermal Energy Storage (Cold UTES) is an ultra-long duration grid energy storage technology. With Cold-UTES, low-cost grid power is converted to cold thermal energy and stored in the native subsurface rock at the point of use. Cold UTES is one approach within the general category of engineered geothermal systems. Cold UTES for peak-hour cooling of data centers (DCs) was studied for deployment in Maricopa County, Arizona and Loudoun County, Virgina using thermal storage capacities from 4 GWh-th to over 1,000 GWh-th (>1 Terawatt-hour). The two sites have different power and transmission systems, available grid energy resources, daily and seasonal load profiles, weather conditions, and grid regulatory requirements. The study results indicate high value for both locations and because of this, likely indicates value across most of the US and the world. The basis of the study was a 1,000 MW-e hourly electric use of DC computing and auxiliary loads, which was modeled as 1 GW-th of thermal load to a dry cooled heat rejection system - i.e. a cooling system that does not consume water. The electric power required for cooling the DC varies as the air temperature changes. In cold weather only the dry-coolers are used, with an electrical load for cooling load as low as 10 MW-e. In hot summer hours, chillers and dry- coolers are required, which raises the electrical load for cooling load to as much as 300 MW-e. The continuous and peak cooling electrical loads result in a grid interconnection requirement of no less than 1,300 MW-e. From both a grid and thermal design modeling perspective the 1.3 GW-e could either be a single facility or result from the total load at multiple sites.

15 GEOTHERMAL ENERGY↗
DOE OSTI2024

Novel One-Step Production of Carbon-Coated Sn Nanoparticles for High-Capacity Anodes in Lithium-Ion Batteries

Lithium-ion batteries offer the highest energy density of any currently available portable energy storage technology. By using different anode materials, these batteries could have an even greater energy density. One material, tin, has a theoretical lithium capacity (994 mAh/g) over three-times higher than commercial carbon anode materials. Unfortunately, to achieve this high capacity, bulk tin undergoes a large volume expansion, and the material pulverizes during cycling, giving a rapid capacity fade. To mitigate this issue, tin must be scaled down to the nano-level to take advantage of unique micromechanics at the nanoscale. Synthesis techniques for Sn nanoparticle anodes are costly and overly complicated for commercial production. A novel one-step process for producing carbon-coated Sn nanoparticles via spark plasma erosion (SPE) shows great promise as a simple, inexpensive production method. The SPE method, characterization of the resulting particles, and their high-capacity reversible electrochemical performance as anodes are described. With only a 10% addition of these novel SPE carbon-coated Sn particles, one anode composition demonstrated a reversible capacity of ~460 mAh/g, achieving the theoretical capacity of that particular electrode formulation. These SPE carbon-coated Sn nanoparticles are drop-in ready for present commercial lithium-ion anode processing and would provide a ~10% increase in the total capacity of current commercial lithium-ion cells.

25 ENERGY STORAGE↗
DOE OSTI2021

Optimizing design and dispatch of a renewable energy system

Renewable energy technologies are becoming increasingly important due to their cost-competitiveness, and because of enhanced climate concerns. We demonstrate the capabilities of an integer-programming optimization model that minimizes capital (investment) and operational costs, and utility charges, while adhering to system sizing constraints, demand requirements, and interoperability characteristics of the systems chosen. Furthermore, the model recommends an optimally sized mix of renewable energy, conventional generation, and energy storage technologies, while simultaneously optimizing the corresponding dispatch strategy. Our case studies explore several venues, i.e., a small campus and a local hospital, with complex utility rate tariffs, multi-technology integration opportunities, and incentives for renewable power production. Using an optimization model, versus applying rules of thumb, can produce millions of dollars in savings over a 25-year time horizon and result in thousands of kilowatts of installed renewable energy.

25 ENERGY STORAGE↗
DOE OSTI2020

Electrical Energy Storage Data Submission Guidelines

Energy storage technologies are positioned to play a substantial role in power delivery systems. They are being touted as an effective new resource to maintain reliability and allow for increased penetration of renewable energy. However, due to their relative infancy, there is a lack of knowledge on how these resources truly operate over time. Data analysis can help ascertain the operational and performance characteristics of these emerging technologies. Rigorous testing and data analysis are important for all stakeholders to ensure a safe, reliable system that performs predictably on a macro level. Standardizing testing and analysis approaches to verifying the performance of energy storage devices, equipment, and systems when integrating them into the grid will improve the understanding and benefit of energy storage over time from technical and economic vantage points. Demonstrating the life-cycle value and capabilities of energy storage systems begins with the data the provider supplies for analysis. After review of energy storage data received from several providers, it has become clear that some of these data are inconsistent and incomplete, raising the question of their efficacy for robust analysis. This report reviews and proposes general guidelines such as sampling rates and data points that providers must supply for robust data analysis to take place. Consistent guidelines are the basis of the proper protocol and ensuing standards to (a) reduce the time it takes data to reach those who are providing analysis; (b) allow them to better understand the energy storage installations; and (c) enable them to provide high-quality analysis of the installations. This report is intended to serve as a starting point for what data points should be provided when monitoring. As battery technologies continue to advance and the industry expands, this report will be updated to remain current.

25 ENERGY STORAGE↗
DOE OSTI2025

Porous carbon from lignocellulosic biomass with emphasis on corn plant waste residue for energy storage

The rising global demand for sustainable energy storage materials has driven the search for environmentally friendly and cost-effective electrode options. Hydrothermal conversion of lignocellulosic biomass has gained attention due to its low energy requirements and operation at relatively low temperatures, presenting a green alternative to traditional thermochemical methods. The resulting solid product, hydrochar, has been used as an adsorbent and soil amendment; however, chemical/thermal treatment significantly enhances its physical properties. These structural modifications transform hydrochar into an effective porous carbon electrode, offering abundant sites for electrolyte ion transport, critical for high-performance devices like supercapacitors and batteries. This review first discusses various waste biomass and sustainable feedstocks available globally. It compares two primary thermochemical conversion techniques, pyrolysis and hydrothermal carbonization/liquefaction, and examines their respective solid products, biochar and hydrochar, analyzing differences in their physical and chemical characteristics. The focus is placed on hydrochar, summarizing activation methods to produce porous carbon suitable for energy storage applications. Additionally, this review will include a dedicated section on the application of porous carbon derived from corn plant waste residue, considering that corn is one of the most abundant crops grown worldwide, which makes it an important and promising source for sustainable porous carbon production. The role of machine learning models in optimizing hydrothermal processes to produce high-quality hydrochar is also discussed, emphasizing how data-driven approaches can streamline process development. Finally, the review identifies the current challenges and prospects for lignocellulosic biomass-derived porous carbon as a sustainable electrode material in next-generation energy storage technologies.

25 ENERGY STORAGE↗
NASA NTRS1992

Sodium-sulfur Cell Technology Flight Experiment (SSCT)

The sodium-sulfur battery is emerging as a prime high-temperature energy storage technology for space flight applications. A Na-S cell demonstration is planned for a 1995-96 NASA Space Shuttle flight which focuses on the microgravity effects on individual cells. The experiment is not optimized for battery performance as such. Rather, it maximizes the variety of operating conditions which the Na-S cell is capable of in a relatively short 5-day flight. The demonstration is designed to reveal the effects of microgravity by comparison with ground test control cells experiencing identical test conditions but with gravity. Specifically, limitations of transport dynamics and associated cell performance characteristics should be revealed. The Na-S Cell Technology Flight Experiment consists of three separate experiments designed to determine cell operating characteristics, detailed electrode kinetics and reactant distributions.

Halbach, Carl R.↗