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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 181 records · Page 10
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Black hole and galaxy co-evolution in radio-loud active galactic nuclei at z ~ 0.3–4

The relation between the mass of the supermassive black hole (SMBH) in the center of galaxies and their bulge mass or central velocity dispersion is well known. This suggests a coevolution between the SMBHs and their galaxy hosts. Our aim is to study this relation, specifically, for radio loud galaxies, and as a function of redshift z. We selected a sample of 42 radio galaxies and active galactic nuclei (AGN) with broad emission lines and spectroscopic redshifts between z = 0.3 - 4 by cross-matching the low radio frequency sources from Very Large Array (VLA) FIRST with spectroscopically confirmed galaxies from wide-field surveys, including Sloan Digital Sky Survey (SDSS) DR14 ugriz and Dark Energy Survey (DES) DR2 grzY in the optical, Wield Infrared Survey Explorer (WISE), and the Galaxy And Mass Assembly (GAMA) spectroscopic survey. We characterized the stellar mass (M $\star$ ), star formation, and black hole properties (mass of the central SMBH, Eddington ratio η, and jet power, Q jet ). The relation between SMBH mass, M $\star$ , η, and z is placed into context by comparing them with scaling relations (M BH –M $\star$ , M BH /M $\star$ –z, M BH –Q jet , and Q jet –η) from the literature. On the basis of a multiwavelength spectral energy distribution modeling, our radio sources are broadly consistent with being on the star-forming main sequence. They have sub-Eddington accretion rates, η ≃ 1% on average, as typically found in type I AGN, while higher accretion rates favor more powerful jets to be launched by the central engine. We find overmassive SMBHs in (17 ± 5)% of our radio sources, similarly to previous studies on nearby early-type galaxies. Altogether, an evolutionary scenario in which radio-mode AGN feedback regulates the accretion onto the SMBHs and the stellar mass assembly of the radio sources is discussed, which may explain the observed phenomenology. This pilot study represents a benchmark for future studies using wide-field surveys such as those with Euclid and the Vera Rubin Observatory.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2021

Effect of electrode rinse solutions on the electrodialysis of concentrated salts

The data presented indicate that modest attention to the chemistry of the electrode rinse solution can yield as much as 56% improvement in process efficiency. When operating electrodialysis (ED) with salt concentrations greater than 10,000 mg/l (as NaCl) the amperage can be relatively high even at low voltages. To maximize the overall rate of ion transport from diluate to concentrate, there is a need to minimize resistances in the electrode cells since these can represent as much as 30% of the total resistances in the entire process and in this particular ED unit, represented resistance roughly equivalent to that within the membrane stack. This work describes the performance of a 10-cell pair, 200 cm 2 (0.02 m 2 ) per membrane, pilot ED unit operated in batch mode at 5 V potential. The feedstock to the stack was varied from 0.5% to 6% NaCl. Results from Volt-amp profiles (2.0–15 V) were used as the rationale for choosing the preferred electrode rinse solution, 90 g/l (kg/m 3 ) disodium sulfate at pH 12.5. The recommended solution of 30 g/l (kg/m 3 ) disodium sulfate at neutral pH was tested against stronger solutions (60, 90, and 120 g/l (kg/m 3 ) disodium sulfate) at neutral pH and with 1 g/l (kg/m 3 ) sodium hydroxide added to yield solutions at pH 12.5. There were stark differences in the performance of the ED unit between the solutions at pH 7 and those at pH 12.5. The slopes of the Volt-amp profiles improved indicating less resistance to ion flow at pH 12.5. Most of the difference can be attributed to the greater conductivity of sodium hydroxide compared to disodium sulfate, where even a modest addition of 1 g/l (kg/m 3 ) sodium hydroxide increased the conductivity of the solution between 8 and 20% depending on the concentration of disodium sulfate. Most notably, the initiation voltage was 2.39 ± 0.08 V with solutions at pH 7 and 1.99 V ± 0.04 V when the rinse solutions were around pH 12.5, a difference of around 0.42 V. Since the full batch runs were performed at 5.0 V, this 0.42 V differential represented a loss of 8% in process efficiency. A series of tests showed a shift in initiation voltage occurred between pH 11.5 and 12.5. Nernst equations for water electrolysis are coupled with a simple flux model that estimates the concentration of hydroxide and hydronium ions at the electrode surfaces. This model indicates that the potential demanded by the electrodes is directly linked to the current. Furthermore, there is a steep drop in the potential demanded by the anode when there is sufficient hydroxide available to generate oxygen from hydroxide as opposed to generation from water. The voltage demand is minimal at pH 12.5 and reflective of the reference standard voltage (just over 1.23 V predicted at 0.1 amps). However, the flux model predicts that the voltage demanded by the electrodes at pH 7 is 1.61 V at 0.1 amps (the lowest amperage measurable with the power pack). In conclusion, comparing this result to the reference standard (E 0 = -1.23 V) yields a satisfactory explanation for the observed difference below reference standard of 0.42 V.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2025

A Combined Water and CO 2 Direct Air Capture System (Final Technical Report)

The primary objective of the project was to demonstrate the technical and economic performance of a technology that simultaneously captures CO 2 and water from the air – a Hybrid Direct Air Capture system (HDAC). In HDAC, air is passed over water capture section as well as a CO 2 selective sorbent to remove CO 2 from the air stream. Combining potable water generation and CO 2 capture in a single device with the unique energy conserving features of the proposed design enables long-term projected CAPEX under $\$$750/t-CO 2 and levelized cost of capture (LCOC) of $\$$140/t-CO 2 . Project DE-FE-0031970 "A Combined Water and CO 2 Direct Air Capture System" ran for four years and three months from 10/01/2020 to 12/31/2024 for three budget periods and an extension period. The total project budget at completion was $\$$3,534,408 consisting of a $\$$2,680,064 federal share and $\$$854,344 cost share. The pilot plant was successfully designed, engineered, built and commissioned during the initial three budget periods. The plant demonstrated successful water capture during this period, whereas initial CO 2 capture was well below target values. The project team requested an extension period during which alternate materials and beds were evaluated. By the end of the project, both moisture swing adsorption of CO 2 and water capture had successfully been demonstrated at target capture rates making further scale-up of the technology viable.

42 ENGINEERING↗
DOE OSTI2023

Optimization of operational strategies for rich gas enhanced oil recovery based on a pilot test in the Bakken tight oil reservoir

Horizontal well drilling and multistage hydraulic fracturing have been demonstrated as effective approaches for stimulating oil production in the Bakken tight oil reservoir. However, after multiple years of production, primary oil recovery in the Bakken is generally less than 10% of the estimated original oil in place. Gas huff ‘n’ puff (HnP) has been tested in the Bakken Formation as an enhanced oil recovery (EOR) method; however, most field pilot test results showed no significant incremental oil production. One of the factors affecting HnP EOR performance is premature gas breakthrough, which is one of the most critical issues observed in the field because of the presence of interwell fractures. Consequently, injected gas rapidly reaches adjacent production wells without contacting reservoir rock and increasing oil recovery. Proper conformance control is therefore needed to avoid early gas breakthrough and improve EOR performance. In this study, a rich gas EOR pilot in the Bakken was carefully analyzed to collect the essential reservoir and operational data. A simulation model with 16 wells was then developed to reproduce the production history and predict the EOR performance with and without conformance control. EOR operational strategies, including single- and multiple-well HnP, with different gas injection constraints were investigated. The simulation results of single-well HnP without conformance control showed that a rich gas injection rate of at least 10 MMscfd was needed to yield meaningful incremental oil production. The strategy of conformance control via water injection could significantly improve oil production in the HnP well, but injecting an excessive amount of water also leads to water breakthrough and loss of oil production in the offset wells. By analyzing the production performance of the wells individually, the arrangement of wells was optimized for multiple-well HnP EOR. The multiwell results showed that rich gas EOR could improve oil production up to 7.4% by employing conformance control strategies. Furthermore, replacing rich gas with propane as the injection gas could result in 14% of incremental oil production.

02 PETROLEUM↗
DOE OSTI2022

Experimental Investigation of Polymer-Induced Fouling of Heater Tubes in the First-Ever Polymer Flood on Alaska North Slope Part II

A polymer flood pilot has been ongoing in the Schrader Bluff viscous oil reservoir at Milne Point on the Alaska North Slope. The results from the pilot are encouraging. However, a major concern of the operator is the influence of polymer on the production system after breakthrough, especially the fouling in heat exchangers. This work applies a multiexperimental approach to study the severity of polymer-induced fouling in both dynamic and static states of produced fluids to determine safe operating conditions. Dynamic scale loop (DSL) tests were conducted to study fouling due to polymer at different skin temperatures (165–350°F) in a dynamic state of fluid flow where the fluids’ flow mimics the residence time of fluids in the heat exchanger of the field pilot. Static deposit tests were also conducted at similar skin temperatures of 165–250°F using a novel experimental apparatus designed and built in-house. It was found that at higher skin temperatures of 250–350°F, tube blocking was observed in the DSL tests, whereas the tests at 165–200°F did not show any tube blocking, even in a more extended test period. The deposit test showed that the deposit rate generally increases with skin temperature, and the presence of polymer aggravates the fouling. The copper tube performs best when the skin temperatures are 165–200°F, while the stainless steel tube performs best at a skin temperature of 250°F. These experiments also manifested the influence of the cloudpoint of the solution as the deposit rate increased significantly when the skin temperature was higher than the solution cloudpoint. The study provides a source of practical guidance to the field operations.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

Vitrification of Inactive Incineration Ash in a Full Industrial Scale In Can Melter - 20502

In the framework of the H2020 THERAMIN project funded by the European Commission, CEA performed a pilot-scale trial consisting of the vitrification of inactive ash (Al, Ca, Si, Zn, Bi, K, Mg, etc.) using the In- Can Melter technology. These ashes were coming from incineration of simulated technological wastes such as cotton, latex, neoprene, polyethylene. The borosilicate glass feasibility was first evaluated at a laboratory scale (10-100 g of glass). The volatile behavior of fly ash was controlled by pelletizing to avoid pipes clogging when performing the pilot scale test. A 10 wt.% inorganic binder was added to obtain cohesive pellets. The glass frit composition was selected and its ratio was fixed at 50 wt.%. After this step, a bench test (1 kg of glass) was done to verify the absence of container corrosion. Finally, it was followed by a pilot scale test (50 kg of glass) with 75,000 ash pellets used. The same glass microstructure and chemical composition were observed at each scale. Typical crystals of apatites (Ca, P), zincochromites (Zn, Cr, Al) and bismuth alloys (Bi, Sb) dispersed into a borosilicate glass matrix were observed. The chemical durability of the wasteform was measured during 28 days in a 90 deg. C water. Although there were durable crystalline phases, the hydrolysis rate of the vitreous part is relatively high because of the B and Na contents. However, leach rate profiles suggest that an alteration layer will form, leading to an alteration rate decrease. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2021

Kiloparsec-scale AGN outflows and feedback in merger-free galaxies

ABSTRACT Recent observations and simulations have challenged the long-held paradigm that mergers are the dominant mechanism driving the growth of both galaxies and supermassive black holes (SMBH), in favour of non-merger (secular) processes. In this pilot study of merger-free SMBH and galaxy growth, we use Keck Cosmic Web Imager spectral observations to examine four low-redshift (0.043 < z < 0.073) disc-dominated ‘bulgeless’ galaxies hosting luminous active galactic nucleus (AGN), assumed to be merger-free. We detect blueshifted broadened [O iii] emission from outflows in all four sources, which the $\mathrm{[O\, \small {III}]}$/$\rm {H}\beta$ ratios reveal are ionized by the AGN. We calculate outflow rates in the range $0.12{-}0.7~\rm {M}_{\odot }~\rm {yr}^{-1}$, with velocities of $675{-}1710~\rm {km}~\rm {s}^{-1}$, large radial extents of $0.6{-}2.4~\rm {kpc}$, and SMBH accretion rates of $0.02{-}0.07~\rm {M}_{\odot }~\rm {yr}^{-1}$. We find that the outflow rates, kinematics, and energy injection rates are typical of the wider population of low-redshift AGN, and have velocities exceeding the galaxy escape velocity by a factor of ∼30, suggesting that these outflows will have a substantial impact through AGN feedback. Therefore, if both merger-driven and non-merger-driven SMBH growth lead to co-evolution, this suggests that co-evolution is regulated by feedback in both scenarios. Simulations find that bars and spiral arms can drive inflows to galactic centers at rates an order of magnitude larger than the combined SMBH accretion and outflow rates of our four targets. This work therefore provides further evidence that non-merger processes are sufficient to fuel SMBH growth and AGN outflows in disc galaxies.

Smethurst, R. J. (ORCID:0000000164177196)↗
DOE OSTI2022

Carbon-negative production of acetone and isopropanol by gas fermentation at industrial pilot scale

Many industrial chemicals that are produced from fossil resources could be manufactured more sustainably through fermentation. In this work, we describe the development of a carbon-negative fermentation route to producing the industrially important chemicals acetone and isopropanol from abundant, low-cost waste gas feedstocks, such as industrial emissions and syngas. Using a combinatorial pathway library approach, we first mined a historical industrial strain collection for superior enzymes that we used to engineer the autotrophic acetogen Clostridium autoethanogenum. Next, we used omics analysis, kinetic modeling and cell-free prototyping to optimize flux. Finally, we scaled-up our optimized strains for continuous production at rates of up to ~3 g/L/h and ~90% selectivity. Life cycle analysis confirmed a negative carbon footprint for the products. Unlike traditional production processes, which result in release of greenhouse gases, our process fixes carbon. These results show that engineered acetogens enable sustainable, high-efficiency, high-selectivity chemicals production. We expect that our approach can be readily adapted to a wide range of commodity chemicals.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2024

Ion Exchange Processes for CO 2 Mineralization Using Industrial Waste Streams: Pilot Plant Demonstration and Life Cycle Assessment

Abstract An attractive technique for removing CO 2 from the environment is sequestration within stable carbonate solids (e. g., calcite). However, continuous addition of alkalinity is required to achieve favorable conditions for carbonate precipitation (pH>8) from aqueous streams containing dissolved CO 2 (pH<4.5) and Ca 2+ ions. In this study, a pH‐swing process using ion exchange was demonstrated to process 300 L of produced water brine per day for CO 2 mineralization. Proton titration capacities were quantified for aqueous streams in equilibrium with gas streams at various concentrations of CO 2 (pCO 2 =0.03–0.20 atm) and at various flow rates (0.5–2.0 L min −1 ). Energy intensities for the process were determined to be between 30 and 65 kWh per tonne of CO 2 sequestered depending on the composition of the brine stream. A life cycle assessment was performed to analyze the net carbon emissions of the technology which indicated a net CO 2 reduction for pCO 2 ≥0.12 atm (−0.06–−0.39 kg CO 2 e per kg precipitated CaCO 3 ) utilizing calcium‐rich brines. The results from this study indicate the ion exchange process can be used as a scalable method to provide alkalinity necessary for the capture and storage of CO 2 in Ca‐rich waste streams.

Chemistry↗
DOE OSTI2024

Advances in the Large Area Picosecond Photo-Detector (LAPPD TM ): 8" × 8" MCP-PMT with Capacitively Coupled Readout

Abstract We present advances made in the Large Area Picosecond Photodetector (LAPPD), an 8" × 8" microchannel plate photomultiplier tube (MCP-PMT), since pilot production was initiated at Incom, Inc. in 2018. The Gen-I LAPPD utilizes a stripline anode for direct charge readout. The novel Gen-II LAPPD employs an internal resistive thin-film which capacitively couples to a customizable external signal readout board, streamlining production and increasing customer flexibility. The Gen-II LAPPD, with an active area of 373 cm 2 , is capable of high single photoelectron (PE) gain of ∼10 7 , low dark rates (∼1 kHz/cm 2 ), single PE (SPE) timing resolution of ∼65 ps, and 𝒪(mm) position resolution. Coupled with a UV-grade fused silica window, the LAPPD features a high quantum efficiency (QE) bialkali photocathode of >30% at 365 nm with spectral response down to ∼165 nm. The LAPPD is an excellent candidate for electromagnetic calorimeter (ECAL) timing layers, photon-based neutrino detectors, high energy collider experiments, medical imaging systems, and nuclear non-proliferation applications.

Instruments & Instrumentation↗
DOE OSTI2025

Approach for High Methanol Substitution by Energy with Conventional and Bio Pilot Fuels

Green methanol is emerging as a promising route to decarbonize the commercial marine industry. However, methanol is not a drop-in fuel in the compression ignition engines that dominate the marine industry because it is difficult to ignite due to its low cetane number and high latent heat of vaporization. The most straight-forward way to use methanol in the compression ignition engines is to premix the methanol, such as with port fuel injection during the intake stroke, and igniting the methanol with a diesel pilot injection. Because diesel fuel is still used in this strategy, it does not fully displace the petroleum diesel fuel. To completely displace the petroleum-derived diesel fuel, this investigation presents experimental results comparing diesel and biodiesel pilot ignition in a dual-fuel strategy with methanol in a marine-variant of a Cat® C18 18 L engine with a 145 mm bore. Engine performance and emissions characteristics are presented that include effects of diesel vs. biodiesel across a series of fuel injection timing and other operating parameters, including intake manifold pressure and engine load. Results presented include in-cylinder pressure and combustion-related findings about heat release, methanol fuel energy substitution rates greater than 75% from 1 to 18 bar BMEP on a single cylinder engine at 1800 RPM. Criteria pollutants including particulate matter, NOx (NO and NO2), unburned fuel, and formaldehyde, as well as the overall BSFC and FSN of the combustion process relative to the baseline diesel operation.

Splitter, Derek [ORNL] (ORCID:0000000174044047)↗
DOE OSTI2020

System Design of a 2.0 MWth Sodium/Molten Salt Pilot System

Nitrate molten salt concentrating solar power (CSP) systems are currently deployed globally and are considered state-of the art heat transfer fluids (HTFs) for present day high-temperature operation. Although slightly higher limits may be possible with molten salt, to fully realize SunShot efficiency goals of $15/kWhth HTFs and an LCOE of 6¢/kWh, HTF technologies working at higher temperatures (e.g., 650 °C to 750 °C) will require an alternative to molten salts, such as with alkali metal systems. This investigation explores the development of a 2.0 MWth sodium receiver system that employs a sodium receiver as the HTF, as well as with a ternary chloride (20%NaCl/40%MgCl/40%KCl by mol wt.%) salt as a thermal energy storage (TES) medium to facilitate a 6-hr. storage duration. A sodium-to-salt heat exchanger model as well as a salt-to-sCO2 primary heat exchanger model are employed and evaluated in this investigation. A thermodynamic system design model was developed using Engineering Equation Solver (EES) where state properties were calculated at inlets and outlets along both hot and cold legs of the pilot-scale plant. This investigation assesses receiver performance as well as system efficiency studies for the pump and system operational ranges. Results found that high efficiency sodium receivers were found to have higher heat transfer coefficients and required far less spreading of incident flux. The system performance model results suggest that for a pump speed of 2400 RPM, respective hot and cold pump TDH values were determined to be 260.1–307 ft. and 260.1–307 ft for pump flow rates of 90–120 GPM.

41 EE - Solar Energy Technologies Office (EE-4S)↗
DOE OSTI2022

Process Model-Based Validation of the Intensification of Biomass Fast Pyrolysis in a Fluidized Bed via Autothermal Operation

A model for the fluidized-bed pyrolysis of biomass is extended to enable the simulation of intensified autothermal operation. In this system, partial oxidation of char and pyrolysate species replaces an external heat source to supply the enthalpy of pyrolysis, greatly increasing the throughput of a given fast pyrolysis reactor. Oxidation reactions are compiled from CRECK and other literature sources and extended to cover the species found in pyrolysis products, including a derivation of the catalytic effect of ash on char combustion from experimental studies at Iowa State University (ISU). Results indicate a roughly 3-fold increase in biomass throughput for a given reactor volume at the pilot scale with minimal loss of valuable products, in agreement with published data from the 3 × 10 -2 m 3 reactor operated by ISU. Additionally, a proposal for a 250 ton/day commercial-scale biomass pyrolysis reactor is analyzed, showing that the same size reactor operated by heating the fluidizing gas externally would have only one-tenth the capacity; if operated by heating the sand externally, the sand would need to circulate at an impractical 0.7 bed volume per minute rate to maintain a 250 ton/day biomass throughput.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2024

Analyzing Potential Failures and Effects in a Pilot-Scale Biomass Preprocessing Facility for Improved Reliability

This study demonstrates a failure identification methodology applied to a preprocessing facility generating conversion-ready feedstocks from biomass meeting conversion process critical quality attribute (CQA) specifications. Failure Modes and Effects Analysis (FMEA) was used as an industrially relevant risk analysis approach to evaluate a logging residue preprocessing system to prepare feedstock for pyrolysis conversion. Risk evaluations considered both system-level and operation unit-level assessments considering process efficiency, product quality, cost, sustainability, and safety. Key outputs included estimations of semi-quantitative risk scores for each failure, identification of the failure impacts, identification of failure causes associated with material attributes and process parameters, ranking success rates of failure detection methods, and speculation of potential mitigation strategies for decreasing failure risk scores. Results showed that deviations from moisture specifications had cascading consequences for other CQAs along with process safety implications. Failures linked to fixed carbon specifications carried the highest risk scores for product quality and process efficiency impacts. As increased throughput can be inversely related to meeting product quality specifications; achieving throughput and other material-based CQAs simultaneously will likely require system optimization or prioritization based on system economics. Ultimately, this work successfully demonstrates FMEA as a risk analysis approach for other bioenergy process systems.

09 BIOMASS FUELS↗
DOE OSTI2020

Pyrolysis of Radioactive Spent Resins in the PRIME Installation - 20190

Montair and Belgoprocess developed the pilot PRIME (Pyrolysis Resins In Mobile Electric) Installation for treatment of spent resins in one single reactor without pre-treatment and without intermixing of other waste, allowing for easy traceability and isotopic characterization of the end product. Both low level waste (LLW, < 2 mSv/h) and medium level waste (MLW, > 2 mSv/h) can be treated in the installation. The PRIME pilot installation is designed to treat 2 batches of 100 liter of saturated ion exchange resins over a period of 24 hours. A dosing unit with screw feeder is used for the dosing of the saturated ion exchange resins to the pyrolysis reactor. This completely new developed innovative pyrolysis reactor contains a special design mechanical stirrer and can operate at a temperature of up to 600 deg. C under inert conditions. As a result, the organic molecules will decompose at an accelerated rate until only the mineralized material remains. The lower temperature and the absence of oxygen also prevent the breakdown of ion exchange resins into (powdery) ash, which is a considerable advantage during further handling. Gases that are released during drying and pyrolysis are treated in an also newly developed thermal oxidizer, which uses an innovative, electrically heated design instead of a traditional natural gas- or fuel oil secondary combustion chamber design. After passing through the thermal oxidizer, the gases are cooled down to saturation temperature and treated in the wet scrubbing system. An extraction fan keeps the system under negative pressure to prevent the possibility of any off-gas leakage out of the system. A series of tests were performed successfully with wet cationic resins, anionic resins and a mixture of both. The results of these tests are described in the presentation. For intellectual property protection, the system and process of pyrolysis of organic waste and the system of thermal oxidation of pyrolysis gases described in this paper are patent pending. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2023

Safety and efficacy of peripheral nerve blocks to treat refractory headaches after aneurysmal subarachnoid hemorrhage – A pilot observational study

Objectives: Headache after aneurysmal subarachnoid hemorrhage (HASH) is common, severe, and often refractory to conventional treatments. Current treatment standards include medications including opioids, until the pain is mitigated. Peripheral nerve blocks (PNBs) may be an effective therapeutic option for HASH. We conducted a small before-and-after study of PNBs to determine safety, feasibility, and efficacy in treatment of HASH. Methods: We conducted a pilot before-and-after observational study and collected data for 5 patients in a retrospective control group and 5 patients in a prospective intervention PNB group over a 12-month period. All patients received a standard treatment of medications including acetaminophen, magnesium, gabapentin, dexamethasone and anti-spasmodics or anti-emetics as needed. Patients in the intervention group received bilateral greater occipital, lesser occipital, and supraorbital PNBs in addition to medications. The primary outcome was pain severity, measured by Numeric pain rating scale (NPRS). All patients were followed for 1 week following enrollment. Results: The mean ages in the PNB group and control group were 58.6 and 57.4, respectively. One patient in the control group developed radiographic vasospasm. Three patients in both groups had radiographic hydrocephalus and IVH, requiring external ventricular drain (EVD) placement. The PNB group had an average reduction in mean raw pain score of 2.76 (4.68, 1.92 p = 0.024), and relative pain score by 0.26 (0.48, 0.22 p = 0.026), compared to the control group. The reduction occurred immediately after PNB administration. Conclusion: PNB can be a safe, feasible and effective treatment modality for HASH. Further investigations with a larger sample size are warranted.

60 APPLIED LIFE SCIENCES↗
DOE OSTI2025

Development of the Well-to-Wake Life Cycle Assessment Model for Marine Fuels in R&D GREET 2025

The Marine analysis capabilities in the 2025 Research and Development Greenhouse gases, Regulated Emissions, and Energy use in Technologies (R&D GREET) have been updated to incorporate the latest findings from the Fourth International Maritime Organization (IMO) GHG Study.1 To support these updates and enhance user flexibility, the former single marine module used in previous R&D GREET versions has been split into two workbook tabs: The Marine_Fuel tab, which covers the fuel-cycle, and the Marine_Trip tab, which covers the trip-cycle. In the Marine_Fuel tab, fuel cycle results for 39 marine fuels are available—assuming a slow speed diesel engine—and can be seen in Appendix A. However, there are options for changing feedstocks for multiple fuels, ability to view results with or without pilot fuels for fuels such as methanol and ammonia, and carbon capture options. All these combinations make the number of total possible pathways over one hundred. For each pathway, life cycle emission results are divided into feedstock, conversion, and combustion categories, along with pilot fuel supply chain emissions for fuels used in dual fuel engines. In the newly created Marine_Trip tab, users can view the life cycle emissions of using these fuels from a trip perspective. Compared to R&D GREET 2024, 16 new types of vessels are added in R&D GREET 2025. Examples of results assuming the default size for each vessel type are available in Appendix A. Additional information categories on vessels are included such as vessel size, main propulsion type, engine power rating, combustion cycle, etc. based on the Fourth IMO GHG Study. Operational mode of the trip, fuel consumption, and load calculation were updated based on the report. The fuel consumption calculation also incorporates low-load adjustment, speed–power correction, weather correction, and fouling correction factors. Furthermore, fuel consumption in boilers or steam turbines is also added for the first time, besides fuel use in main propulsion engines and auxiliary engines. This effort makes the R&D GREET Marine capabilities more robust than before. Users will be able to estimate fuel consumption more accurately for more diverse choices of vessel categories, vessel sizes, and energy converters.

09 BIOMASS FUELS↗
DOE OSTI2022

Pilot Test of a Nanoporous, Super-hydrophobic Membrane Contactor Process for Post-combustion CO 2 Capture

GTI Energy and Air Liquide Advanced Separations (ALaS) have been developing a novel hollow fiber membrane contactor (HFMC) technology for post-combustion CO 2 capture. The process combines advantageous features of both absorption and membrane-based separation processes to separate CO 2 from flue gas cost-effectively. The key component of the HFMC technology is the super-hydrophobic, porous hollow fiber, which is made from polyether ether ketone (PEEK). Compared to conventional absorption/desorption technologies, the critical advantage of the HFMC process is the high contact surface area provided by the hollow fibers enabling an increased volumetric mass-transfer rate. In the PEEK HFMC process, the specific surface area has been increased by an order of magnitude over structurally packed or trayed columns, resulting in compact systems with small footprints.

20 FOSSIL-FUELED POWER PLANTS↗