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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 181 records · Page 10
All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

Metastable‐State Photoacids with Fast Reverse Reactions

Metastable-state photoacid (mPAH) has become a common tool for controlling and driving chemical processes with light. mPAHs with fast reverse reactions are desirable for precise temporal control or generating quick pulses of proton concentration. Here, in this work, different approaches towards fast reversing mPAHs are studied. Experimental and computational results showed that stabilizing the charge–transfer intermediate is an effective way to increase the rate. A novel mPAH with a reverse reaction ≈500 times faster than the most used mPAH in methanol is developed. Another water-soluble mPAH showed a reverse reaction with a rate constant of 7.8 s −1 , which is the fastest ever reported. The half-life of the acidic state is calculated to be 89 ms, which allowed to demonstrate sub-second switching using this mPAH.

Abbood, Rana [Florida Institute of Technology, Mel↗
DOE OSTI2020

Growth of concomitant laser-driven collisionless and resistive electron filamentation instabilities over large spatiotemporal scales

Collective processes in plasmas often induce microinstabilities that play an important role in many space or laboratory plasma environments. Particularly of note is the Weibel-type current filamentation instability, which is believed to drive the creation of collisionless shocks in weakly magnetized astrophysical plasmas. In this paper, this instability class is studied through interactions of ultraintense and short laser pulses with solid foils, leading to localized generation of megaelectronvolt electrons. Proton radiographic measurements of both low- and high-resistivity targets show two distinct, superimposed electromagnetic field patterns arising from the interpenetration of the megaelectronvolt electrons and the background plasma. Particle-in-cell simulations and theoretical estimates suggest that the collisionless Weibel instability building up in the dilute expanding plasmas formed at the target surfaces causes the observed azimuthally symmetric electromagnetic filaments. For a sufficiently high resistivity of the target foil, an additional resistive instability is triggered in the bulk target, giving rise to radially elongated filaments. The data reveal the growth of both filamentation instabilities over large temporal (tens of picoseconds) and spatial (hundreds of micrometres) scales.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
NASA NTRS1972

Electron/proton spectrometer certification documentation analyses

A compilation of analyses generated during the development of the electron-proton spectrometer for the Skylab program is presented. The data documents the analyses required by the electron-proton spectrometer verification plan. The verification plan was generated to satisfy the ancillary hardware requirements of the Apollo Applications program. The certification of the spectrometer requires that various tests, inspections, and analyses be documented, approved, and accepted by reliability and quality control personnel of the spectrometer development program.

Gleeson, P.↗
NASA NTRS1983

An imaging telescope for high energy gamma-ray astronomy

Recent tests of a gamma-ray imaging telescope, which incorporated a coded aperture mask and multiwire proportional counter system produced good images of a tritium target source which was used to generate the 20 MeV protons at a proton Van de Graaff accelerator. This paper indicates what performance might be expected if a large area drift chamber were used in conjunction with a coded aperture mask. The prospects for achieving significant scientific results if such a system were flown on a variety of space vehicles are discussed.

Frye, G.↗
NASA NTRS1984

Beryllium-10 contents of core samples from the St. Severin meteorite

Beryllium-10 contents in the 20-28 dpm/kg range, averaging 24.5 + or - 0.9 dpm/kg, have been obtained for 11 samples taken from along the 35-cm core AIII of the St. Severin LL chondrite. Be-10 content increases with depth in the outermost 8 cm, and there is little change in content at greater depths. Significant disagreement is noted between the measured values and the results of calculations based on the cross sections for proton-induced Be-generating reactions. Cosmogenic Be-10 in stony meteorites is better described as a medium-energy product than a high energy one.

Tuniz, C.↗
NASA NTRS1989

Solar cosmic ray effects in the lower ionosphere

The polar cap absorption (PCA) events are the most remarkable geophysical phenomena in the high latitude ionosphere. Their effects are extended on the whole polar region in both hemispheres. The PCA events are caused by the intense fluxes of the solar cosmic rays (SCR) which are generated by the solar proton flares. Entering into the Earth's magnetosphere and ionosphere the SCR fluxes create excessive anomal ionization at the ionospheric heights of 50 to 100 km which exceeds usual undisturbed level of ionization in several orders of magnitude. The PCA events can be considered as catastrophic in relation to the polar ionosphere because all radio systems using ionospheric radio channels ceased to operate during these events. On the other hand the abnormally high level of ionization in the ionospheric D region during the PCA events create excellent opportunities to conduct fruitful aeronomical research for the lower ionosphere. Obvious scientific and practical importance of the PCA events leads to publishing of special PCA catalogues. The ionospheric effects caused by the SCR fluxes were profoundly described in the classical paper (Bailey, 1964). Nevertheless several aspects of this problem were not studied properly. An attempt is made to clarify these questions.

Shirochkov, A. V.↗
NASA NTRS1994

Electromagnetic waves with frequencies near the local proton gyrofrequency: ISEE-3 1 AU observations

Low Frequency (LF) electromagnetic waves with periods near the local proton gyrofrequency have been detected in interplanetary space by the magnetometer onboard International-Sun-Earth-Explorer-3 (ISEE-3). Transverse peak-to-peak amplitudes as large as delta vector B/absolute value of B approximately 0.4 have been noted with compressional components (Delta absolute value of B/absolute value of B) typically less than or = 0.1. Generally, the waves have even smaller amplitudes, or are not detectable within the solar wind turbulence. The waves are elliptically/linearly polarized and are often, but not always, found to propagate nearly along vector B(sub zero). Both right- and left-hand polarizations in the spacecraft-frame have been detected. The waves are observed during all orientations of the interplanetary magnetic field, with the Parker spiral orientation being the most common case. Because the waves are detected at and near the local proton cyclotron frequency, the generation mechanism must almost certainly be solar wind pickup of freshly created hydrogen ions. Possible sources for the hydrogen are the Earth's atmosphere, coronal mass ejections from the Sun, comets and interstellar neutral atoms. At this time it is not obvious which potential source is the correct one. Statistical tests employing over one year of ISEE-3 data will be done in the near future to eliminate/confirm some of these possibilities.

Tsurutani, Bruce T.↗
NASA NTRS1997

Gamma-rays from supernova remnants and the signatures of diffusive shock acceleration

A nonlinear shock acceleration model which generates non-thermal proton distributions and includes a self-consistent determination of shock hydrodynamics, is considered. Gamma ray spectra are obtained for supernova remnants, allowing for the cessation of acceleration to high energies due to the finite ages and the sizes of the remnants. Gamma ray spectral cutoffs can be observed in the TeV range for reasonable remnant parameters and deviations from power law behavior are found at all energies from 1 MeV to cutoff. Correlated observations by the International Gamma Ray Astrophysics Laboratory, Whipple and other instruments may provide stringent constraints to understanding supernova remnants.

Baring, Matthew G.↗
NASA NTRS2004

Electrochemical Reconstitution of Biomolecules for Applications as Electrocatalysts for the Bionanofuel Cell

Platinum-cored ferritins were synthesized as electrocatalysts by electrochemical biomineralization of immobilized apoferritin with platinum. The platinum cored ferritin was fabricated by exposing the immobilized apoferritin to platinum ions at a reduction potential. On the platinum-cored ferritin, oxygen is reduced to water with four protons and four electrons generated from the anode. The ferritin acts as a nano-scale template, a biocompatible cage, and a separator between the nanoparticles. This results in a smaller catalyst loading of the electrodes for fuel cells or other electrochemical devices. In addition, the catalytic activity of the ferritin-stabilized platinum nanoparticles is enhanced by the large surface area and particle size phenomena. The work presented herein details the immobilization of ferritin with various surface modifications, the electrochemical biomineralization of ferritin with different inorganic cores, and the fabrication of self-assembled 2-D arrays with thiolated ferritin.

Kim, Jae-Woo↗
NASA NTRS1974

Intensity and energy spectrum of electrons accelerated in the earth's bow shock

Shock waves accelerate charged particles in the solar atmosphere, in interplanetary space and around the earth's magnetosphere. Acceleration of both electrons and protons occurs in the earth's bow-shock. The acceleration of protons up to 100 keV appears to be a steady state process and may even occur upstream from the bow shock due to waves generated by reflected solar wind protons. The electrons, on the other hand, are known to be accelerated in or near the shock. The intensity of these electrons ranges from about 100 to 2,000 per sr-sq cm-sec-keV at 14 keV. The energy spectrum is not a simple power low and is highly variable. If segments of the spectra are fitted to a power low, slopes ranging from -2 to -4.5 result over the energy range 0.5 to 100 keV.

Anderson, K. A.↗
DOE OSTI2024

Search for a third-generation leptoquark coupled to a τ lepton and a b quark through single, pair, and nonresonant production in proton-proton collisions at $ \sqrt{s} $ = 13 TeV

A search is presented for a third-generation leptoquark (LQ) coupled exclusively to a τ lepton and a b quark. The search is based on proton-proton collision data at a center-of-mass energy of 13 TeV recorded with the CMS detector, corresponding to an integrated luminosity of 138 fb$^{−1}$. Events with τ leptons and a varying number of jets originating from b quarks are considered, targeting the single and pair production of LQs, as well as nonresonant t-channel LQ exchange. An excess is observed in the data with respect to the background expectation in the combined analysis of all search regions. For a benchmark LQ mass of 2 TeV and an LQ-b-τ coupling strength of 2.5, the excess reaches a local significance of up to 2.8 standard deviations. Upper limits at the 95% confidence level are placed on the LQ production cross section in the LQ mass range 0.5–2.3 TeV, and up to 3 TeV for t-channel LQ exchange. Leptoquarks are excluded below masses of 1.22–1.88 TeV for different LQ models and varying coupling strengths up to 2.5. The study of nonresonant ττ production through t-channel LQ exchange allows lower limits on the LQ mass of up to 2.3 TeV to be obtained.[graphic not available: see fulltext]

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2020

Proton affinities of pertechnetate (TcO 4 - ) and perrhenate (ReO 4 - )

The anions pertechnetate, TcO 4 - , and perrhenate, ReO 4 - , exhibit very similar chemical and physical properties. Revealing and understanding disparities between them enhances fundamental understanding of both. Electrospray ionization generated the gas-phase proton bound dimer (TcO 4 - )(H + )(ReO 4 - ). Collision induced dissociation of the dimer yielded predominantly HTcO 4 - and ReO 4 - , which according to Cooks’ kinetic method indicates that the proton affinity (PA) of TcO 4 - is greater than that of Re O 4 - . Density functional theory computations agree with the experimental observation, providing PA[TcO 4 - ] = 300.1 kcal mol -1 and PA[ReO 4 - ] = 297.2 kcal mol -1 . Attempts to rationalize these relative PAs based on elementary molecular parameters such as atomic charges indicate that the entirety of bond formation and concomitant bond disruption needs to be considered to understand the energies associated with such protonation processes. Although in both the gas and solution phases, TcO 4 - is a stronger base than ReO 4 - , it is noted that the significance of even such qualitative accordance is tempered by the very different natures of the underlying phenomena.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1991

Generation of ultrahigh-energy gamma rays in accreting x ray pulsars

Relativistic protons producing ultrahigh energy gamma rays as a result of nuclear collisions ought to be generated in close proximity to the surface of a neutron star due to accretion. The main features of the mechanism in question are a high efficiency of conversion of the gravitational energy of the accreting matter into acceleration energy and a high efficiency of the acceleration itself. It is shown that in accretion to a neutron star with a strong magnetic field, a loss cone type distribution of accreting protons is formed, which due to instability effectively generates small scale Alfven and proton cyclotron waves, as well as nonlinear waves (magneto-acoustic and Alfven solitons). The electric field of the moving solitons may accelerate the protons to energies of greater than 10(exp 15) eV. The region of acceleration is not locally isolated, but extends from its surface. New possible sources of ultrahigh energy gamma rays are predicted. They may be binary x ray systems containing neutron stars with magnetic fields of about 10(exp 9) gauss.

Gnedin, Yu. N.↗
DOE OSTI2023

Quantum Emitter Formation Dynamics and Probing of Radiation-Induced Atomic Disorder in Silicon

Near-infrared color centers in silicon are emerging candidates for on-chip integrated quantum emitters, optical-access quantum memories, and sensing. We access ensemble G-color-center formation dynamics and radiation-induced atomic disorder in silicon for a series of megaelectronvolt proton-flux conditions. The photoluminescence results reveal that the G centers are formed more efficiently by pulsed-proton irradiation than by continuous-wave proton irradiation. The enhanced transient excitations and dynamic annealing within nanoseconds allows optimization of the ratio of G-center formation to nonradiative defect accumulation. The G centers preserve narrow line widths of about 0.1 nm when they are generated by moderate pulsed-proton fluences, while the line width broadens significantly as the pulsed-proton fluence increases. This implies vacancy or interstitial clustering by overlapping collision cascades. The tracking of G-center properties for a series of irradiation conditions enables sensitive probing of atomic disorder, serving as a complementary analytical method for sensing damage accumulation. Aided by ab initio electronic structure calculations, we provide insight into the atomic disorder induced inhomogeneous broadening by introducing vacancies, silicon interstitials, and oriented strain fields in the vicinity of a G center. A vacancy leads to a tensile strain and can result in either a red shift or a blue shift of the G-center emission, depending on its position relative to the G center. Meanwhile, Si interstitials lead to compressive strain, which results in a monotonic red shift. In conclusion, high-flux and tunable ion pulses enable the exploration of the fundamental dynamics of radiation-induced defects as well as methods for the optimization of G-center formation and qubit synthesis for quantum information processing.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
NASA NTRS1992

X-ray flares from runaway pair production in active galactic nuclei

The hard X-ray spectrum of AGNs is nonthermal, probably arising from an electron-positron pair cascade, with some emission reflected off relatively cold matter. There has been interest in models on which protons are accelerated and create relativistic electrons on interaction with a local radiation field. It is shown here that a sufficient column density of protons can lead to runaway pair production: photons generated by the relativistic pairs are the targets for the protons to produce more pairs. This can produce X-ray fluxes with the characteristics observed in AGN. The model predicts the maximum ratio of luminosity to source size as well as their spectrum in the early phases. The same mechanism may also be able to create the knots of synchrotron-radiating pair plasma seen in sources such as 3C273.

Kirk, J. G.↗
DOE OSTI2020

The Catalytic Reduction of Dinitrogen Under Mild Conditions (Final Report)

In order to use molecular hydrogen as an alternative to fossil fuels, large quantities of hydrogen (or protons and electrons) would have to be generated from water using a method based on solar energy and stored as a molecule in which hydrogen is a high weight percentage. The hydrogen must then be generated as needed from the form in which it is stored. An attractive molecule for this purpose is ammonia (~17% hydrogen by weight). Among the many problems that must be addressed for a successful implementation of this approach in the long term is the reduction of nitrogen catalytically to ammonia with protons and electrons under mild conditions, a goal that is addressed in this proposal. The first abiological catalytic reduction of N 2 to NH 3 by protons and electrons under mild conditions (22 °C and 1 atm) employed molybdenum catalysts, [(HIPTNCH 2 CH 2 ) 3 N]Mo (HIPTN 3 N 3- ), where HIPT (hexaisopropylterphenyl) is 3,5- (2,4,6-i-Pr 3 C 6 H 2 ) 2 C 6 H 3 . A total of approximately four turnovers (to give a maximum of eight equivalents of ammonia) along with approximately one equivalent of hydrogen per N 2 reduced, were found. A limitation of this catalytic approach is loss of the ligand from the metal. This project is aimed at developing a complex that contains a ligand that will not be removed from the metal. A macrocyclic TREN-based ligand of this type has been synthesized recently. The project is aimed at making similar ligands and molybdenum complexes that contain them and testing the new catalysts for catalytic reduction of dinitrogen. The results of these investigations will help guide further design of ligands for more efficient reduction of nitrogen to ammonia and ultimately an integrated device in which protons and electrons are generated using solar energy and employed to reduce nitrogen to ammonia using molybdenum catalysts.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

Proton switching molecular magnetoelectricity

Abstract The convergence of proton conduction and multiferroics is generating a compelling opportunity to achieve strong magnetoelectric coupling and magneto-ionics, offering a versatile platform to realize molecular magnetoelectrics. Here we describe machine learning coupled with additive manufacturing to accelerate the design strategy for hydrogen-bonded multiferroic macromolecules accompanied by strong proton dependence of magnetic properties. The proton switching magnetoelectricity occurs in three-dimensional molecular heterogeneous solids. It consists of a molecular magnet network as proton reservoir to modulate ferroelectric polarization, while molecular ferroelectrics charging proton transfer to reversibly manipulate magnetism. The magnetoelectric coupling induces a reversible 29% magnetization control at ferroelectric phase transition with a broad thermal hysteresis width of 160 K (192 K to 352 K), while a room-temperature reversible magnetic modulation is realized at a low electric field stimulus of 1 kV cm −1 . The findings of electrostatic proton transfer provide a pathway of proton mediated magnetization control in hierarchical molecular multiferroics.

36 MATERIALS SCIENCE↗