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All sources NASA NTRS DOE OSTI

NASA NTRS1987

Self-contained space qualifiable optical contamination monitor

Experiments operating in the VUV as well as those employing cryocooled optical surfaces are the most seriously affected by spacecraft contamination due to outgassing of foreign materials, reaction byproducts of thruster firings, system venting emissions, etc. Attention is presently given to a self-contained optical contamination monitor, furnishing in-flight and/or real-time monitoring of VUV reflectivity and transmittance. The time-lining of measurement results with other spacecraft events will allow the direct evaluation of spacecraft operation effects on critical optical surfaces.

Jarratt, R. V., Jr.↗

NASA NTRS1987

Space station contamination control study: Internal combustion, phase 1

Contamination inside Space Station modules was studied to determine the best methods of controlling contamination. The work was conducted in five tasks that identified existing contamination control requirements, analyzed contamination levels, developed outgassing specification for materials, wrote a contamination control plan, and evaluated current materials of offgassing tests used by NASA. It is concluded that current contamination control methods can be made to function on the Space Station for up to 1000 days, but that current methods are deficient for periods longer than about 1000 days.

Ruggeri, Robert T.↗

NASA NTRS1996

Highly Efficient Molecular Adsorbers

Molecular adsorbers developed to reduce contamination of sensitive optoelectronic components inside housings of scientific instruments. Contaminants stick to surfaces of these devices. Needed in situations in which simply venting contaminants to environment not an option because environment even more contaminating. Useful for variety of purposes in addition to suppressing contamination. Used as collection devices for sensitive total-mass-loss measurements on specimens of materials exhibiting low outgassing or as passive witness plates for collection of contaminants to be analyzed subsequently. Temperature-differential desorption from adsorbers used for preliminary separation of chemical species prior to mass spectroscopy or as alternative to gas chromatography/mass spectroscopy.

Voecks, Gerald E.↗

NASA NTRS2013

Molecular Contamination Investigation Facility (MCIF) Capabilities

This facility was used to guide the development of ASTM E 1559 center dot Multiple Quartz Crystal Microbalances (QCMs), large sample and spectral effects capability center dot Several instrumented, high vacuum chamber systems are used to evaluate the molecular outgassing characteristics of materials, flight components and other sensitive surfaces. Test materials for spacecraft/instrument selection center.Test flight components for acceptable molecular outgas levels center dot Determine time/temperature vacuum bake-out requirements center. Data used to set limits for use of materials and specific components center. Provide Input Data to Contamination Transport Models -Applied to numerous flight projects over the past 20 years.

Soules, David M.↗

NASA NTRS2014

MAVEN Contamination Venting and Outgassing Analysis

Mars Atmosphere and Volatile EvolutioN (MAVEN) is the first mission to focus its study on the Mars upper atmosphere. MAVEN will study the evolution of the Mars atmosphere and climate, by examining the conduit through which the atmosphere has to pass as it is lost to the upper atmosphere. An analysis was performed for the MAVEN mission to address two distinct concerns. The first goal of the analysis was to perform an outgassing study to determine where species outgassed from spacecraft materials would redistribute to and how much of the released material might accumulate on sensitive surfaces. The second portion of the analysis serves to predict what effect, if any, Mars atmospheric gases trapped within the spacecraft could have on instrument measurements when re-released through vents. The re-release of atmospheric gases is of interest to this mission because vented gases from a higher pressure spacecraft interior could bias instrument measurements of the Mars atmosphere depending on the flow rates and directions.

Petro, Elaine M.↗

DOE OSTI2025

Effects of Surface Treatments on the Outgassing of 3D-Printed 316L Stainless Steel.

Fermi National Accelerator Laboratory (Fermilab) is a world leader in designing and operating particle accelerators for nuclear and particle physics research. These accelerators rely on electric fields to propel particle beams, which are then directed and focused using magnetic fields. To ensure these beams travel without interference, they must move through an ultra-high vacuum environment, typically around 10⁻⁹ torr. Maintaining such a vacuum requires materials with exceptionally low outgassing rates. 316L stainless steel is a common material choice for vacuum systems due to its low outgassing rates, excellent corrosion resistance, non-magnetic properties, and high mechanical strength. When manufactured using traditional methods like machining, extrusion, and casting, the vacuum properties of 316L stainless steel are well understood. However, the behavior of 316L stainless steel produced through additive manufacturing, such as Direct Metal Laser Sintering (DMLS), is not as well documented. This study aims to determine the outgassing rate of 316L stainless steel fabricated using DMLS. The investigation focuses on measuring the outgassing rates of 1.5 2 vacuum reducers and evaluating the effects of surface preparation techniques, such as mechanical polishing and electropolishing, on the outgassing performance. Understanding the outgassing performance of 3D-printed 316L stainless steel could enable Fermilab engineers to adopt this fabrication method for producing complex parts designed for ultra-high vacuum environments. These advancements have the potential to benefit projects, such as the Long-Baseline Neutrino Facility (LBNF) and the Proton Improvement Plan-II (PIP-II), by improving design flexibility and fostering innovation in accelerator development.

Cloud, Jaiden [Central State University]↗

NASA NTRS1974

Performance of solar shields

The loss of the micrometeoroid shield from the Orbital Workshop section of Skylab 1 about 63 seconds after lift-off, was the catalyst for a prodigious effort to develop a substitute for the passive portion of the thermal control system. An intensive effort is described in which numerous potential thermal shield materials were assessed, and during which period ten specific shield designs were developed and carried through various stages of development and test. Thermal shield materials data are discussed, including optical, strength, fatigue, outgassing, tackiness, ultraviolet radiation, and material memory properties. Specifically addressed are thermal shield materials selection criteria and the design, development, and test requirements associated with the successful development of Skylab thermal shields, and specifically the two thermal shields subsequently deployed over the exposed gold foil skin of the Orbital Workshop. Also considered are the general performance and thermal improvements provided by both the parasol design deployed by the Skylab 1 crew, and the sail design deployed by the Skylab 2 crew.

Schwinghamer, R. J.↗

NASA NTRS1975

Performance of solar shields

The loss of the micrometeoroid shield from the Orbital Workshop section of Skylab I, about 63 seconds after lift-off, proved to be the harbinger of a prodigious effort to quickly develop a workable substitute for the carefully tailored passive portion of the thermal-control system. The paper describes the intensive ten-day around-the-clock effort in which numerous potential thermal-shield materials were assessed, and during which period ten specific shield designs were developed and carried through various stages of development and test. Thermal-shield materials data are discussed, including optical, strength, fatigue, outgassing, tackiness, ultraviolet radiation, and material 'memory' properties.

Schwinghamer, R. J.↗

NASA NTRS2000

Material Total Mass Loss in Vacuum Obtained From Various Outgassing Systems

Several instruments including the Cahn Microbalance, the Knudsen Cell, the micro-CVCM, and the vacuum Thermogravimetric Analyzer (TGA) were used in the testing of a graphite/epoxy (GR/EP) composite that is proposed for use as a rigidizing element of an inflatable deployment system. This GR/EP will be cured in situ. The purpose of this testing is to estimate the gaseous production resulting from the curing of the GR/EP composite, to predict the resulting pressure, and to calculate the required venting. Every test was conducted under vacuum at 125 degrees C for 24 hours. Upon comparison of the results, the ASTM E-595 was noted to have given readings that were consistently lower than those obtained using the other instruments, which otherwise provided similar results. The GR/EP was tested using several different geometric arrangements. This paper describes the analysis evaluating the molecular and continuum flow of the outgassing products issuing from the exit port of the ASTM E-595 system. The effective flow conductance provided by the physical dimensions of the vent passage of the ASTM E-595 system and that of the material sample among other factors were investigated to explain the reduced amount of outgassing released during the 24-hour test period.

Scialdone, John↗

NASA NTRS2006

Insitu Calibration of Quartz Crystal Microbalances

Computer models that predict the rate at which molecular contamination will deposit on optical surfaces typically use outgassing source terms, measured with quartz crystal microbalances, as a basis for the prediction. The American Society of Testing and Materials, Standard Test Method for Contamination Outgassing Characteristics of Spacecraft Materials (Method E-1559), is probably the best know technique used by the aerospace community to measure the outgassing rates or source terms of materials. A simple method for the insitu calibration of quartz crystal microbalances, based on the heat of enthalphy of Adipic Acid, has been developed and demonstrated by the Marshall Space Flight Center, Environmental Effects Group. The calibration has been demonstrated over a sample temperature range of 25 to 66 degrees Celsius and deposition rates of 7 x 10 (exp -11) grams/cm(sup 2)-s and greater, for several measurement system configurations. This calibration technique is fully compatible with the American Society for Testing and Materials, Method E-1559, as well as other methodology. The calibration requires no modification of outgassing facilities employing an effusion cell and does not degrade the performance or function of typical vacuum systems.

Albyn, Keith↗

NASA NTRS1980

Nonmetallic materials contamination studies

In order to impose adequate contamination control requirements in the selection of Wide Field Planetary Camera (WFPC) materials and to develop a data base of potential optical degradation of the WFPC charge-couple device window, the outgassing properties of WFPC materials and the collected volatile condensed material (CVCM) effects on MgF2 transmittance were measured. Changes in the transmittance were monitored in the wavelength region from 115 nm to 300 nm for selected CVCM thicknesses up to 150 nm. The outgassing properties of reemitted CVCM were also studied.

Muscari, J. A.↗

NASA NTRS2005

Materials Chemistry Issues in the Development of a Single-Crystal Solar/Thermal Refractive Secondary Concentrator

A translucent crystal concentrates and transmits energy to a heat exchanger, which in turn heats a propellant gas, working gas of a dynamic power system, or a thermopile. Materials are the limiting issue in such a system. Central is the durability of the crystal, which must maintain the required chemical, physical/optical, and mechanical properties as it is heated and cooled. This report summarizes available data to date on the materials issues with this system. We focus on the current leading candidate materials, which are sapphire (Al2O3) for higher temperatures and silica (SiO2) for lower temperatures. We use data from thermochemical calculations; laboratory coupon tests with silica and sapphire; and system tests with sapphire. The required chemical properties include low-vapor pressure and interfacial stability with supporting structural materials. Optical properties such as transmittance and index of refraction must be maintained. Thermomechanical stability is a major challenge for a large, single-crystal ceramic and has been discussed in another report. In addition to the crystal, other materials in the proposed system include refractory metals (Nb, Ta, Mo, W, and Re), carbon (C), and high-temperature ceramic insulation. The major issue here is low levels of oxygen, which lead to volatile refractory metal oxides and rapid consumption of the refractory metal. Interfacial reactions between the ceramic crystal and refractory metal are also discussed. Finally, high-temperature ceramic insulating materials are also likely to be used in this system. Outgassing is a major issue for these materials. The products of outgassing are typically reactive with the refractory metals and must be minimized.

Jacobson, Nathan S.↗

NASA NTRS1990

The growth of zinc selenide single crystals by physical vapor transport in microgravity

Growth and characterization studies will be performed on zinc selenide single crystals. The high temperature outgassing behavior of the silica ampoule material will be studied in order to develop a cleaning and bake-out procedure that will minimize the amount of impurities introduced into the vapor from the ampoule materials and in particular during the seal-off procedure. The outgassing behavior of the ZnSe starting material will be studied during high vacuum refinement at elevated temperatures in order to develop a temperature pressure program that will optimize the removal of impurities while minimizing a shift in stoichiometry due to preferred evaporation of the higher fugacity component. The mass spectrometer system was completed, and after calibration, will be used to perform the above tasks. The system and its operation is described in detail.

Anderson, Elmer E.↗

NASA NTRS1982

J series thruster thermal test results

Test experience with J series ion thrusters have indicated that the present thruster design may result in excessive temperatures in areas which utilize organic materials such as wire insulation, with the resultant outgassing and potential contamination of insulating materials. Further, it appears that thermal data obtained with earlier thruster designs, such as the 700 series thruster, may not be directly applicable to the J series design. Two J series thrusters were fitted with thermocouples and critical temperatures measured for a variety of configurations and operating parameters. Completely enclosing the thruster to reduce facility contamination significantly increased temperatures prompting the selection of a compromise geometry for life testing. The operating parameter having the largest effect on temperatures was discharge power, while beam power affected little else than extraction system temperatures. Several off-normal operating modes were also investigated. Data believed to be sufficient to effectively modify existing thermal models were obtained from the tests.

Bechtel, R. T.↗

NASA NTRS1982

Effect of vacuum processing on outgassing within an orbiting molecular shield

The limiting hydrogen number density in an orbiting molecular shield is highly dependent on the outgassing rates from the materials of construction for the shield, experimental apparatus, and other hardware contained within the shield. Ordinary degassing temperatures used for ultrahigh vacuum studies (less than 450 C) are not sufficient to process metals so that the contribution to the number density within the shield due to outgassing is less than the theoretically attainable level (approximately 200 per cu. cm). Pure aluminum and type 347 stainless steel were studied as candidate shield materials. Measurements of their hydrogen concentration and diffusion coefficients were made, and the effects of high temperature vacuum processing (greater than 600 C) on their resulting outgassing rates was determined. The densities in a molecular shield due to the outgassing from either metal were substantially less ( 0.003) than the density due to the ambient atomic hydrogen flux at an orbital altitude of 500 km.

Outlaw, R. A.↗

DOE OSTI2022

Outgassing of casted and 3D printed silicones

Outgassing of 3D printed and casted silica-filled silicones was studied using a standard ASTM E-595 procedure and a modified Soreq’s method that allows very sensitive measurements of the outgassing kinetics even at low temperatures, 20 – 50 °C. We studied three different silica-filled silicones, non-porous cased M9787, and 3D printed LL50 and 40P materials. The present report shows that vacuum outgassing products of polysiloxane-based materials include multiple species. In addition to chemisorbed and physisorbed water outgassing, previously studied by TPD, polymer fragments of varying sizes evaporate as well. The chemical composition of the condensable volatile species collected on a Germanium substrate, was analyzed by FTIR. It was shown that all studied materials produce mostly PDMS-based outgassing products that form stable droplet-like structure on the Ge substrate. The highest amount of the condensable volatile species was measured for LL50. Isothermal TGA in nitrogen atmosphere of the LL50 material was compared to the standard vacuum outgassing. The results of TGA showed lower mass loss and higher water regain. The kinetics of the outgassing at relatively low temperatures of 20, 30 and 50 °C was studied using Thermoelectric Quartz Crystal Microbalance (TQCM). The TQCM surface was held at -10 °C to enhance condensation of the outgassed moisture. The analysis presented here, when combined with the extensive previous work on moisture outgassing, provides a better understanding of the aging mechanism of polysiloxane-based materials. In this work we show that outgassing techniques, usually applied for qualification of polymers for space-related applications, may be used as a complementary method to study thermal degradation and aging of silica-based silicones. Our results indicate that the long-term degradation mechanics and thermal degradation products depend primarily on the chemical composition of silicone-based material and only slightly affected by the manufacturing process. Surprisingly, the surface-to-volume ratio of the 3D printed vs. casted/molded materials showed only minor effect on the outgassing kinetic parameters.

36 MATERIALS SCIENCE↗

NASA NTRS1972

The effect of ambient pressure on the evaporation rate of materials

A simple expression is obtained using a diffusion model for the effect of ambient pressure on the outgassing or evaporation rate of materials. The correctness of the expression is demonstrated by comparing the estimates from this expression with actual weight loss measurements. It is shown that the rate of mass loss is governed by the ratio of mean free path to the characteristic dimension of the surface in question.

Naumann, R. J.↗

NASA NTRS2009

Light-Curing Adhesive Repair Tapes

Adhesive tapes, the adhesive resins of which can be cured (and thereby rigidized) by exposure to ultraviolet and/or visible light, are being developed as repair patch materials. The tapes, including their resin components, consist entirely of solid, low-outgassing, nonhazardous or minimally hazardous materials. They can be used in air or in vacuum and can be cured rapidly, even at temperatures as low as -20 C. Although these tapes were originally intended for use in repairing structures in outer space, they can also be used on Earth for quickly repairing a wide variety of structures. They can be expected to be especially useful in situations in which it is necessary to rigidize tapes after wrapping them around or pressing them onto the parts to be repaired.

Allred, Ronald↗