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At least 181 records · Page 10

Diazo Printing of ERTS Color Composites

The author has identified the following significant results. ERTS-1 color composites were made with the help of a Diazo developer and printer. Five single channel, density standards were established, using typical ERTS images, in order to determine exposure time. These standards were used to develop a graph from which the exposure time for any transparency can be estimated. Exposure times varied from 3 to 30 minutes, and clear colored polyester sheets from two manufactures were used with slightly different, but equally successful, results.

Mcmurtry, G. J.

Real time outdoor exposure testing of solar cell modules and component materials

Plastic samples, solar cell modules, and sub-modules were exposed at test sites in Florida, Arizona, Puerto Rico, and Cleveland, Ohio, in order to determine materials suitable for use in solar cell modules with a proposed 20-year lifetime. Various environments were encountered including subtropical, subtropical with a sea air atmosphere, desert, rain forest, normal urban, and urban-polluted. The samples were exposed for periods up to six months. Materials found not suitable were polyurethane, polyester, Kapton, Mylar, and UV-stabilized Lexan. Suitable materials were acrylic, FEP-A, and glass. The results of exposure of polyvinylidene fluoride were dependent on the specific formulation, but several types appear suitable. RTV silicone rubber (clear) appears to pick up and hold dirt both as a free film and as a potting medium for modules. The results indicate that dirt accumulation and cleanability are important factors in the selection of solar cell module covers and encapsulants.

Anagnostou, E.

Fretting of AISI 9310 and selected fretting resistant surface treatments

Fretting wear experiments were conducted with uncoated AISI 9310 mating surfaces, and with combinations incorporating a selected coating to one of the mating surfaces. Wear measurements and SEM observations indicated that surface fatigue, as made evident by spallation and surface crack formation, is an important mechanism in promoting fretting wear to uncoated 9310. Increasing humidity resulted in accelerated fretting, and a very noticeable difference in nature of the fretting debris. Of the coatings evaluated, aluminum bronze with a polyester additive was most effective at reducing wear and minimizing fretting damage to the mating uncoated surface, by means of a selflubricating film that developed on the fretting surfaces. Chromium plate performed as an effective protective coating, itself resisting fretting and not accelerating damage to the uncoated surface.

Bill, R. C.

Fretting of AISI 9310 and selected fretting resistant surface treatments

Fretting wear experiments were conducted with uncoated AISI 9310 mating surfaces, and with combinations incorporating a selected coating to one of the mating surfaces. Wear measurements and SEM observations indicated that surface fatigue, as made evident by spallation and surface crack formation, is an important mechanism in promoting fretting wear to uncoated 9310. Increasing humidity resulted in accelerated fretting, and a very noticeable difference in nature of the fretting debris. Of the coatings evaluated, alumimum bronze with a polyester additive was most effective at reducing wear and minimizing fretting damage to the mating uncoated surface, by means of a self-lubricating film that developed on the fretting surfaces. Chromium plate performed as an effective protective coating, itself resisting fretting and not accelerating damage to the uncoated surface.

Bill, R. C.

Studies with the Arapahoe smoke chamber

Samples of polymethyl methacrylate, polyvinyl chloride, polyester, and polystyrene were evaluated using the Arapahoe smoke chamber. These same materials had been previously evaluated using the National Bureau of Standards (NBS) smoke chamber. The percent smoke based on initial weight as determined using the Arapahoe smoke chamber appeared to correlate with the maximum specific optical density under flaming conditions as determined using the NBS smoke chamber. In addition, the percent smoke based on weight loss as determined using the Arapahoe smoke chamber appeared to correlate with the maximum specific optical density under nonflaming conditions as determined using the NBS smoke chamber. The Arapahoe smoke chamber also offers the advantage of high sample throughput and the possibility of related studies of smoke particulates.

Hilado, C. J.

The stereoisomeric composition of phytanyl chains in lipids of Dead Sea sediments

Lipid extracts from five recent Dead Sea sediments were analyzed for isoprenoid compounds and the following were isolated: free and phospholipid-bound di-O-phytanylglycerol, free phytanol and free and esterified phytanic acid. The phytanyl groups of the diether and the free phytanol were oxidized to the corresponding phytanic acid; the stereoisomeric composition of the derived phytanic acids as well as of the ester-bound phytanic acid was determined by open-tubular gas-liquid chromatography of the corresponding methyl esters on butanediolsuccinate polyester. Only the 3R, 7R, 11R-isomer of phytanic acid was detected in each of the phytanate samples, indicating that these phytanyl chains in the Dead Sea sediments are most likely derived from extremely halophilic bacteria rather than from phytol of chlorophyll origin. These findings also provide further evidence that the mixtures of RRR and SRR-phytanic acids previously isolated from organic-rich shales were most likely derived from the phytyl chain in chlorophyll.

Anderson, R.

Silver-Teflon coating improvement

Approximately forty adhesives were subjected to laboratory screening. Seven candidate adhesives were selected from the screening tests and evaluated in a thermal vacuum test on radiator panels similar to the anticipated flight hardware configuration. Several classes of adhesives based on epoxide, polyester, silicone, and urethane resin systems were tested. These included contact adhesives, heat cured adhesives, heat and pressure cured adhesives, pressure sensitive adhesives, and two part paint-on or spray-on adhesives. The panels were tested in a space environmental simulation laboratory chamber during the July 9-20, 1973 time span.

Reed, M. W.

Materials for encapsulation systems for terrestrial photovoltaic arrays

The paper is concerned with glass and polymeric candidate materials and processes for potential encapsulation systems that could be used in low-cost long-life terrestrial photovoltaic arrays. The characteristics of encapsulation systems in use are reviewed, and the properties of proposed materials are examined. These materials include acrylics, epoxies, fluorocarbons, polycarbonates, polyesters, polyimides, polyxylylenes, and silicones. Properties of glass types are also considered. The prospects for glass and polymeric systems are analyzed, and the knowledge gained from a study of existing systems is discussed with attention to weather/aging effects, failures, environments, hazards, costs, development efforts, and materials choices.

Carmichael, D. C.

Toxicity of pyrolysis gases from some cellular polymers

Various samples of cellular polymers were evaluated for toxicity of pyrolysis gases, using the screening test method developed at the University of San Francisco. The cellular polymer samples included polyimide, polymethacrylimide, polybismaleimide, polyurethane, polyisocyanurate, polyethylene, polychloroprene, polyvinyl chloride, polystyrene, polysiloxane, and polyphosphazene. The cellular polymers exhibited varying levels of toxicity under these test conditions. Among the rigid cellular polymers, times to death were shortest with the imide type foams and longest with polyvinyl chloride and polystyrene. Among the flexible cellular polymers, times to death were shortest with polyimide and polyester, and longest with polychloroprene and polysiloxane. Increased char yield was not necessarily associated with reduced toxicity.

Hilado, C. J.

Feasibility of an orbital simulator of stratospheric photochemistry

It is proposed that a stratospheric photochemistry simulator could be created in sun-synchronous orbit, so that diffusion and photochemistry could be decoupled and uncertainties in photochemical reaction rates could be substantially reduced. The proposed test chamber is described, and it is suggested that the technology of superpressure balloons seems to be the best short-term solution to the construction of the proposed facility. Both unreinforced polyester films and gelatin films are considered as candidate chamber coatings. It is noted that the experiments can be performed early in the space-manufacturing era and that at least three dedicated Shuttle launches will be required to establish the proposed facility.

Matloff, G. L.

Flame-resistant textiles

Flame resistance treatment for acid resistant polyamide fibers involving photoaddition of fluorocarbons to surface has been scaled up to treat 10 yards of commercial width (41 in.) fabric. Process may be applicable to other low cost polyamides, polyesters, and textiles.

Fogg, L. C.

Thermal performance evaluation of the Calmac (liquid) solar collector

The procedures used and the results obtained during the evaluation test program on the S. N. 1, (liquid) solar collector are presented. The flat plate collector uses water as the working fluid. The absorber plate is aluminum with plastic tubes coated with urethane black. The glazing consists of .040 in fiberglass reinforced polyester. The collector weight is 78.5 pounds with overall external dimensions of approximately 50.3in. x 98.3in. x 3.8in. The following information is given: thermal performance data under simulated conditions, structural behavior under static loading, and the effects of long term exposure to natural weathering. These tests were conducted using the MSFC Solar Simulator.

Usher, H.

Further development of ultrasonic techniques for non-destructive evaluation based on Fourier analysis of signals from irregular and inhomogeneous structures

To investigate the use of Fourier analysis techniques model systems had to be designed to test some of the general properties of the interaction of sound with an inhomogeneity. The first models investigated were suspensions of solid spheres in water. These systems allowed comparison between theoretical computation of the frequency dependence of the attenuation coefficient and measurement of the attenuation coefficient over a range of frequencies. Ultrasonic scattering processes in both suspensions of hard spheres in water, and suspensions of hard spheres in polyester resin were investigated. The second model system was constructed to test the applicability of partial wave analysis to the description of an inhomogeneity in a solid, and to test the range of material properties over which the measurement systems were valid.

Miller, J. G.

Ignition characteristics of some aircraft interior fabrics

Six samples of aircraft interior fabrics were evaluated with regard to resistance to ignition by radiant heat. Five samples were aircraft seat upholstery fabrics and one sample was an aircraft curtain fabric. The aircraft seat fabrics were 100% wool (2 samples), 83% wool/17% nylon, 49% wool/51% polyvinyl chloride, and 100% rayon. The aircraft curtain fabric was 92% modacrylic/8% polyester. The five samples of aircraft seat upholstery fabrics were also evaluated with regard to resistance to ignition by a smoldering cigarette. The four samples of wool-containing aircraft seat fabrics appeared to be superior to the sample of rayon seat fabric in resistance to ignition, both by radiant heat and by a smoldering cigarette.

Hilado, C. J.

Evaluations of candidate encapsulation designs and materials for low-cost silicon photovoltaic arrays

Three encapsulation designs for silicon photovoltaic arrays based on cells with silk-screened Ag metallization have been evaluated: transparent polymeric coatings over cells laminated between two films or sheets of polymeric materials; cells adhesively bonded to a glass cover with a polymer pottant and a glass or other substrate component. Silicone and acrylic coatings were assessed, together with acrylic sheet, 0.635 mm fiberglass-reinforced polyester sheet, 0.102 mm polycarbonate/acrylic dual-layer film, 0.127 mm fluorocarbon film, soda-lime glass, borosilicate glass, low-iron glass, and several adhesives. The encapsulation materials were characterized by light transmittance measurements, determination of moisture barrier properties and bond strengths, and by the performance of cells before and after encapsulation. Silicon and acrylic coatings provided inadequate protection. Acrylic and fluorocarbon films displayed good weatherability and acceptable optical transmittance. Borosilicate, low-iron and soda-lime-float glasses were found to be acceptable candidate encapsulants for most environments.

Gaines, G. B.

Silicone modified resins for graphite fiber laminates

The development of silicon modified resins for graphite fiber laminates which will prevent the dispersal of graphite fibers when the composites are burned is discussed. Eighty-five silicone modified resins were synthesized and evaluated including unsaturated polyesters, thermosetting methacrylates, epoxies, polyimides, and phenolics. Neat resins were judged in terms of Si content, homogeneity, hardness, Char formation, and thermal stability. Char formation was estimated by thermogravimetry to 1,000 C in air and in N2. Thermal stability was evaluated by isothermal weight loss measurements for 200 hrs in air at three temperatures. Four silicone modified epoxies were selected for evaluation in unidirectional filament wound graphite laminates. Neat samples of these resins had 1,000 C char residues of 25 to 50%. The highest flexural values measured for the laminates were a strength of 140 kpsi and a modulus of 10 Mpsi. The highest interlaminar shear strength was 5.3 kpsi.

Frost, L. W.

Methods for an investigation of the effect of material components on the mechanical characteristics of glass-fiber-reinforced plastics

The materials used in the production of glass reinforced plastics are discussed. Specific emphasis is given to matrix polyester materials, the reinforcing glass materials, and aspects of specimen preparation. Various methods of investigation are described, giving attention to optical impregnation and wetting measurements and the gravimetric determination of the angle of contact. Deformation measurements and approaches utilizing a piezoelectric device are also considered.

Willax, H. O.

Prepolymer dianhydrides

A process for preparing dianhydrides that are miscible with hydroxyl prepolymers at moderate temperatures and can cure hydroxyl prepolymers to elastomers at moderate temperatures is disclosed. The dianhydrides are prepared by solution reaction of a prepolymer diol with excess hydride followed by removal of unreacted dianhydride. The prepolymer dianhydrides are miscible with hydroxyl substituted hydrocarbon prepolymers and cure the prepolymers to polyester-linked elastomers.

Rhein, R. A.