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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 181 records · Page 10
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NASA NTRS1973

On ultraviolet absorption by molecular hydrogen in stellar atmospheres.

The total LTE opacity expected for a variety of temperatures and pressures has been calculated for a mixture of solar composition. The absorption coefficient for the H2 singlet transition between 1300 and 2000 A was obtained from computations at 5000 K by Sando and Dalgarno (1971). It is found that a correct estimate of the resonance broadening in Lyman-alpha wings leads to important modifications of the UV opacity.

Praderie, F.↗
NASA NTRS1973

The heating of interstellar clouds by vibrationally excited molecular hydrogen.

We discuss the possibility that vibrationally excited H2 may be collisionally de-excited, so providing a heating mechanism for interstellar clouds which operates by coupling the stellar radiation to the gas. The majority of excitations in the Lyman and Werner bands of H2 return the molecules to the ground electronic state in a vibrationally excited level, the most favoured being v'' = 7. We compare the hearing rate obtained in this way with other mechanisms which have been postulated, and present the results of calculations of temperature as a function of depth into clouds of different densities.

Stecher, T. P.↗
NASA NTRS1974

Microbial detection method based on sensing molecular hydrogen

An approach involving the measurement of hydrogen evolution by test organisms was used to detect and enumerate various members of the Enterobacteriaceae group. The experimental setup for measuring hydrogen evolution consisted of a test tube containing two electrodes plus broth and organisms. The test tube was kept in a water bath at a temperature of 35 C. It is pointed out that the hydrogen-sensing method, coupled with the pressure transducer technique reported by Wilkins (1974) could be used in various experiments in which gas production by microorganisms is being measured.

Wilkins, J. R.↗
NASA NTRS1974

Microbial detection method based on sensing molecular hydrogen

A simple method for detecting bacteria, based on the time of hydrogen evolution, was developed and tested against various members of the Enterobacteriaceae group. The test system consisted of (1) two electrodes, platinum and a reference electrode, (2) a buffer amplifier, and (3) a strip-chart recorder. Hydrogen evolution was measured by an increase in voltage in the negative (cathodic) direction. A linear relationship was established between inoculum size and the time hydrogen was detected (lag period). Lag times ranged from 1 h for 1 million cells/ml to 7 h for 1 cell/ml. For each 10-fold decrease in inoculum, length of the lag period increased 60 to 70 min. Based on the linear relationship between inoculum and lag period, these results indicate the potential application of the hydrogen-sensing method for rapidly detecting coliforms and other gas-producing microorganisms in a variety of clinical, food, and other samples.

Wilkins, J. R.↗
NASA NTRS1974

Column densities of interstellar molecular hydrogen

Equivalent widths of some 50 lines in the 0-0 to 5-0 Lyman bands of H2 are reported in the spectra of 28 stars. Curves of growth are given and column densities for levels from J = 0 to J = 5 are tabulated, with a few values and upper limits for N(6) and N(7), together with values for b, the velocity spread parameter. In three Orion stars and in rho Leo pairs of components are detected, the difference in radial velocity is determined, and column densities are measured or estimated; tentative identifications are made with the components observed by Hobbs (1969) in the Na D-lines. Column densities for HD are given for 13 stars. Upper limits for column densities in the first and second vibrational levels are listed for several stars; the ratio of N(J = 0) in the v double prime = 1 level to that in the ground vibrational level is less than 2.4 x 10 to the minus 8th power in zeta Oph. Values of a rotational excitation temperature for the higher J levels are given for all the stars. Data are presented which show an apparent increase of velocity dispersion with J for a number of stars, as measured both from the curves of growth and from line widths.

Spitzer, L., Jr.↗
NASA NTRS1975

Depletion of the F2 region ionosphere and the protonosphere by the release of molecular hydrogen

Theoretical models have been used to investigate the effects of artificially injected H2 gas on plasma densities in the ionospheric F region and the overlying protonosphere. Owing to large reaction rates between H2 and ionospheric O(+) ions, plasma densities in both daytime and nighttime ionospheres can be greatly reduced by modest amounts of released H2 gas. One hundred kg of H2 released at 300-km altitude reduces local O(+) densities by more than three orders of magnitude and produces about a 5% depression in H(+) densities in the overlying protonosphere. These results suggest that it should be possible to conduct controlled chemical-modification experiments for investigation of many outstanding ionospheric and magnetospheric problems.

Bernhardt, P. A.↗
NASA NTRS1975

Molecular hydrogen in the Galaxy and galactic gamma rays

Recent surveys of 2.6-cm CO emission and 100-MeV gamma-radiation in the galactic plane reveal a striking correlation suggesting that both emissions may be primarily proportional to the line-of-sight column density of H2 in the inner Galaxy. Both the gamma-ray and CO data suggest a prominent ring or arm consisting of cool clouds of H2 at a galactocentric distance of about 5 kpc with a mean total hydrogen density equivalent to approximately 5 atoms per cu cm. Estimates are made of column densities of H2 at 0 deg galactic longitude and are compared with estimates from infrared and X-ray absorption measurements. These estimates are all consistent, indicating that H2 is far more abundant than H I in the inner Galaxy and is the key to a more satisfactory explanation of the gamma-ray observations than previous suggestions. The importance of H2 in understanding galactic gamma-ray observations is also reflected in the correlation of galactic-latitude distribution of gamma-rays and dense dust clouds. The deduced cosmic-ray distribution inferred from the calculations is similar to that of galactic supernova remnants, suggesting a galactic origin for most cosmic rays.

Stecker, F. W.↗
NASA NTRS1975

A search for molecular hydrogen fluorescence near 100 km

The fluorescence of H2 in the Lyman band system, excited by solar extreme ultraviolet radiation, provides a means for the optical detection of H2 in the upper atmosphere. In particular, the Ly beta line of hydrogen is nearly degenerate with the (6,0) P1 transition, and absorption in this line produces fluorescence in the v-prime = 6 progression, principally at 1265, 1366, 1462 and 1608 A. Absorption by O2 rapidly attenuates the Ly beta from an overhead sun below 100 km and also significantly attenuates the fluorescent radiation. Far-ultraviolet dayglow spectra from 1130 to 1510 A obtained from an Aerobee rocket experiment on 11 December 1972 give an upper limit for any H2 emission which is a factor of 5 higher than expected according to recent hydrogen models.

Feldman, P. D.↗
NASA NTRS1976

Interstellar molecular hydrogen toward zeta Puppis

This paper reports the measurement of some 136 interstellar H2 absorption lines found in a continuous scan of the far-ultraviolet spectrum of zeta Pup at 0.05-A resolution with the Copernicus telescope. Absorptions from only the rotational levels 0 to 5 of the lowest vibrational state of the ground electronic state were observed. The total H2 column density is 2.8 by 10 to the 14th power molecules/sq cm; the ratio of H nuclei in H2 to the number in H I plus molecules is 6 by 10 to the -6th power; the population of the rotational levels can be represented by a single excitation temperature of 1120 (plus or minus 80) K. The radial velocities of all rotational levels were the same within 7 km/s and differed from most atoms and first ions by no more than 4.5 km/s on the average. The tables also list the best available data on wavelengths, oscillator strengths, and radiative damping constants for all the H2 lines with zero vibrational level likely to be observed in the interstellar gas.

Morton, D. C.↗
NASA NTRS1976

Components in interstellar molecular hydrogen

Results are reported for precise spectrophotometric measurements of the profiles of selected Lyman absorption lines produced by hydrogen molecules in various rotational levels along the line of sight to 13 stars which have shown some evidence for an increase in line width with increasing rotational quantum number (J). The line profiles were measured by multiple scans with the Copernicus satellite telescope. Based on analysis of the radial velocities, derivations of the column densities, and line-profile fitting, the following conclusions are made: (1) the increase in interstellar H2 line width with increasing J results from the presence of the most shortward component, which is relatively weak at low J but becomes more important at higher J; (2) the relative column densities found for the different J levels in each component may be fitted by a theoretical model in which rotational excitation is due to absorption of UV photons followed by radiative quadrupole spontaneous transitions or collisionally induced downward transitions between different J levels; (3) the atomic hydrogen density is between 300 and 1000 per cu cm in the most shortward component for each of three stars; (4) the approaching gas which produces each shortward component must be in the form of thin sheets; and (5) the sheets are the compressed gas behind a shock front moving through the interstellar medium.

Spitzer, L., Jr.↗
NASA NTRS1976

Molecular hydrogen in interstellar dark clouds

A simplified H2 formation mechanism is proposed in which small interstellar grains furnish the reaction sites. This mechanism results in a maximum value for the rate constant of about 2 by 10 to the -18th power per cu cm/sec for dark clouds at 10 K. Also, the nascent molecules are ejected in excited states, in qualitative agreement with Copernicus observations. A time-dependent treatment of the chemical evolution of a dark cloud with little or no ionizing radiation shows that the clouds require more than 10 million years to achieve chemical equilibrium. The observed residual atomic hydrogen in several dark clouds suggests that the clouds are 1 to 10 million years old. Other consequences of the temporal cloud model are in accord with astronomical observations.

Allen, M.↗
NASA NTRS1976

Absolute rate of the reaction of Cl(p-2) with molecular hydrogen from 200 - 500 K

Rate constants for the reaction of atomic chlorine with hydrogen are measured from 200 - 500 K using the flash photolysis-resonance fluorescence technique. The results are compared with previous work and are discussed with particular reference to the equilibrium constant for the reaction and to relative rate data for chlorine atom reactions. Theoretical calculations, using the BEBO method with tunneling, give excellent agreement with experiment.

Whytock, D. A.↗
NASA NTRS1978

The ratio of carbon monoxide to molecular hydrogen in interstellar dark clouds

LTE (C-13)O column densities are compared with the corresponding values of beam-convolved visual extinction at more than 100 locations within 38 different interstellar dark clouds. A roughly linear correlation is found to exist between these two quantities for visual extinctions in the range from about 1.5 to 5 mag. It is argued that this correlation can be extended up to about 10 mag and that the standard gas-to-extinction ratio can be expected to remain valid in the sources studied. The correlation of LTE (C-13)O column density with visual extinction is used to obtain an equation for the H2 column density associated with a given (C-13)O column density. It is shown that if the clouds studied are assumed to be chemically homogeneous, the equation obtained implies that at least 12% of all gas-phase carbon is in the form of CO. Comparison of the observational data with various theories proposed for molecule formation in dark clouds indicates that Langer's (1977) ion-molecule scheme accounts well for the observations when the fractionation channel of Watson et al. (1976) is included.

Dickman, R. L.↗
NASA NTRS1981

Discovery of the molecular hydrogen ion (h2(+)) in the planetary nebulae

Low-dispersion spectra of fifteen planetaries and hot subdwarfs were obtained with the short wavelength prime camera on IUE and continuous flux distributions corrected for interstellar extinction were derived. Several planetaries, particularly the young planetaries of high surface brightness, show anomalous flux distributions. The most anomalous case is NGC 6210. These anomalies may be explained as absorption by H2+ H2(+) in the nebula.

Heap, S. R.↗