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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 181 records · Page 10

The 2175-A feature from irradiated graphitic particles

In diffuse clouds, a subpopulation of the carbon grains is graphitized by UV starlight during cloud lifetimes of roughly 100 Myr. Graphitic dust created in this way will behave like monosize Rayleigh particles and produce a 2175-A absorption band showing a Lorentzian profile. A physical model is outlined in which the strength and width of the band correlate with the dust grain environment, but the central wavelength is fixed by the Froehlich frequency for surface plasmons in a homogeneous sphere. On this model, the band appears strong and narrow only in dust clouds where the flux of UV starlight is high and the H atom gas density is low. The width of the band increases from diffuse to dense clouds mainly as a result of gas-phase H atoms accreted on to the grain surface. It is shown that hydrogenation weakens the band in dense clouds, and thus explains the anticorrelation between band strength and high carbon depletion. The model as a whole uses only 30 percent of the cosmic carbon and gives good agreement with observations of the 2175-A feature and the average interstellar extinction law.

Sorrell, Wilfred H.↗

Emission processes and dynamics of hot gases in astrophysics

A detailed model was developed for Kepler's supernova remnant (SNR). Observations of the SNR revealed a strong interaction with the surrounding circumstellar medium, which was studied through both analytical and numerical calculations. Effects were studied of electron thermal conduction on the structure of radiative interstellar shock waves. An explanation is sought for the observed line emission from metal rich ejecta in SNR, incorporating atomic data. Light echoes around SN 1987A was also studied. Analysis of infrared and scattered circumstellar light echoes was accomplished with early observations to set limits on the mass of circumstellar dust. Work was completed on the emission from heavy element gas ejected in the supernova explosion of massive stars. It was assumed that a radioactive energy source was present and calculated the detailed heating and ionization of the gas. The evolution was studied of SNR in the very high pressure environment of a starburst galaxy.

Chevalier, Roger A.↗

Long chain carbon molecules and diffuse interstellar lines

An estimate of the abundances of chain hydrocarbon molecules expected in dense interstellar clouds as a result of gas-phase chemistry alone supports the hypothesis that the long chain molecules are responsible for the diffuse interstellar lines seen in the optical spectra of stars lying behind fairly low-density interstellar clouds. In particular, it is shown that the equilibrium abundances of the long chain carbon molecules may remain quite high even for molecules with as many as 11 carbon atoms.

Mitchell, G. F.↗

The 158 micron (CII) mapping of galaxies: Probing the atomic medium

Using the MPE/UCB Far-infrared Imaging Fabry-Perot Interferometer (FIFI) on the Kuiper Airborne Observatory (KAO), we have made large scale maps of (CII) in the spiral galaxies NGC 6946, NGC 891, M83 and the peculiar elliptical Cen A, thus allowing for the first time, detailed studies of the spatial distribution of the FIR line emission in external galaxies. We find that the (CII) emission comes from a mixture of components of interstellar gas. The brightest emission is associated with the nuclear regions, a second component traces the spiral arms as seen in the nearly face on spiral galaxies NGC 6946 and M83 and the largest star forming/H2 regions contained within them, and another extended component of low brightness can be detected in all of the galaxies far from the nucleus, beyond the extent of CO emission.

Madden, S. C.↗

Formation of chondrules by drag heating in dust-enriched environments

The solar system which had a beginning, 4.6 billion years ago is discussed. The atoms that make up the solar system are much older than that, however: they were also part of the universe that existed before the solar system formed. The presence and location of the atoms of silicon, iron, calcium, that make up the Earth and other planets before there was a solar system is questioned. Astronomical it is shown that they existed in tiny dust grains which, along with molecules of gas, wandered about in the vast reaches of space between the stars of our galaxy. The solar system was formed when one particular cloud of interstellar dust and gas became dense enough to be gravitationally unstable: the gravitational pull that dust grains and gas molecules exerted on one another caused the cloud to collapse.

Wood, J. A.↗

An H I absorption line survey of Messier 31

The 21-cm absorption through the disk of M31 has been observed, using the VLA to study the cool atomic phase of the interstellar medium in this nearby spiral galaxy. It is found that the abundance of diffuse clouds with tau between 0.125 and 1 in M31 is no higher than in the solar neighborhood of the Milky Way. The mean spin temperature, 300 K, is similar to or higher than the local value. The fraction of the neutral atomic hydrogen in the cool phase is about 0.25 or less. These results imply that M31 has a mixture of warm and cool interstellar phases similar to that in our vicinity of the Milky Way, which suggests either that the heating and cooling balance occurs in a similar pressure environment, or that whatever dynamical processes determine the mixture of warm and cool gas reach a similar equilibrium in M31 as here. Specifically, the warm neutral medium seems to be a robust phase, with a much larger filling-factor than the cool clouds.

Dickey, John M.↗

The dense interstellar medium and the birthplaces of OB stars

A review is presented of Stromgren's research on the relationships among atomic, ionized, and molecular hydrogen in the Galaxy and the spatial distribution and kinematics of OB stars. Particular attention is given to the development of density-wave theory, the implication that the pattern of the formation of OB stars in a spiral galaxy should rotate at a constant angular speed, which differs generally from the mean material speed of the interstellar gas. Other theories involving the mechanical support of molecular clouds; triggered star formation; and the relationships among H2, H I, and H II are discussed.

Shu, Frank H.↗

Infrared spectroscopy of interstellar shocks

Infrared emission lines from interstellar shocks provide valuable diagnostics for violent events in the interstellar medium, such as supernova remnants and mass outflow from young stellar objects. There are two types of interstellar shocks: in J shocks, gas properties 'jump' from their preshock to their postshock values in a shock front with a thickness equal to or less than one mean free path; radiation is emitted behind the shock front, primarily in the visible and ultraviolet, but with a few strong infrared lines, such as OI(63 microns). Such shocks occur in ionized or neutral atomic gas, or at high velocities (equal to or greater than 50 km/s) in molecular gas. In C shocks, gas is accelerated and heated by collisions between charged particles, which have a low concentration and are coupled to the magnetic field, and neutral particles; radiation is generated throughout the shock and is emitted almost entirely in infrared emission lines. Such shocks occur in weakly ionized molecular gas for shock velocities below about 50 km/s.

Mckee, C. F.↗

Collisional Excitation and Non-LTE Modeling of Interstellar Chiral Propylene Oxide

Abstract The first set of theoretical rotational cross sections for propylene oxide (CH 3 CHCH 2 O) colliding with cold He atoms has been obtained at the full quantum level using a high-accuracy potential energy surface. By scaling the collision reduced mass, rotational rate coefficients for collisions with para-H 2 are deduced in the temperature range 5–30 K. These collisional coefficients are combined with radiative data in a non-LTE radiative transfer model in order to reproduce observations of propylene oxide made toward the Sagittarius B2(N) molecular cloud with the Green Bank and Parkes radio telescopes. The three detected absorption lines are found to probe the cold (∼10 K) and translucent ( n H ∼ 2000 cm −3 ) gas in the outer edges of the extended Sgr B2(N) envelope. The derived column density for propylene oxide is N tot ∼ 3 × 10 12 cm −2 , corresponding to a fractional abundance relative to total hydrogen of ∼2.5 × 10 −11 . The present results are expected to help our understanding of the chemistry of propylene oxide, including a potential enantiomeric excess, in the cold interstellar medium.

79 ASTRONOMY AND ASTROPHYSICS↗

The relationship between the galactic matter distribution, cosmic-ray dynamics, and gamma-ray production

The concept that cosmic-ray density is related to the matter to which cosmic rays are dynamically coupled through magnetic fields on the scale of galactic arm segments is considered with specific reference to gamma-ray astronomy. A model of the galactic-matter and cosmic-ray distributions is developed on the basis of 21-cm radio surveys and recent observations of the 2.6-mm CO emission line by assuming that cosmic rays are galactic in origin, their column density is proportional to the total interstellar-gas column density, their scale height is considerably larger than that of the matter, and the Galaxy is a spiral with an arm/interarm density ratio of about 3 to 1. It is found that there is a good correlation between the observed gamma-ray intensity and that predicted on the basis of essentially complete coupling of cosmic rays to the best estimate of atomic and molecular hydrogen in the Galaxy. Individual maxima observed in gamma-radiation from the central region of the Galaxy are shown to be well correlated with those predicted to result from certain spiral-arm tangents if all the matter is assumed to be modulated in a particular spiral-arm segment pattern.

Kniffen, D. A.↗

Electron heating of inflowing interstellar gas

The heating of inflowing interstellar gas by solar electrons is calculated. In the present work it is assumed that the thermal energy of the electrons is constant with distance from the Sun and that the inflowing gas follows Keplerian trajectories, and the contours of constant temperature so obtained are given. At a heliocentric distance of 1 AU the estimated temperature is 500 K upwind and 2000 K downwind for hydrogen atoms, and is 240 K downwind and 100 K upwind for helium.

Wu, F.-M.↗

Cosmic abundance of boron.

All abundances are expressed relative to a million atoms of Si. An average abundance of boron in ordinary chondrites is 6.2. The boron abundance in meteorites is highly variable. It has been found that the abundances in carbonaceous chondrites are very much higher than those in ordinary chondrites. The condensation of boron and beryllium from a cooling, low-pressure gas of solar composition is discussed together with the occurrence of boron in the interstellar medium, questions of element abundances in the sun, problems of boron production by cosmic rays, and boron production from supernovae.

Cameron, A. G. W.↗

Directed Gas-Phase Formation of the 1-Cyanovinyl Radical (H 2 CCCN, X 2 A′) in the Interstellar Medium

The formation pathways to nitrogen-containing molecules and radicals are crucial to the understanding of the carbon–nitrogen chemistry in interstellar and atmospheric environments. While over 65 nitrogen-containing neutral species have been observed in deep space to date, their formation mechanisms─in particular, those of radical species─remain largely speculative. The crossed molecular beam technique in conjunction with electronic structure and statistical calculations was utilized to offer a detailed overview of the fundamental pathways in the gas-phase bimolecular reaction of ground-state atomic carbon (C, 3 P) with acetonitrile-d 3 (CD 3 CN, X 1 A 1 ) under single-collision conditions leading to the formation of the 1-cyanovinyl radical (D 2 CCCN, X 2 A′) coupled with deuterium atom loss. Here, the indirect reaction was initiated by barrierless carbon-atom addition, with the most probable route involving carbon addition across the carbon–nitrogen nitrile triple bond of acetonitrile, forming a three-membered ring intermediate followed by ring-opening and unimolecular decomposition via atomic deuterium loss from the C3 carbon atom. The reaction was overall exoergic, and intermediates and transition states lie lower in energy than the separated reactants, unlocking the reaction of carbon with acetonitrile in low-temperature environments such as cold molecular clouds, e.g., Taurus Molecular Cloud (TMC-1), and planetary atmospheres, e.g., Saturn’s moon Titan. In these environments, the 1-cyanovinyl radical may act as a building block for cyano-substituted polycyclic aromatic hydrocarbons and N-heterocycles, thus furthering our understanding of the complex carbon–nitrogen chemistry in deep space.

Chemical reactions↗

Detection of CO J = 2 goes to 1 emission from the polar rings of NGC 2685 and NGC 4650A

We report the detection of the J = 2 goes to 1 (230 GHz) line of carbon monoxide in the polar rings of the galaxies NGC 2685 and NGC 4650A, and we use the results in a simple analysis of the composition of the neutral interstellar medium therein. Only 17%-35% of the gas mass of the NGC 4650A ring is provided by molecular clouds, perhaps consistent with the conventional picture of the origin of polar rings in the capture of a dwarf galaxy or tidal mass transfer from a spiral galaxy. The polar ring of NGC 2685, however, is quite rich in molecular matter, with an H2 mass greater than the neutral atomic hydrogen mass. Such a composition may be difficult to explain with the picture that applies to NGC 4650A.

Watson, Dan M.↗

Structure and dynamics of amorphous water ice

Further insight into the structure and dynamics of amorphous water ice, at low temperatures, was obtained by trapping in it Ar, Ne, H2, and D2. Ballistic water-vapor deposition results in the growth of smooth, approximately 1 x 0.2 micrometer2, ice needles. The amorphous ice seems to exist in at least two separate forms, at T < 85 K and at 85 < T < 136.8 K, and transform irreversibly from one form to the other through a series of temperature-dependent metastable states. The channels formed by the water hexagons in the ice are wide enough to allow the free penetration of H2 and D2 into the ice matrix even in the relatively compact cubic ice, resulting in H2-(D2-) to-ice ratios (by number) as high as 0.63. The larger Ar atoms can penetrate only into the wider channels of amorphous ice, and Ne is an intermediate case. Dynamic percolation behavior explains the emergence of Ar and Ne (but not H2 and D2) for the ice, upon warming, in small and big gas jets. The big jets, each containing approximately 5 x 10(10) atoms, break and propel the ice needles. Dynamic percolation also explains the collapse of the ice matrix under bombardment by Ar , at a pressure exceeding 2.6 dyn cm-2, and the burial of huge amounts of gas inside the collapsed matrix, up to an Ar-to-ice of 3.3 (by number). The experimental results could be relevant to comets, icy satellites, and icy grain mantles in dense interstellar clouds.

NASA Program Exobiology↗

A new technique for in situ measurement of the composition of neutral gas in interplanetary space

Neutral atoms in interplanetary space play an important role in many processes relevant to the formation and evolution of the Solar System. An experimental approach is proposed for in situ atom detection based on the conversion of neutral atoms to negative ions at a specially prepared sensitive surface. Negative ions are subsequently analyzed and detected in an essentially noise-free mode. The use of the technique for in situ study of the composition of neutral interstellar atoms is considered. It is shown that interstellar H, D, and O atoms and possibly H2 molecules can be measured by the proposed technique. The experiment can be performed from a high-apogee Earth-orbiting satellite or from a deep space probe. Possible applications of the technique are discussed.

Gruntman, Michael A.↗

Interstellar and intergalactic matter and radiation

A brief summary of recent studies of the interstellar medium is given. Most attention is then devoted to a review of the evidence for the presence of intergalactic matter and radiation in the universe. It is concluded that the only important constituents which may make a sizable contribution to the total mass-energy are intergalactic gas and condensed objects with a very high mass-to-light ratio. If the QSOs are not at cosmological distances, cold atomic hydrogen may still be the most important constituent and may contribute much more mass than do the galaxies. The X-ray observations still do not unambiguously show that very hot gas is present, though it is very likely on general grounds that some hot gas is present in clusters of galaxies. The question of whether or not large amounts of matter, enough to close the universe, are present, remains unsettled. From the theoretical standpoint the answer depends almost completely on the approach taken to the problem of galaxy formation and to the cosmological model which is favored.

Burbidge, G. R.↗

Low-mass spiral galaxies with little molecular gas and prodigious star formation

A comparison of CO and H I properties is used here to demonstrate that many CO-poor low-mass Virgo spiral galaxies are rich in atomic gas, which implies that the lack of CO emission from them is due, at least partly, to a lack of molecular gas. Despite the paucity of molecular gas, these H I-rich, CO-poor, low-mass spiral galaxies are undergoing extensive massive star formation. A column density of 10 to the 21st nuclei/sq cm is a necessary but insufficient condition for the creation of an H2-dominated interstellar medium.

Kenney, Jeffrey D.↗