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NASA NTRS1995

Positions and Intensities in the 3v2/v2+v4 Vibrational System of 14NH3 Near 4 micron meters

Ammonia is the fourth most abundant constituent in the atmospheres of Jupiter and Saturn, after hydrogen, helium and methane. This relative abundance is attested by the presence in the infrared planetary spectra of many absorption features observed in the range of fundamental bands and also in the higher bands. Reported are experimental line positions and intensities of selected ammonia bands.

ammonia Jupiter Saturn spectroscopy planetary gass↗

NASA NTRS2015

Challenges of Rover Navigation at the Lunar Poles

Observations from Lunar Prospector, LCROSS, Lunar Reconnaissance Orbiter (LRO), and other missions have contributed evidence that water and other volatiles exist at the lunar poles in permanently shadowed regions. Combining a surface rover and a volatile prospecting and analysis payload would enable the detection and characterization of volatiles in terms of nature, abundance, and distribution. This knowledge could have impact on planetary science, in-situ resource utilization, and human exploration of space. While Lunar equatorial regions of the Moon have been explored by manned (Apollo) and robotic missions (Lunokhod, Cheng'e), no surface mission has reached the lunar poles.

Robotics↗

NASA NTRS1982

The ionization structure of planetary nebulae. 3: NGC 7009

Spectrophotometric observations of emission line intensities were made in 8 positions in the planetary nebula NGC 7009. For the 6 brightest positions, the coverage is from 1400 A to 10,000 A. Standard equations used to correct for the existence of elements in other than the optical observable ionization stages give results over a wide range of ionization that are consistent and agree with abundances calculated using ultraviolet lines. This result is particularly gratifying for N because previously the standard formula gave inconsistent abundances in NGC 7009. The major outstanding problem is that the lambda 4267 CII line implies a C(2+) abundance as much as 12 times greater than that determined from the UV lines. This discrepancy is greatest nearest the central star, as is the case in the planetary nebula NGC 6720. The logarithmic abundances (relative to H=12.00) are: He=11.07, 0=8.68, N=8.10, Ne=8.16, C=8.18, Ar=6.36, and S=7.12. The average of the Ne, Ar, and S abundances agrees to within 5% of that for NGC 6720, but the O, N, nd C abundances average 1.9 times lower in NGC 7009, suggesting that here may have been mixing of processed material in the planetary precursor in NGC 6720.

Barker, T.↗

NASA NTRS2005

Laboratory Evaluation and Application of Microwave Absorption Properties under Simulated Conditions for Planetary Atmospheres

Radio absorptivity data for planetary atmospheres obtained from spacecraft radio occultation experiments, entry probe radio signal absorption measurements, and earth- based or spacecraft-based radio astronomical (emission) observations can be used to infer abundances of microwave absorbing constituents in those atmospheres, as long as reliable information regarding the microwave absorbing properties of potential constituents is available. The use of theoretically-derived microwave absorption properties for such atmospheric constituents, or the use of laboratory measurements of such properties taken under environmental conditions that are significantly different than those of the planetary atmosphere being studied, often leads to significant misinterpretation of available opacity data. For example, new laboratory measurements completed recently by Mohammed and Steffes (2003 and 2004) under this grant (NAG5-12122,5/1/02-4/30/05), have shown that the millimeter-wavelength opacities from both gaseous phosphine (PH3) and gaseous ammonia ("3) under simulated conditions for the outer planets vary significantly from that predicted by theory over a wide range of temperatures and pressures. These results have directly impacted planning and scientific goals for study of Saturn's atmosphere with the Cassini Radio Science Experiment, as discussed below. The recognition of the need to make such laboratory measurements of simulated planetary atmospheres over a range of temperatures and pressures which correspond to the altitudes probed by both radio occultation experiments and radio astronomical observations, and over a range of frequencies which correspond to those used in both spacecraft entry probe and orbiter (or flyby) radio occultation experiments and radio astronomical observations, has led to the development of a facility at Georgia Tech which is capable of making such measurements. It has been the goal of this investigation to conduct such measurements and to apply the results to a wide range of planetary observations, both spacecraft and earth-based, in order to determine the identity and abundance profiles of constituents in those planetary atmospheres.

Steffes, Paul G.↗

NASA NTRS1996

Ways that our Solar System helps us understand the formation of other planetary systems and ways that it doesn't

Models of planetary formation can be tested by comparison of their ability to predict features of our Solar System in a consistent way, and then extrapolated to other hypothetical planetary systems by different choice of parameters. When this is done, it is found that the resulting systems are insensitive to direct effects of the mass of the star, but do strongly depend on the properties of the disk, principally its surface density. Major uncertainty results from lack of an adequate theoretical model that predicts the existence, size, and distribution of analogs of our Solar System, particularly the gas giants Jupiter and Saturn. Nevertheless, reasons can be found for expecting that planetary systems, including those containing biologically habitable planets similar to Earth, may be abundant in the Galaxy and Universe.

NASA Discipline Exobiology↗

NASA NTRS1994

Degassing history and evolution of volcanic activity of terrestrial planets based on radiogenic noble gas degassing models

Current abundances of radiogenic noble gases (4-He, 40-Ar, 129-Xe) in the planetary atmospheres provide valuable information on planetary evolution through their degassing histories. Of these, 40-Ar (from 40-K with half life 1.25 Ga) can be used to envisage long-term degassing from their interior. Present amounts of 36 and 40-Ar should have information on timing and degree of degassing from the interior. On the other hand, 129-Xe (from 129-I with half life 17 Ma) is used in discussing early planetary degassing. Because life time of helium in the atmosphere is short, atmospheric 4-He (from 235-U, 238-U, 232-Th) data might be used only for current degassing. The relative abundance of 40-Ar in the Cytherean atmosphere is 0.26 of that in the Earth's atmosphere. We have executed numerical calculation of a 40-Ar degassing model along with mantle evolution and melt migration. Our result shows that the average magma production rate on Venus is about 5 (km(exp 3)/yr). Duration of plate motion on Venus, if existed, would be less than several hundred million years.

Sasaki, S.↗

NASA NTRS2002

Laboratory Evaluation and Application of Microwave Absorption Properties under Simulated Conditions for Planetary Atmospheres

Radio absorptivity data for planetary atmospheres obtained from spacecraft radio occultation experiments, entry probe radio signal absorption measurements, and earth-based or spacecraft-based radio astronomical (emission) observations can be used to infer abundances of microwave absorbing constituents in those atmospheres, as long as reliable information regarding the microwave absorbing properties of potential constituents is available. The use of theoretically-derived microwave absorption properties for such atmospheric constituents, or the use of laboratory measurements of such properties taken under environmental conditions that are significantly different than those of the planetary atmosphere being studied, often leads to significant misinterpretation of available opacity data. Laboratory measurements have shown that the centimeter-wavelength opacity from gaseous phosphine (PH3) under simulated conditions for the outer planets far exceeds that predicted from theory over a wide range of temperatures and pressures. This fundamentally changed the resulting interpretation of Voyager radio occultation data at Saturn and Neptune. It also directly impacts planning and scientific goals for study of Saturn's atmosphere with the Cassini Radio Science Experiment and the Rossini RADAR instrument. The recognition of the need to make such laboratory measurements of simulated planetary atmospheres over a range of temperatures and pressures which correspond to the altitudes probed by both radio occultation experiments and radio astronomical observations, and over a range of frequencies which correspond to those used in both spacecraft entry probe and orbiter (or flyby) radio occultation experiments and radio astronomical observations, has led to the development of a facility at Georgia Tech which is capable of making such measurements. It has been the goal of this investigation to conduct such measurements and to apply the results to a wide range of planetary observations, both spacecraft- and earth-based, in order to determine the identity and abundance profiles of constituents in those planetary atmospheres,

Steffes, Paul G.↗

NASA NTRS1986

Observations of composition from Pioneer Venus

Long latitude distributions of atmospheric neutral hydrogen were derived at Venus for the period 1979 to 1980. In-situ measurements of H+, O+, O, and CO2 obtained from the ion and neutral mass spectrometers on the Pioneer Venus orbiter are combined with the appropriate chemical equilibrium relationship to determine the abundance of neutral hydrogen which is very difficult to measure directly. The measurements are all obtained below 165 km on the nightside and below 200 km on the dayside, based on evidence for chemical equilibrium prevailing up to those altitudes. During the period examined nearly three complete diurnal cycles were available and a comparison of the year-to-year variation in hydrogen content is made across the dawn region where the distributions of light gases are most pronounced. The dawn bulge in H (and also in He) which was reported from the first diurnal cycle by Brinton et al. is found to persist. Superimposed upon the diurnal variation are strong day-to-day variations in which n(H) changes by as much as a factor of five. Such variations are linked to pronounced changes in the ion and neutral composition which sometimes occur in association with solar wind disturbances passing the planet. The interaction of the solar wind and the planetary environment somehow results in large changes in the relative abundances and scale heights of the ion and neutral species, thus modifying the derived values of n(H). These variations in the ion distributions are not surprising owing to the strong dependence of the nightside ionization upon convection from the dayside and associated sensitivity of this convection to changes in solar wind pressure and interplanetary magnetic field variations. The variation exhibited by the neutrals, however, appears to require some other explanation owing to the limited momemtum transfer between the ions and neturals. Allowing for these short term perturbations, there appears to be no clear evidence for interannual variation in n(H) during the period examined, apparently consistent with the very small change in solar EUV flux over the same interval.

Taylor, H. A., Jr.↗

NASA NTRS2000

Mineralogical and Geochemical Analyses of Antarctic Lake Sediments: A Reflectance and Moessbauer Spectroscopy Study with Applications for Remote Sensing on Mars

Lakebottom sediments from the Dry Valleys region of Antarctica have been analyzed here in order to study the influence of water chemistry on the mineralogy and geochemistry of these sediments, as well as to evaluate techniques for remote spectral identification of potential biomarker minerals on Mars. Lakes from the Dry Valleys region of Antarctica have been investigated as possible analogs for extinct lake environments on early Mars. Sediment cores were collected in the present study from perennially ice-covered Lake Hoare in the Taylor Valley. These sediments were taken from a core in an oxic region of the lake and another core in an anoxic zone. Differences between the two cores were observed in the sediment color, Fe(II)/Fe(III) ratio, the presence of pyrite, the abundance of Fe, S and some trace elements, and the C, N and S isotope fractionation patterns. The results of visible-infrared reflectance spectroscopy (0.3-25 microns) Mossbauer spectroscopy (77 and 4 K) and X-ray diffraction are combined to determine the mineralogy and composition of these samples. The sediments are dominated by plagioclase, K-feldspar, quartz and pyroxene. Algal mats grow on the bottom of the lake and organic material has been found throughout the cores. Calcite is abundant in some layers of the aerobic core (shallow region) and pyrite is abundant in some layers of the anaerobic core (deep region). Analysis of the spectroscopic features due to organics and carbonates with respect to the abundance of organic C and carbonate contents was performed in order to select optimal spectral bands for remote identification of these components in planetary regoliths. Carbonate bands near 4 and 6.8 microns (approx.2500 and 1500/cm) were detected for carbonate abundances as low as 0.1 wt.% CO2. Organic features at 3.38, 3.42 and 3.51 microns (2960, 2925 and 2850/cm) were detected for organic C abundances as low as 0.06 wt.% C. The d13C trends show a more complex organic history for the anaerobic sediments than for the aerobic sediments. The biogenic pyrite found in the anaerobic core is associated with lighter d34S values and high organic C levels and could be used as a biomarker mineral for paleolakes on Mars.

Froeschl, Heinz↗

NASA NTRS1999

Spectroscopic Study of HD 179821 (IRAS 19114+0002): Proto-Planetary Nebula or Supergiant?

A detailed chemical composition analysis of the bright post-AGB candidate HD 179821 (IRAS 19114 + 0002) is presented. The LTE analysis, based on high-resolution (R approximately equal 50,000) and high-quality (S/N approximately equal 300) spectra, yields atmospheric parameters T(sub eff) = 6750 K, log g = 0.5, and xi(sub t) = 5.25 km/s. The elemental abundance results of HD 179821 are found to be [Fe/H] = -0.1, [C/Fe] = +0.2, [N/Fe] = +1.3, [O/Fe] = +0.2, [alpha-process/Fe] = +0.5, and [s-process/Fe] = +0.4. These values clearly differ from the elemental abundances of Population I F supergiants. The C, N, and O abundances and the total CNO abundance value relative to Fe, [C+N+O/Fe] = +0.5, indicate that the photosphere of HD 179821 is contaminated with both the H- and He-burning products of the AGB phase. The evidence for He burning through the 3.alpha process and deep AGB mixing also comes from the observed overabundances of s-process elements. Remarkably, the abundance of the element Na is found to be very large, [Na/Fe] = +0.9. The ratio O/C = 2.6 indicates that the atmosphere is oxygen rich. The results of this abundance study support the argument that HD 179821 is a proto-planetary nebula,. probably with an intermediate-mass progenitor. However, the strength of the O I triplet lines at 7774 A and the distance derived from the interstellar Na I D1 and D2 components imply that the star is a luminous object (M(sub bol) approximately -8.9 +/- 1) and thus a massive supergiant. Thus, while this study contributes important new observational results for this star, an unambiguous determination of its evolutionary status has yet to be achieved.

Reddy, B. E.↗

NASA NTRS1982

Orientation of planetary O/plus/ fluxes and magnetic field lines in the Venus wake

The presence of 'contaminant' heavy ions of planetary origin in the solar wind has long been the subject of intense theoretical and experimental research. Studies of their abundance, acceleration, and direction of motion are important because of their implications on the composition and dynamics of planetary and cometary plasma wakes. The plasma and magnetic field observations made with the Pioneer Venus Orbiter (PVO) at Venus have provided the opportunity to examine the conditions in which planetary ions are picked up by the solar wind. We show here that in the outer regions of the Venusian far wake the displacement of planetary O(plus) particles, characteristic of the Venus upper ionosphere, does not occur necessarily along the magnetic field lines but approximately in the direction of the shocked solar wind.

Perez-De-tejada, H.↗

NASA NTRS2004

Heterodyne Spectroscopy in the Thermal Infrared Region: A Window on Physics and Chemistry

The thermal infrared region contains molecular bands of many of the most important species in gaseous astronomical sources. True shapes and frequencies of emission and absorption spectral lines from these constituents of planetary and stellar atmospheres contain unique information on local temperature and abundance distribution, non-thermal effects, composition, local dynamics and winds. Heterodyne spectroscopy in the thermal infrared can remotely measure true line shapes in relatively cool and thin regions and enable the retrieval of detailed information about local physics and chemistry. The concept and techniques for heterodyne detection will be discussed including examples of thermal infrared photomixers and instrumentation used in studies of several astronomical sources. Use of heterodyne detection to study non-LTE phenomena, planetary aurora, minor planetary species and gas velocities (winds) will be discussed. A discussion of future technological developments and relation to space flight missions will be addressed.

Kostiuk, Theodor↗

NASA NTRS2011

Stable Chlorine Isotopes and Elemental Chlorine by Thermal Ionization Mass Spectrometry and Ion Chromatography; Martian Meteorites, Carbonaceous Chondrites and Standard Rocks

Recently significantly large mass fractionation of stable chlorine isotopes has been reported for terrestrial and lunar samples [1,2]. In addition, in view of possible early solar system processes [3] and also potential perchlorate-related fluid/microbial activities on the Martian surface [4,5], a large chlorine isotopic fractionation might be expected for some types of planetary materials. Due to analytical difficulties of isotopic and elemental analyses, however, current chlorine analyses for planetary materials are controversial among different laboratories, particularly between IRMS (gas source mass spectrometry) and TIMS (Thermal Ionization Mass Spectrometry) groups [i.e. 1,6,7] for isotopic analyses, as well as between those doing pyrohydrolysis and other groups [i.e. 6,8]. Additional careful investigations of Cl isotope and elemental abundances are required to confirm real chlorine isotope and elemental variations for planetary materials. We have developed a TIMS technique combined with HF-leaching/ion chromatography at NASA JSC that is applicable to analysis of small amounts of meteoritic and planetary materials. We present here results for several standard rocks and meteorites, including Martian meteorites.

Nakamura, N.↗

NASA NTRS1988

Spectroscopic observations of the high-ionization planetary nebula NGC 2242 and the H II region K4-45

New optical spectra of two suspected planetary nebulae, K4-45 and NGC 2242, are presented. It is shown that K4-45 (PK 96 + 1) is a reddened H II region with approximately solar abundances, excited by an early B type star. NGC 2242 (PK 170 + 15) is a planetary nebula of exceptionally high ionization, exhibiting He II, and forbidden Ne V, Ar V, Ne III, and O III emission lines. The lack of He I emission and the presence of strong forbidden Ne V and He II emission indicate an optically thin nebula that is ionized by a central star with an effective temperature greater than 100,000 K.

Garnett, Donald R.↗

NASA NTRS1977

The atmosphere of Jupiter from earth-based and spacecraft observations in the thermal infrared

The temperature and cloud structure, relative abundances of H2 and He, and the global climatology of Jupiter's atmosphere have been deduced from Pioneer 10 and 11 infrared radiometer data, along with earth-based observations of the spectrum at 8-14 and 12-24 microns. The H2 and He abundances are near those expected from 'solar' composition. The effective planetary temperature is 125 + or - 3 K. Temperatures at 1.0 bar are near 165 K and drop to 100-110 K at 0.1 bar; an overlying thermal inversion reaches 133-145 K near 0.03 bar. Temperature profiles for various regions of the planet may be quite similar, with differences due to the presence or absence of a thick cloud near 0.7 bar, close to the temperature where NH3 saturation is expected. Remaining problems in the remote sounding of Jupiter's atmosphere are accurate calibration of the global energy balance, sounding in the presence of significant heterogeneity, and temperature recovery of the thermally inverted stratosphere.

Orton, G. S.↗

NASA NTRS1990

Planetary atmospheres: Microwave spectroscopic and space physics

Ground-based spectroscopic observations of isotopes of CO in the atmosphere of Mars, Venus, and Titan were collected over the 1982-1990 period. These observations were analyzed to obtain information on the photochemistry, dynamics, and thermal profiles of these planetary atmospheres. In the cases of the mesosphere (80-100 km altitude) of Venus and the lower atmosphere (0-70 km altitude) of Mars, the primary conclusion of this research is that significant interannual variation in the global, thermal, and compositional structures of these atmospheres occur over 10 year periods. The Titan studies have focussed on pinning down the true atmosphere CO abundance. A more detailed summary of the results for each of these planetary atmospheres is provided.

Clancy, R. Todd↗

NASA NTRS1991

Planetary atmospheres: Microwave spectroscopic studies of planetary atmospheres

Ground-based spectroscopic observations of isotopes of CO in the atmospheres of Mars, Venus, and Titan have been collected over the 1982-1990 period. These observations have been analyzed to obtain information on the photochemistry, dynamics, and thermal profiles of these planetary atmospheres. In the cases of the mesosphere (80-100 km altitude) of Venus and the lower atmosphere (0-70 km altitude) of Mars, the primary conclusion of this research is that significant interannual variations in the global thermal and compositional structures of these atmospheres occur over 10 year periods. The Titan studies have focussed on pinning down the true atmospheric CO abundance. A more detailed summary of the results for each of these planetary atmospheres is provided.

Clancy, R. Todd↗

NASA NTRS1989

The ionization structure of planetary nebulae. IX - NGC 1535

The ionization structure of planetary nebula NGC 1535 was investigated using spectrophotometric observations of emission-line intensities over the spectral range 1400-7200 A, which were carried out in five positions in this nebula. The results obtained on the ionic abundances of He, O, N, Ne, C, and Ar in NGC 1535 suggest that it is a planetary nebula that formed initially in a somewhat metal-poor region and has undergone little or no enhancement of its original abundances by mixing with nuclear-processed material.

Barker, Timothy↗