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NASA NTRS2020

Thermal Evolution and Core Formation on Asteroid 4 Vesta in the Magma Ocean Regime

Geochemical observations of the eucrite and diogenite meteorites, together with observations made by NASA’s Dawn spacecraft while orbiting asteroid 4 Vesta, indicate that Vesta has differentiated to form a crust, mantle, and core. Eucrite and diogenite petrology is best explained by solidification of the crust from a magma ocean constituting 60-70% of Vesta’s silicates [3], or a temperature of ~1550 °C. The abundances of moderately siderophile elements (Ni, Co, Mo, W, and P) in eucrites require that essentially all of the metallic phase in Vesta segregated to form a core prior to eucrite formation and likely reached a temperature of 1450- 1575 °C. These observations provide important constraints on Vesta’s thermal evolution. The high inferred temperature indicates that convective heat transport must have been important during part of Vesta’s thermal evolution. In this study, we model Vesta’s thermal evolution in the magma ocean regime.

Kiefer, Walter S.↗

NASA NTRS1972

Chemical fractionations in meteorites. V - Volatile and siderophile elements in achondrites and ocean ridge basalts.

Eighteen achondrites and 4 terrestrial basalts (3 ocean ridge, 1 continental) were analyzed by radiochemical neutron activation analysis for Ag, Au, Bi, Br, Cd, Co, Cs, Cu, Ga, In, Ir, Rb, Se, Tl and Zn. Samples included 7 eucrites, 5 howardites, 2 nakhlites, 2 shergottites, an angrite, and an aubrite. Light and dark portions of the gas-rich meteorites Kapoeta and Pesyanoe were analyzed separately. Nakhlites and shergottites have volatile element abundances similar to those in ocean ridge basalts; eucrites, howardites, and angrites show greater depletions by an order of magnitude and less similar abundance patterns. In terms of a two-component model of planetary accretion, the parent planets contained the following percentages of low-temperature material: eucrites 0.8, nakhlites 38, shergottites 28. Shergottites may be genetically related to L-chondrites. The siderophile element pattern of achondrites resembles that of the moon, but with less extreme depletions.

Laul, J. C.↗

NASA NTRS1971

A re-examination of relationships among pyroxene-plagioclase achondrites.

In light of the new data of Jerome (1970), a brief discussion of genetic relationships between eucrites, howardites and diogenites is presented. Howardites are not direct products of magmatic crystallization, as has sometimes been postulated, but instead are interpreted as polymict breccias resulting from the mechanical mixture of eucrites and diogenites. Testing of this model by means of chemical arguments is made complicated however by the probable presence of a chondritic component in howardites and by a sequence analogous to terrestrial differentiation series, among the eucrites themselves.

Jerome, D. Y.↗

NASA NTRS1980

Modal studies of mesosiderites and related achondrites, including the new mesosiderite ALHA 77219

The Antarctic meteorite ALHA 77219 is found to be a new mesosiderite. It contains about 25% metal + troilite (+ rust) and the brecciated silicate portion is dominated by orthopyroxene (En 68-71). These features, together with the presence of olivine surrounded by coronas, and abundant tridymite + phosphate conform to the characteristics of mesosiderites. A comparison of the modal abundances of minerals in 77219 with modes of 20 mesosiderites, 14 howardites, six basaltic eucrites, three feldspar cumulate eucrites, and one orthopyroxene cumulate eucrite shows that there are major differences between mesosiderites and howardites. These differences are described in detail.

Prinz, M.↗

NASA NTRS1983

The nomenclature of polymict basaltic achondrites

The system of nomenclature for basaltic achondrite meteorites is discussed, and new classification criteria are proposed. Under the new system, all achondrites are divided intno the broad groupings 'monomict' and 'polymict' by the number of lithologies present. The monomicts are classified structurally as brecciated or unbreccciated and as eucrites, diogenites, or cumulate eucrites. The polymicts are classified using an arbitrary mineral-chemical standard based on the percentage content of diogenite (magnesium orthopyroxenite): diogenites have more than 90 percent, eucrites have less than 10 percent, and all other polymicts area howardites. Tables listing all known achondrites by classification are provided.

Delaney, J. S.↗

NASA NTRS1991

Megaregolith insulation and the duration of cooling to isotopic closure within differential asteroids and the moon

Global cooling of the moon and large (R = 40-250 km) asterodis, was modeled, starting at or near the solidus. A crucial factor in determining the prevailing interval (Ic) of cooling between igenous crystallization and isotopic closure, for any given depth in the crust, is the extent to which the body is insulated by a regolith/megaregolith layer of porous, fragmental impact debris. Given plausible assumptions regarding the thicknesses of such layers on the moon and the eucrite parent asteroid (and regarding the radius of the eucrite asteroid), the results indicate that deep-crustal regions tend to remain above the Nd and Sr isotopic closure temperature for intervals that are long in comparison to the precision of modern Nd- and Sr-based age measurements, and in comparison to suggested chronologic scenarios of global differentiation. Ic intervals of as long as 100 my may be common among available samples of primordial, deep-crustal cumulates from both bodies. Chronologies for the gross solidification of the moon and the eucrite asteroid should allow for the possibility that any single age for a coarse-grained 'plutonic' or cumulate-textured rock might be many tens of millions of years younger than the igneous crystallization age.

Warren, Paul H.↗

NASA NTRS1991

Partial melting of the Allende (CV3) meteorite - Implications for origins of basaltic meteorites

Eucrites and angrites are distinct types of basaltic meteorites whose origins are poorly known. Experiments in which samples of the Allende (CV3) carbonaceous chondrite were partially melted indicate that partial melts can resemble either eucrites or angrites, depending only on the oxygen fugacity. Melts are eucritic if this variable is below that of the iron-wuestite buffer or angritic if above it. With changing pressure, the graphite-oxygen redox reaction can produce oxygen fugacities that are above or below those of the iron-wuestite buffer. Therefore, a single, homogeneous, carbonaceous planetoid greater than 110 kilometers in radius could produce melts of drastically different composition, depending on the depth of melting.

Jurewicz, A. J. G.↗

NASA NTRS1993

Chips off of asteroid 4 Vesta - Evidence for the parent body of basaltic achondrite meteorites

For more than two decades, asteroid 4 Vesta has been debated as the source for the eucrite, diogenite, and howardite classes of basaltic achondrite meteorites. Its basaltic achondrite spectral properties are unlike those of other large main-belt asteroids. Telescopic measurements have revealed 20 small main-belt asteroids that have distinctive optical reflectance spectral features similar to those of Vesta and eucrite and diogenite meteorites. Twelve have orbits that are similar to Vesta's and were previously predicted to be dynamically associated with Vesta. Eight bridge the orbital space between Vesta and the 3:1 resonance, a proposed source region for meteorites. These asteroids are most probably multikilometer-sized fragments excavated from Vesta through one or more impacts. The sizes, ejection velocities of 500 meters per second, and proximity of these fragments to the 3:1 resonance establish Vesta as a dynamically viable source for eucrite, diogenite, and howardite meteorites.

Binzel, Richard P.↗

NASA NTRS1993

Partial melting of ordinary chondrites: Lost City (H) and St. Severin (LL)

Eucrites and diogenites are examples of asteroidal basalts and orthopyroxenites, respectively. As they are found intermingled in howardites, which are inferred to be regolith breccias, eucrites and diogenites are thought to be genetically related. But the details of this relationship and of their individual origins remain controversial. Work by Jurewicz et al. showed that 1170-1180 C partial melts of the (anhydrous) Murchison (CM) chondrite have major element compositions extremely similar to primitive eucrites, such as Sioux County. However, the MnO contents of these melts were about half that of Sioux County, a problem for the simple partial melting model. In addition, partial melting of Murchison could not produce diogenites, because residual pyroxenes in the Murchison experiments were too Fe- and Ca-rich and were minor phases at all but the lowest temperatures. A parent magma for diogenites needs an expanded low-calcium pyroxene field. In their partial melting study of an L6 chondrite, Kushiro and Mysen found that ordinary chondrites did have an expanded low-Ca pyroxene field over that of CV chondrites (i.e., Allende), probably because ordinary chondrites have lower Mg/Si ratios. This study expands that of both Kushiro and Mysen and Jurewicz et al. to the Lost City (H) and St. Severin (LL) chondrites at temperatures ranging from 1170 to 1325 C, at an fO2 of one log unit below the iron-wuestite buffer (IW-1).

Jurewicz, Amy J. G.↗

NASA NTRS1994

Partial melting of the St. Severin (LL) and Lost City (H) ordinary chondrites: One step backwards and two steps forward

This study looks at partial melting in H and LL chondrites at nearly one atmosphere of total pressure as part of a continuing study of the origins of basaltic achondrites. Previously, melting experiments on anhydrous CM and CV chondrites showed that, near its solidus, the CM chondrite produced melts having major element chemistries similar to the Sioux County eucrite; but, the pyroxenes in the residuum were too iron-rich to form diogenites. Our preliminary results from melting experiments on ordinary (H, LL) chondrites suggested that, although the melts did not look like any known eucrites, pyroxenes from these charges bracketed the compositional range of pyroxenes found in diogenites. We had used the Fe/Mg exchange coefficients calculated for olivine, pyroxene, and melt in these charges to evaluate the approach to equilibrium, which appeared to be excellent. Unfortunately, mass balance calculations later indicated to us that, unlike our CM and CV charges, the LL and H experimental charges had lost significant amounts of iron to their (Pt or PtRh) supports. Apparently, pyroxene stability in chondritic systems is quite sensitive to the amount of FeO, and it was this unrecognized change in the bulk iron content which had stabilized the high temperature, highly magnesian pyroxenes. Accordingly, this work reinvestigates the phase equilibria of ordinary chondrites, eliminating iron and nickel loss, and reports significant differences. It also looks closely at how the iron and sodium in the bulk charge affect the stability of pyroxene, and it comments on how these new results apply to the problems of diogenite and eucrite petrogenesis.

Jurewicz, A. J. G.↗

NASA NTRS1994

Mineralogy and Ar-39 - Ar-40 of an old pristine basalt: Thermal history of the HED parent body

Previous investigations of mineral chemistry and Rb-Sr and Sm-Nd ages indicated that clast,84 from eucrite Yamato 75011 had preserved the pristine nature of its initial crystallization during an early stage of the HED parent body. Microscale mineralogy and Ar-39-Ar-40 ages of this clast, however, revealed local disturbance of microtextures and partially reset ages. This evidence suggests that, in addition to initial crystallization and rapid cooling, the Y75011,84 clast experienced shock deformation, reheating of short duration at higher temperature, and brecciation. These characteristics suggest two or more impact events. Fe-rich olivine filling fractures in pyroxene may have been introduced during the accompanying shock fracturing. The inferred Ar-39-Ar-40 degassing ages for Y75011 matrix and clast, 84 are 3.94 +/- 0.04 Ga and 3.98 +/- 0.03 Ga, respectively. The suggested degassing age for a clast from Y790020, believed to be paired with Y75011, is approximately 4.03 Ga, but could be younger. We consider it likely that all three samples experienced a common degassing event 3.95 +/- 0.05 Ga ago, but we cannot rule out two or more events spaced over a approximately 0.1 Ga interval. Higher temperature extractions of the two clast samples show significantly older apparent ages up to approximately 4.5 Ga and suggest that the time/temperature regime of this event was not sufficient to degas Ar totally. Most likely, the K-Ar ages were reset by thermal metamorphism associated with one or more impact events associated with shock fracturing, formation of Fe-rich olivine veins, and/or meteorite brecciation. The pyroxene annealing that commonly occurs in many eucrites is likely to be a much earlier process than the impact-produced textural changes and reset K-Ar ages observed in these meteorites. The existence of mineralogical and chronological evidence for metamorphism in an otherwise pristine eucrite suggests that the HED parent body experienced an extensive degree of early cratering.

Takeda, Hiroshi↗

NASA NTRS2004

Lunar and Planetary Science XXXV: Achondrites: An Awesome Assortment

The session "chondrites: An Awesome Assortment" included the following reports:Nucleation of the Widmanstatten Pattern in Iron Meteorites; Compositions of the Group IVB Iron Meteorites; Sm-Nd Age and Initial 87Sr/86Sr for Yamato 980318: An Old Cumulate Eucrite; Petrology of New Stannern-trend Eucrites and Eucrite Genesis; The Dichotomous HED Meteorite Suite; Early Thermal Evolution of HED Parent Body; Thermal History of the Lodranite Yamato 74357: Constraints from Compositional Zoning and Fe-Mg Ordering; Late Thermal Evolution of Acapulcoites-Lodranites Parent Body: Evidence from Sm-Nd Isotopes and Trace Elements of the LEW 86220 Acapulcoite; Partial Melting Under Reducing Conditions: How are Primitive Achondrites Formed?; Evolution of the Ureilite Parent Body; Complex, Contrasting Behavior of Chromium During Late-Stage Processes in Ureilites; Sahara 99555 and D Orbigny: Possible Pristine Parent Magma of Quenched Angrites; and Devolatilized-Allende Partial Melts as an Analog for Primitive Angrite Magmas.

Source record↗

NASA NTRS2005

Pristine Igneous Rocks and the Early Differentiation of Planetary Materials

Our studies are highly interdisciplinary, but are focused on the processes and products of early planetary and asteroidal differentiation, especially the genesis of the ancient lunar crust. The compositional diversity that we explore is the residue of process diversity, which has strong relevance for comparative planetology. Most of the accessible lunar crust consists of materials hybridized by impact-mixing. Our lunar research concentrates on the rare pristine (unmixed) samples that reflect the original genetic diversity of the early crust. Among HED basalts (eucrites and clasts in howardites), we distinguish as pristine the small minority that escaped the pervasive thermal metamorphism of the parent asteroid's crust. We have found a correlation between metamorphically pristine HED basalts and the similarly small minority of compositionally evolved "Stannern trend" samples, which are enriched in incompatible elements and titanium compared to main group eucrites, and yet have relatively high mg ratios. Other topics under investigation included: lunar and SNC (martian?) meteorites; igneous meteorites in general; impact breccias, especially metal-rich Apollo samples and polymict eucrites; siderophile compositions of the lunar and martian mantles; and planetary bulk compositions and origins.

Warren, Paul H.↗

NASA NTRS2008

Meteorite Dunite Breccia MIL 03443: A Probable Crustal Cumulate Closely Related to Diogenites from the HED Parent Asteroid

There are numerous types of differentiated meteorites, but most represent either the crusts or cores of their parent asteroids. Ureilites, olivine-pyroxene-graphite rocks, are exceptions; they are mantle restites [1]. Dunite is expected to be a common mantle lithology in differentiated asteroids. In particular, models of the eucrite parent asteroid contain large volumes of dunite mantle [2-4]. Yet dunites are very rare among meteorites, and none are known associated with the howardite, eucrite, diogenite (HED) suite. Spectroscopic measurements of 4 Vesta, the probable HED parent asteroid, show one region with an olivine signature [5] although the surface is dominated by basaltic and orthopyroxenitic material equated with eucrites and diogenites [6]. One might expect that a small number of dunitic or olivine-rich meteorites might be delivered along with the HED suite. The 46 gram meteoritic dunite MIL 03443 (Fig. 1) was recovered from the Miller Range ice field of Antarctica. This meteorite was tentatively classified as a mesosiderite because large, dunitic clasts are found in this type of meteorite, but it was noted that MIL 03443 could represent a dunite sample of the HED suite [7]. Here I will present a preliminary petrologic study of two thin sections of this meteorite.

Mittlefehldt, David W.↗

NASA NTRS2006

The Dos and Don'ts of how to Build a Planet, Using the Moon as an Example

The bulk chemical compositions of planets may yield important clues concerning planetary origins. Failing that, bulk compositions are still important, in that they constrain calculation of planetary mineralogies and also constrain the petrogenesis of basaltic magmas. In the case of the Earth, there is little or no debate about the composition of the Earth's upper mantle. This is because our sample collections contain peridotitic xenoliths of that mantle. The most fertile of these are believed to have been little modified from their primary compositions. Using these samples and chondritic meteorites as a starting point, small perturbations on the compositions of existing samples allow useful reconstruction of the bulk silicate Earth (BSE). Elsewhere, I have argued that the next simplest case is the Eucrite Parent Body (EPB). Reconstructions based on Sc partitioning indicate that the EPB can be well approximated by a mixture of 20% eucrite and 80% equilibrium olivine. This leads to a parent body that is similar to CO (or devolatilized CM) chondrites. Partial melting experiments on CM chondrites confirm this model, because the residual solids in these experiments are dominated by olivine with minor pigonite [3]. The most difficult bodies to reconstruct are those that have undergone the most differentiation. Both the Moon and Mars may have passed through a magma ocean stage. In any event, lunar and martian basalts, unlike eucrites, were not derived from undifferentiated source regions. Reconstructions are primarily based on compositional trends within the basalts themselves with some critical assumptions: (i) Refractory lithophile elements (Ca, Al, REE, actinides) are presumed to be in chondritic relative abundances; and (ii) some major element ratio is believed to exist in a chondritic ratio (e.g., Mg/Si, Mg/Al). The most commonly used parameter is Mg/Si.

Jones, J. H.↗

NASA NTRS2011

Investigation of Orthopyroxene Diversity in Howardite Meteorites

The howardite, eucrite and diogenite (HED) family of meteorites is considered to originate from the asteroid 4-Vesta [1]. Howardites are polymict breccias made mostly of diogenitic and eucritic debris [2], and have recently been divided into two types: regolithic and fragmental [3]. Regolithic howardites have higher noble gas contents due to solar wind exposure, have a greater abundance of impact-produced glass, are richer in siderophile elements, e.g. Ni, and may preferentially have a mixing ratio of eucrite to diogenite of approx.2:1 [3]. The hypothesis is that these characteristics are a result of originating from an ancient, well-mixed regolith [3]. Fragmental howardites, by contract, show less evidence of regolithic processing and are suggested to have originated in more recently formed impact ejecta [3]. Our work aims to evaluate this hypothesis. We have examined the compositional variations of orthopyroxene (diogenite) clasts within eight howardites. We posited that because regolithic howardites sampled a wider range of the asteroid surface, they would contain orthopyroxene fragments with wider ranges in incompatible element contents than would fragmental howardites that sampled fewer diogenitic source rocks. One purpose of developing an additional method to differentiate regolithic and fragmental howardites is to aid in interpretation of data expected from the Dawn mission to 4-Vesta. The Dawn analyses will be of the regolith layers, making an understanding of regolithic meteorites and the processes by which they were formed an important constraint on understanding Dawn data.

Johnson, Kristin N.↗

NASA NTRS2011

Carbonaceous Chondrite-Rich Howardites; The Potential for Hydrous Lithologies on the HED Parent

Howardites, eucrites, and diogenites, collectively referred to as the "HED's", are a clan of meteorites thought to represent three different lithologies from a common parent body. Collectively they are the most abundant type of achondrites in terrestrial collections. Eucrites are crustal basalts and gabbros, diogenites are mostly orthopyroxenites and are taken to represent lower crust or upper mantle materials, and howardites are mixed breccias containing both lithologies and are generally regarded as derived from the regolith or near-surface. The presence of exogenous chondritic material in howardite breccias has long been recognized. As a group, howardites exhibit divergence in bulk chemistry from what would be produced by mixing of diogenite and eucrite end-members exclusively, a phenomenon most evident in elevated concentrations of siderophile elements. Despite this chemical evidence for chondritic input in howardite breccias, chondritic clasts have only been identified in a minority of samples, and typically at levels of only a few percent. Three recent Antarctic howardite finds, the paired Mt. Pratt (PRA) 04401 and PRA 04402 and Scott Glacier (SCO) 06040, are notable for their high proportion of carbonaceous chondrite clasts. PRA 04401 is particularly well-endowed, with large chondritic clasts occupying more than half of the modal area of the sections we examined. Previously only a few percent chondritic clasts had been observed to occur in howardites. PRA 04401 is the most chondrite-rich howardite known

Herrin, J. S.↗

NASA NTRS2011

The Regolith of 4 Vesta: Perspectives from Howardite Meteorites and Dawn Mission Observations

4 Vesta is the largest asteroid with a basaltic surface, the only surviving differentiated asteroid recording igneous processes from the earliest phase of solar system history. The Dawn spacecraft is in orbit about Vesta pursuing a campaign of high resolution imaging and visible and infrared spectrometry of the surface; compositional mapping by gamma-ray and neutron spectrometry will follow. Vesta is heavily cratered with a surface covered by impact debris, a regolith. One important goal of the Dawn mission is to develop an understanding of regolith processes that are affecting this surface debris. Regolith characteristics are a record of interaction with the environment (e.g., impactors, dust, solar wind, galactic cosmic-rays) and give evidence of surface processes (down-gravity movement, etc.). Regolith mineralogy and composition reflect the local bedrock, with influences from regional and global mixing. Understanding regolith processes will aid in determining the lithology of underlying crust. Vesta is most likely the parent asteroid of the howardite, eucrite and diogenite meteorites. Eucrites are intrusive and extrusive mafic rocks composed mostly of ferroan low-Ca clinopyroxene and calcic plagioclase, while diogenites are cumulate magnesian orthopyroxenites. Magmatism occurred within a few million years of the formation of the solar system and then ceased. Impacts into the igneous crust produced the howardites - polymict breccias composed of mineral and lithic debris derived mostly from eucrites and diogenites. Some howardites are true regolith breccias formed by lithification of extensively impact-gardened surface debris. However, howardites have a number of significant petrologic and compositional differences from mature lunar regolith breccias and soils reflecting the different environment around Vesta compared to that at 1 AU. The most significant differences are the higher impactor flux with a lower mean impact velocity and the lower gravity. As a result, regolith processes on Vesta differ in detail from those on the Moon. Laboratory study of howardites and orbital investigation of Vesta will allow for development of robust models of regolith formation on hand sample to multi-kilometer scales.

Mittlefehldt, David W.↗