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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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Linkage Transformations in a Three-Dimensional Covalent Organic Framework for High-Capacity Adsorption of Perfluoroalkyl Substances
Despite their many advantages, covalent organic frameworks (COFs) built from three-dimensional monomers are synthetically difficult to functionalize. Herein, we provide a new synthetic approach to the functionalization of a three-dimensional covalent organic framework (COF-300) by using a series of solid-state linkage transformations. By reducing the imine linkages of the framework to amine linkages, we produced a more hydrolytically stable material and liberated a nucleophilic amino group, poised for further functionalization. We then treated the amine-linked COF with diverse electrophiles to generate a library of functionalized materials, which we tested for their ability to adsorb perfluoroalkyl substances (PFAS) from water. The framework functionalized with dimethylammonium groups, COF-300-dimethyl, adsorbed more than 250 mg of perfluorooctanoic acid (PFOA) per 1 g of COF, which represents an approximately 14,500-fold improvement over that of COF-300 and underscores the importance of electrostatic interactions to PFAS adsorption performance. In conclusion, this work provides a conceptually new approach to the design and synthesis of functional three-dimensional COFs.
High-Capacity, Cooperative CO 2 Capture in a Diamine-Appended Metal–Organic Framework through a Combined Chemisorptive and Physisorptive Mechanism
Not Available
A novel P3-type Na2/3Mg1/3Mn2/3O2 as high capacity sodium-ion cathode using reversible oxygen redox
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High capacity ammonia adsorption in a robust metal–organic framework mediated by reversible host–guest interactions
To understand the exceptional adsorption of ammonia (NH 3 ) in MFM-300(Sc) (19.5 mmol g -1 at 273 K and 1 bar without hysteresis), we report a systematic investigation of the mechanism of adsorption by a combination of in situ neutron powder diffraction, inelastic neutron scattering, synchrotron infrared microspectroscopy, and solid-state 45 Sc NMR spectroscopy. These complementary techniques reveal the formation of reversible host–guest supramolecular interactions, which explains directly the observed excellent reversibility of this material over 90 adsorption–desorption cycles.
Triphilic organochalcogen compounds for high-capacity and stable solid-state lithium–sulfur batteries
Triphilic organochalcogen compounds are added to solid-state sulfur cathodes to establish intimate and durable interfacial contact among cathode components, enhancing ion and electron transport, active material utilization, and cycling stability.
Non-neutral plasma manipulation techniques in development of a high-capacity positron trap
Preliminary experiments have been performed toward the development of a multi-cell Penning–Malmberg trap for the storage of large numbers of positrons (≥10 10 e + ). We introduce the master-cell test trap and the diagnostic tools for first experiments with electrons. The usage of a phosphor screen to measure the z-integrated plasma distribution and the number of confined particles is demonstrated, as well as the trap alignment to the magnetic field ( B = 3.1 T) using the m = 1 diocotron mode. The plasma parameters and expansion are described along with the autoresonant excitation of the diocotron mode using rotating dipole fields and frequency chirped sinusoidal drive signals. We analyze the reproducibility of the excitation and use these findings to settle on the path for the next generation multi-cell test device.
Generalized Optimization of High-Capacity Compressive Imaging Systems
One of the greatest challenges in applying compressive sensing (CS) signal processing techniques to electromagnetic imaging applications is designing a sensing matrix that has good reconstruction capabilities. Compressive reflector antennas (CRAs) are a class of antennas that have been shown to provide enhanced image reconstruction performance over traditional reflector antennas (TRAs) when CS techniques are employed. In this article, we present a unified CRA design method, which considers both the sensing capacity and efficiency of the antenna and can be used for both compressive imaging and multiple-input multiple-output (MIMO) communication applications. The unified design method is assessed for a CRA configuration in which dielectric scatterers are added to the surface of a TRA. The design results demonstrate the ability of the unified design method to enhance the CS reconstruction capabilities of the CRA.
The multifunctional use of an aqueous battery for a high capacity jellyfish robot
The batteries that power untethered underwater vehicles (UUVs) serve a single purpose: to provide energy to electronics and motors; the more energy required, the bigger the robot must be to accommodate space for more energy storage. By choosing batteries composed primarily of liquid media [e.g., redox flow batteries (RFBs)], the increased weight can be better distributed for improved capacity with reduced inertial moment. Here, we formed an RFB into the shape of a jellyfish, using two redox chemistries and architectures: (i) a secondary ZnBr 2 battery and (ii) a hybrid primary/secondary ZnI 2 battery. A UUV was able to be powered solely by RFBs with increased volumetric (Q~ 11 ampere-hours per liter) and areal (108 milliampere-hours per square centimeter) energy density, resulting in a long operational lifetime (T~ 1.5 hours) for UUVs composed of primarily electrochemically energy-dense liquid (~90% of the robot’s weight).
Perspective—Potential Benefit of Li-Rich Cathode Materials: Reduction of Co and Ni Content Rather than Achievement of Ultra-High Capacities
In the conventional cycling protocol for lithium and manganese rich NMC layered oxides (LMRNMC), the upper cutoff voltage V cut is extended to ~ 4.8, to achieve capacities of similar to 250 mAh g -1 . With this mode of operation, structural rearrangements result in voltage fade upon cycling. Herein, a strategy is proposed to avoid these structural rearrangements based on (a) restricting V cut to values < ~ 4.6 to shut down the bulk instabilities, and (b) application of a (preferably) semi-coherent coating that protects the surface oxygen. The potential benefit of this strategy would be to minimize Co and Ni content, compared to Ni-rich NMC.
Multifunctional, Self-Healing Polyelectrolyte Gels for Long-Cycle-Life, High-Capacity Sulfur Cathodes in Li-S Batteries (FY2020 Final Report)
The project aims to develop polyelectrolyte gels consisting of partially crosslinked ionomer, interpenetrated with self-healing/polysulfide-trapping chains and swelled with a mixture of room temperature ionic liquid (RTIL) and lithium salt. To our knowledge, no other sulfur-based cathode design has combined self-healing behavior, polysulfide containment, and lithium dendrite suppression into a single design. We have demonstrated the benefits of multifunctional ionomer gel polyelectrolytes / gel cathodes with self-healing properties, as well as chemical modification of mesoporous carbons for S/C composite cathodes. Success of the proposed program of study would have wide ranging impact on the electric vehicle industry and society as a whole. A Li-S battery system with the capability of doubling lithium-ion energy density would enable the production of lighter, longer range electric vehicles at a cost that is affordable to the average U.S. household. The availability of such vehicles should lead to wide-ranging adoption over the coming years which, in combination with increased renewable electricity generation, will drastically decrease carbon emissions across the country and reduce U.S. dependency on fossil fuel sources.
Development of High-Capacity Cathodes and Robust Solid Electrolytes
In Phase 1, the University of Texas at Austin explored many methods of cathode design, synthesis, and modification, while also developing an understanding of the relationships among the cathode, anode, and electrolyte. Some of the major accomplishments are highlighted in this report.
High Capacity Retention in Lithium Batteries Utilizing Nano Iron Sulfide Particles.
Abstract not provided.
Presentation: Bench Scale Development of a Novel Direct Air Capture Technology Using High Capacity Structured Sorbents
The presentation provides a status report of bench-scale development of a DAC technology, specifically sorbent washcoat optimization, desporption method optimization, testing, and bench-scale design & fabrication.