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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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NASA NTRS1987

Silsesquioxanes as precursors to ceramic composites

Silsesquioxanes having the general structure RSiO(1.5), where R = methyl, propyl, or phenyl, melt flow at 70 to 100 C. Above 100 C, free OH groups condense. At 225 C further crosslinking occurs, and the materials form thermosets. Pyrolysis, with accompanying loss of volatiles, takes place at nominally 525 C. At higher temperatures, the R group serves as an internal carbon source for carbo-thermal reduction to SiC accompanied by the evolution of CO. By blending silsesquioxanes with varying R groups, both the melt rheology and composition of the fired ceramic can be controlled. Fibers can be spun from the melt which are stable in argon in 1400 C. The silsesquioxanes also were used as matrix precursors for Nicalon and alpha-SiC platelet reinforced composites.

Hurwitz, F. I.↗
NASA NTRS1987

Constraints on possible precursor AGN sources of the cosmic X-ray background

New limits on small-scale surface brightness fluctuations of the residual cosmic X-ray background are used to reevaluate the conjecture that unresolved precursor AGN sources could be the origin of the flux. The large number of these predominantly X-ray-emitting objects thereby required imposes that their lifetime be longer than previously considered. Attention is drawn to the fact that the reduction in the effective Eddington luminosity limit for such sources due to electron-positron pair opacity could have the effect of increasing their lifetime to an appropriate level.

Boldt, Elihu↗
NASA NTRS1989

Structural comparison of nickel electrodes and precursor phases

Researchers summarize previous Raman spectroscopic results and discuss important structural differences in the various phases of active mass and active mass precursors. Raman spectra provide unique signatures for these phases, and allow one to distinguish each phase, even when the compound is amorphous to x rays (i.e., does not scatter x rays because of a lack of order and/or small particle size). The structural changes incurred during formation, charge and discharge, cobalt addition, and aging are discussed. The oxidation states and dopant contents are explained in terms of the nonstoichiometric structures.

Cornilsen, Bahne C.↗
NASA NTRS1989

Model estimates of enhanced photochemical production of ozone resulting from convective transport of precursors

Vertical profiles of net photochemical ozone production rates and total tropospheric column production rates were estimated using two models, a simple photochemical box model and a time-dependent one-dimensional transport/kinetics model. Photochemical production of ozone is found to dominate over destruction throughout the vertical extent of the troposphere over the central United States during typical summertime convective conditions. The column net production can be enhanced by the transport of the ozone precursors NO and NMHC from the boundary layer to the free troposphere by convective activity.

Pickering, Kenneth E.↗
NASA NTRS1989

Periodic amplitude variations as precursors of plumes of equatorial ionospheric irregularities

Periodic amplitude fluctuations of VHF signals from a geostationary satellite monitored from near the magnetic equator have been observed in the evening hours as precursors of strong Rayleigh fading associated with plumes of irregularities. These periodic fluctuations called amplitude waves exhibit amplitude changes of only 1 to 2 dB and have been observed for up to 30 minutes before the onset of strong scintillations. Individual fades are correlated over distances of at least 120 km in the magnetic east-west direction. The velocity of these wavelike disturbances has been found to be approximately 140 m/s eastward with a corresponding wavelength of 25 km.

Klobuchar, J. A.↗
NASA NTRS1990

Structural comparison of nickel electrodes and precursor phases

In this paper the previous Raman spectroscopic results are summarized and important structural differences in the various phases of active mass and active mass precursors are discussed. Raman spectra provide unique signatures for these phases, and allow one to distinguish each phase, even when the compound is amorphous to X-rays (i.e., does not scatter X-rays because of a lack of order and/or small particle size). The structural changes incurred during formation, charge and discharge, cobalt addition, and aging wil be discussed. The oxidation states and dopant contents are explained in terms of the nonstoichiometric structures.

Cornilsen, Bahne C.↗
NASA NTRS1991

Phase Transformations In Mullite-Precursor Xerogels

Report describes experimental study of phase transformations occurring in monophasic and diphasic xerogels of overall stoichiometric mullite composition during thermal treatment. Mullite valued as refractory material because of relatively high mechanical strength, excellent resistance to thermal shock, high resistance to creep, low density, low thermal conductivity, and stability at high temperature. Part of continuing effort to develop precursor materials transformed into mullite and sintered at temperatures low enough to avoid degradation of non-mullite reinforcing fibers in manufacture of mullite/fiber composites.

Hyatt, Mark J.↗
NASA NTRS1991

Formation of Apollo 14 aluminous mare basalts by replenishment fractional crystallization and assimilation of precursor crust

Apollo 14 aluminous mare basalts (AMB) have been the subject of considerable controversy. These basalts were divided into 5 distinct groups on the basis of RE and HFS element abundances. The groups are similar in major element compositions but display an 8 fold variation in REE abundances. Open-system processes were explored which are common on Earth: combined replenishment fractional crystallization (RFC); and assimilation fractional crystallization (AFC), where the assimilant is a partial melt of precursor crust. RFC often produces decoupled major and trace element variations, while AFC can produce significant variation in incompatible trace element ratios. A model was envisioned by which magmas of Group 5 composition were emplaced in shallow chambers. The Apollo 14 AMB was modeled by RFC using a parental magma of Group 5 composition with the fractionating assemblage consisting of 60 pct. Px, 30 pct. Plag, and 3 pct. Il.

Dickinson, Tammy L.↗
NASA NTRS1992

Glass precursor approach to high-temperature superconductors

The available studies on the synthesis of high T sub c superconductors (HTS) via the glass precursor approach were reviewed. Melts of the Bi-Sr-Ca-Cu-O system as well as those doped with oxides of some other elements (Pb, Al, V, Te, Nb, etc.) could be quenched into glasses which, on further heat treatments under appropriate conditions, crystallized into the superconducting phase(s). The nature of the HTS phase(s) formed depends on the annealing temperature, time, atmosphere, and the cooling rate and also on the glass composition. Long term annealing was needed to obtain a large fraction of the 110 K phase. The high T sub c phase did not crystallize out directly from the glass matrix, but was preceded by the precipitation of other phases. The 110 K HTS was produced at high temperatures by reaction between the phases formed at lower temperatures resulting in multiphase material. The presence of a glass former such as B2O3 was necessary for the Y-Ba-Cu-O melt to form a glass on fast cooling. A discontinuous YBa2Cu3O(7-delta) HTS phase crystallized out on heat treatment of this glass. Attempts to prepare Tl-Ba-Ca-Cu-O system in the glassy state were not successful.

Bansal, Narottam P.↗
NASA NTRS1992

An acetate precursor process for BSCCO (2223) thin films and coprecipitated powders

Since the discovery of high temperature superconducting oxides much attention has been paid to finding better and useful ways to take advantage of the special properties exhibited by these materials. One such process is the development of thin films for engineering applications. Another such process is the coprecipitation route to producing superconducting powders. An acetate precursor process for use in thin film fabrication and a chemical coprecipitation route to Bismuth based superconducting materials has been developed. Data obtained from the thin film process were inconclusive to date and require more study. The chemical coprecipitation method of producing bulk material is a viable method, and is preferred over the previously used solid state route. This method of powder production appears to be an excellent route to producing thin section tape cast material and screen printed devices, as it requires less calcines than the oxide route to produce quality powders.

Haertling, Gene H.↗
NASA NTRS1991

Gas dynamic heating of chondrule precursor grains in the solar nebula

In the present investigation of solar nebula gasdynamic processes which may account for the melting of chondrule precursor grains, both drag heating due to grain relative motion and heating due to collisions with gas molecules in thermal motion are considered in conjunction with the effect of thermally emitted radiation on grain heating and cooling. The melting of chondrule-sized grains is most directly associated with those dust-rich and optically thick zones in which thermal radiation from neighboring grains balances grain radiative cooling. Nebular shock fronts may be capable of furnishing the requisite relative velocities and heated gas regions.

Hood, L. L.↗
NASA NTRS1992

Precursor Space Station Freedom experiments

The NASA Office of Aeronautics and Space Technology uses the In-Space Technology Experiments Program (IN-STEP) as the primary management vehicle to pursue innovative and potentially high payoff space technology experiments. The purpose of this presentation is to provide an overview of the IN-STEP approach in developing precursor Space Station experiments; identify those experiments now in the program; review the key points of the IN-STEP 1992 Announcement of Opportunity; and describe the OAST in-space technology experiments development process.

Breckenridge, Roger A.↗
NASA NTRS1993

An approach for finding long period elliptical orbits for precursor SEI missions

Precursors for Solar System Exploration Initiative (SEI) missions may require long period elliptical orbits about a planet. These orbits will typically have periods on the order of tens to hundreds of days. Some potential uses for these orbits may include the following: studying the effects of galactic cosmic radiation, parking orbits for engineering and operational test of systems, and ferrying orbits between libration points and low altitude orbits. This report presents an approach that can be used to find these orbits. The approach consists of three major steps. First, it uses a restricted three-body targeting algorithm to determine the initial conditions which satisfy certain desired final conditions in a system of two massive primaries. Then the initial conditions are transformed to an inertial coordinate system for use by a special perturbation method. Finally, using the special perturbation method, other perturbations (e.g., sun third body and solar radiation pressure) can be easily incorporated to determine their effects on the nominal trajectory. An algorithm potentially suitable for on-board guidance will also be discussed. This algorithm uses an analytic method relying on Chebyshev polynomials to compute the desired position and velocity of the satellite as a function of time. Together with navigation updates, this algorithm can be implemented to predict the size and timing for AV corrections.

Fraietta, Michael F.↗
NASA NTRS1991

Melatonin and its precursors in Y79 human retinoblastoma cells - Effect of sodium butyrate

We studied the release of melatonin and the production of its precursors, 5-hydroxytryptophan and serotonin, in cultured Y79 human retinoblastoma cells. This biosynthetic capability was found to be dependent on cell differentiation, which was initiated by culturing Y79 cells for 7 days in dishes coated with poly-D-lysine to promote cell adhesion to the surface of the culture dishes. Differentiation was further induced by exposing the cell monolayer to sodium butyrate (3 mM) for three days. This protocol dramatically increased the release of melatonin, and the syntheses of 5-hydroxytryptophan and serotonin in response to forskolin stimulation. Exposure to dopamine or L-DOPA markedly diminished the forskolin-stimulated release of melatonin, as well as the production of 5-hydroxytryptophan and serotonin. These observations indicate that Y79 cells represent a primitive cell line which, following appropriate differentiation can display biochemical characteristics similar to those of the human retina. Moreover, serotonin synthesis and melatonin release appear to be coupled in Y79 ceils.

Deng, Mei H.↗
NASA NTRS1991

Melatonin and its precursors in Y79 human retinoblastoma cells: Effect of sodium butyrate

The release of melatonin and the production of its precursors, S-hydroxytryptophan and serotonin, in cultured Y79 human retinoblastoma cells were studied. This biosynthetic capability was found to be dependent on cell differentiation, which was initiated by culturing Y79 cells for 7 days in dishes coated with poly-D-lysine to promote cell adhesion to the surface of the culture dishes. Differentiation was further induced by exposing the cell monolayer to sodium butyrate (3 mM) for 3 days. This protocol dramatically increased the release of melatonin, and the syntheses of 5-hydroxytryptophan and serotonin in response to forskolin stimulation. Exposure to dopamine (10 micro-M) or L-DOPA (100 micro-M) markedly diminished the forskolin-stimulated release of melatonin, as well as the production of 5-hydroxytryptophan and serotonin. These observations indicate that Y79 cells represent a primitive cell line which, following appropriate differentiation (e.g. treatment with sodium butyrate) can display biochemical characteristics similar to those of the human retina. Moreover, serotonin synthesis and melatonin release appear to be coupled in Y79 cells. The inhibition of melatonin release by dopamine supports the hypothesis that in these cells, melatonin and dopamine are components of a retinal feedback loop.

Deng, Mei Hua↗
NASA NTRS1993

Flash melting of chondrule precursors in excess of 1600 C. Series 1: Type 2 (B1) chondrule composition experiments

Several questions in chondrule production remain an enigma despite years of experiments. What were the melting temperatures experienced by chondrules? What were the physical characteristics of chondrule precursors? How and why did volatile elements (i.e. Na) found within chondrules survive the formation process? We present the initial results of a series of experiments designed to investigate the above questions by using flash melting to duplicate the melting stage of chondrule formation.

Connolly, Harold C., Jr.↗
NASA NTRS1994

The origin of refractory precursor components of chondrules

A percentage of all chondrules from carbonaceous chondrites are intermediate in major-element composition between the rare Ca,Al-rich chondrules and the more abundant ferromagnesian chondrules. Some of them possess fractionated REE and trace-element patterns similar to those in CAI's (Ca-Al-rich inclusions). The abundance patterns are controlled primarily by volatilities expected from a solar composition. On the basis of refractory lithophile fractionations, it is suggested that one of the refractory precursors of C chondrules is a condensate from the nebular gas or an evaporative residue of primitive dust clumps.

Misawa, K.↗
NASA NTRS1994

Chondrule precursors and cooling paths: The sulfur evidence

The behavior of moderately volatile elements (Na and S) is controversial but critical in understanding chondrule precursors and heating processes. Sulfide appeared to be present in most chondrules, but S should have been vaporized during chondrule formation. In fact, S is extensively redistributed in the course of metamorphism, and its abundance at the end of chondrule formation can only be inferred from the least equilibrated chondrites. Our study of 530 chondrules from Renazzo (CR2) and Semarkona (LL3.0) shows partial volatilization of S during chondrule formation and our melting experiments define conditions for total loss or partial retention of S.

Zanda, B.↗