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At least 181 records · Page 10

Reduced Organic Outgassing in the NASA Osiris-Rex and Hayabusa2 Curation Facility by Careful Selection and Implementation of Cleanroom Construction Materials

In October 2021, NASA Johnson Space Center (JSC) Astromaterials Acquisition and Cu-ration Office in JSC bldg. 31 completed construction and commissioning of the OSIRIS-REx and Hayabusa2cleanroom laboratory suites along with new precision cleaning and advanced curation laboratories: •OSIRIS-REx Curation Cleanroom: ISO Class 5•Hayabusa2 Curation Cleanroom: ISO Class 5•Final Precision Cleaning Cleanroom: ISO Class 5•Advanced Precision Cleaning Cleanroom: ISO Class 6•PreClean Precision Cleaning Cleanroom: ISO Class 6•Advanced Curation Cleanroom: ISO Class 7The new curation facilities are designed for initial receiving, basic characterization, curation processing, and preliminary examination of carbonaceous asteroidal material. The facilities are also designed to enable long-term pristine sample storage to preserve the scientific integrity of each sample to enable decades of future re-search by the international science community. The scientific study of organics in general is critical for both missions. The OSIRIS-REx mission executed a stringent contamination control plan [1] where all sample hardware at time of sample acquisition would be at Level 100 A/2 per IEST-STD-CC1246D (non-volatile residue (NVR) < 500 ng/cm2). In addition, the mission imposed a requirement of <180 ng/cm2 for amino acids (and hydrazine) [1]. Given these mission requirements, long-term storage preservation requirements, and information from the Organic Contamination Baseline Study at JSC [2], the JSC Curation team decided to carefully select cleanroom construction materials that would not hinder the scientific search for amino acids and the study of organics in the samples [3].

astromaterials curation↗

Volatile Composition and Outgassing in C/2018 Y1 (Iwamoto): Extending Limits for High-Resolution Infrared Cometary Spectroscopy between 2.8 and 5.0 µm

We used the powerful high spectral resolution cross-dispersed facility spectrograph, iSHELL, at the NASAInfrared Telescope Facility(IRTF)to observe C/2018 Y1(Iwamoto), a long-period comet from the Oort cloud.We report production rates for water and eight other parent molecules(native ices),C2H6, CO, CH4,H2CO,CH3OH, HCN, NH3, and C2H2, on three preperihelion UT dates, 2019 January 13 and(near perihelion)February4–5. We present abundance ratios relative to both C2H6(a nonpolar molecule)and H2O(a polar molecule), thereby providing a more complete picture of the parent volatile composition of C/2018 Y1 and potential associations of ices in its nucleus. Overall, the measured spatial distributions for polar molecules(in particular, H2O and CH3OH)were broader, exhibiting more complex structure compared with nonpolar or weakly polar species(CH4,C2H6, andCO). Our January 13 results permitted quantitatively assessing the significant improvement in sensitivity delivered by iSHELL compared with previous capabilities at the IRTF. The efficient spectral coverage of iSHELL plus the favorable geocentric Doppler shift of C/2018 Y1 allowed for measuring>50% of CH4ν3-band emission intensity on both January 13 and February 5. Compositionally, compared to their respective mean abundances among comets from the Oort cloud, C2H6and CH3OH were enriched, CH4and HCN were near normal, and all other species were depleted. The abundance ratio CH3OH/C2H6was higher by 45%±8% on January 13 versusFebruary 5, whereas CH4/C2H6was unchanged within the uncertainty, suggesting nonhomogeneous composition among regions of the nucleus dominating activity on these dates

Michael A. Disanti↗

Comparison of Neutral Outgassing of Comet 67P/Churyumov-Gerasimenko Inbound and Outbound Beyond 3 Au From ROSINA/DFMS

Context. Pre-equinox measurements of comet 67P/Churyumov-Gerasimenko with the mass spectrometer ROSINA/DFMS on board the Rosetta spacecraft revealed a strongly heterogeneous coma. The abundances of major and various minor volatile species were found to depend on the latitude and longitude of the nadir point of the spacecraft. The observed time variability of coma species remained consistent for about three months up to equinox. The chemical variability could be generally interpreted in terms of surface temperature and seasonal effects superposed on some kind of chemical heterogeneity of the nucleus. Aims. We compare here pre-equinox (inbound) ROSINA/DFMS measurements from 2014 to measurements taken after the outbound equinox in 2016, both at heliocentric distances larger than 3 AU. For a direct comparison we limit our observations to the southern hemisphere. Methods. We report the similarities and differences in the concentrations and time variability of neutral species under similar insolation conditions (heliocentric distance and season) pre- and post-equinox, and interpret them in light of the previously published observations. In addition, we extend both the pre- and post-equinox analysis by comparing species concentrations with a mixture of CO2 and H2O. Results. Our results show significant changes in the abundances of neutral species in the coma from pre- to post-equinox that are indicative of seasonally driven nucleus heterogeneity. Conclusions. The observed pre- and post-equinox patterns can generally be explained by the strong erosion in the southern hemisphere that moves volatile-rich layers near the surface.

comets↗

Sulfur outgassing and in-gassing in lunar orange glass beads and implications for 33S “Anomaly” in the Moon

Our recent investigations have discovered inward diffusion (in-gassing) of moderately volatile elements (MVEs; e.g., Na, K and Cu) from volcanic gas into volcanic beads/droplets. In this work, we examine the distribution of sulfur in lunar orange glass beads. Our analyses reveal that sulfur exhibits a non-uniform distribution across the beads, forming “U” or “W” shaped profiles typical of in-gassing. A model developed to assess sulfur contributions from different sources (original magmatic sulfur versus atmospheric in-gassed sulfur) in the orange beads indicates that atmospheric sulfur in-gassed during eruption contributes approximately 9–24 % to the total sulfur content of an orange bead, averaging around 16 %. This in-gassed sulfur is derived from the eruption plume, where atmospheric sulfur could undergo photochemical reactions induced by UV light, leading to mass independent fractionation and a distinct sulfur isotope signature. Interestingly, a recent study discovered a small mass independent isotope fractionation of sulfur in lunar orange glass beads in drive tube 74002/1 and a lack of such mass independent isotope fractionation in black glass beads in the same lunar sample. This finding contrasts with sulfur in lunar basalts, which typically exhibit mass dependent fractionation. With our work, the observed mass independent fractionation signal in sulfur isotopes of orange beads can be attributed to the in-gassing of photolytic sulfur in the optically thin part of the eruption plume where UV light can penetrate. Using the sulfur isotope data of lunar orange beads, we estimate that the Δ33S value of atmospheric sulfur is approximately −0.18 ‰. Our study provides new insights into the complex dynamics of volatile elements in lunar volcanic processes, highlighting the role of in-gassing in shaping sulfur isotope signatures in volcanic glass beads.

Xue Su↗