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NASA NTRS2005

Convective Formation of Pileus Cloud Near the Tropopause

Pileus clouds form where humid, stably stratified air is mechanically displaced vertically ahead of rising convection. This paper describes convective formation of pileus cloud in the tropopause transition layer (TTL), and explores a possible link to the formation of long-lasting cirrus at cold temperatures. In-situ measurements from off the coast of Honduras during the July 2002 CRYSTALFACE experiment show an example of TTL cirrus associated with, and penetrated by, deep convection. The cirrus was enriched with total water compared to its surroundings, but composed of extremely small ice crystals with effective radii between 2 and 4 m. Through gravity wave analysis, and intercomparison of measured and simulated cloud microphysics, it is argued that the TTL cirrus in this case originated neither from convectively-forced gravity wave motions nor environmental mixing alone. Rather, it is hypothesized that some combination was involved in which, first, convection forced pileus cloud to form from TTL air; second, it punctured the pileus layer, contributing larger ice crystals through interfacial mixing; third, the addition of condensate inhibited evaporation of the original pileus ice crystals in the warm phase of the ensuing gravity wave; fourth, through successive pulses, deep convection formed the observed layer of TTL cirrus. While the general incidence and longevity of pileus cloud remains unknown, in-situ measurements, and satellite-based Microwave Limb Sounder retrievals, suggest that much of the tropical TTL is sufficiently humid to be susceptible to its formation. Where these clouds form and persist, there is potential for an irreversible repartition from water vapor to ice at cold temperatures.

Garrett, Timothy J.↗

DOE OSTI2024

The generation of a multiphase medium in ‘Splash’ bridge systems: towards an understanding of star formation suppression in turbulent galaxy systems

ABSTRACT Cloud–cloud collisions in splash bridges produced in gas-rich disc galaxy collisions offer a brief but interesting environment to study the effects of shocks and turbulence on star formation rates in the diffuse intergalactic medium, far from the significant feedback effects of massive star formation and active galactic nucleus. Expanding on our earlier work, we describe simulated collisions between counter-rotating disc galaxies of relatively similar mass, focusing on the thermal and kinematic effects of relative inclination and disc offset at the closest approach. This includes essential heating and cooling signatures, which go some way towards explaining the luminous power in H$_2$ and [C ii] emission in the Taffy bridge, as well as providing a partial explanation of the turbulent nature of the recently observed compact CO-emitting clouds observed in Taffy by the Atacama Large Millimeter Array (ALMA). The models show counter-rotating disc collisions result in swirling, shearing kinematics for the gas in much of the post-collision bridge. Gas with little specific angular momentum due to collisions between counter-rotating streams accumulates near the centre of mass. The disturbances and mixing in the bridge drive continuing cloud collisions, differential shock heating, and cooling throughout. A wide range of relative gas phases and line-of-sight velocity distributions are found in the bridges, depending sensitively on initial disc orientations, and the resulting variety of cloud collision histories. Most cloud collisions can occur promptly or persist for quite a long duration. Cold and hot phases can largely overlap throughout the bridge or can be separated into different parts of the bridge.

79 ASTRONOMY AND ASTROPHYSICS↗

DOE OSTI2026

JWST Observations of Starbursts: Dust Processing in the M82 Superwind

We present JWST MIRI and NIRCam imaging of the inner ∼5 kpc of the M82 superwind at ~ $0''_{.}05 - 0''_{.}375$(∼0.9–6.5 pc) resolution. Targeted filters probe emission from polycyclic aromatic hydrocarbons (PAHs; F335M, F360M, F770W, F1130W) and continuum (F250M, F360M) The images reveal a network of cool wind filaments traced by PAHs. PAH surface brightness declines with the inverse square of distance to the midplane, suggesting that the incident radiation field from the starburst drives the observed PAH intensity out to ±2.5 kpc. The 3.3/11.3 and 3.3/7.7 μm band ratios show uniformity with distance from the starburst, though comparisons with mid-IR dust emission models indicate a modest shift toward larger PAHs. Outside the disk, 11.3/7.7 μm increases moderately, reflecting that PAHs become more neutral with distance from the starburst as they are exposed to a declining radiation field and ionization parameter. Overall, PAHs in the wind are consistent with standard-to-large sizes and standard-to-high ionization states. Including Spitzer and Herschel data, PAH abundance (q PAH ) is set at ∼1% in the starburst and remains unchanging out to ±5 kpc off the disk. This flat q PAH profile suggests that PAHs are shielded from the hot wind, perhaps residing in the surface layers of cool clouds, with possible replenishment from cloud interiors and enrichment of the halo from previous bursts. In this picture, clouds are not dense enough to promote PAH growth, and they likely undergo radiative cooling and mixing with the hot phase to survive the gauntlet for at least ∼20 Myr.

Cronin, Serena A. [University of Maryland, College↗

NASA NTRS2019

Detailed Infrared Study of Amorphous to Crystalline Propionitrile Ices Relevant to Observed Spectra of Titan's Stratospheric Ice Clouds

We have conducted a comprehensive study of propionitrile (C2H5CN) ice from the amorphous to crystalline phase in order to provide detailed information on this specific cyanide, which may potentially contribute to the chemical composition of the Haystack ice cloud observed in Titan's stratosphere by the Cassini Composite InfraRed Spectrometer (CIRS). Infrared transmission spectra of thin films of pure propionitrile ices deposited at low temperature (30-160 K) were collected from 50 cm1 to 11,700 cm1 (200-0.85 m). The far-infrared spectral region was specifically targeted to compare with CIRS far-infrared limb spectra. The temperature and time evolution of C2H5CN ice was thoroughly investigated to better understand discrepancies reported in pre- viously published laboratory studies on the crystalline phase of C2H5CN. Specifically, we observe peculiar temperature and time-driven ice phase transitions, revealed by significant spectral variations in the ice, which stabilizes once a complete crystalline phase is achieved. From these results, the crystalline phase of propionitrile ice was identified at deposition temperatures greater than or equal to 135 K and < 140 K. Our findings corro- borate previous studies that ruled out pure propionitrile ice as the sole chemical identity of Titan's observed Haystack emission feature. In order to understand and identify the Haystack cloud, we have initiated co-de- position experiments that incorporate mixtures of Titan-relevant organics, many of which have corresponding vapors that are abundantly present in Titan's stratosphere. In this paper, we present the result of one example of a co-deposited ternary ice mixture containing 16% hydrogen cyanide (HCN), 23% C2H5CN, and 61% benzene (C6H6). Although this co-condensed ice mixture is the best fit thus far obtained to match the broad width of the Haystack, it is still not the appropriate chemical candidate. However, it reveals an intriguing result: the strong lattice mode of pure C2H5CN ice is drastically altered by the surrounding molecules as a result of mixing in a co- condensed phase. The laboratory results reported here on propionitrile ice may help to further constrain the chemical identification of Titan's stratospheric Haystack ice cloud, as well as improve on the current state of knowledge of Titan's stratospheric ice cloud chemistry.

Nna-Mvondo, Delphine↗

NASA NTRS2019

Detailed Infrared Study of Amorphous to Crystalline Propionitrile Ices Relevant to Observed Spectra of Titan's Stratospheric Ice Clouds

We have conducted a comprehensive study of propionitrile (C2H5CN) ice from the amorphous to crystalline phase in order to provide detailed information on this specific cyanide, which may potentially contribute to the chemical composition of the Haystack ice cloud observed in Titan's stratosphere by the Cassini Composite InfraRed spectrometer (CIRS). Infrared transmission spectra of thin films of pure propionitrile ices deposited at low temperature (30–160 K) were collected from 50 cm(exp −1) to 11,700 cm(exp −1) (200–0.85 μm). The far-infrared spectral region was specifically targeted to compare with CIRS far-infrared limb spectra. The temperature and time evolution of C2H5CN ice was thoroughly investigated to better understand discrepancies reported in previously published laboratory studies on the crystalline phase of C2H5CN. Specifically, we observe peculiar temperature and time-driven ice phase transitions, revealed by significant spectral variations in the ice, which stabilizes once a complete crystalline phase is achieved. From these results, the crystalline phase of propionitrile ice was identified at deposition temperatures greater than or equal to 135 K and <140 K. Our findings corroborate previous studies that ruled out pure propionitrile ice as the sole chemical identity of Titan's observed Haystack emission feature. In order to understand and identify the Haystack cloud, we have initiated co-deposition experiments that incorporate mixtures of Titan-relevant organics, many of which have corresponding vapors that are abundantly present in Titan's stratosphere. In this paper, we present the result of one example of a co-deposited ternary ice mixture containing 16% hydrogen cyanide (HCN), 23% C2H5CN, and 61% benzene (C6H6). Although this co-condensed ice mixture is the best fit thus far obtained to match the broad width of the Haystack, it is still not the appropriate chemical candidate. However, it reveals an intriguing result: the strong lattice mode of pure C2H5CN ice is drastically altered by the surrounding molecules as a result of mixing in a co-condensed phase. The laboratory results reported here on propionitrile ice may help to further constrain the chemical identification of Titan's stratospheric Haystack ice cloud, as well as improve on the current state of knowledge of Titan's stratospheric ice cloud chemistry.

Delphine Nna-Mvondo↗

NASA NTRS1998

Total Lightning and Radar Storm Characteristics Associated with Severe Storms in Central Florida

A number of prior studies have examined the association of lightning activity with the occurrence of severe weather and tornadoes, in particular. High flash rates are often observed in tornadic storms (Taylor, 1973; Johnson, 1980; Goodman and Knupp, 1993) but not always. Taylor found that 23% of nontornadic storms and 1% of non-severe storms had sferics rates comparable to the tornadic storms. MacGorman (1993) found that storms with mesocyclones produced more frequent intracloud (IC) lightning than cloud-to-ground (CG) lightning. MacGorman (1993) and others suggest that the lightning activity accompanying tomadic storms will be dominated by intracloud lightning-with an increase in intracloud and total flash rates as the updraft increases in depth, size, and velocity. In a recent study, Perez et al. (1998) found that CG flash rates alone are too variable to be a useful predictor of (F4, F5) tornado formation. Studies of non-tomadic storms have also shown that total lightning flash rates track the updraft, with rates increasing as the updraft intensities and decreasing rapidly with cessation of vertical growth or downburst onset (Goodman et al., 1988; Williams et al., 1989). Such relationships result from the development of mixed phase precipitation and increased hydrometer collisions that lead to the efficient separation of charge. Correlations between updraft strength and other variables such as cloud-top height, cloud water mass, and hail size have also been observed.

Goodman, Steven J.↗

DOE OSTI2025

The Importance of an Ensemble Approach for Modeling Aerosol‐Convection Interactions

Aerosol-convection interactions modulate cloud microphysics, thermodynamics, and updraft intensity, contributing to climate-scale aerosol-radiative forcing. However, quantifying aerosol indirect effects in mixed-phase deep convection remains challenging due to uncertainties in parameterized physics and initial conditions driving nonlinear evolution of convective processes. This study investigates the convective updraft sensitivity to random initial temperature perturbations using an idealized ensemble modeling framework informed by in situ thermodynamic and aerosol observations from the DOE TRACER field campaign. We analyze the impact of small-scale initial perturbations on updraft velocity and supersaturation, and determine the ensemble size required to minimize stochastic internal variability. Results show that minor thermodynamic perturbations can produce updraft variability comparable to aerosol-induced changes reported in prior work. An ensemble of 10 members sufficiently reduces variability, enabling robust investigation of aerosol-related updraft invigoration and informing the design of future ensemble-based aerosol-convection interaction studies in environments with significant spatiotemporal mesoscale thermodynamic and aerosol heterogeneity.

aerosol-convection interactions↗

NASA NTRS1994

Solid carbon monoxide in the Serpens dark cloud

The 4.67 micrometer absorption feature of solid CO is an important signature of grain mantles in molecular clouds. This paper presents new observations of solid CO absorption in the spectra of four infrared sources in and behind the Serpens dark cloud. We also present supplementary 2.0-2.5 micrometer spectra which clarify the nature of selected sources. Solid CO profiles are compared with models based on laboratory data. In common with previous studies of other clouds, we find that the observed profiles are consistent with the presence of two distinct phases of CO-bearing ice, one dominated either by CO itself or by CO mixed with absorption relative to that of the water-ice feature at 3.1 micrometers is unusually high in Serpens: we deduce column densities for CO and H2O in solid form and conclude that the mean CO abundance in dust is 40% of the H2O abundance, compared with values in the range 0%-30% typical of other molecular clouds. On the basis of its 2.0-2.5 micrometer spectrum and near-infrared colors, we deduce the infrared source CK 2 to be a K5-M0 III field star situated behind the Serpens cloud and suffering 40-50 mag of visual extinction. Assuming empirical correlations between extinction and total (gas + dust) CO column density, we estimate the CO depletion (i.e., the fraction of interstellar CO in the line of sight tied up in grains) to be approximately 40% in the intracloud medium of the Serpens cloud, comparable with previous estimates for the Taurus dark cloud, and much higher than that found in the environments of protostellar objects.

Chiar, J. E.↗

NASA NTRS2005

Anvil Glaciation in a Deep Cumulus Updraught over Florida Simulated with the Explicit Microphysics Model. I: Impact of Various Nucleation Processes

Simulations of a cumulonimbus cloud observed in the Cirrus regional Study of Tropical Anvils and Cirrus Layers-Florida Area Cirrus Experiment (CRYSTAL-FACE) with an advanced version of the Explicit Microphysics Model (EMM) are presented. The EMM has size-resolved aerosols and predicts the time evolution of sizes, bulk densities and axial ratios of ice particles. Observations by multiple aircraft in the troposphere provide inputs to the model, including observations of the ice nuclei and of the entire size distribution of condensation nuclei. Homogeneous droplet freezing is found to be the source of almost all of the ice crystals in the anvil updraught of this particular model cloud. Most of the simulated droplets that freeze to form anvil crystals appear to be nucleated by activation of aerosols far above cloud base in the interior of the cloud ("secondary" or "in cloud" droplet nucleation). This is partly because primary droplets formed at cloud base are invariably depleted by accretion before they can reach the anvil base in the updraught, which promotes an increase with height of the average supersaturation in the updraught aloft. More than half of these aerosols, activated far above cloud base, are entrained into the updraught of this model cloud from the lateral environment above about 5 km above mean sea level. This confirms the importance of remote sources of atmospheric aerosol for anvil glaciation. Other nucleation processes impinge indirectly upon the anvil glaciation by modifying the concentration of supercooled droplets in the upper levels of the mixed-phase region. For instance, the warm-rain process produces a massive indirect impact on the anvil crystal concentration, because it determines the mass of precipitation forming in the updraught. It competes with homogeneous freezing as a sink for cloud droplets. The effects from turbulent enhancement of the warm-rain process and from the nucleation processes on the anvil ice properties are assessed.

Phillips, Vaughan T. J.↗

NASA NTRS2006

Vibrational Spectroscopy after OSU - From C2- to Interstellar Polycyclic Aromatic Hydrocarbons

The composition of interstellar ice and dust provides insight into the chemical history of the interstellar medium and early solar system. It is now possible to probe this unique and unusual chemistry and determine the composition of these microscopic interstellar particles which are hundreds to many thousands of light years away thanks to substantial progress in two areas: astronomical spectroscopic techniques in the middle-infrared, the spectral region most diagnostic of chemical composition, and laboratory simulations which realistically reproduce the critical conditions in various interstellar environments. High quality infrared spectra of many different astronomical sources, some associated with giant, dark molecular clouds -the birthplace of stars and planets- and others in more tenuous, UV radiation rich regions are now available. The fundamentals of IR spectroscopy and what comparisons of astronomical IR spectra with laboratory spectra of materials prepared under realistic simulated interstellar conditions tell us about the components of these materials is the subject of this talk. These observations have shown that mixed molecular ices comprised of H2O, CH3OH, CO, NH3 and H2CO contain most of the molecular material in molecular clouds and that gas phase, ionized polycyclic aromatic hydrocarbons (PAHs) are widespread and surprisingly abundant throughout most of the interstellar medium.

Allamandola, Louis J.↗

NASA NTRS2019

MARCI-observed clouds in the Hellas Basin during northern hemisphere summer on Mars: Interpretation with the NASA/Ames Legacy Mars Global Climate Model

We present a study that is motivated by a population of water ice clouds in the Hellas Basin that has been observed by the MARs Color Imager (MARCI) instrument on the Mars Reconnaissance Orbiter (MRO) to persist throughout the majority of Northern Hemisphere (NH) summer. Although water ice clouds are present in Hellas at very low opacities throughout NH spring, they noticeably thicken after L(sub s) 60° and continue to do so until their peak optical thickness is attained at L(sub s) ~120°. They dissipate rapidly from L(sub s) 120° to 150°, and by L(sub s) 150°, the only clouds in Hellas are on the southern side of the basin and are indistinguishable from the polar hood clouds. We use the NASA/Ames Legacy Mars Global Climate Model (GCM), which is supported by the Agency’s Mars Climate Modeling Center, to investigate the dynamical and microphysical mechanisms that control the formation and evolution of Hellas water ice clouds. We show that water is transported from the North Polar Residual Cap (NPRC) southward across the equator and into the Hellas region. Water vapor is confined down low by cloud formation in the aphelion cloud belt, thus limiting the effectiveness of transport by the zonal mean overturning circulation (i.e., the Hadley cell). Thus, contrary to the commonly held conceptual understanding that the Hadley cell controls cross-equatorial water transport during this season, we show that the southward transport of water is done primarily in the vapor phase by stationary eddies at nearly all latitudes, including across the equator. Clouds form near the surface in the basin as moist air mixes with cold polar air on the western side of Hellas and are subsequently transported clockwise around the north side of the basin by the low-level cyclonic circulation. The simulated Hellas clouds have small particle sizes (~3–5 μm), are very low, and exist as long as the NPRC is exposed.

M. A. Kahre↗

NASA NTRS1978

Photometry and polarimetry of Jupiter at large phase angles. I - Analysis of imaging data of a prominent belt and a zone from Pioneer 10

Photopolarimetric observations of a prominent bright zone and a dark belt of Jupiter in red and blue light are analyzed which were performed by Pioneer 10 at phase angles of 12, 23, 34, 109, 120, 127, and 150 deg. Geometric and photometric reductions of the imaging data are described, the instrument sensitivity at various times is evaluated, and the data are referred to an absolute scale. The observations are analyzed in detail by comparing the data with results of radiative-transfer calculations for specific scattering models of Jupiter's atmosphere. These models include those with a vertical structure consisting of a layer of Rayleigh-scattering gas above a semiinfinite mixture of cloud particles and gas, those having a small quantity of aerosols in the gas above either the diffuse cloud in a reflecting-scattering model or the top cloud of a two-cloud-layer model, those in which a forward-scattering haze is mixed uniformly with gas, and those containing dust layers. It is found that in both the belt and the zone in red as well as blue light, cloud phase functions are required which provide both strong forward scattering and some backscattering.

Tomasko, M. G.↗

NASA NTRS2002

The Exobiological Role of Interstellar Polycyclic Aromatic Hydrocarbons and Ices

Tremendous strides have been made in our understanding of interstellar material over the past twenty years thanks to significant, parallel developments in observational astronomy and laboratory astrophysics. Before this time, the composition of interstellar dust was largely guessed-at, the presence of ices in interstellar clouds ignored, and the notion that large, gas phase, carbon rich molecules might be abundant and widespread throughout the interstellar medium (ISM) considered impossible. Today, the composition of dust in the ISM is reasonably well constrained to micron-sized cold refractory materials comprised of amorphous and crystalline silicates mixed with an amorphous carbonaceous material containing aromatic structural units and short, branched aliphatic chains. Shrouded within the protective confines of cold, opaque molecular clouds--the birthplace of stars and planets--these cold dust particles secrete mantles of mixed molecular ices whose compositions are also well constrained. Finally, amidst the molecular inventory of these ice mantles are likely to be found polycyclic aromatic hydrocarbons (PAHs), shockingly large molecules by the standards of interstellar chemistry, the telltale infrared spectral signature of which is now recognized throughout the Universe. In the first part of this talk, we will review the spectroscopic evidence that forms the basis for the currently accepted abundance and ubiquity of PANs in the ISM. We will then look at a few specific examples which illustrate how experimental and theoretical data can be applied to interpret the interstellar spectra and track how the PAN population evolves as it passes from its formation site in the circumstellar outflows of dying stars, through the various phases of the ISM, and into forn~iing planetary systems. Nevertheless, despite the fact that PANs likely represent the single largest molecular reservoir of organic carbon in evolving planetary systems, they are not what would be considered "biogenic" molecules. Although interesting from a chemical and astrophysical standpoint, in the absence of a mechanism by which this population can be dislodged from the precipitous thermodynamic well afforded by their extensive aromatic networks, they are of little Astrobiological significance. Consequently, for the remainder of the talk, we will consider the photochemical evolution of PANS under conditions similar to those found in the ISM and in proto-planetary systems with an eye toward means by which this rich repository of pre-biotic organic "ore" might be converted into materials of greater importance to Astrobiology.

Hudgins, Douglas M.↗

NASA NTRS1990

Microgravity acoustic mixing for particle cloud combustors

Experimental and theoretical investigations of acoustic mixing procedures designed to uniformly distribute fuel particles in a combustion tube for application in the proposed Particle Cloud Combustion Experiment (PCCE) are described. Two acoustic mixing methods are investigated: mixing in a cylindrical tube using high frequency spinning modes generated by suitably phased, or quadrature speakers, and acoustic premixing in a sphere. Quadrature mixing leads to rapid circumferential circulation of the powder around the tube. Good mixing is observed in the circulating regions. However, because axial inhomogeneities are necessarily present in the acoustic field, this circulation does not extend throughout the tube. Simultaneous operation of the quadrature-speaker set and the axial-speaker was observed to produce considerably enhanced mixing compared to operation of the quadrature-speaker set alone. Mixing experiments using both types of speakers were free of the longitudinal powder drift observed using axial-speakers alone. Vigorous powder mixing was obtained in the sphere for many normal modes: however, in no case was the powder observed to fill the sphere entirely. Theoretical analysis indicated that mixing under steady conditions cannot fill more than a hemisphere except under very unusual conditions. Premixing in a hemisphere may be satisfactory; otherwise, complete mixing in microgravity might be possible by operating the speaker in short bursts. A general conclusion is that acoustic transients are more likely to produce good mixing than steady state conditions. The reason is that in steady conditions, flow structures like nodal planes are possible and often even unavoidable. These tend to separate the mixing region into cells across which powder cannot be transferred. In contrast, transients not only are free of such structures, they also have the characteristics, desirable for mixing, of randomness and disorder. This conclusion is corroborated by mixing experiments using axial waves.

Pla, Frederic↗

DOE OSTI2024

Enrichment of Phosphates, Lead, and Mixed Soil–Organic Particles in INPs at the Southern Great Plains Site

Ice nucleating particles (INPs) are rare particles that initiate primary ice formation, a critical step required for subsequent important cloud microphysical processes that ultimately govern cloud phase and cloud radiative properties. Laboratory studies have found that organic-rich dusts, such as those found in soils, are more efficient INPs compared to mineral dust. However, the atmospheric relevance of these organic-rich dusts are not well understood, particularly in regions with significant agricultural activity. The Agricultural Ice nuclei at the Southern Great Plains field campaign (AGINSGP) was conducted in rural Oklahoma to investigate how soil dusts contribute to INP populations in the Great Plains. We present chemical characterization of ambient and ice crystal residual particles from a single day of sampling, using single particle mass spectrometry (SPMS) and scanning microscopy. Ambient particles were primarily carbonaceous or secondary aerosol, while the fraction of dust particles was higher in the residual particles. We also observed an unusual particle type consisting of a carbonaceous core mixed with dust fragments on the surface, which was found in higher proportion in residuals. Dust particles measured during residual sampling contained greater proportions of phosphate $(^{63}\text{PO}^-_2$ and $^{79}\text{PO}^-_3)$ and lead ( 206 Pb + ). Strong sulfate signals were not seen in the residual dust particles measured by the SPMS, while nitrate was slightly depleted relative to ambient dust. This study shows that organic-rich soils may be important contributors to the ambient INP population in agricultural regions.

54 ENVIRONMENTAL SCIENCES↗

NASA NTRS2001

Ice Nucleation in Deep Convection

The processes controlling production of ice crystals in deep, rapidly ascending convective columns are poorly understood due to the difficulties involved with either modeling or in situ sampling of these violent clouds. A large number of ice crystals are no doubt generated when droplets freeze at about -40 C. However, at higher levels, these crystals are likely depleted due to precipitation and detrainment. As the ice surface area decreases, the relative humidity can increase well above ice saturation, resulting in bursts of ice nucleation. We will present simulations of these processes using a large-eddy simulation model with detailed microphysics. Size bins are included for aerosols, liquid droplets, ice crystals, and mixed-phase (ice/liquid) hydrometers. Microphysical processes simulated include droplet activation, freezing, melting, homogeneous freezing of sulfate aerosols, and heterogeneous ice nucleation. We are focusing on the importance of ice nucleation events in the upper part of the cloud at temperatures below -40 C. We will show that the ultimate evolution of the cloud in this region (and the anvil produced by the convection) is sensitive to these ice nucleation events, and hence to the composition of upper tropospheric aerosols that get entrained into the convective column.

Jensen, Eric↗

NASA NTRS2000

From Interstellar PAHs and Ices to the Origin of Life

Tremendous strides have been made in our understanding of interstellar material over the past twenty years thanks to significant, parallel developments in observational astronomy and laboratory astrophysics. Twenty years ago the composition of interstellar dust was largely guessed at, the concept of ices in dense molecular clouds ignored, and the notion of large, abundant, gas phase, carbon rich molecules widespread throughout the interstellar medium (ISM) considered impossible. Today the composition of dust in the diffuse ISM is reasonably well constrained to micron-sized cold refractory materials comprised of amorphous and crystalline silicates mixed with an amorphous carbonaceous material containing aromatic structural units and short, branched aliphatic chains. In dense molecular clouds, the birthplace of stars and planets, these cold dust particles are coated with mixed molecular ices whose composition is very well constrained. Lastly, the signature of carbon-rich polycyclic aromatic hydrocarbons (PAHs), shockingly large molecules by earlier interstellar chemistry standards, is widespread throughout the Universe. The first part of this lecture will describe how infrared studies of interstellar space, combined with laboratory simulations, have revealed the composition of interstellar ices (the building blocks of comets) and the high abundance and nature of interstellar PAHs. The laboratory database has now enabled us to gain insight into the identities, concentrations, and physical state of many interstellar materials. Within a dense molecular cloud, and especially in the solar nebula during the star and planet formation stage, the materials frozen into interstellar/precometary ices are photoprocessed by ultraviolet light, producing more complex molecules. The remainder of the presentation will focus on the photochemical evolution of these materials and the possible role of these compounds on the early Earth. As these materials are thought to be the building blocks of comets and related to the carbonaceous components of micrometeorites, they are likely to have been important sources of complex organic materials on the early Earth and their composition may be related to the origin of life.

Allamandola, Louis J.↗

NASA NTRS2019

Detailed infrared study of amorphous to crystalline propionitrile ices relevant to observed spectra of Titan's stratospheric ice clouds

We have conducted a comprehensive study of propionitrile (C2H5CN) ice from the amorphous to crystalline phase in order to provide detailed information on this specific cyanide, which may potentially contribute to the chemical composition of the Haystack ice cloud observed in Titan’s stratosphere by the Cassini Composite InfraRed Spectrometer (CIRS). Infrared transmission spectra of thin films of pure propionitrile ices deposited at low temperature (30 – 160 K) were collected from 50 cm-1 to 11,700 cm-1 (200 – 0.85 μm). The far-infrared spectral region was specifically targeted to compare with CIRS far-infrared limb spectra. The temperature and time evolution of C2H5CN ice was thoroughly investigated to better understand discrepancies reported in previously published laboratory studies on the crystalline phase of C2H5CN. Specifically, we observe peculiar temperature and time-driven ice phase transitions, revealed by significant spectral variations in the ice, which stabilizes once a complete crystalline phase is achieved. From these results, the crystalline phase of propionitrile ice was identified at deposition temperatures greater than or equal to 135 K and less than 140 K. Our findings corroborate previous studies that ruled out pure propionitrile ice as the sole chemical identity of Titan’s observed Haystack emission feature. As a result, we have initiated co-deposition experiments that incorporate mixtures of Titan-relevant organics, many of which have corresponding vapors that are abundantly present in Titan's stratosphere. In this paper, we present one example of a co-deposited trinary ice mixture containing 16% hydrogen cyanide (HCN), 23% C2H5CN, and 61% benzene (C6H6). Although this co-condensed ice mixture is a poor spectral match for the Haystack, it reveals an intriguing result: the strong lattice mode of pure C2H5CN ice is drastically altered by the surrounding molecules as a result of mixing in a co-condensed phase. The laboratory results reported here on propionitrile ice may help to further constrain the chemical identification of Titan’s stratospheric Haystack ice cloud, as well as improve on the current state of knowledge of Titan's stratospheric ice cloud chemistry.

Ices↗