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Hinged cradle-microswitch arrangement maintains a soldering iron at less than peak temperature when not in use. The microswitch introduces a voltage reducing element into the soldering iron power circuit when the iron is placed on the cradle. The iron, when removed from the cradle, returns to operating temperature in 15 to 30 seconds.
Sliding friction and wear experiments were conducted with ternary ordered alloys of iron and cobalt containing various amounts of silicon to 5 weight percent. The friction and wear of these alloys were compared to those for binary iron-cobalt alloys in the ordered and disordered states and to those for the conventionally used bearing material, 440-C. Environments in which experiments were conducted included air, argon, and 0.25percent stearic acid in hexadecane. Results indicate that a ternary iron - cobalt - 5-percent-silicon alloy exhibits lower friction and wear than the simple binary iron-cobalt alloy. It exhibits lower wear than 440-C in all three environments. Friction was lower for the alloy in argon than in air. Auger analysis of the surface of the ternary alloy indicated segregation of silicon at the surface as a result of sliding.
The interaction of sulfur and oxygen with an iron surface was studied with Auger spectroscopy analysis both statically and during sliding-friction experiments in a vacuum environment. Oxygen, hydrogen sulfide, methyl mercaptan, and sulfur dioxide were adsorbed to an iron surface. Results indicate that sulfide films formed on clean iron surfaces are completely displaced by oxygen. Hydrocarbons containing sulfur, such as methyl mercaptan, adsorb dissociatively. Less sulfur is adsorbed during sliding with hydrogen sulfide and methyl mercaptan than in the absence of sliding. With both oxygen and sulfur dioxide, sliding did not affect the amount of material adsorbed to iron.
Review of analytical data on the iron content of Luna 20 anorthitic plagioclase, obtained by a highly sensitive technique for measuring polarized absorption related to crystal-field splittings and by automated electron microprobe analysis of oriented single crystals. The iron content is found to range from a few hundredths to a few tenths of a weight per cent from crystal to crystal. The optical and chemical properties of the iron appear to be caused by postcrystallization migration and exsolution. Postcrystallization effects may obscure evidence of the original oxidation state and iron concentration of these crystals.
An iron surface was exposed to the extreme-pressure type lubricant benzyl chloride, dichlorophenyl phosphine, dichlorophenyl phosphine sulfide, ophenyl phosphine oxide. Iron, in the sputter-cleaned state, was exposed to these materials statically and during dynamic friction experiments. With benzyl chloride only chlorine adsorbed to the surface, and with dichlorophenyl phosphine no adsorption occurred, while the addition of sulfur to that same molecular structure resulted in the promotion of carbon and chlorine adsorption. substitution of oxygen for sulfur in the dichlorobenzyl phosphine molecule resulted in carbon, chlorine, and oxygen adsorption. With none of the phosphorus containing molecules was phosphorus detected on the surface. Sliding in an atmosphere of benzyl chloride promoted adsorption of chlorine to the iron surface. Increases in load resulted in a decrease in the surface concentration of iron chloride.
The times and temperatures for the growth of single-domain to multidomain iron have been determined in a synthetic glass of Apollo 11 composition. All single-domain iron grows to multidomain iron under the following conditions: at 975 C in about 5 hours; at 900 C in about 18 days; at 810 C in about 320 days; and at 700 C in about 1100 years (extrapolated). The results, together with thermal constraints on the metamorphism of lunar breccias, indicate cooling rates of breccias containing single domain iron are appropriate for formation in an ejecta blanket.
A vuggy breccia fragment from sample 67482 contains an iron crystal with a previously unreported crystal form, the trigonal trisoctahedron. The dominant habit is the trapezohedron with smaller cube and trisoctahedron faces. The geometric relationship of the iron crystal to the plagioclase-pyroxene substrate indicates that the iron crystal was the last mineral to form in the vug. The open network of plagioclase and pyroxene crystals lining the vug wall and the iron crystals with well-developed crystal faces suggests growth from a vapor phase.-
The outermost few atomic layers of lunar soil samples were studied by Auger spectroscopy and were found to contain in each case two to three times more iron than the mean bulk composition of the sample. The amount of excess iron is found to be closely correlated with the optical albedo in the manner that would be theoretically expected if the iron provided absorption centers. Crushed lunar rocks of similar mean composition, but lacking the extra iron coating of the soil grains, have a much higher albedo than most lunar soils sampled or observed on the lunar surface.
The permeabilities of protium, deuterium, and tritium in foil specimens of Marz grade iron, 4130 steel, Armco iron, HP-9-4-20, and T-1 steels were studied at hydrogen pressures between 0.02 and 0.5 MPa over the temperature range 260-700 K. The permeability was measured by a pressure-rise method, deuterium counting with a detector, and radioactivity counting. Good agreement is found between the measurement techniques used. It is shown that the permeabilities of protium, deuterium, and tritium in iron and T-1 steel at temperatures as low as 260 K are in good agreement with the equation proposed by Gonzalez (1967). However, the permeabilities of HP-9-4-20 and 4130 steel to hydrogen are typically lower than predicted. The isotope effect on hydrogen permeability of HP-9-4-20, 4130 and T-1 steels, and high-purity iron can be estimated by an inverse square root of mass correction.
Artificial ablation studies were performed on iron and nickel-iron samples using an arc-heated plasma of ionized air. Experiment conditions simulated a meteoroid traveling about 12 km/sec at an altitude of 70 km. The artificially produced fusion crusts and ablation debris show features very similar to natural fusion crusts of the iron meteorites Boguslavka, Norfork, and N'Kandhla and to magnetic spherules recovered from Mn nodules. X-ray diffraction, electron microprobe, optical, and scanning electron microscope analyses reveal that important mineralogical, elemental, and textural changes occur during ablation. Some metal is melted and ablated. The outer margin of the melted rind is oxidized and recrystallizes as a discontinuous crust of magnetite and wustite. Adjacent to the oxidized metallic ablation zone is an unoxidized metallic ablation zone in which structures such as Widmannstatten bands are obliterated as the metal is transformed to unequilibrated alpha 2 nickel-iron. Volatile elements are vaporized and less volatile elements undergo fractionation.
Determinations of the abundances of iron and related elements in the photosphere, chromosphere, and corona of the sun as well as in solar and galactic cosmic rays are reviewed and compared with abundances derived from meteoritic data. Observed solar system abundances are found to be in accord with predictions of nucleosynthesis under either hydrostatic or explosive conditions but cannot yet be used to define these processes uniquely. The distribution of iron among planets and meteorites can probably be adequately modelled by condensation and fragmentation under equilibrium conditions above about 700 K, but below that temperature it is likely that inhibited solid-state diffusion perturbed attainment of equilibrium. Pertinent factors which are presently unknown include the mechanism responsible for metal-silicate fractionation, the grain size achieved by metallic iron in the nebula, and whether iron-bearing silicate formed prior to accretion.
Reflected light microscopy provides information on first-order shock transitions in iron and iron-nickel and permits discrimination of microstructures due to shock transitions from those imparted by thermal transitions. In addition, thin-foil electron microscopy is used to characterize magnetic transitions in fine-particle iron. First-order magnetic phase changes, such as that from the antiferromagnetic face centered cubic state to the ferromagnetic body centered cubic state, are studied with the aim of calibrating the shock and thermal mechanisms of magnetization in iron with a particle size range between 250 and 1200 A. The efficiency of remanence due to shock transition is also estimated.
Sliding friction experiments were conducted with the noble metals copper, silver, and gold and two binary alloys of these metals contacting iron in the presence of various adsorbates including, oxygen, methyl mercaptan, and methyl chloride. A pin on disk specimen configuration was used with a load of 100 grams, sliding velocity of 60 mm/min; at 25 C with the surfaces saturated with the adsorbates. Auger emission spectroscopy was used to monitor surface films. Results of the experiments indicate that friction and transfer characteristics are highly specific with respect to both the noble metal and surface film present. With all three metals and films transfer of the noble metal to iron occurred very rapidly. With all metals and films transfer of the noble metal to iron continuously increased with repeated passes except for silver and copper sliding on iron sulfide.
Sliding friction experiments were conducted with various iron-chromium alloys in contact with (1) themselves, (2) single crystal silicon carbide disks, and (3) single crystal abrasive grit of silicon carbide. Results indicate the coefficients of friction for the alloys sliding against themselves are between those for pure iron and pure chromium, and are only slightly different with 1, 5, 9, 14, and 19 weight percent chromium in iron. The wear is due, primarily, to shearing, or tearing fracture, of the cohesive bonds in the bulk metal and plowing of the bulk by lumps of wear debris. There are only slight differences in the coefficients of friction for the various alloys when sliding on silicon carbide. The coefficient of friction for the alloys are higher than those for pure iron and pure chromium. Alloy hardening observed in the alloys plays a dominant role in controlling the abrasive friction and wear behavior of the alloys.
Sliding friction experiments were conducted with various iron-base binary alloys (alloying elements were Ti, Cr, Mn, Ni, Rh, and W) in contact with a rider of 0.025-millimeter-radius, single-crystal silicon carbide in mineral oil. Results indicate that atomic size and content of alloying element play a dominant role in controlling the abrasive-wear and -friction properties of iron-base binary alloys. The coefficient of friction and groove height (wear volume) general alloy decrease, and the contact pressure increases in solute content. There appears to be very good correlation of the solute to iron atomic radius ratio with the decreasing rate of coefficient of friction, the decreasing rate of groove height (wear volume), and the increasing rate of contact pressure with increasing solute content C. Those rates increase as the solute to iron atomic radius ratio increases from unity.
It is shown that intracluster (IC) iron, whose presence is deduced from observations of an X-ray emission feature in the spectra of some X-ray clusters, could not have sedimented in the cluster core in a Hubble time. It is therefore concluded that the iron and gas are likely to be similarly distributed. Estimates of the total IC iron mass are given, and the possibility that the iron has been convected to the IC space by galactic winds from the visible cluster galaxies is briefly considered.
A summary of the observational evidence of iron lines from satellite X-ray detectors and binary X-ray pulsars is presented. The current theories consider that the continua X-rays from X-ray pulsars originate at or near the surface of neutron stars, and they can then heat or fluoresce iron ions in surrounding physical regions to create the observed emission. Measurements of the line energy, intensity, and width, and the phase dependence of these quantities can help determine the relative importance of contributions of relative sources. The evidence is presented that the iron emission from some sources contains more than one component, and the spectra of other X-ray binaries including transients and cataclysmic variables also contain iron lines. Some implications of the observed line emission are discussed.
The interpretation that the soft X-ray emission of Her X-1 is due to reprocessing of the primary hard X-rays intercepted by a plasma layer in the Alfven surface imposes quite a stringent - but not an unreasonable - constraint on its parameters. By using the Alfven shell parameters constrained by this interpretation, the degree of ionization of the Alfven shell is calculated. Because the flux of hard X-ray from the neutron star is greatly attenuated inside the Alfven shell, except for a skin depth from its inner surface, the degree of ionization is determined by photoionization due to soft X-rays produced within the Alfven shell. On one hand, the large soft X-ray luminosity, which is about the same as the hard X-ray luminosity, indicates that a substantial fraction of primary hard X-rays is absorbed by the Alfven shell. On the other hand, the fact that the hard X-ray spectrum of Her X-1 observed during the high state shows neither a significant absorption feature down to about 3 keV nor an iron K-absorption dip tells us that the hard X-rays observed at the earth are mostly not reprocessed. This apparent conflict is resolved if the Alfven shell is clumpy (i.e., made of streams or blobs). The observed iron-line feature around 6.5 keV (E.W. about 300 keV) is explained by fluorescent iron K photons produced as a by-product of reprocessing of the hard X-rays by the Alfven shell; for this a large enhancement of the iron abundance with respect to the solar value is not required.