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At least 181 records · Page 10

Is Water Necessary for Life?

The universality of water as the solvent for life is usually justified by its role in supporting the rich organic chemistry. It has been pointed out, however, that even richer synthetic chemistry is possible in other organic solvents. Does it mean that water is not necessary for life? Here, other, essential criteria for solvent for life that have not been sufficiently considered are discussed. In biological systems, complex molecules are not only constantly synthesized but also degraded. Solvent-mediated degradation is essential for regulating cell content, preventing overcrowding and allowing for recycling organic material. Achieving a balance between synthetic and degradative processes is facile in water, but not in many other organic liquids. Thus, the so-called “water paradox” according to which water is both necessary to life and toxic to biopolymer synthesis might not be paradoxical at all. The machinery of life is based on non-covalent interactions that do not involve making or breaking chemical bonds. Their strength needs to be properly tuned. If they are too weak, there might be undesired response to natural fluctuations of physical or chemical parameters. If they are too strong, the kinetics and energetics of cellular processes could adversely influenced. The solvent must allow for balancing these interactions, which provides strong, universal constraints on the medium for life. Water influences non-covalent interactions mainly by two mechanisms. First, it reduces strong, electrostatic interactions between molecules, chemical groups or atoms carrying electric charge or dipole. Second, it induces the hydrophobic effect, the tendency to remove non-polar (hydrophobic) molecules and groups from direct contact with aqueous solution and, instead, interact with each other. In living systems, the hydrophobic effect is largely responsible for self-organization of molecules to more complex structures, such as aggregation of lipid molecules to form biological membranes and protein folding. Water exists as stable liquid in a large temperature range, and the hydrophobic effects are a consequence of the temperature insensitivity of essential properties of its liquid state. In summary, water accomplishes an amazing feat – it reduces strong interactions between dissolved species and simultaneously increases the strength of weak interactions, bringing all of them to the right range. Once we consider not only synthetic capabilities but also other required traits of the solvent for life, no viable alternative to water is currently known.

Life↗

Magnetic and Electric Field Polarizations of Oblique Magnetospheric Chorus Waves

A theory was developed to explain the properties of the chorus magnetic and electric field components in the case of an arbitrary propagation angle. The new theory shows that a whistler wave has circularly polarized magnetic fields for oblique propagation. This theoretical result is verified by GEOTAIL observations. The wave electric field polarization plane is not orthogonal to the wave vector, and in general is highly elliptically polarized. A special case of the whistler wave called the Gendrin mode is also discussed. This will help to construct a detailed and realistic picture of wave interaction with magnetosphere electrons. It is the purpose of this innovation to study the magnetic and electric polarization properties of chorus at all frequencies, and at all angles of propagation. Even though general expressions for electromagnetic wave polarization in anisotropic plasma are derived in many textbooks, to the knowledge of the innovators, a detailed analysis for oblique whistler wave mode is lacking. Knowledge of the polarization properties is critical for theoretical calculations of resonant wave-particle interactions.

Verkhoglyadova, Olga↗

Estimating the Relative Water Content of Single Leaves from Optical Polarization Measurements

Remotely sensing the water status of plants and the water content of canopies remain long-term goals of remote sensing research. For monitoring canopy water status, existing approaches such as the Crop Water Stress Index and the Equivalent Water Thickness have limitations. The CWSI does not work well in humid regions, requires estimates of the vapor pressure deficit near the canopy during the remote sensing over-flight and, once stomata close, provides little information regarding the canopy water status. The EWI is based upon the physics of water-light interaction, not plant physiology. In this research, we applied optical polarization techniques to monitor the VISNIR light reflected from the leaf interior, R, as well as the leaf transmittance, T, as the relative water content (RWC) of corn (Zea mays) leaves decreased. Our results show that R and T both changed nonlinearly as each leaf dried, R increasing and T decreasing. Our results tie changes in the VISNIR R and T to leaf physiological changes linking the light scattered out of the drying leaf interior to its relative water content and to changes in leaf cellular structure and pigments. Our results suggest remotely sensing the physiological water status of a single leaf and perhaps of a plant canopy might be possible in the future. However, using our approach to estimate the water status of a leaf does not appear possible at present, because our results display too much variability that we do not yet understand.

Leaf Reflectance↗

O(+)-O collision frequency in high-speed flows

Throughout much of the terrestrial thermosphere and ionosphere, the motions of the neutral and ionized constituents are closely coupled and relative velocities are small, of the order of 100 m/s or less. This is particularly true at midlatitudes to low latitudes where typical velocities in the neutral gas due to tidal forcing are only 20-50 m/s. However, the solar wind-magnetosphere interaction drives a large-scale convection pattern in the polar ionosphere. When the rapid adjustment of the plasma to changes in the solar wind is combined with the slower response of the more massive neutral gas, large relative velocities on the order of 1 km/s can exist for substantial lengths of time. This will be more common during periods of high geomagnetic activity, as a result of the greater number of magnetic substorms and other particle precipitation events. When a significant relative velocity is present, the calculation of interaction parameters of the two gases passing through each other, such as collision frequency, must include that velocity. These effects are usually neglected when interpreting wind and ion drift observations. We show how the collision frequency is affected by a directed velocity between any two gases interacting with a power law or exponential potential energy curved. The directed velocity increases the collision frequency at all temperatures for most ion-neutral interactions. For certain power law potentials, such as the charge quadrupole, the collision frequency is decreased. We present an analytic solution for the high-speed collision integral using the resonance charge exchange cross section.

Pesnell, William Dean↗

Geophysical Phenomena in the Polar Cap During Northward Interplanetary Magnetic Field; IUGG General Assembly, 20th, Vienna, Austria, August 1991

The interaction of the Earth's magnetosphere with the solar wind and northward interplanetary magnetic field (IMF) continues to raise scientific interest and controversy. A selected group of papers from a conference on this topic discuss the following subjects: electric field generation, theoretical models of polar-cap convection, polar-cap distributions, dependencies of the polar-cap auroral distribution, and boundary populations in the polar-caps. Also discussed are satellite observations of polar arcs and mapping of the ionospheric convection response.

Troshichev, O. A.↗

Magnetospheric and auroral plasmas: A short survey of progress, 1971 - 1975

Milestones in researches of auroral and magnetospheric plasmas for the past quadrennium 1971 - 1975 are reviewed. Findings, including those of the polar cusp, the polar wind, the explosive disruptions of the magnetotail, the interactions of hot plasmas with the plasmapause, the auroral field-aligned currents, and the striking 'inverted-V' electron precipitation events, are reported. Solutions to major questions concerning the origins and acceleration of these plasmas are discussed. A comprehensive bibliography of current research is included.

Frank, L. A.↗

Magnetospheric and auroral plasmas - A short survey of progress

Important milestones in our researches of auroral and magnetospheric plasmas for the past quadrennium 1971-1975 are reviewed. Many exciting findings, including those of the polar cusp, the polar wind, the explosive disruptions of the magnetotail, the interactions of hot plasmas with the plasmapause, the auroral field-aligned currents, and the striking inverted V electron precipitation events, were reported during this period. Solutions to major questions concerning the origins and acceleration of these plasmas appear possible in the near future. A comprehensive bibliography of current research is appended to this brief survey of auroral and magnetospheric plasmas.

Frank, L. A.↗

Coordinated analysis of various auroral measurements made during NASA's 1968 and 1969 airborne auroral expeditions

Auroral optical measurements made aboard NASA's CV 990 were analyzed. The measurements analyzed form a small part of extensive spectroscopic, photometric and photographic data gathered during the 1968 and 1969 Airborne Auroral Expeditions. Simultaneous particle measurements from ESRO IA satellite were used in the analysis. Information about magnetospheric boundaries, interaction between magnetosheath particles and the terrestrial ionosphere, the polar bulge in helium abundance and excitation mechanisms of the triplet state of atmospheric N2 in auroras was obtained. Further analysis of the data is required to elucidate the relation between 3466 and 5200 A emissions of NI and the excitation of 3726-3729 A emissions from atomic oxygen ions in auroras.

Sivjee, G. G.↗

An ab initio investigation of possible intermediates in the reaction of the hydroxyl and hydroperoxyl radicals

Ab initio quantum chemical techniques have been used to investigate covalently-bonded and hydrogen-bonded species that may be important intermediates in the reaction of hydroxyl and hydroperoxyl radicals. Stable structures of both types were identified. Basic sets of polarized double-zeta quality and large scale configuration interaction wave functions have been utilized. Based upon electronic energies, the covalently-bonded HOOOH species is found to be 26.4 kcal/mol more stable than the OH and HO2 radicals. Similarly, the hydrogen-bonded HO-HO2 species is found to have an electronic energy 4.7 kcal/mol below that of the component radicals, after correction is made for the basis set superposition error. The hydrogen-bonded form is found to be planar, to possess one relatively 'normal' hydrogen bond, and to have lowest energy 3A-prime and 1A-prime states that are essentially degenerate. The 1A-double prime and 3A-double prime excited states produced by rotation of the unpaired OH electron into the molecular plane are found to be very slightly bound.

Jackels, C. F.↗

Polar thermospheric Joule heating, and redistribution of recombination energy in the upper mesosphere

Kellogg (1961), suggested that transport of atomic oxygen from the summer into the winter hemisphere and subsequent release of energy by three body recombination, O+O+N2 yields O2+N2+E, may contribute significantly to the so-called mesopause temperature anomaly. Earlier model calculations have shown that Kellogg's mechanism produces about a 10-percent increase in the temperature from summer to winter at 90 km. This process, however, is partly compensated by differential heating from absorption of UV radiation associated with dissociation of O2. In the auroral region of the thermosphere, there is a steady energy dissipation by Joule heating causing a redistribution and depletion of atomic oxygen due to wind-induced diffusion. With the removal of O, latent chemical energy normally released by three body recombination is also removed, and the result is that the temperature decreases by almost 2 percent near 90 km. Through dynamic feedback, this process reduces the depletion of atomic oxygen by about 25 percent and the temperature perturbation in the exosphere from 10 to 7 percent at polar latitudes. Under the influence of the internal dynamo interaction, the prevailing zonal circulation in the upper thermosphere changes direction when the redistribution of recombination energy is considered.

Mayr, H. G.↗

Particle acceleration by electromagnetic ion cyclotron turbulence

The LF EM-turbulence which furnishes energy for the acceleration of ions in various regions of the earth's magnetosphere efficiently accomplishes its transfer of energy from waves to particles through ion cyclotron resonance (ICR) with the left-hand polarized component of the turbulence; the result of this interaction is a heating of the particle distribution. A general theoretical treatment of ICR heating in a weakly inhomogeneous magnetic geometry is presented, en route to a more detailed examination of auroral ion conics' formation. A substantial simplification of the analysis of the altitude-asymptotic form of the conic distribution is obtained via the similarity transformation introduced into the properties of the electric field spectral density and the earth's dipolar magnetic field.

Crew, G. B.↗

PASP, a high voltage array/plasma interaction experiment

The author discusses the photovoltaic array space power (PASP) experiment, which is designed to obtain data on the interaction between high-voltage photovoltaic arrays and the polar, low-earth plasma environment. Up to six small test arrays (three each of planar and concentrator designs) can be voltage biased over a range of +/- 500 V. During the bias voltage sequence, the array current leakage is measured and array arc events are monitored. If any arcing occurs the arc characteristics will be measured by a transient pulse monitor. An emitter is included to allow voltage bias to be applied to a plasma-charged or uncharged spacecraft. Similarly, the frames of the concentrator arrays can be left floating or can be tied to the negative array terminal. An environmental data scan is made before each bias voltage sequence. This scan collects information on the plasma, array-current-versus-voltage curves, and neutral particle partial pressure. The requirement for high voltages created problems which were met by circuit isolation and logical fault protection.

Burger, Dale R.↗

CATLAC - Calibration and Validation Analysis Tool of Local Area Coverage for the SeaWiFS Mission

Calibration and validation Analysis Tool of Local Area Coverage (CATLAC) is an analysis package for selecting and graphically displaying Earth and space targets for calibration and validation activities on a polar orbiting satellite. The package is written in the Interactive Data Language (IDL) and includes a graphical user interface. Although it is designed specifically for the Sea-viewing Wide Field-of-view Sensor (SeaWiFS) mission, the package can be used for analysis on other Earth-viewing missions. An individual can use text or graphical methods in CATLAC to select Earth targets to be scanned by a satellite. Additional onboard calibration activities (such as observations of the moon, or solar irradiance from a solar diffuser), which use data recorder time, can also be specified. All information pertinent to the creation of a command schedule can be written to a file which is read by a command scheduler. The scheduler can be invoked and the Local Area Coverage (LAC) recording periods can be visually verified using CATLAC. The schedule can also be verified by examining record and error files written by the scheduler.

Woodward, Robert H.↗

Geometric Properties of Possible Volcanoes in the South Polar Region, Mars

In 1987 Tanaka and Scott mapped the south polar region of Mars using Viking Orbiter data and identified several features as volcanoes, probable volcanoes of uncertain origin, or mountains of uncertain origin. Several workers have since studied these features using Mars Orbiter Laser Altimetry (MOLA) data. In the north polar region of Mars volcanic edifices have been identified that have surrounding annular depressions, perhaps formed when magma chamber heat melted surrounding ground ice causing surface subsidence. Our objective is to use Martian south polar volcanoes as indicators of magma-ground ice interactions and as indicators of regional eruptive styles. In this study we use high resolution MOLA data to characterize the geometric parameters of mapped volcanoes and mountains and systematically search for any unidentified volcanic edifices from latitude 55 S to the South Pole.

Polit, A. T.↗

The Sources of Bz Fluctuations within CIRs: Magnetic Storms During the Descending Phase of the Solar Cycle

This presentation examines the magnetic field fluctuations within Corotating Interaction Regions (CIRs) detected by Ulysses at mid- and low-latitudes. CIRs are formed by the interaction of high-speed streams flowing from the polar coronal hole with slow-speed streams. Several wave modes are identified, and the effectiveness of these waves causing magnetic storms at Earth will be discussed.

Space Physics Magnetic Storms Solar Cycles Sun↗

X-ray Evolution of the Nova V959 Mon Suggests a Delayed Ejection and a Non-Radiative Shock

X-ray observations of shocked gas in novae can provide a useful probe of the dynamics of the ejecta. Here we report on X-ray observations of the nova V959 Mon, which was also detected in GeV gamma-rays with the Fermi satellite. We find that the X-ray spectra are consistent with a two-temperature plasma model with non-solar abundances. We interpret the X-rays as due to shock interaction between the slow equatorial torus and the fast polar outflow that were inferred from radio observations ofV959 Mon. We further propose that the hotter component, responsible for most of the flux, is from the reverse shock driven into the fast outflow. We find a systematic drop in the column density of the absorber between days 60 and 140, consistent with the expectations for such a picture. We present intriguing evidence for a delay of around 40 d in the expulsion of the ejecta from the central binary. Moreover, we infer a relatively small (a few times 10−6Msun) ejecta mass ahead of the shock, considerably lower than the mass of 104K gas inferred from radio observations. Finally, we infer that the dominant X-ray shock was likely notradiative at the time of our observations, and that the shock power was considerably higher than the observed X-ray luminosity. It is unclear why high X-ray luminosity, closer to the inferred shock power, is never seen in novae at early times, when the shock is expected to have high enough density to be radiative.

Thomas Nelson↗

Lunar electromagnetic scattering. I - Propagation parallel to the diamagnetic cavity axis.

A general analytic solution is obtained for the interaction of the moon and its downstream cavity with a linearly polarized plane electromagnetic wave propagating parallel to the cavity axis. The solution is formulated in terms of a spherical moon model with arbitrary radially dependent electromagnetic parameters and a nonconducting cylindrical downstream cavity. Use is made of a number of approximations that are consistent with the physical nature of the interaction between the moon and the solar wind.

Schwartz, K.↗

Bit-Serial Adder Based on Quantum Dots

A proposed integrated circuit based on quantum-dot cellular automata (QCA) would function as a bit-serial adder. This circuit would serve as a prototype building block for demonstrating the feasibility of quantum-dots computing and for the further development of increasingly complex and increasingly capable quantum-dots computing circuits. QCA-based bit-serial adders would be especially useful in that they would enable the development of highly parallel and systolic processors for implementing fast Fourier, cosine, Hartley, and wavelet transforms. The proposed circuit would complement the QCA-based circuits described in "Implementing Permutation Matrices by Use of Quantum Dots" (NPO-20801), NASA Tech Briefs, Vol. 25, No. 10 (October 2001), page 42 and "Compact Interconnection Networks Based on Quantum Dots" (NPO-20855), which appears elsewhere in this issue. Those articles described the limitations of very-large-scale-integrated (VLSI) circuitry and the major potential advantage afforded by QCA. To recapitulate: In a VLSI circuit, signal paths that are required not to interact with each other must not cross in the same plane. In contrast, for reasons too complex to describe in the limited space available for this article, suitably designed and operated QCA-based signal paths that are required not to interact with each other can nevertheless be allowed to cross each other in the same plane without adverse effect. In principle, this characteristic could be exploited to design compact, coplanar, simple (relative to VLSI) QCA-based networks to implement complex, advanced interconnection schemes. To enable a meaningful description of the proposed bit-serial adder, it is necessary to further recapitulate the description of a quantum-dot cellular automation from the first-mentioned prior article: A quantum-dot cellular automaton contains four quantum dots positioned at the corners of a square cell. The cell contains two extra mobile electrons that can tunnel (in the quantum-mechanical sense) between neighboring dots within the cell. The Coulomb repulsion between the two electrons tends to make them occupy antipodal dots in the cell. For an isolated cell, there are two energetically equivalent arrangements (denoted polarization states) of the extra electrons. The cell polarization is used to encode binary information. Because the polarization of a nonisolated cell depends on Coulomb-repulsion interactions with neighboring cells, universal logic gates and binary wires could be constructed, in principle, by arraying QCA of suitable design in suitable patterns. Again, for reasons too complex to describe here, in order to ensure accuracy and timeliness of the output of a QCA array, it is necessary to resort to an adiabatic switching scheme in which the QCA array is divided into subarrays, each controlled by a different phase of a multiphase clock signal. In this scheme, each subarray is given time to perform its computation, then its state is frozen by raising its inter-dot potential barriers and its output is fed as the input to the successor subarray. The successor subarray is kept in an unpolarized state so it does not influence the calculation of preceding subarray. Such a clocking scheme is consistent with pipeline computation in the sense that each different subarray can perform a different part of an overall computation. In other words, QCA arrays are inherently suitable for pipeline and, moreover, systolic computations. This sequential or pipeline aspect of QCA would be utilized in the proposed bit-serial adders.

Fijany, Amir↗