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An NOy* Algorithm for SOLVE

De-nitrification and excess re-nitrification was widely observed by ER-2 instruments in the Arctic vortex during SOLVE in winter/spring 2000. Analyses of these events requires a knowledge of the initial or pre-vortex state of the sampled air masses. The canonical relationship of NOy to the long-lived tracer N2O observed in the unperturbed stratosphere is generally used for this purpose. In this paper we will attempt to establish the current unperturbed NOy:N2O relationship (NOy* algorithm) using the ensemble of extra-vortex data from in situ instruments flying on the ER-2 and DC-8, and from the Mark IV remote measurements on the OMS balloon. Initial analysis indicates a change in the SOLVE NOy* from the values predicted by the 1994 Northern Hemisphere NOy* algorithm which was derived from the observations in the ASHOE/MAESA campaign.

Loewenstein, M.↗

RACORO Continental Boundary Layer Cloud Investigations: 1. Case Study Development and Ensemble Large-Scale Forcings

Observation-based modeling case studies of continental boundary layer clouds have been developed to study cloudy boundary layers, aerosol influences upon them, and their representation in cloud- and global-scale models. Three 60 h case study periods span the temporal evolution of cumulus, stratiform, and drizzling boundary layer cloud systems, representing mixed and transitional states rather than idealized or canonical cases. Based on in situ measurements from the Routine AAF (Atmospheric Radiation Measurement (ARM) Aerial Facility) CLOWD (Clouds with Low Optical Water Depth) Optical Radiative Observations (RACORO) field campaign and remote sensing observations, the cases are designed with a modular configuration to simplify use in large-eddy simulations (LES) and single-column models. Aircraft measurements of aerosol number size distribution are fit to lognormal functions for concise representation in models. Values of the aerosol hygroscopicity parameter, kappa, are derived from observations to be approximately 0.10, which are lower than the 0.3 typical over continents and suggestive of a large aerosol organic fraction. Ensemble large-scale forcing data sets are derived from the ARM variational analysis, European Centre for Medium-Range Weather Forecasts, and a multiscale data assimilation system. The forcings are assessed through comparison of measured bulk atmospheric and cloud properties to those computed in "trial" large-eddy simulations, where more efficient run times are enabled through modest reductions in grid resolution and domain size compared to the full-sized LES grid. Simulations capture many of the general features observed, but the state-of-the-art forcings were limited at representing details of cloud onset, and tight gradients and high-resolution transients of importance. Methods for improving the initial conditions and forcings are discussed. The cases developed are available to the general modeling community for studying continental boundary clouds.

Boundary layers↗

Mid-Pliocene Atlantic Meridional Overturning Circulation simulated in PlioMIP2

In the Pliocene Model Intercomparison Project Phase 2 (PlioMIP2), coupled climate models have been used to simulate an interglacial climate during the mid-Piacenzian warm period (mPWP; 3.264 to 3.025 Ma). Here, we compare the Atlantic Meridional Overturning Circulation (AMOC), poleward ocean heat transport and sea surface warming in the Atlantic simulated with these models. In PlioMIP2, all models simulate an intensified mid-Pliocene AMOC. However, there is no consistent response in the simulated Atlantic ocean heat transport nor in the depth of the Atlantic overturning cell. The models show a large spread in the simulated AMOC maximum, the Atlantic ocean heat transport and the surface warming in the North Atlantic. Although a few models simulate a surface warming of ~8–12°C in the North Atlantic, similar to the reconstruction from Pliocene Research, Interpretation and Synoptic Mapping (PRISM) version 4, most models appear to underestimate this warming. The large model spread and model–data discrepancies in the PlioMIP2 ensemble do not support the hypothesis that an intensification of the AMOC, together with an increase in northward ocean heat transport, is the dominant mechanism for the mid-Pliocene warm climate over the North Atlantic.

Pliocene Model Intercomparison Project Phase 2 (Pl↗

Deep near-infrared survey of the Southern Sky (DENIS)

DENIS (Deep Near-Infrared Survey of the Southern Sky) will be the first complete census of astronomical sources in the near-infrared spectral range. The challenges of this novel survey are both scientific and technical. Phenomena radiating in the near-infrared range from brown dwarfs to galaxies in the early stages of cosmological evolution, the scientific exploitation of data relevant over such a wide range requires pooling expertise from several of the leading European astronomical centers. The technical challenges of a project which will provide an order of magnitude more sources than given by the IRAS space mission, and which will involve advanced data-handling and image-processing techniques, likewise require pooling of hardware and software resources, as well as of human expertise. The DENIS project team is composed of some 40 scientists, computer specialists, and engineers located in 5 European Community countries (France, Germany, Italy, The Netherlands, and Spain), with important contributions from specialists in Australia, Brazil, Chile, and Hungary. DENIS will survey the entire southern sky in 3 colors, namely in the I band at a wavelength of 0.8 micron, in the 1.25 micron J band, and in the 2.15 micron K' band. The sensitivity limits will be 18th magnitude in the I band, 16th in the J band, and 14.5th in the K' band. The angular resolution achieved will be 1 arcsecond in the I band, and 3.0 arcseconds in the J and K' bands. The European Southern Observatory 1 m telescope on La Silla will be dedicated to survey use during operations expected to last four years, commencing in late 1993. DENIS aims to provide the astronomical community with complete digitized infrared images of the full southern sky and a catalogue of extracted objects, both of the best quality and in readily accessible form. This will be achieved through dedicated software packages and specialized catalogues, and with assistance from the Leiden and Paris Data Analysis Centers. The data will be mailed on DAT tapes from La Silla to the two Data Analysis Centers for further processing. Two centers are necessary because of the shear quantity of data and because of the complementary roles the Centers will develop, each exploiting its own particular expertise. The Leiden Data Analysis Center (LDAC) will extract objects, establish their parameters, and archive them into a source catalogue. The LDAC will collaborate with the Groningen Space Research group that has gained experience in infrared image handling from the IRAS satellite. The Paris Data Analysis Center (PDAC) will be responsible for archiving and preprocessing the raw data to provide a homogeneous set of data suitable for further reduction in both the Leiden and Paris data analysis streams. The PDAC will also extract and archive images for the sources flagged by the LDAC as extended, and create a catalogue of galaxies. In exploiting the DENIS data we foresee the collaboration with other data analysis centers, such as the Observatoire de Lyon where the relevant DENIS catalogue of galaxies can be incorporated into their extragalactic database. The Point Sources and the Small Extended Sources catalogues could be incorporated in the Late Type Star database at Montpellier, and in the SIMBAD database as CDS. At Groningen the IRAS Point Source catalogue and/or image data can be merged with the DENIS catalogues. At Meudon algorithms and software will be developed with main goal assessing the limits reachable for the homogeneity and intrinsic consistency between the ensemble of the images in the data base (flat-fielding, relative positioning of the fields, bootstrapped flux calibration) but also for the data analysis.

Deul, E.↗

An application of the Multi-Purpose System Simulation /MPSS/ model to the Monitor and Control Display System /MACDS/ at the National Aeronautics and Space Administration /NASA/ Goddard Space Flight Center /GSFC/

The Multi-Purpose System Simulator (MPSS) model was used to investigate the current and projected performance of the Monitor and Control Display System (MACDS) at the Goddard Space Flight Center in processing and displaying launch data adequately. MACDS consists of two interconnected mini-computers with associated terminal input and display output equipment and a disk-stored data base. Three configurations of MACDS were evaluated via MPSS and their performances ascertained. First, the current version of MACDS was found inadequate to handle projected launch data loads because of unacceptable data backlogging. Second, the current MACDS hardware with enhanced software was capable of handling two times the anticipated data loads. Third, an up-graded hardware ensemble combined with the enhanced software was capable of handling four times the anticipated data loads.

Mill, F. W.↗

MERRA-2 Ocean: The NASA Global Modeling and Assimilation Office's Weakly Coupled Atmosphere-Ocean Reanalysis Using GEOS-S2S Version 3

The NASA Modern Era Reanalysis for Research and Applications (MERRA2) has been a respected and widely used reanalysis that has so far been restricted to the atmosphere. Now a newly released version of the atmosphere/ocean coupled data assimilation system (AODAS) has been developed by the NASA/Goddard Global Modeling and Assimilation Office to perform a retrospective ocean reanalysis from 1982 to present. In addition to assimilating all available in situ data (e.g. Argo, mooring, XBT and CTD data) and altimetry information into the ocean, the new version (GEOS-S2S Version 3) model includes a higher resolution, eddy-permitting ocean model than previous versions, a more realistic implementation of the atmosphere-ocean interface layer, and an improved coupling between glacier and ocean (among other improvements). In addition, this ocean data assimilation was expanded to include the assimilation of satellite sea surface salinity. The MERRA-2 AODAS will be described, and preliminary results will be shown from the assimilation reanalysis and from retrospective forecasts issued using a new ensemble strategy. Following the Global Ocean Data Assimilation Experiment (GODAE) protocols, we will present Class 1 through Class 4 validation results from the ocean reanalysis. Results indicate an improved ocean mixed layer depth, improved salinity near Greenland, an improved diurnal cycle of the sea surface skin temperature, an improved estimate of ocean evaporation, and better representation of western boundary currents (e.g. Gulf Stream) from our new ocean reanalysis. One of the motivations of this project is to provide optimal initial states for ENSO forecasting. Therefore, we will also present some preliminary results of retrospective ENSO forecasts. After thorough testing, it is expected that the GEOS-S2S Version 3 will replace our contributions to North American Multi-Model Ensemble (NMME), WCRP Subseasonal to Seasonal (S2S), and IRI seasonal prediction forecast projects.

Molod, Andrea↗

Improving the SMAP Level-4 Soil Moisture Product

The NASA Soil Moisture Active Passive (SMAP) mission generates, among other data sets, the Level 4 Soil Moisture (L4 SM) product. The L4 SM algorithm is based on the assimilation of SMAP radiometer brightness temperature observations into the NASA Catchment land surface model using a spatially distributed ensemble Kalman filter. The L4 SM data are published with a mean latency of approx. 2.5 days from the time of observation and provide global, three-hourly, 9 km resolution estimates of surface and root-zone soil moisture and related land surface states and fluxes. In 2018, the product was upgraded from Version 3 to Version 4. Underlying the new version is a revised modeling system that includes improved input parameter datasets for land cover, topography, and vegetation height that are based on recent, high quality space-borne remote sensing observations. Land cover inputs were updated to the GlobCover2009 product, which is based on satellite observations from the Medium Resolution Imaging Spectrometer. Topographic statistics now rely on observations from the Shuttle Radar Topography Mission. Finally, vegetation height inputs are derived from space-borne Lidar measurements. Additionally, SMAP Level-2 soil moisture retrievals and in situ soil moisture measurements were used to calibrate a particular Catchment model parameter that governs the recharge of soil moisture from the models root-zone excess reservoir into the surface excess reservoir. Specifically, the replenishment of soil moisture near the surface from below under non-equilibrium conditions was substantially reduced, which brings the models surface soil moisture more in line with the SMAP Level 2 and in situ soil moisture. Finally, the calibration of the assimilated SMAP brightness temperatures changed substantially from Version 3 to Version 4. Considerable effort went into the version upgrade, creating an expectation that the new version is improved over the old version. Indeed, some aspects of the new version are clearly better. However, other aspects are not, and on balance, the overall improvement is modest at best. In this presentation we summarize the skill of the new and old versions vs. independent in situ measurements and in terms of data assimilation diagnostics, including, for example, the statistics of the (soil moisture) analysis increments and the observation minus forecast (brightness temperatures) residuals. We share our experience with trying to improve to the L4 SM product and the lessons learned from the effort.

Reichle, Rolf↗

Reducing Multisensor Satellite Monthly Mean Aerosol Optical Depth Uncertainty: 1. Objective Assessment of Current AERONET Locations

Various space-based sensors have been designed and corresponding algorithms developed to retrieve aerosol optical depth (AOD), the very basic aerosol optical property, yet considerable disagreement still exists across these different satellite data sets. Surface-based observations aim to provide ground truth for validating satellite data; hence, their deployment locations should preferably contain as much spatial information as possible, i.e., high spatial representativeness. Using a novel Ensemble Kalman Filter (EnKF)- based approach, we objectively evaluate the spatial representativeness of current Aerosol Robotic Network (AERONET) sites. Multisensor monthly mean AOD data sets from Moderate Resolution Imaging Spectroradiometer, Multiangle Imaging Spectroradiometer, Sea-viewing Wide Field-of-view Sensor, Ozone Monitoring Instrument, and Polarization and Anisotropy of Reflectances for Atmospheric Sciences coupled with Observations from a Lidar are combined into a 605-member ensemble, and AERONET data are considered as the observations to be assimilated into this ensemble using the EnKF. The assessment is made by comparing the analysis error variance (that has been constrained by ground-based measurements), with the background error variance (based on satellite data alone). Results show that the total uncertainty is reduced by approximately 27% on average and could reach above 50% over certain places. The uncertainty reduction pattern also has distinct seasonal patterns, corresponding to the spatial distribution of seasonally varying aerosol types, such as dust in the spring for Northern Hemisphere and biomass burning in the fall for Southern Hemisphere. Dust and biomass burning sites have the highest spatial representativeness, rural and oceanic sites can also represent moderate spatial information, whereas the representativeness of urban sites is relatively localized. A spatial score ranging from 1 to 3 is assigned to each AERONET site based on the uncertainty reduction, indicating its representativeness level.

aerosol optical depth↗

Inferring Land Surface Model Parameters for the Assimilation of Satellite-Based L-Band Brightness Temperature Observations into a Soil Moisture Analysis System

The Soil Moisture and Ocean Salinity (SMOS) satellite mission provides global measurements of L-band brightness temperatures at horizontal and vertical polarization and a variety of incidence angles that are sensitive to moisture and temperature conditions in the top few centimeters of the soil. These L-band observations can therefore be assimilated into a land surface model to obtain surface and root zone soil moisture estimates. As part of the observation operator, such an assimilation system requires a radiative transfer model (RTM) that converts geophysical fields (including soil moisture and soil temperature) into modeled L-band brightness temperatures. At the global scale, the RTM parameters and the climatological soil moisture conditions are still poorly known. Using look-up tables from the literature to estimate the RTM parameters usually results in modeled L-band brightness temperatures that are strongly biased against the SMOS observations, with biases varying regionally and seasonally. Such biases must be addressed within the land data assimilation system. In this presentation, the estimation of the RTM parameters is discussed for the NASA GEOS-5 land data assimilation system, which is based on the ensemble Kalman filter (EnKF) and the Catchment land surface model. In the GEOS-5 land data assimilation system, soil moisture and brightness temperature biases are addressed in three stages. First, the global soil properties and soil hydraulic parameters that are used in the Catchment model were revised to minimize the bias in the modeled soil moisture, as verified against available in situ soil moisture measurements. Second, key parameters of the "tau-omega" RTM were calibrated prior to data assimilation using an objective function that minimizes the climatological differences between the modeled L-band brightness temperatures and the corresponding SMOS observations. Calibrated parameters include soil roughness parameters, vegetation structure parameters, and the single scattering albedo. After this climatological calibration, the modeling system can provide L-band brightness temperatures with a global mean absolute bias of less than 10K against SMOS observations, across multiple incidence angles and for horizontal and vertical polarization. Third, seasonal and regional variations in the residual biases are addressed by estimating the vegetation optical depth through state augmentation during the assimilation of the L-band brightness temperatures. This strategy, tested here with SMOS data, is part of the baseline approach for the Level 4 Surface and Root Zone Soil Moisture data product from the planned Soil Moisture Active Passive (SMAP) satellite mission.

Reichle, Rolf H.↗

Using Ensemble Decisions and Active Selection to Improve Low-Cost Labeling for Multi-View Data

This paper seeks to improve low-cost labeling in terms of training set reliability (the fraction of correctly labeled training items) and test set performance for multi-view learning methods. Co-training is a popular multiview learning method that combines high-confidence example selection with low-cost (self) labeling. However, co-training with certain base learning algorithms significantly reduces training set reliability, causing an associated drop in prediction accuracy. We propose the use of ensemble labeling to improve reliability in such cases. We also discuss and show promising results on combining low-cost ensemble labeling with active (low-confidence) example selection. We unify these example selection and labeling strategies under collaborative learning, a family of techniques for multi-view learning that we are developing for distributed, sensor-network environments.

machine learning↗

Investigation of Seasonal Landscape Freeze/Thaw Cycles in Relation to Cloud Structure in the High Northern Latitudes

The seasonal freezing and thawing of Earth's cryosphere (the portion of Earth's surface permanently or seasonally frozen) has an immense impact on Earth's climate as well as on its water, carbon and energy cycles. During the spring, snowmelt and the transition between frozen and non-frozen states lowers Earth's surface albedo. This change in albedo causes more solar radiation to be absorbed by the land surface, raising surface soil and air temperatures as much as 5 C within a few days. The transition of ice into liquid water not only raises the surface humidity, but also greatly affects the energy exchange between the land surface and the atmosphere as the phase change creates a latent energy dominated system. There is strong evidence to suggest that the thawing of the cryosphere during spring and refreezing during autumn is correlated to local atmospheric conditions such as cloud structure and frequency. Understanding the influence of land surface freeze/thaw cycles on atmospheric structure can help improve our understanding of links between seasonal land surface state and weather and climate, providing insight into associated changes in Earth's water, carbon, and energy cycles that are driven by climate change.Information on both the freeze/thaw states of Earth's land surface and cloud characteristics is derived from data sets collected by NOAA's Special Sensor Microwave/Imager (SSM/I), the Advanced Microwave Scanning Radiometer on NASA's Earth Observing System(AMSR-E), NASA's CloudSat, and NASA's SeaWinds-on-QuickSCAT Earth remote sensing satellite instruments. These instruments take advantage of the microwave spectrum to collect an ensemble of atmospheric and land surface data. Our analysis uses data from radars (active instruments which transmit a microwave signal toward Earth and measure the resultant backscatter) and radiometers (passive devices which measure Earth's natural microwave emission) to accurately characterize salient details on Earth's surface and atmospheric states. By comparing the cloud measurements and the surface freeze-thaw data sets, a correlation between the two phenomena can be developed.

clouds↗

Basin-Scale Assessment of the Land Surface Energy Budget in the National Centers for Environmental Prediction Operational and Research NLDAS-2 Systems

This paper compares the annual and monthly components of the simulated energy budget from the North American Land Data Assimilation System phase 2 (NLDAS-2) with reference products over the domains of the 12 River Forecast Centers (RFCs) of the continental United States (CONUS). The simulations are calculated from both operational and research versions of NLDAS-2. The reference radiation components are obtained from the National Aeronautics and Space Administration Surface Radiation Budget product. The reference sensible and latent heat fluxes are obtained from a multitree ensemble method applied to gridded FLUXNET data from the Max Planck Institute, Germany. As these references are obtained from different data sources, they cannot fully close the energy budget, although the range of closure error is less than 15%formean annual results. The analysis here demonstrates the usefulness of basin-scale surface energy budget analysis for evaluating model skill and deficiencies. The operational (i.e., Noah, Mosaic, and VIC) and research (i.e., Noah-I and VIC4.0.5) NLDAS-2 land surface models exhibit similarities and differences in depicting basin-averaged energy components. For example, the energy components of the five models have similar seasonal cycles, but with different magnitudes. Generally, Noah and VIC overestimate (underestimate) sensible (latent) heat flux over several RFCs of the eastern CONUS. In contrast, Mosaic underestimates (overestimates) sensible (latent) heat flux over almost all 12 RFCs. The research Noah-I and VIC4.0.5 versions show moderate-to-large improvements (basin and model dependent) relative to their operational versions, which indicates likely pathways for future improvements in the operational NLDAS-2 system.

Energy↗

Assimilation of SMOS Retrieved Soil Moisture into the Land Information System

Soil moisture retrievals from the Soil Moisture and Ocean Salinity (SMOS) instrument are assimilated into the Noah land surface model (LSM) within the NASA Land Information System (LIS). Before assimilation, SMOS retrievals are bias-corrected to match the model climatological distribution using a Cumulative Distribution Function (CDF) matching approach. Data assimilation is done via the Ensemble Kalman Filter. The goal is to improve the representation of soil moisture within the LSM, and ultimately to improve numerical weather forecasts through better land surface initialization. We present a case study showing a large area of irrigation in the lower Mississippi River Valley, in an area with extensive rice agriculture. High soil moisture value in this region are observed by SMOS, but not captured in the forcing data. After assimilation, the model fields reflect the observed geographic patterns of soil moisture. Plans for a modeling experiment and operational use of the data are given. This work helps prepare for the assimilation of Soil Moisture Active/Passive (SMAP) retrievals in the near future.

Data Assimilation↗

Thematic mapper intraband radiometric performance

There are small differences between the average DN for the 16 detectors in each band, typically 0.8 DN; the standard deviations also differ typically by 0.4 DN. Differences of mode in a band are as large as 6 DN. Some DN levels appear to be strongly favored over adjacent levels. Differences between forward and reverse scans are approximately 0.1 DN in the mean, and 0 to 0.6 DN in the standard deviation. Geometrically resampled images (P data), in which the fixed correspondence between lines and single detectors is lost, are statistically similiar to the ensemble of detectors in each band in A data. The magnitude of inter-detector variation is readily seen by making an image of the first derivative in the vertical (line) direction of a flat field and stretching progressively wider ranges to gray; most detectors differ from their neighbors by 1 to 2 DN. The film output from the GSFC filmwriter used for TM images was found to have scale errors in both sample and line directions corresponding to four pixels in a TM image, and skew corresponding to three pixels.

Kieffer, H. H.↗

SMAP Data Assimilation at the GMAO

The NASA Soil Moisture Active Passive (SMAP) mission has been providing L-band (1.4 GHz) passive microwave brightness temperature (Tb) observations since April 2015. These observations are sensitive to surface(0-5 cm) soil moisture. Several of the key applications targeted by SMAP, however, require knowledge of deeper-layer, root zone (0-100 cm) soil moisture, which is not directly measured by SMAP. The NASA Global Modeling and Assimilation Office (GMAO) contributes to SMAP by providing Level 4 data, including the Level 4 Surface and Root Zone Soil Moisture(L4_SM) product, which is based on the assimilation of SMAP Tb observations in the ensemble-based NASA GEOS-5 land surface data assimilation system. The L4_SM product offers global data every three hours at 9 km resolution, thereby interpolating and extrapolating the coarser- scale (40 km) SMAP observations in time and in space (both horizontally and vertically). Since October 31, 2015, beta-version L4_SM data have been available to the public from the National Snow and Ice Data Center for the period March 31, 2015, to near present, with a mean latency of approx. 2.5 days.

Land Surface Model↗

Synergy of Observations and Dynamo Models to Understand and Predict Solar Activity Cycles

The long-standing problem of understanding the evolution of the global magnetic fields that drive solar activity through different temporal scales is becoming more tractable because, in addition to 400 years of sunspot records, we now have almost 4 solar cycles of magnetic field observations. These observations allow us to discern physical connections between dynamo model variables and observations using data assimilation analysis. In particular, the Ensemble Kalman Filter approach takes into account uncertainties in both observations and modeling and allows us to make reliable forecasts of solar cycle activity by using a relatively simple non-linear dynamical model of the solar dynamo. To expand this approach for more complex 2D and 3D dynamo modeling, it is necessary to decompose the observed synoptic magnetograms into poloidal and toroidal field components. In this presentation I will present initial results on magnetogram decomposition and assimilation of magnetogram data into dynamo modeling.

Kitiashvili, Irina N.↗

Synergy of Observations and Dynamo Models to Understand and Predict Solar Activity Cycles

The long-standing problem of understanding the evolution of the global magnetic fields that drive solar activity through different temporal scales is becoming more tractable because, in addition to 400 years of sunspot records, we now have almost 4 solar cycles of magnetic field observations. These observations allow us to discern physical connections between dynamo model variables and observations using data assimilation analysis. In particular, the Ensemble Kalman Filter approach takes into account uncertainties in both observations and modeling and allows us to make reliable forecasts of solar cycle activity cycles by using a relatively simple non-linear dynamical model of the solar dynamo. To expand this approach for more complex 2D and 3D dynamo modeling, it is necessary to decompose the observed synoptic magnetograms into poloidal and toroidal field components. In this presentation I will present initial results on magnetogram decomposition and assimilation of magnetogram data into dynamo modeling.

Synergy↗

Empirical relationships between gas abundances and UV selective extinction

Several studies of gas-phase abundances in lines of sight through the outer edges of dense clouds are summarized. These lines of sight have 0.4 less than E(B-V) less than 1.1 and have inferred spatial densities of a few hundred cm(-3). The primary thrust of these studies has been to compare gaseous abundances in interstellar clouds that have various types of peculiar selective extinction. To date, the most notable result has been an empirical relationship between the CN/Fe I abundance ratio and the depth of the 2200 A extinction bump. It is not clear at the present time, however, whether these two parameters are linearly correlated or the data are organized into two discrete ensembles. Based on 19 samples and assuming the clouds form discrete ensembles, lines of sight that have a CN/Fe I abundance ratio greater than 0.3 (dex) appear to have a shallow 2.57 plus or minus 0.55 bump compared to 3.60 plus or minus 0.36 for other dense clouds and compared to the 3.6 Seaton (1979) average. The difference in the strength of the extinction bump between these two ensembles is 1.03 plus or minus 0.23. Although a high-resolution IUE survey of dense clouds is far from complete, the few lines of sight with shallow extinction bumps all show preferential depletion of certain elements, while those lines of sight with normal 2200 A bumps do not. Ca II, Cr II, and Mn II appear to exhibit the strongest preferential depletion compared to S II, P II, and Mg II. Fe II and Si II depletions also appear to be enhanced somewhat in the shallow-bump lines of sight. It should be noted that Copernicus data suggest all elements, including the so-called nondepletors, deplete in diffuse clouds (Snow and Jenkins 1980, Joseph 1988). Those lines of sight through dense clouds that have normal 2200 A extinction bumps appear to be extensions of the depletions found in the diffuse interstellar medium. That is, the overall level of depletion is enhanced, but the element-to-element abundances are similar to those in diffuse clouds. In a separate study, the abundances of neutral atoms were studied in a dense cloud having a shallow 2200 A bump and in one with a normal strength bump.

Joseph, Charles L.↗