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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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NASA NTRS1996

Infrared, Submillimeter, and RadioAstronomy Program Astophysics Division

The object of my research for the NASA grant NAGW-4769 was to observe infrared spectra of molecular ions with special astrophysical interest in plasmas both in the laboratory and in space. Progress made during the period from September 1995 to September 1996 is summarized in the following: 1. Detection of Interstellar H3(+) The discovery of interstellar H3(+) through its mid-infrared absorption spectrum was by far the most inspiring development during this fiscal year. H3(+), the simplest stable polyatomic system, has been postulated to play the central role in the ion-neutral reaction scheme of interstellar chemistry, but its presence had not been directly observed in spite of intensive searches by several groups. 2. Observation of High Revibrational States of H3(+). The initial discovery of H3(+) in the Jovian aurora region was made through the identification of the 2(nu)(sub 2)(sup 2) approaches O overtone band indicating the population of H3(+) in high revibration state. 3. Observation of Ortho-Para H3(+) selection rules in plasma chemistry. Celection rules that relate quantum states before and ufter various processes are fascinating subject based on the symmetry argument. 4. Spectroscopy of other ions. Spectroscopy of carbocations ch3(+), CH2(+), C2H3(+) and C2H2(+) has been continued.

Oka, Takeshi↗
NASA NTRS1995

Infrared Spectroscopy of Matrix-Isolated Polycyclic Aromatic Hydrocarbon Cations: The Members of the Thermodynamically Most Favorable Series through Coronene - Part 2

Gaseous, ionized polycyclic aromatic hydrocarbons (PAHS) are thought to be responsible for a very common family of interstellar infrared emission bands. Here the near- and mid-infrared spectra of the cations of the five most thermodynamically favored PAHs up to coronene: phenanthrene, pyrene, benzo[e]pyrene, benzo-[ghi]perylene, and coronene, are presented to test this hypothesis. For those molecules that have been studied previously (pyrene, pyrene-d(sub 10), and coronene), band positions and relative intensities are in agreement. In all of these cases we report additional features. Absolute integrated absorbance values are given for the phenanthrene, perdeuteriophenanthrene, pyrene, benzo[ghi]perylene, and coronene cations. With the exception of coronene, the cation bands corresponding to the CC modes are typically 2-5 times more intense than those of the CH out-of-plane bending vibrations. For the cations, the CC stretching and CH in-plane bending modes give rise to bands that are an order of magnitude stronger than those of the neutral species, and the CH out-of-plane bends produce bands that are 5-20 times weaker than those of the neutral species. This behavior is similar to that found in most other PAH cations studied to date. The astronomical implications of these PAH cation spectra are also discussed.

Hudgins, D. M.↗
NASA NTRS1996

Spectral Irradiance Calibration in the Infrared. 7. 5-14 microns Spectroscopy of the Asteroids Ceres, Vesta, and Pallas

We describe our efforts to seek "closure" in our infrared absolute calibration scheme by comparing spectra of asteroids, absolutely calibrated through reference stars, with "Standard Thermal Models" and "Thermophysical Models" for these bodies. Our use of continuous 5-14 microns airborne spectra provides complete sampling of the rise to, and peak, of the infrared spectral energy distribution and constrains these models. Such models currently support the absolute calibration of ISO-PHOT at far-infrared wave- lengths (as far as 300 microns), and contribute to that of the Mid-Infrared Spectrometer on the "Infrared Telescope in Space" in the 6-12 microns region. The best match to our observed spectra of Ceres and Vesta is a, standard thermal model using a beaming factor of unity. We also report the presence of three emissivity features in Ceres which may complicate the traditional model extrapolation to the far-infrared from contemporaneous ground-based N-band photometry that is used to support calibration of, for example, ISO-PHOT. While identification of specific materials that cause these features is not made, we discuss families of minerals that may be responsible.

Cohen, Martin↗
NASA NTRS1998

Sensitivity of the terrestrial planet finder

A key long-term goal of NASA's Origins program is the detection and characterization of habitable planets orbiting stars within the solar neighborhood. A cold, space-borne interferometer operating in the mid-infrared with a approx. 75 m baseline can null the light of a parent star and detect the million-times fainter radiation from an Earth-like planet located in the "habitable zone" around stars as far as 15 pc away. Such an interferometer, designated the Terrestrial Planet Finder (TPF) by NASA, could even detect atmospheric signatures of species such as CO2, O3, and H2O indicative of either the possibility or presence of primitive life. This talk highlights some of the sensitivity issues affecting the detectability of terrestrial planets. Sensitivity calculations show that a system consisting of 2 m apertures operating at 5 AU or 4 m apertures operating at 1 AU can detect terrestrial planets in reasonable integration times for levels of exo-zodiacal emission up to 10 times that seen in our solar system (hereafter denoted as 10xSS). Additionally, simulations show that confusion noise from structures in the exo-zodiacal cloud should not impede planet detection until the exo-zodiacal emission reaches the 10xSS level.

Beichman, Charles↗
NASA NTRS1998

IRTS observation of zodiacal light and emission

We present the infrared spectrum of the zodiacal light and emission obtained by the Near-Infrared Spectrometer (NIRS) and Mid-Infrared Spectrometer (MIRS) onboard the Infrared Telescope in Space (IRTS). The wavelength coverages and spectral resolutions are 1.4-4.0 microns and 0.12 microns for the NIRS, and 4.5-11.7 microns and 0.23-0.36 microns for the MIRS respectively. Both instruments have the same beam size of 8 arcminutes square. The IRTS observations were made for 1995 March 29 - April 26. Here we present the data of two days, April 19 and April 20.

Matsumoto, T.↗
NASA NTRS1996

Modeling of the Dust and Gas Outflows from OH 26.5+0.6: The Superwind

We have observed the extreme OH/IR star, OH 26.5+0.6, in the infrared dust continuum and in the sub- millimeter rotational lines of CO. Mid-infrared images reveal the compact nature of the circumstellar shell (less than 0.5 sec). A deep 9.7 microns absorption feature and an absorption at 18 microns show that the dust mass-loss rate is very high. However, the low antenna temperatures of CO J = 1-0 and 2-1 lines suggest that the outer part of the circumstellar shell is much more tenuous. In order to resolve this discrepancy, we have observed the J = 3-2 and 4-3 CO rotational transitions. We have developed a model for the circumstellar shell for OH 26.5 + 0.6 which is consistent with the infrared and submillimeter observations. The dust and gas data are well fitted by a two-shell model, consisting of a dense shell surrounded by a more tenuous shell. The former we identify with the superwind (M = 5.5 x 10(exp -4) solar mass/ yr), and the latter we identify with mass loss on the asymptotic giant branch (AGB) (M = 10(exp -6) solar mass/ yr). The transition between the two mass-loss phases is shown to be rather abrupt ((Delta)t less than 150 yr). Depending on the mass of the progenitor, this superwind phase may be the last thermal pulse (for M(sub *) less than 1.5 solar mass), or the first of a series of the superwind phases (for up to 8 solar mass), punctuated by a period of low mass-loss rates, before the star evolves off the AGB.

Justtanont, K.↗
NASA NTRS1998

Alignment and Polarization Sensitivity Study for the Cassini-Composite InfraRed Spectrometer (CIRS) Far InfraRed (FIR) Interferometer

The Composite InfraRed Spectrometer (CIRS) instrument flying on the Cassini spacecraft to Saturn is a cryogenic spectrometer with far-infrared (FIR) and mid-infrared (MIR) channels. The CIRS FIR channel is a polarizing interferometer that contains three polarizing grid components. These components are an input polarizer, a polarizing beamsplitter, and an output polarizer/analyzer. They consist of a 1.5 micron thick mylar substrate with 2 gm wide copper wires, with 2 gm spacing (4 micron pitch) photolithographically deposited on the substrate. This paper details the polarization sensitivity studies performed on the output polarizer/analyzer, and the alignment sensitivity studies performed on the input polarizer and beamsplitter components in the FIR interferometer.

Crooke, Julie A.↗
NASA NTRS1998

Maintaining Flatness of a Large Aperture Potassium Bromide Beamsplitter Through Mounting and Vibration

The Composite Infrared Spectrometer (CIRS) instrument on the Cassini Mission launched in October of 1997. The CIRS instrument contains a mid-infrared (MIR) and a far-infrared interferometer (FIR) and operates at 170 Kelvin. The MIR is a Michelson Fourier transform spectrometer utilizing a 76 mm (3 inch) diameter potassium bromide beamsplitter and compensator pair. The potassium bromide elements were tested to verify effects of cooldown and vibration prior to integration into the instrument. The instrument was then aligned at ambient temperatures, tested cryogenically and re-verified after vibration. 'Me stringent design optical figure requirements for the beamsplitter and compensator included fabrication errors, mounting stresses and vibration load effects. This paper describes the challenges encountered in mounting the elements to minimize distortion and to survive vibration.

Losch, Patricia↗
NASA NTRS1996

ISO Observations of Starless Bok Globules: Usually No Embedded Stars

We have used ISOCAM to search the cores of a sample of small Bok globules previously classified to be mostly starless based on analysis of IRAS data. The ISO observations at 6.75microns (LW2 filter) and 14.5microns (LW3 filter) were sufficiently deep to enable detection of any low-mass hydrogen burning star or young stellar object (YSO) embedded in these globules. Of the 20 Bok globules observed by ISOCAM to date, we have reduced the data for 14. Of these, 13 show no evidence for faint red (S(sub v)(LW3) greater than S(sub v)(LW2)) stars missed by IRAS. One (CB68) does show the first mid-infrared detection of the very cool IRAS source toward this cloud, and may be a Class I or 0 YSO. We conclude, based on these new ISO observations, that Bok globules which have no IRAS sources are in general bona fide starless molecular clouds.

Clemens, D.↗
NASA NTRS1998

Remote Sensing of Tropospheric Aerosols from Space: Past, Present, and Future

Aerosol particles originate from man-made sources such as urban/industrial activities,rurning associated with land use processes, wind-blown dust, and natural sources. Their interaction with sunlight and their effect on cloud microphysics forms a major uncertainty in predicting climate change. Furthermore, the lifetime of only a few days causes high spatial variability in aerosol optical and radiative properties that requires global observations from space. Remote sensing of aerosol properties from space is reviewed both for present and planned national and international satellite sensors. Techniques that are being used to enhance our ability to characterize the global distribution of aerosol properties include well-calibrated multispectral radiometers, multispectral polarimeters, and multi-angle spectroradiometers. Though most of these sensor systems rely primarily on visible to mid-infrared spectral channels, the availability of of thermal channels to aid in cloud screening is an important additional piece of information that is not always incorporated into the sensor design. In this paper we describe the various satellite sensor systems being developed by Europe, Japan, and the U.S., and highlight the advantages and disadvantages of each of these systems for aerosol applications. An important underlying theme is that the remote sensing of aerosol properties, especially aerosol size distribution and single scattering albedo, is exceedingly difficult. As a consequence, no one sensor system is capable of providing totally unambiguous information, and hence a careful intercomparison of derived products from different sensors, together with a comprehensive network of ground-based sun-photometer and sky radiometer systems, are required to advance our quantitative understanding of global aerosol characteristics.

King, Michael D.↗
NASA NTRS1998

A Very High Resolution Mid Infrared Spectrograph for SOFIA

The purpose of this project was to study the design of a high resolution mid-infrared spectrograph for the SOFIA airborne observatory. The primary motivation for the construction and use of such an instrument is the study of vibrational transitions of molecules in molecular clouds, circumstellar inflows and outflows, and planetary atmospheres, which are blocked from ground-based observations by absorption by the Earth's atmosphere. The instrument design studied is a cross-dispersed grating spectrograph with several modes of operation giving spectral resolving powers of approximately 4000, 20,000, and 100,000. In the two lower resolution modes a single grating is used in a long-slit spectrograph. At high resolution that grating serves as the cross-disperser for a 1-m long echelon, a very coarsely and steeply ruled grating, diamond-machined in aluminum. Several design study tasks were carried out: 1. An optical and mechanical design was developed. It differed from the preliminary design by using a reflecting focal reducer in the fore-optics and by rearranging the echelon and cross-dispersing chambers to improve the efficiency of the long-slit modes. 2. A finite-element analysis of the dewar and echelon support structures was done. It led us to change the echelon support to improve its rigidity. 3. Further information was obtained which convinced us that Hyperfine Inc. was capable of diamond-machining the echelon. 4. Several possible vendors of readout electronics and software were identified. It was decided that it is more cost-effective to purchase these items rather than developing them ourselves. 5. Observing and calibration procedures were studied. we did not identify significant changes needed from procedures used previously. 6. Possible expansions of instrument capabilities, including wavelength coverage, were studied. It appears unlikely that the echelon will perform well at wavelengths shortward of 5 microns, but the spectral coverage could be extended longward of 28 microns with the use of an Si:Sb detector. No patentable inventions were made during this study. Based on this design study, a proposal was submitted to construct the instrument. It was chosen as one of the first-light instruments for SOFIA.

Lacy, John H.↗
NASA NTRS1998

Alignment and Polarization Sensitivity Study on the Cassini: CIRS FIR Interferometer

The Composite InfraRed Spectrometer (CIRS) instrument flying on the Cassini spacecraft to Saturn is a cryogenic spectrometer with far-infrared (FIR) and mid-infrared (MIR) channels. The CIRS FIR channel is a polarizing interferometer that contains three polarizing grid components. These components are an input polarizer, a polarizing beamsplitter, and an output polarizer/analyzer. They consist of a 1.5 micron thick mylar substrate with 2 microns wide copper wires, with 2 microns spacing (4 microns pitch) photolithographically deposited on the substrate. This paper details the alignment sensitivity studies performed on the polarizing beamsplitter, and the polarization sensitivity studies performed on all three polarizing components in the FIR interferometer.

Crooke, Julie↗
NASA NTRS1994

Infrared Spectroscopy of Polycyclic Aromatic Hydrocarbon Cations: The Members - 3

In spite of the fact that the infrared spectroscopic properties of only a few isolated ionized polycyclic aromatic hydrocarbons (PAHs) are known, gaseous, ionized PAHs are thought to be responsible for a very common family of infrared interstellar emission bands. In order to provide a data base to test this hypothesis and, if borne out, to use this emission band family as a probe of many different interstellar environments, we are carrying out a thorough study of the infrared spectroscopic properties of neutral and ionized PAHs in argon matrices. Here we present the near and mid-infrared spectra of the cations of the five most thermodynamically favored PAHs up to coronene: phenanthrene, pyrene, benzo[e]pyrene, benzo[ghilperylene, and coronene. The properties of naphthalene, the first member of the series, are given elsewhere. The spectra of perdeuterated phenanthrene and pyrene are also reported. For those molecules which have been previously studied (pyrene, d(10)-pyrene, and coronene), band positions and relative intensities are in agreement. In all cases we report additional features. Absolute integrated absorbance values are given for the phenanthrene, perdeutero-phenanthrene, pyrene, benzo[ghi]perylene, and coronene cations. With the exception of coronene,the cation bands corresponding to the CC modes are typically 2-5 times more intense than those of the CH out-of-plane bending vibrations. For the cations the CC stretching and CH in-plane bending modes give rise to bands which are an order of magnitude stronger than for the neutral species, and the CH out-of-plane bends produce bands which are 5-20 times weaker than in the neutral species. This behavior is similar to that found in most other PAH cations studied to date. The astronomical implications of these PAH cation spectra are also discussed.

Hudgins, D. M.↗
NASA NTRS1997

Infrared Fiber Optic Sensors

Successive years of Small Business Innovation Research (SBIR) contracts from Langley Research Center to Sensiv Inc., a joint venture between Foster-Miller Inc. and Isorad, Ltd., assisted in the creation of remote fiber optic sensing systems. NASA's SBIR interest in infrared, fiber optic sensor technology was geared to monitoring the curing cycles of advanced composite materials. These funds helped in the fabrication of an infrared, fiber optic sensor to track the molecular vibrational characteristics of a composite part while it is being cured. Foster-Miller ingenuity allowed infrared transmitting optical fibers to combine with Fourier Transform Infrared spectroscopy to enable remote sensing. Sensiv probes operate in the mid-infrared range of the spectrum, although modifications to the instrument also permits its use in the near-infrared region. The Sensiv needle-probe is built to be placed in a liquid or powder and analyze the chemicals in the mixture. Other applications of the probe system include food processing control; combustion control in furnaces; and maintenance problem solving.

Source record↗
NASA NTRS1995

Infrared spectroscopy of matrix-isolated polycyclic aromatic hydrocarbon cations. 2. The members of the thermodynamically most favorable series through coronene

Gaseous, ionized polycyclic aromatic hydrocarbons (PAHs) are thought to be responsible for a very common family of interstellar infrared emission bands. Here the near- and mid-infrared spectra of the cations of the five most thermodynamically favored PAHs up to coronene:phenanthrene, pyrene, benzo[e]pyrene, benzo[ghi]perylene, and coronene, are presented to test this hypothesis. For those molecules that have been studied previously (pyrene, pyrene-d10, and coronene), band positions and relative intensities are in agreement. In all of these cases we report additional features. Absolute integrated absorbance values are given for the phenanthrene, perdeuteriophenanthrene, pyrene, benzo[ghi]perylene, and coronene cations. With the exception of coronene, the cation bands corresponding to the CC modes are typically 2-5 times more intense than those of the CH out-of-plane bending vibrations. For the cations, the CC stretching and CH in-plane bending modes give rise to bands that are an order of magnitude stronger than those of the neutral species, and the CH out-of-plane bends produce bands that are 5-20 times weaker than those of the neutral species. This behavior is similar to that found in most other PAH cations studied to date. The astronomical implications of these PAH cation spectra are also discussed.

NASA Discipline Exobiology↗
NASA NTRS1998

Observations of CH4, C2H6, and C2H2 in the stratosphere of Jupiter

We have performed high-resolution spectral observations at mid-infrared wavelengths of CH4 (8.14 micrometers), C2H6 (12.16 micrometers), and C2H2 (13.45 micrometers) on Jupiter. These emission features probe the stratosphere of the planet and provide information on the carbon-based photochemical processes taking place in that region of the atmosphere. The observations were performed using our cryogenic echelle spectrometer CELESTE, in conjunction with the McMath-Pierce 1.5-m solar telescope between November 1994 and February 1995. We used the methane observations to derive the temperature profile of the jovian atmosphere in the 1-10 mbar region of the stratosphere. This profile was then used in conjunction with height-dependent mixing ratios of each hydrocarbon to determine global abundances for ethane and acetylene. The resulting mixing ratios are 3.9(+1.9)(-1.3) x 10(-6) for C2H6 (5 mbar pressure level), and 2.3 +/- 0.5 x 10(-8) for C2H2 (8 mbar pressure level), where the quoted uncertainties are derived from model variations in the temperature profile which match the methane observation uncertainties. c1998 Academic Press.

Jupiter↗
NASA NTRS1997

Deep 12 and 25 Micron Imaging with the Wide Field Infrared Explorer

The Wide Field Infrared Explorer is a new NASA Small Explorer class observatory to be launced in late 1998. It will survey hundreds of square degrees of high latitude sky in the mid-infrared 12 and 25 micron bands to flux densities up to a factor of 1000 better than IRAS.

Micron Imaging Wide Field Infrared Explorer lumino↗
NASA NTRS1996

ISOCAM* Observations of NGC 6946: Mid-IR Structure

The nearby spiral galaxy NGC 6946 was observed with ISO-CAM in the mid-infrared, achieving 7inch resolution and sub-MJy sr(sup -1) sensitivity. Images taken with CAM filters LW2 (7(micro)m) and LW3 (15(micro)m) are analyzed to determine the morphology of this galaxy and understand beter the emission mechanisms.

Infrared galaxies morphology individual galaxies N↗