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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 181 records · Page 10
All sourcesNASA NTRSDOE OSTI
NASA NTRS1983

Homogeneous processes of atmospheric interest

Upper atmospheric research programs in the department of chemical kinetics are reported. Topics discussed include: (1) third-order rate constants of atmospheric importance; (2) a computational study of the HO2 + HO2 and DO2 + DO2 reactions; (3) measurement and estimation of rate constants for modeling reactive systems; (4) kinetics and thermodynamics of ion-molecule association reactions; (5) entropy barriers in ion-molecule reactions; (6) reaction rate constant for OH + HOONO2 yields products over the temperature range 246 to 324 K; (7) very low-pressure photolysis of tert-bytyl nitrite at 248 nm; (8) summary of preliminary data for the photolysis of C1ONO2 and N2O5 at 285 nm; and (9) heterogeneous reaction of N2O5 and H2O.

Rossi, M. J.↗
NASA NTRS1985

Was core formation violent enough to homogenize the early mantle?

The dynamics of iron, its thermal state and its phase in the accreting Earth probably played a major role in the Earth's early thermal evolution. Plausible impact thermal histories make it possible that pure iron was molten in the accreting Earth after it was about 10% grown. Hence, iron eutectic alloys (FeS, FeO) certainly were. Additionally, the initial temperature of the core is an important constraint on the secular cooling of the early Earth and on the strength of the early geodynamo. Whether iron is solid or molten would influence geochemical equilibria in the upper and lower mantle; the mode of core formation, by spherical or near-spherical blobs, stalk-like instabilities, or something more catastrophic would influence the partitioning of siderophiles between silicate and iron phases. Early descent of iron (during accretion) favors partitioning according to low-pressure phase equilibria, whereas late descent favors higher pressure. The later core formation occurs, the greater the heat pulse, due to the strong dependence of gravitational potential energy on planetary radius. The heat may homogenize the mantle if core formation is global; otherwise, heterogeneity of iron differentiation may leave some of the pre-archean mantle unaffected. The larger the chunks of proto-core (and hence smaller surface/volume ratios) the greater the heterogeneity.

Cooperman, S. A.↗
NASA NTRS1984

Cyclic oxidation behavior of beta+gamma overlay coatings on gamma and gamma+gamma-prime alloys

Detailed experimental studies of the cyclic oxidation behavior of low-pressure plasma sprayed beta+gamma coasting on gamma-phase Ni-Cr-Al alloys have shown the correlation of weight change, oxide type, and Cr and Al concentration-distance profiles as a function of oxidation time. Of special interest was the transition to breakway oxidation due to the loss of the Al flux to the oxide and the failure of the coated alloy to form an Al2O3-rich oxide scale. The experimental results on beta+gamma/gamma coating systems were used as the basis of a numerical model (ternary, semi-infinite, finite-difference analysis) which accurately predicted changes in Cr and Al concentration-distance profiles. The model was used to study parameters critical to enhancing the life of coatings which fail by a combination of Al loss in forming the oxide scale and Al loss via interdiffusion with the substrate alloy. Comparisons of beta+gamma/gamma coating behavior are made to the oxidation of coated gamma+gamma-prime substrates, both ternary Ni-Cr-Al alloys and Mar-M 247-type alloys.

Nesbitt, J. A.↗
NASA NTRS1983

Deposition of silicon nitride from SiCl4 and NH3 in a low pressure RF plasma

Silicon nitride coatings were deposited in a low-pressure (1-10 Torr) RF plasma from SiCl4 and NH3 in the presence of argon onto stainless martensitic steel grounded and floating substrates at 300 C and 440 C respectively. The heating of the substrates depends mainly on the position and the induced RF power. The coatings were identified as silicon nitride by X-ray investigation and were found to contain chlorine by energy-dispersive analysis of X-rays. The growth rate, the microhardness and the chlorine concentration of the coatings were determined as a function of the total gas pressure, the RF power input and the NH3-to-SiCl4 ratio. It was observed that the coatings on the floating substrates have higher deposition rates and are of superior quality.

Ron, Y.↗
NASA NTRS1985

Late-Quaternary climatic change on the American North Pacific Coast

The late Quaternary climate of the North Pacific, where according to modelling the solar radiation in the early Holocene at the time of the summer solstice is high and in the late Holocene is relatively low, is investigated. Quantitative temperature and precipitation estimates from southern Alaska are compared with estimates from western Washington and British Columbia. Data extending over more than 10,000 years show a broadly consistent pattern of climatic change in general agreement with predicted variations in solar radiation and their effect on atmospheric circulation and seasonal duration of pressure systems over the North Pacific Ocean. In the early Holocene, the subtropical North Pacific anticyclone annually regulated climate for a longer period at higher latitudes than at present, so that warmth and dryness increased in southern Alaska. The Aleutian low-pressure center intensified during the late Holocene, resulting in colder and more humid coastal climate and increased frequency of glacier growth in the cordillera.

Heusser, C. J.↗
NASA NTRS1985

Variations in stratospheric aerosol optical depth during northern warmings

In this paper, the properties of the stratospheric aerosol optical depth (above 50 mbar) have been studied by using aerosol extinction profiles (at 1 micron) derived from the Stratospheric Aerosol Measurement and Stratospheric Aerosol and Gas Experiment (SAGE) during warming periods in the Northern Hemisphere. It is shown that, during the disturbed periods in winter, low values of aerosol optical depth (less than 0.0002) are found within the low-pressure system(s) (at the 30-mbar pressure surface), while high values are found outside. Similar characteristics are found to exist for the simultaneously observed SAGE O3 and NO2 columnar density distributions. Strong longitudinal gradients are shown with the low values within and wherever the vortex exists. This characteristic is maintained during and after the circumpolar vortex is disturbed, even after breakdown, indicating an isolation of the material within the vortex.

Wang, P.-H.↗
NASA NTRS1984

Thermal barrier coating life prediction model development

Thermal barrier coatings (TBCs) for turbine airfoils in high-performance engines represent an advanced materials technology that has both performance and durability benefits. In order to achieve these benefits, however, the TBC system must be reliable. Prediction of the lives of two types of strain-tolerant and oxidation-resistant TBC systems that are produced by commercial coating suppliers to the gas turbine industry is examined. The plasma sprayed TBC system, composed of a low-pressure plasma spray (LPPS) applied oxidation resistant NiCrAlY bond coating and an air-plasma-sprayed yttria (8 percent) partially stabilized zirconia insulative layer is applied by both Chromalloy and Klock. The second type of TBC is applied by the electron beam-physical vapor depositon (EB-PVD) process by Temescal.

Strangman, T. E.↗
NASA NTRS1985

Coating life prediction

The investigation combines both experimental studies and numerical modeling to predict coating life in an oxidizing environment. The experimental work provides both input to and verification of two numerical models. The coatings being examined are an aluminide coating on Udimet 700 (U-700), a low-pressure plasma spray (LPPS) Ni-18Co-17Cr-24Al-0.2Y overlay coating also on U- 700, and bulk deposits of the LPPS NiCoCrAlY coating.

Nesbitt, James A.↗
NASA NTRS1957

Nonmetallic Material Compatibility with Liquid Fluorine

Static tests were made on the compatibility of liquid fluorine with several nonmetallic materials at -3200 F and at pressures of 0 and 1500 pounds per square inch gage. The results are compared with those from previous work with gaseous fluorine at the same pressures, but at atmospheric temperature. In general, although environmental effects were not always consistent, reactivity was least with the low-temperature, low-pressure liquid fluorine. Reactivity was greatest with the warm, high-pressure gaseous fluorine. None of the liquids and greases tested was found to be entirely suitable for use in fluorine systems. Polytrifluorochloroethylene and N-43, the formula for which is (C4F9)3N, did not react with liquid fluorine at atmospheric pressure or 1500 pounds per square inch gage under static conditions, but they did react when injected into liquid fluorine at 1500 pounds per square inch gage; they also reacted with gaseous fluorine at 1500 pounds per square inch gage. While water did not react with liquid fluorine at 1500 pounds per square inch gage, it is known to react violently with fluorine under other conditions. The pipe-thread lubricant Q-Seal did not react with liquid fluorine, but did react with gaseous fluorine at 1500 pounds per square inch gage. Of the solids, ruby (Al2O3) and Teflon did not react under the test conditions. The results show that the compatibility of fluorine with nonmetals depends on the state of the fluorine and the system design.

Price, Harold G , Jr↗
NASA NTRS1926

Experimental investigation of the physical properties of medium and heavy oils, their vaporization and use in explosion engines. Part I

While little has been accomplished in obtaining an abundant supply of light oils from coal and heavy oils, progress has been made on engine design to make use of the heavier oils. Progress has been made in two different directions which are outlined in this paper: the group of engines with medium and high-pressure carburetion in the cylinder; and the group of engines with low-pressure carburetion of the heavy oils before reaching the cylinder.

OILS↗
NASA NTRS1940

Stability of Castering Wheels for Aircraft Landing Gears

A theoretical study was made of the shimmy of castering wheels. The theory is based on the discovery of a phenomenon called kinematic shimmy. Experimental checks, use being made of a model having low-pressure tires, are reported and the applicability of the results to full scale is discussed. Theoretical methods of estimating the spindle viscous damping and the spindle solid friction necessary to avoid shimmy are given. A new method of avoiding shimmy -- lateral freedom -- is introduced.

Kantrowitz, Arthur↗
NASA NTRS1953

Aerodynamic Forces and Loadings on Symmetrical Circular-Arc Airfoils with Plain Leading-Edge and Plain Trailing-Edge Flaps

An investigation has been made in the Langley two-dimensional low-turbulence tunnel and in the Langley two-dimensional low-pressure tunnel of 6- and 10-percent-thick symmetrical circular-arc airfoil sections at low Mach numbers and several Reynolds numbers. The airfoils were equipped with 0.15-chord plain leading-edge flaps and 0.20-chord plan trailing-edge flaps. The section lift and pitching-moment characteristics were determined for both airfoils with the flaps deflected individually and in combination. The section drag characteristics were obtained for the 6-percent-thick airfoil with the flaps partly deflected as low-drag-control flaps and for airfoils with the flaps neutral. Surface pressures were measured on the 6-percent-thick airfoil section with the flaps deflected either individually or in appropriate combination to furnish flap load and hinge-moment data applicable to the structural design of the airfoil. A generalized method is developed that permits the determination of the chordwise pressure distribution over sharp-edge airfoils with plain leading-edge flaps and plain trailing-edge flaps of arbitrary size and deflection.

Cahill, Jones F↗
NASA NTRS1931

Effect of viscosity in speed measurements with double-throat Venturi tubes

In order to clarify the viscosity effect some experiments were made in the Gottigen low-pressure tunnel with the Bruhn double-throat Venturi tube. This type of tunnel makes it possible to vary the pressure and thereby the density within wide limits and consequently, to examine the viscosity effect. This, however, did not impair the results because pressure and temperature were determined at different periods.

Peters, H↗
NASA NTRS1959

Review of Aircraft Altitude Errors Due to Static-Pressure Source and Description of Nose-Boom Installations for Aerodynamic Compensation of Error

A brief review of airplane altitude errors due to typical pressure installations at the fuselage nose, the wing tip, and the vertical fins is presented. A static-pressure tube designed to compensate for the position errors of fuselage-nose installations in the subsonic speed range is described. This type of tube has an ogival nose shape with the static-pressure orifices located in the low-pressure region near the tip. The results of wind-tunnel tests of these compensated tubes at two distances ahead of a model of an aircraft showed the position errors to be compensated to within 1/2 percent of the static pressure through a Mach number range up to about 1.0. This accuracy of sensing free-stream static pressure was extended up to a Mach number of about 1.15 by use of an orifice arrangement for producing approximate free-stream pressures at supersonic speeds and induced pressures for compensation of error at subsonic speeds.

Gracey, William↗
NASA NTRS1959

Tire-to-Surface Friction Especially Under Wet Conditions

The results of measurements of the maximum friction available in braking on various runway surfaces under various conditions is shown for a C-123B airplane and comparisons of measurements with a tire-friction cart on the same runways are made. The.results of studies of wet-surface friction made with a 12-inch-diameter low-pressure tire on a tire-friction treadmill, with an automobile tire on the tire-friction cart, and with a 44 x 13 extra-high-pressure type VII aircraft tire at the Langley landing-loads track are compared. Preliminary results of tests on the tire-friction treadmill under wet-surface conditions to determine the effect of the wiping action of the front wheel of a tandem-wheel arrangement on the friction available in braking for the rear wheel are given.

Sawyer, Richard H.↗
NASA NTRS1961

Alignment Charts for Transport Properties Viscosity, Thermal Conductivity, and Diffusion Coefficients for Nonpolar Gases and Gas Mixtures at Low Density

Alignment charts (nomographs) designed to permit rapid calculations of the low-pressure transport properties of nonpolar gases and gas mixtures are presented. Calculations for pure gases are based on the rigorous kinetic theory of gases as applied to a realistic intermolecular force law. Mixture viscosities and conductivities are calculated from good approximations derived from rigorous theory. The properties are calculable with a precision of 2 percent or better. Accuracy depends on how well the constants characterizing the Intermolecular force law are known; if constants are derived from experimental data, results should be accurate to 5 percent or better. Force constants are tabulated for 65 gases.

Brokaw, Richard S.↗
NASA NTRS1985

Simulation of Blunt-Fin-Induced Shock-Wave and Turbulent Boundary-Layer Interaction

The Reynolds-averaged Navier-Stokes equations are solved numerically for supersonic flow over a blunt fin mounted on a flat plate. The fin shock causes the boundary layer to separate. which results in a complicated, three-dimensional shock-wave and boundary-layer interaction. The computed results are in good agreement with the mean static pressure measured on the fin and the flat plate. The main features, such as peak pressure on the fin leading edge and a double peak on the plate. are predicted well. The role of the horseshoe vortex is discussed. This vortex leads to the development of high-speed flow and, hence, low-pressure regions on the fin and the plate. Different thicknesses of the incoming boundary layer have been studied. Varying the thicknesses by an order of magnitude shows that the size of the horseshoe vortex and, therefore, the spatial extent of the interaction are dominated by inviscid flow and only weakly dependent on the Reynolds number. Colored graphics are used to show details of the interaction flow field.

Hung, Ching-Mao↗
NASA NTRS1937

Stability of Castering Wheels for Aircraft Landing Gears, Special Report

In many installations of castering rubber-tired wheels there is a tendency for the wheel to oscillate violently about the spindle axis. This phenomenon, popularly called 'shimmy,' has occurred in some airplane tail wheels and has been corrected in two ways: first by the application of friction in the spindles of the tail wheels; and, second, by locking the wheels while taxiing at high speeds. Shimmy is common with the large wheels used as nose wheels in tricycle landing gears and, since it is impossible to lock the wheels, friction in the nose-wheel spindle has been the sole means of correction. Because the nose wheel is larger than the conventional tail wheel and usually carries a greater load, the larger amounts of spindle friction necessary to prevent shimmy are objectionable. the present paper presents a theoretical and experimental study of the problem of the stability of castering wheels for airplane landing gears. On the basis of simplified assumptions induced from experimental observations, a theoretical study has been made of the shimmy of castering wheels. The theory is based on the discovery of a phenomenon called 'kinematic shimmy' and is compared quantitatively with the results of model experiments. Experimental checks, using a model having low-pressure tires, are reported and the applicability of the results to full scale is discussed. Theoretical methods of estimating the spindle viscous damping and spindle solid friction necessary to avoid shimmy - lateral freedom - is introduced.

Kantrowitz, Arthur↗