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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 181 records · Page 10
All sourcesNASA NTRSDOE OSTI
NASA NTRSDate not supplied

An Overview of Experiments in The Entry Systems Modeling Project

The Entry Systems Modeling (ESM) project has invested in experiments designed to enhance understanding of salient interactions between thermal protection materials (TPS) and mission-relevant planetary entry environments. An arc-jet campaign has been carried out at the Aerodynamic Heating Facility (AHF) to investigate the spallation of fiber particles as a function of gas composition and to measure the effect of pyrolysis gas flow on the in-depth temperature response of phenolic impregnated carbon ablator (PICA). Moreover, fundamental insights into the pyrolysis and oxidation mechanisms of the phenolic binding agent of FiberForm will be discussed. Finally, two new apparatus developed at NASA will be presented that were designed to interrogate phenomena associated with the production of gases and particles generated under simulated flight conditions.

Material Response↗
DOE OSTI2022

Compositionally complex doping for zero-strain zero-cobalt layered cathodes

We report the high volatility of the price of cobalt and the geopolitical limitations of cobalt mining have made the elimination of Co a pressing need for the automotive industry. Owing to their high energy density and low-cost advantages, high-Ni and low-Co or Co-free (zero-Co) layered cathodes have become the most promising cathodes for next-generation lithium-ion batteries. However, current high-Ni cathode materials, without exception, suffer severely from their intrinsic thermal and chemo-mechanical instabilities and insufficient cycle life. Here, in this paper, by using a new compositionally complex (high-entropy) doping strategy, we successfully fabricate a high-Ni, zero-Co layered cathode that has extremely high thermal and cycling stability. Combining X-ray diffraction, transmission electron microscopy and nanotomography, we find that the cathode exhibits nearly zero volumetric change over a wide electrochemical window, resulting in greatly reduced lattice defects and local strain-induced cracks. In-situ heating experiments reveal that the thermal stability of the new cathode is significantly improved, reaching the level of the ultra-stable NMC-532. Owing to the considerably increased thermal stability and the zero volumetric change, it exhibits greatly improved capacity retention. This work, by resolving the long-standing safety and stability concerns for high-Ni, zero-Co cathode materials, offers a commercially viable cathode for safe, long-life lithium-ion batteries and a universal strategy for suppressing strain and phase transformation in intercalation electrodes.

25 ENERGY STORAGE↗
DOE OSTI2024

Environmental and economic analyses of chemical recycling via dissolution of waste polyethylene terephthalate

Globally, more than 1000 organizations and 175 nations are facing the plastic waste problem and have realized the need to transition from “linear-to-circular” economy of plastics. While the current mechanical recycling technologies for plastics are struggling to increase the U.S. plastic recycling rates beyond 9%, chemical recycling technologies become important complementary technologies to the predominant mechanical recycling that are needed to realize the circular economy in plastics supply chains. Dissolution is one such chemical recycling technology that can recycle waste plastic back into high-quality virgin grade plastic. However, the environmental and economic impacts of chemical recycling of waste polyethylene terephthalate (PET) via dissolution technology using a green solvent are unknown. Our study evaluated environmental metrics such as greenhouse gas (GHG) emissions and cumulative energy demand, and economic metrics such as net present value (NPV), minimum selling price, payback period, return on investment, and discounted internal rate of return for three dissolution processes with polymer recovery via anti-solvent, evaporation, and cooling precipitation techniques. The dissolution process with evaporation technique was the most economically favorable, whereas that with cooling technique was the most environmentally favorable. The anti-solvent approach had low economic performance and the highest environmental impacts. The NPV for all of these technologies ranged from $2.67 MM to $10.93 MM for a capacity of 8,400 MT/year and was found to be the highest for dissolution with evaporation approach and the least for anti-solvent approach. The cradle-to-gate GHG emissions and energy demand for PET dissolution processes ranged from 1.33-3.77 kg CO2-eq/kg of chemically recycled (CR) PET and18.9-56.1 MJ/kg of CR-PET, respectively. These economic and environmental metrics will be helpful in evaluating the sustainability of circular PET supply chains in the U.S.

09 BIOMASS FUELS↗
DOE OSTI2023

Incombustible Polymer Electrolyte Boosting Safety of Solid–State Lithium Batteries: A Review

Lithium-ion batteries with their portability, high energy density, and reusability are frequently used in today's world. Under extreme conditions, lithium-ion batteries leak, burn, and even explode. Therefore, improving the safety of lithium-ion batteries has become a focus of attention. Researchers believe using a solid electrolyte instead of a liquid one can solve the lithium battery safety issue. Due to the low price, good processability and high safety of the solid polymer electrolytes, increasing attention have been paid to them. However, polymer electrolytes can also decompose and burn under extreme conditions. Moreover, lithium dendrites are formed continuously due to the uneven charge distribution on the surface of the lithium metal anode. A short circuit caused by a lithium dendrite can cause the battery to thermal runaway. As a result, the safety of polymer solid-state batteries remains a challenge. In this review, the thermal runaway mechanism of the batteries is summarized, and the batteries abuse test standard is introduced. In addition, the recent works on the high-safety polymer electrolytes and the solution strategies of lithium anode problems in polymer batteries are reviewed. Finally, the development direction of safe polymer solid lithium batteries is prospected.

25 ENERGY STORAGE↗
NASA NTRS1979

A comparison of hydraulic, pneumatic, and electro-mechanical actuators for general aviation flight controls

Mathematical models for electromechanical (EM), pneumatic and hydraulic actuations are discussed. It is shown that EM and hydraulic actuators provide better and faster time responses than pneumatic actuators but EM actuators utilizing the recently developed samarium-cobalt technology have significant advantages in terms of size, weight and power requirements. In terms of ease and flexibility of installation EM actuators apparently have several advantages over hydraulic actuators, and cost is a primary reason for the popularity of EM actuation for secondary control function since no additional systems need to be added to the aircraft. While new rare earth magnets are currently in developmental stage, costs are relatively high; but continued research should bring prices down.

Roskam, J.↗
DOE OSTI2020

Dual Phase Soft Magnetic Laminates for Low-cost, Non/Reduced-Rare-Earth Containing Electrical Machines

To accelerate the mass market adoption of electric drive vehicles, the key technology barriers in electric motors are (1) magnet cost and rare-earth element price volatility; (2) non-rare-earth electric motor performance; and (3) materials property optimization. The goal of this project was to address these barriers by advancing a unique and innovative dual phase soft magnetic material technology and demonstrating the material in a 30-kW synchronous reluctance motor without using any permanent magnet for electric vehicles. Dual phase magnetic materials offer the electric motor designer the ability to locally control the magnetic saturation level in a motor laminate, while at the same time enhancing the mechanical strength of the laminate material, resulting in an enhancement in motor performance and efficiency. Scalable dual phase soft magnetic laminates manufacturing technologies were developed in collaboration with multiple US manufacturers. 1000 lbs of alloy sheet with a thickness of 0.25mm and width of 280 mm was manufactured within the specifications. Batch sizes of up to 240 laminates per run were produced from the alloy sheet. Two prototype motors with dual phase soft magnetic laminates were designed, built, and tested. The major goal of building the subscale prototype as a pathway to develop scalable manufacturing technologies for the dual phase soft magnetic laminates was met. The additional goal of building and testing the subscale prototype in order to validate the calculated performance with the tested motor performance was also met. For the full-scale 30kW continuous power synchronous reluctance motor prototype, the tested performance met the targets in terms of continuous power at the operating speeds up to 8000 rpm. Post-test studies were conducted and the root causes for the discrepancy between the predicted and tested peak power, continuous power at high speed range, and efficiency were identified. Further modeling study showed that the dual phase rotor machine has a 27% higher torque to active weight ratio than an equivalent performance silicon steel rotor machine. Application space and multiple discussions with traction motor and electric vehicle manufacturers for commercialization of the dual phase soft magnetic material technology were identified and conducted. An initial cost model was established based on the developed manufacturing technologies with the US manufacturers. Future paths for further cost reduction were identified, including increasing the market volume by broadening the applications of the dual phase soft magnetic laminate technology for electric machines in other energy sections such as oil & gas, heating, ventilation, and air conditioning (HVAC), and power generation.

33 ADVANCED PROPULSION SYSTEMS↗
DOE OSTI2020

Modulating electrode utilization in lithium-ion cells with silicon-bearing anodes

The stability of silicon-containing anodes can, in principle, be extended by constraining these electrodes to limited states of lithiation. Partial utilization of the anode lessens the volume changes experienced by silicon particles during cycling, which can mitigate mechanisms of performance degradation. In full-cells, anode utilization can be modulated by adjusting the relative capacities of the negative and positive electrodes - the N/P ratio. Here, we examine how the N/P ratio affects the long-term stability of Si-based full-cells, and investigate how this parameter would impact the cost and energy of realistic Li-ion cells. Here, we show that, for some configurations, cell failure due to rapid anode degradation can only by avoided at higher N/P ratios. The price of this enhanced stability is accelerated impedance rise at the cathode. Surprisingly, when electrode expansion is taken into account, increasing N/P ratio can actually increase the specific energy and energy density of silicon-rich Li-ion cells.

25 ENERGY STORAGE↗
NASA NTRS1988

Mass spectrometric studies of trimethylindium pyrolysis

The kinetics of the pyrolysis of trimethylindium (TMIn) in He, D2, and H2 carriers was investigated using the atmospheric pressure flow-tube apparatus described by Larsen et al. (1987) and a time-of-flight mass spectrometer. The rate constant for the pyrolysis of TMIn in He was found to be comparable to that found by Jacko and Price (1964) for TMIn in toluene carrier (a radical scavenger), indicating that TMIn decomposes in He not by radical attack of methyl groups, but by homolytic fission. The decomposition of TMIn is enhanced in D2 and H2 carriers, where the principal products are CH3D and C2H6, and CH4 and C2H6, respectively, indicating that the reaction pathway in these carriers is different from those in He and toluene. The pyrolysis in H2 and D2 is attributed to a radical attack by H or D on TMIn. A reaction mechanism involving a short-lived hypervalent DTMIn species was proposed and was tested using numerical modeling techniques.

Buchan, N. I.↗
DOE OSTI2021

Systematic discovery of pseudomonad genetic factors involved in sensitivity to tailocins

Tailocins are bactericidal protein complexes produced by a wide variety of bacteria that kill closely related strains and may play a role in microbial community structure. Thanks to their high specificity, tailocins have been proposed as precision antibacterial agents for therapeutic applications. Compared to tailed phages, with whom they share an evolutionary and morphological relationship, bacterially produced tailocins kill their host upon production but producing strains display resistance to self-intoxication. Though lipopolysaccharide (LPS) has been shown to act as a receptor for tailocins, the breadth of factors involved in tailocin sensitivity, and the mechanisms behind resistance to self-intoxication, remain unclear. Here, we employed genome-wide screens in four non-model pseudomonads to identify mutants with altered fitness in the presence of tailocins produced by closely related pseudomonads. Our mutant screens identified O-antigen composition and display as most important in defining sensitivity to our tailocins. In addition, the screens suggest LPS thinning as a mechanism by which resistant strains can become more sensitive to tailocins. Furthermore, we validate many of these novel findings, and extend these observations of tailocin sensitivity to 130 genome-sequenced pseudomonads. This work offers insights into tailocin–bacteria interactions, informing the potential use of tailocins in microbiome manipulation and antibacterial therapy.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2023

Experimental and numerical investigation of proppant embedment and conductivity reduction within a fracture in the Caney Shale, Southern Oklahoma, USA

The current worldwide energy supply is insufficient to meet the rising demand. As a result, the energy prices are expected to keep soaring despite the recent increases in a variety of renewable energy resources. Although not renewable, shale oil and gas — “unconventional” hydrocarbon resources are relatively clean forms of energy resources, which still hold a vast share of the energy market. For many oil and gas companies, meeting profitable production goals from shale reservoirs is sometimes challenging, due to the loss of fracture conductivity and premature declines in the production. In this paper we investigate the stress-dependent changes in the hydraulic conductivity of proppant-filled fractures and mechanical fracture–proppant interactions in Caney Shale, a calcareous, organic-rich mudrock, through laboratory experiments and numerical modeling. American Petroleum Institute (API) fracture conductivity tests were conducted using 2% KCl on five locations within the Caney Shale that consisted of selecting three brittle (reservoir) zones and two ductile zones. Confining pressures ranged from 1,000 psi to 12,000 psi at 210 °F. Conductivity, permeability as well as embedment were measured during the test. Also, an additional, laboratory in-situ visualization test was conducted to examine the detailed proppant-shale matrix interaction under elevated stress (3,920 psi effective stress) and temperature (252 °F), with a synthetic reservoir fluid. Our experimental results have confirmed that improved fracture conductivity is attributed to proppant size, and that the increase in porosity of the proppant pack, closure pressure changes and the reduction in fracture conductivity are a function of many factors such as fracture closure stress.

04 OIL SHALES AND TAR SANDS↗
DOE OSTI2024

Equitable Transactive Market Design to Coordinate Networked Microgrids with Mixed Ownership

This paper presents an inter-microgrid peer-topeer (P2P) transactive market mechanism to support the coordination of multiple microgrids in a mixed-ownership environment, while enabling prosumers to actively participate in the market to get their own benefits. An equitable P2P transactive energy market is designed, in which the energy burden to customers within microgrids is fairly distributed by leveraging a peer-to-peer communication network among MG owners and the distribution system operator (DSO). To reach the market settlement, a consensus-based distributed optimization algorithm is introduced to enable each MG owner and the DSO to distributedly determine the cleared price which is compensated by a household-income-based discount factor to encourage the energy-burden equity among customers in networked microgrids service territory. Numerical results on the modified 123 node test feeder including 6 microgrids are used to demonstrate the operation of the introduced equitable transactive energy market.

Vu, Thanh Long↗
NASA NTRS1975

Effect of post cure time and temperature on the properties of two phenolic-fiber composites

Some effects of post-cure time and temperature on the physicomechanical properties of a phenolic-asbestos and a phenolic-glass composite are studied. The molding and post-curing procedures are discussed along with physical and mechanical test results. It is found that the specific gravity of the panels tested decreased slightly but the hardness always increased with post cure, and that the mechanical properties had different patterns of response to increasing post-cure time and temperature. For tensile properties, strength decreased, modulus increased, and elongation at break exhibited little change. In general, the phenolic-asbestos showed more positive response to post cure than did the phenolic-glass. Mold venting is found to impart better properties to the composites concerned.

Lucy, M. H.↗
NASA NTRS2005

The Optical Afterglow of a Short Gamma-ray Burst

It has long been known that there are two classes of gamma-ray bursts (GRBs), principally distinguished by their durations. The breakthrough in our understanding of long-duration GRBs (greater than 2 seconds in duration), that ultimately linked them with energetic Type Ic supernovae, came about from the discovery of their long-lived X-ray and optical "afterglow", when precise and rapid localizations of the sources could finally be obtained. Recently, X-ray localizations have become available for short (less than 2 seconds in duration) GRBs, a hitherto elusive GRB population, that has evaded optical detection for more than thirty years. Here we report the discovery of transient optical emission (R approximately 23 mag) associated with a short GRB. This first short GRB afterglow is localized with sub-arcsecond accuracy onto the outskirts of a blue dwarf galaxy. Unless the optical and X-ray afterglow arise from different mechanisms our observations 33 h after the GRB suggest that, analogously to long GRBs, we observe synchrotron emission from ultrarelativistic ejecta (ZZZ CAN WE LIMIT GAMMA?). In contrast, we did not detect a bright supernova, as found in most nearby long GRB afterglows, which suggests a different origidstrongly constrain the nature of the short GRB progenitors.

Hjorth, Jens↗
NASA NTRS1979

The use of wood for wind turbine blade construction

The interrelationships between moisture and wood, conditions for dry rot spore activity, the protection of wood fibers from moisture, wood resin composites, wood laminating, quality control, and the mechanical properties of wood are discussed. The laminated veneer and the bonded sawn stock fabrication techniques, used in the construction of a turbine blade with a monocoque 'D' section forming the leading edge and a built up trailing edge section, are described. A 20 foot root end sample complete with 24 bonded-in studs was successfully subjected to large onetime loads in both the flatwise and edgewise directions, and to fatigue tests. Results indicate that wood is both a viable and advantageous material for use in wind turbine blades. The basic material is reasonably priced, domestically available, ecologically sound, and easily fabricated with low energy consumption.

Gougeon, M.↗
DOE OSTI2026

Chain entanglements enable regeneration of high-performance thermosets

Thermoset plastics underpin structural materials, electronics and transportation, yet the permanent covalent networks that prevent flow and provide dimensional stability also make them difficult to recycle without sacrificing performance. In this work we show that high-performance thermosets can be built around dense chain entanglements, the physical interlacing of long polymer strands, rather than dense permanent crosslinks, with only a small number of selectively cleavable junctions preserving connectivity. Long, rigid, entangled polyolefin backbones generated by frontal polymerization form glassy polymers with high stiffness, high toughness and excellent creep suppression yet can be fully deconstructed into soluble, linear oligomers. Varying oligomer length and end-group chemistry enables their reuse as re-entangling building blocks that regenerate thermosets with thermal and mechanical properties that remain unchanged across generations. The strategy further extends to high-temperature fibre-reinforced composite matrices and additively manufactured structures, establishing chain entanglement as a design principle for durable, regenerable thermosets.

36 MATERIALS SCIENCE↗
DOE OSTI2022

Motivation, benefits, and challenges for new photovoltaic material & module developments

Abstract In the last decade and longer, photovoltaic module manufacturers have experienced a rapidly growing market along with a dramatic decrease in module prices. Such cost pressures have resulted in a drive to develop and implement new module designs, which either increase performance and/or lifetime of the modules or decrease the cost to produce them. In this paper, the main motivations and benefits but also challenges for material innovations will be discussed. Many of these innovations include the use of new and novel materials in place of more conventional materials or designs. As a result, modules are being produced and sold without a long-term understanding about the performance and reliability of these new materials. This has led to unexpected new failure mechanisms occurring few years after deployment, such as potential induced degradation or backsheet cracking. None of these failure modes have been detected after the back then common single stress tests. New accelerated test approaches are based on a combination or sequence of multiple stressors that better reflect outdoor conditions. That allows for identification of new degradation modes linked to new module materials or module designs.

Oreski, G. (ORCID:0000000342239047)↗
DOE OSTI2020

NMT1 and NMT2 are lysine myristoyltransferases regulating the ARF6 GTPase cycle

Abstract Lysine fatty acylation in mammalian cells was discovered nearly three decades ago, yet the enzymes catalyzing it remain unknown. Unexpectedly, we find that human N-terminal glycine myristoyltransferases (NMT) 1 and 2 can efficiently myristoylate specific lysine residues. They modify ADP-ribosylation factor 6 (ARF6) on lysine 3 allowing it to remain on membranes during the GTPase cycle. We demonstrate that the NAD + -dependent deacylase SIRT2 removes the myristoyl group, and our evidence suggests that NMT prefers the GTP-bound while SIRT2 prefers the GDP-bound ARF6. This allows the lysine myrisotylation-demyristoylation cycle to couple to and promote the GTPase cycle of ARF6. Our study provides an explanation for the puzzling dissimilarity of ARF6 to other ARFs and suggests the existence of other substrates regulated by this previously unknown function of NMT. Furthermore, we identified a NMT/SIRT2-ARF6 regulatory axis, which may offer new ways to treat human diseases.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2025

Respiration Signal Pattern Analysis for Doppler Radar Sensor with Passive Node and Its Application in Occupancy Sensing of a Stationary Subject

Doppler radar node occupancy sensors are promising for applications in smart buildings due to their simple circuits and price advantage compared to quadrature radar sensors. However, single-channel sensitivity limitations may result in low sensitivity and misinterpreted motion rates if the detected subject is at or close to “null” points. We designed and tested a novel method to eliminate such limits, demonstrating that passive nodes can be used to detect a sedentary person regardless of position. This method is based on characteristics of chest motion due to respiration, found via both simulations and experiments based on a sinusoidal model and a more realistic model of cardiorespiratory motion. In addition, respiratory rate variability is considered to distinguish a true human presence from a mechanical target. Sensor node data were collected simultaneously with an infrared camera system, which provided a respiration signal reference, to test the algorithm with 19 human subjects and a mechanical target. The results indicate that a human presence was detected with 100% accuracy and successfully differentiated from a mechanical target in a controlled environment. The developed method can greatly improve the occupancy detection accuracy of single-channel radar-based occupancy sensors and facilitate their adoption in smart building applications.

Song, Chenyan↗