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Results for “exchange reaction”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 181 records · Page 10
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

A DNA molecular printer capable of programmable positioning and patterning in two dimensions

Nanoscale manipulation and patterning usually require costly and sensitive top-down techniques such as those used in scanning probe microscopies or in semiconductor lithography. DNA nanotechnology enables exploration of bottom-up fabrication and has previously been used to design self-assembling components capable of linear and rotary motion. In this work, we combine three independently controllable DNA origami linear actuators to create a nanoscale robotic printer. The two-axis positioning mechanism comprises a moveable gantry, running on parallel rails, threading a mobile sleeve. We show that the device is capable of reversibly positioning a write head over a canvas through the addition of signaling oligonucleotides. We demonstrate “write” functionality by using the head to catalyze a local DNA strand–exchange reaction, selectively modifying pixels on a canvas. Furthermore, this work demonstrates the power of DNA nanotechnology for creating nanoscale robotic components and could find application in surface manufacturing, biophysical studies, and templated chemistry.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
DOE OSTI2025

Half-life determination of heavy ions in a storage ring considering feeding and depleting background processes

Heavy-ion storage rings have relatively large momentum acceptance which allows for multiple ion species to circulate at the same time. This needs to be considered in radioactive decay measurements of highly charged ions, where atomic charge exchange reactions can significantly alter the intensities of parent and daughter ions. In this study, we investigate this effect using the decay curves of ion numbers in the recent 205 Tl 81+ bound-state beta decay experiment conducted using the Experimental Storage Ring at GSI Darmstadt. To understand the intricate dynamics of ion numbers, we present a set of differential equations that account for various atomic and nuclear reaction processes—bound state beta decay, atomic electron recombination and capture, and electron ionization. By incorporating appropriate boundary conditions, we develop a set of differential equations that accurately simulate the decay curves of various simultaneously stored ions in the storage ring: 205 Tl 81+ , 205 Pb 81+ , 205 Pb 82+ , 200 Hg 79+ , and 200 Hg 80+ . Through a quantitative comparison between simulations and experimental data, we provide insights into the detailed reaction mechanisms governing stored heavy ions within the storage ring. Our approach effectively models charge-changing processes, reduces the complexity of the experimental setup, and provides a simpler method for measuring the decay half-lives of highly charged ions in storage rings.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2026

LBNL_DIATOMICS v1

LBNL_DIATOMICS is a software package developed by P. Zarzycki (Lawrence Berkeley National Laboratory) for computing isotopic effects in diatomic molecules using mass-dependent spectroscopic parameters obtained experimentally or from first principles. The package provides a streamlined pipeline from the potential energy surface to the equilibrium constant of an isotopic exchange reaction.

Zarzycki, Piotr [Lawrence Berkeley National Labora↗
DOE OSTI2021

Nanoscale Structure and Dynamics in Geochemical Systems

Neutron scattering is a powerful tool to elucidate the structure and dynamics of systems that are important to geochemists, including ion association in complex aqueous solutions, solvent-exchange reactions at mineral–water interfaces, and reaction and transport of fluids in nanoporous materials. This article focusses on three techniques: neutron diffraction, which can reveal the atomic-level structure of aqueous solutions and solids; quasi-elastic neutron scattering, which measures the diffusional dynamics at mineral–water interfaces; and small-angle neutron scattering, which can show how properties of nanoporous systems change during gas, liquid, and solute imbibition and reaction. Furthermore, the usefulness and applicability of the experimental results are extended by rigorous comparison to computational simulations.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2025

Pultrusion and Vitrimer Composites: Emerging Pathways for Sustainable Structural Materials

Pultrusion is a manufacturing process used to produce fiber-reinforced polymer composites with excellent mechanical, thermal, and chemical properties. The resulting materials are lightweight, durable, and corrosion-resistant, making them valuable in aerospace, automotive, construction, and energy sectors. However, conventional thermoset composites remain difficult to recycle due to their infusible and insoluble cross-linked structure. This review explores integrating vitrimer technology a novel class of recyclable thermosets with dynamic covalent adaptive networks into the pultrusion process. As only limited studies have directly reported vitrimer pultrusion to date, this review provides a forward-looking perspective, highlighting fundamental principles, challenges, and opportunities that can guide future development of recyclable high-performance composites. Vitrimers combine the mechanical strength (tensile strength and modulus) of thermosets with the reprocessability and reshaping of thermoplastics through dynamic bond exchange mechanisms. These polymers offer high-temperature reprocessability, self-healing, and closed-loop recyclability, where recycling efficiency can be evaluated by the recovery yield retention of mechanical properties and reuse cycles meeting the demand for sustainable manufacturing. Key aspects discussed include resin formulation, fiber impregnation, curing cycles, and die design for vitrimer systems. The temperature-dependent bond exchange reactions present challenges in achieving optimal curing and strong fiber–matrix adhesion. Recent studies indicate that vitrimer-based composites can maintain structural integrity while enabling recycling and repair, with mechanical performance such as flexural and tensile strength comparable to conventional composites. Incorporating vitrimer materials into pultrusion could enable high-performance, lightweight products for a circular economy. The remaining challenges include optimizing curing kinetics, improving interfacial adhesion, and scaling production for widespread industrial adoption.

Fiber composites↗
NASA NTRS1966

Interstellar molecule formation

Interstellar molecule formation by chemical exchange reactions between interstellar gas atoms and atoms chemically bound to interstellar grains

MOLECULAR FORMING↗
NASA NTRS1966

Interstellar molecule formation.

Interstellar molecule formation as result of chemical exchange reactions between atoms of interstellar gas and atoms chemically bound to interstellar grains

INTERSTELLAR MATERIAL↗
NASA NTRS1967

Polymeric Schiff bases. I.

Conjugated, pseudoconjugated and nonconjugated Schiff base polymers synthesized by Schiff base exchange reactions, relating thermal stability to structure

Crivello, J. V.↗
NASA NTRS1967

Polymeric Schiff bases. V.

Isomeric Schiff base polymers synthesis by bis- Schiff-base exchange reaction from appropriate pairs selected from monomers, noting thermal stabilities

Crivello, J. V.↗
NASA NTRS1972

Distinct cooling histories of Apollo 14 basalts.

The subsolidus cooling history of basaltic rocks can be deduced from the distribution of divalent Mg and Fe ions over the two nonequivalent positions M1 and M2 in pyroxene. The ion exchange reaction between M1 and M2 is generally characterized by rapid kinetics. It is found that the normal cooling process of basalt 14053 was interrupted at a temperature below 840 C and that the rock was then quenched extremely rapidly.

Gray, N.↗
NASA NTRS1972

Oxygen and hydrogen ion densities above Millstone Hill.

Measurements of the vertical flux of oxygen ions, when combined with simultaneous measurements of electron density and of electron and ion temperatures, present a unique opportunity to examine conditions in the topside ionosphere. The measured fluxes and densities may be used directly to evaluate terms in the O+ continuity equation without requiring any assumptions to be made about neutral winds, electric fields, or the ambipolar diffusion coefficient. From observations at Millstone Hill we have, in this way, derived the rate of loss of O+ in the charge-exchange reaction with hydrogen, the rate of photoionization of atomic oxygen, and the rate of loss of O+ in reactions with N2 and O2. In combination with laboratory and theoretical results, these rates can be interpreted to yield number densities of the corresponding neutral species. When the measured fluxes are examined for consistency with measured density gradients and temperature profiles, we find clear evidence of wind-induced or electrodynamic vertical drifts larger than 60 m/sec.

Schunk, R. W.↗