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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 181 records · Page 10
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

Direct Observation of Modulated Radical Spin States in Metal–Organic Frameworks by Controlled Flexibility

Owing to their switchable spin states and dynamic electronic character, organic-based radical species have been invoked in phenomena unique to a variety of fields. When incorporated in solid state materials, generation of organic radicals proves challenging due to aggregation. Metal–organic frameworks (MOFs) are promising candidates for immobilization and stabilization of organic radicals because of the tunable spatial arrangement of organic linkers and metal nodes, which sequesters the reactive species. Herein, a flexible, redox-active tetracarboxylic acid linker bearing two imidazole units was chosen to construct a new Zr 6 -MOF, NU-910, with scu topology. By exploiting the structural flexibility of NU-910, we successfully modulate the dynamics between an isolated organic radical species and an organic radical π-dimer species in the MOF system. Single-crystal X-ray diffraction analysis reveals that through solvent exchange from N,N-diethylformamide to acetone, NU-910 undergoes a structural contraction with interlinker distances decreasing from 8.32 Å to 3.20 Å at 100 K. Organic radical species on the bridging linkers are generated via UV light irradiation. Direct observation of temperature-induced spin switches from an isolated radical species to a magnetically silent radical π-dimer in NU-910 after irradiation in the solid state was achieved via variable-temperature single-crystal X-ray diffraction and variable-temperature electron paramagnetic resonance spectroscopy. Ultraviolet–visible–near infrared spectroscopy and density functional theory calculations further substantiated the formation of a radical cation π-dimer upon irradiation. As a result, this work demonstrates the potential of using flexible MOFs as a platform to modulate radical spin states in the solid phase.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

Parameterizing Perennial Bioenergy Crops in Version 5 of the Community Land Model Based on Site‐Level Observations in the Central Midwestern United States

Abstract With projected expansion of biofuel production at a global scale, there is a pressing need to develop adequate representation of bioenergy crops in land surface models to help effectively quantify the biogeophysical and biogeochemical effects of its associated land use changes. This study implements two new perennial bioenergy crops, Miscanthus and switchgrass, into the Community Land Model Version 5 based on site‐level observations from the midwestern United States by modifying parameters associated with photosynthesis, phenology, allocation, decomposition, and carbon cost of nitrogen uptake and integrating concomitantly land management practices. Sensitivity analyses indicate that carbon and energy fluxes of the perennial crops are most sensitive to photosynthesis and phenology parameters. Validation of simulated fluxes against site‐level measurements demonstrates that the model is capable of capturing the overall patterns of energy and carbon fluxes, as well as physiological transitions from leaf emergence to senescence. Compared to annual crops, perennial crops feature longer growing season, greater leaf areas, and higher productivity, leading to increased transpiration, lower annual runoff, and larger carbon uptake. The model simulations suggest that with higher CO 2 assimilation rates and lower demands for nutrients and water, high‐yielding perennial crops are promising alternatives of bioenergy feedstocks compared to traditional annual crops not only for mitigating climate change but also for environmental conservation purposes by reducing fertilizer application and therefore alleviating surface‐ and ground‐water contaminations. Although the local‐scale simulations shed light on potential benefits of using perennial grasses as bioenergy feedstocks, quantifying consequences of their plantations at larger scales warrants additional investigation.

Cheng, Yanyan↗
DOE OSTI2025

Exposing Process‐Level Biases in a Global Cloud Permitting Model With ARM Observations

The emergence of global convective‐permitting models (GCPMs) represents a significant advancement in climate modeling, offering improved representation of deep convection and complex precipitation patterns. In this study, we evaluate the performance of the Simple Cloud‐Resolving E3SM Atmosphere Model (SCREAM) using its doubly periodic configuration (DP‐SCREAM) against large eddy simulations and modern observational data sets from the Atmospheric Radiation Measurement program. We introduce several new transitional cloud regime cases, such as the transition from shallow to deep convection and from stratocumulus to cumulus, as well as cold‐air outbreak scenarios. The results reveal both strengths and limitations of SCREAM, particularly in the accurate simulation of cloud transitions and midlevel convection, with varying degrees of sensitivity to horizontal and vertical resolution. Despite improvements at higher resolutions, key biases remain, including the abrupt transition from shallow to deep convection and the lack of congestus clouds. These findings underscore the need for further refinement in turbulence parameterizations and vertical grid resolution in GCPMs.

Bogenschutz, Peter A. [Lawrence Livermore National↗
NASA NTRS1979

Balloon-borne ultraviolet stellar spectrograph. I - Instrumentation and observation. II - Highlights of first observational results

A dual star-tracking system and a system including a telescope, an echelle spectrograph, and a SEC vidicon are the chief components of the Balloon-borne Ultraviolet Stellar Spectrograph (BUSS), which has flown four successful missions. The BUSS missions have yielded 81 spectra for 56 stars, recorded with a resolution of 0.1 A in the wavelength range from 2200 to 3400 A. BUSS observations include: profiles of Mg II lines indicating considerable mass flow in early-type supergiants; Mg II features suggesting a cool expanding outer shell above a hotter chromosphere; emission features in Zeta Tau (a shell star) indicating infalling material; and emission features of the Be star Phi Per suggesting mass outflow.

Kondo, Y.↗
NASA NTRS1979

International Planetary Patrol observations of Saturn's rings. I - Observations and data reduction

The paper describes the reduction procedure used for observations of Saturn's rings taken with the International Planetary Patrol Network in 1977. Corrections for atmospheric smearing are determined using an assumed ring model and performed by a two-dimensional Wiener filter developed at JPL's Image Processing Laboratory. These smearing corrections are shown to be consistent with the radial profile of the rings, not just on the major axis of the ring system, but over a range of azimuthal angle.

Lumme, K.↗
NASA NTRS1980

Saturn's rings - Particle composition and size distribution as constrained by observations at microwave wavelengths. II - Radio interferometric observations

Theoretical models are presented of the brightness of Saturn's rings at microwave wavelengths (0.34-21.0 cm) including both intrinsic ring emission and diffuse scattering by the rings of the planetary emission. In addition, several previously existing sets of interferometric observations of the Saturn system at 0.83, 3.71, 6.0, 11.1, and 21.0 cm wavelengths are analyzed. A comparison of models and experimental data make it possible to establish improved constraints on the properties of the rings. In particular, it is found that (1) the maximum optical depths in the rings is 1.5 + or - 0.3 referred to visible wavelengths; (2) a significant decrease in ring optical depths from 3.7 to 21.0 cm makes it possible to rule out the possibility that more than 30% of the cross section of the rings is composed of particles larger than about a meter; and (3) the ring particles cannot be primarily of silicate composition (independently of particle size), and the particles cannot be primarily smaller than about 0.1 cm, independently of composition.

Cuzzi, J. N.↗
NASA NTRS1981

Observing facilities at the European Southern Observatory (ESO) in Chile for cometary observations

The (ESO) is located on the mountain La Silla (geographical coordinates: 4h42m55s10 west, -29 deg 15' 25".8 south, 2400 m elevation. The size of the telescopes ranges from a 40 cm Astrograph to the 3.6 m Richey-Chretien telescope. Future telescopes are discussed: a 2.2 m RC-Telescope which will be identical with the German 2.2 m telescope on Calor Alto in SE-Spain, and a 3.5 m telescope, the New Technology Telescope. In addition to these telescopes, a great number of auxiliary instrumentation are operational. Because ESO has to serve all requests of the visiting astronomers these instruments are designed for very different applications. The telescopes and auxiliary instruments that are especially suited for cometary observations are discussed. The dicussion is divided into three parts: photography, photometry-polarimetry and spectroscopy.

Schnur, G. F. O.↗
NASA NTRS1985

Gravity wave spectra observed by Doppler radar: Comparison of a model with mesospheric observations

It was proposed that mesoscale fluctuations of wind and temperature in the free atmosphere are due to gravity waves. Critical tests of this hypothesis must involve the comparison of models based on the theory of buoyancy waves with suitable measurements. The MST (mesosphere-stratosphere-troposphere) radar technique is particularly attractive for this purpose, because it can measure several independent power spectra simultaneously. Observed spectra are derived from mesospheric data taken by the Poker Flat MST radar during June 1983. The spectra were compared with the model spectra for three days when suitable data were available. It was concluded that the mesoscale fluctuations were dominated by gravity waves, and the contribution of two-dimensional turbulence was small.

Vanzandt, T. E.↗
NASA NTRS1989

Middle Atmosphere of the Southern Hemisphere (MASH) Global meteor observations system (GLOBMET) Solar Spectral Irradiance Measurements (SSIM) Global Observations and Studies of Stratospheric Aerosols (GOSSA): Progress with the MASH project

The aim of the MASH project is to study the dynamics of the middle atmosphere in the Southern Hemisphere, emphasizing inter-hemispheric differences. Both observational data and data from simulations with numerical models are being used. It is intended that MASH will be complemented by parallel studies on the transport and photochemistry of trace species in the Southern Hemisphere. Impetus for such studies has come from the unexpected finding of a springtime ozone hole over Antarctica. A summary of recent progress with the MASH project is given. Data from polar orbiting satellites are used to discuss the large scale circulation found in the Southern Hemisphere at extratropical latitudes. Comparisons are made with that of the Northern Hemisphere. Particular attention is paid to the springtime final warming, the most spectacular large scale phenomenon in the statosphere of the Southern Hemisphere. The circulation before and after this event has to be taken into account in theories for the formation and subsequent disappearance of the ozone hole.

Oneill, A.↗
NASA NTRS1989

Ultraviolet events observed in active regions. I - Observations and scenario

UV line data obtained in solar active regions on and near the limb, taken with the Ultraviolet Spectrometer and Polarimeter experiment on the Solar Maximum Mission are examined. The study provides insight into the physical processes behind sudden localized brightenings (or microflares) that occur within these active regions and their relation to surging activity. Time sequences of rasters and rasters through the line (taken in Ly-alpha and N V lines simultaneously) and C IV dopplergrams are the core of these data. They show the brightening events on the disk and Doppler shifts in dynamic events on the disk and above the limb. The study suggests, for the events, a localized energy deposition in a region of the chromosphere that heats the material and produces a pressure pulse. This mechanism explains the brightenings in transition region lines and also the observed surging behavior and jet-like events.

Fontenla, Juan M.↗