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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 181 records · Page 10

Evaluations of an Enhanced Total Hydrocarbon Analyzer With Complex Mixtures of Volatile Organic Compounds

From the earliest manned missions, the volatile organic compound (VOC) content of spacecraft air has been a concern because of a much greater potential for contamination than air in most terrestrial settings. First, the volume of air is small compared to the mass of man- made materials comprising the interior furnishings of the spacecraft. These man-made materials offgas VOCs trapped during manufacture. Second, the nitrogen fraction of the air is recycled. Any VOCs not scrubbed out with charcoal filters or aqueous condensate (mainly water expired by the crew) will accumulate in the air. Third, the crew emits metabolic VOCs. Fourth, experimental payloads can also offgas or accidentally release a VOC; in fact a major organic constituent of the atmosphere is the disinfectant isopropanol released from swabs used in medical experiments.

Cross, John H.↗

In the Beginning...

Having just emerged from the warmest decade on record and watching as the oceans acidify and sea level rises, global resources peak, the world's population continues to climb, and nearly half of all known species face extinction by the end of the century. We stand on the threshold of one of the most important transition in human history-the transition from hunting-and-gathering our energy to cultivating sustainable, carbon-neutral, environmentally-friendly energy supplies. Can we develop an alternative to fossil fuels in time to make a difference for our children and the "children" of all species? NASA puts people into outer space, where all resources (food, water, air, pressure, gravity, energy) are limited and far away and where conditions (temperature, radiation, vacuum) are problematic and dangerous-the life expectancy of an unprotected astronaut (physically exposed to the space environment) is 15 seconds. Therefore, by necessity, NASA has explored and developed "life-support systems" that optimize the use of resources, minimize the use of energy, and recycle, refurbish, re-use everything that on earth would be considered a waste material. Emerging from the legacy of life-support systems, the NASA OMEGA project uses microalgae, municipal wastewater, and the encroaching oceans to address our global needs for a sustainable, carbon-neutral, environmentally friendly energy supply that does not compete with agriculture. The OMEGA project is focused on producing aviation fuel, treating municipal wastewater, and sequestering carbon dioxide. More generally, however, OMEGA is an example of an "ecology of technologies" in which all processes are integrated and inter-dependent and wastes become resources. From a NASA perspective, the OMEGA project is also a reminder that "we are not passengers on Spaceship Earth, we are the crew."

Trent, Jonathan↗

Impact of Powder Variability on the Microstructure and Mechanical Behavior of Selective Laser Melted Alloy 718

Powder-bed additive manufacturing processes use fine powders to build parts layer-by-layer. Alloy 718 powder feedstocks for selective laser melting (SLM) additive manufacturing are produced commercially by both gas and rotary atomization and are available typically in the 10-45 or 15-45 microns size ranges. A comprehensive investigation was conducted to understand the impact of powder variability on the microstructure and mechanical behavior of SLM 718 heat treated to Aerospace Material Specification (AMS) 5664. This study included sixteen virgin powders and three once-recycled powders within the 10-45 and 15-45 microns size ranges that were obtained from seven direct source suppliers and one reseller. Although alike as highly regular spheroids, these powders showed distinct differences in composition (especially Al, C and N contents), particle size distributions, and powder features such as degree of agglomeration, fusion and surface roughness. Compositional differences expectedly had the strongest impact on microstructure. High N and C contents formed TiN-nitrides and/or (Nb,Ti,Mo)-C carbides on the grain boundaries, prevented recrystallization during heat treatment, and resulted in retained (001)-scalloped shaped grains that ranged from 19 to 41 microns in average size. In the absence of this particle pinning, the average grain size of the heat treated SLM 718 ranged from 51 microns to 90 microns. Room temperature tensile and high cycle fatigue (HCF) testing compared as-fabricated (AF) and low stress ground (LSG) surface conditions. Tensile testing revealed consistent behavior between the two surface conditions and amongst the powder lots. The finer grained SLM 718 builds displayed the lowest tensile properties. A SLM 718 build fabricated from a powder with eight times lower C content showed statistically better tensile properties presumably due to enhanced coarsening of (delta)-Ni3Nb precipitates. The specimens from once-recycled powders had slightly higher tensile strengths and slightly higher ductility compared to their virgin equivalents; once-recycling also did not substantially degrade the mean HCF life. The LSG fatigue lives agreed with conventionally manufactured 718 data, while AF lives exhibited a knock-down due to surface roughness. The fatigue lives of AF specimens were statistically equivalent across powder lots except for one and failures typically initiated at stress concentrators associated with SLM surface asperities. Fatigue testing of low stress ground specimens result in both transgranular and within facet crack initiations. More than half of the cracks initiated from these facets for the machined condition; however, these facets appeared to be within grains that were larger-than-average in size. A nitrogen-atomized powder with fine prior particles of TiN-nitrides and M(Ti,Nb,Mo)C carbides from atomization on powder surfaces resulted in the best fatigue performance with segregation of these particles to the SLM 718 grain boundaries leading to higher resistance to early-stage crack propagation. Typically the fine-grained builds with minor phases along the grain boundaries did not perform well in fatigue, whereas a larger-grain build with lower carbon content and coarser delta-Ni3Nb precipitates showed the next best HCF response. Further details of the build microstructure and its impact on tensile and fatigue behavior was considered.

laser deposition↗

Integrating post-manufacturing issues into design and manufacturing decisions

An investigation is conducted on research into some of the fundamental issues underlying the design for manufacturing, service and recycling that affect engineering decisions early in the conceptual design phase of mechanical systems. The investigation focuses on a system-based approach to material selection, manufacturing methods and assembly processes related to overall product requirements, performance and life-cycle costs. Particular emphasis is placed on concurrent engineering decision support for post-manufacturing issues such as serviceability, recyclability, and product retirement.

Eubanks, Charles F.↗

Biotransformation of an uncured composite material

The feasibility of biologically degrading prepreg wastes was studied. The work was conducted with the intention of obtaining baseline data that would facilitate the achievement of two long-range goals. These goals are: (1) the biological remediation of the hazardous components in the prepreg wastes, and (2) providing the potential for recycling the prepreg waste fibers. The experiments examined a prepreg that employs an bismaleimide resin system. Initial results demonstrated an obvious deterioration of the prepreg material when incubated with several bacterial strains. The most active cultures were identified as a mixture of 'Bacillus cereus' and 'Pseudomonas sp'. Gas chromatography analyses revealed seven primary compounds in the resin mixture. Biotransformation studies, using the complete prepreg material, demonstrated on obvious loss of all seven organic compounds. Gas chromatography-mass spectrometry analyses resulted in structure assignments for the two primary components of the resin. Both were analogs of Bisphenol A; one being bismaleimide, and the other being Bisphenol A containing a diglycidyl moiety. The 'diglycidyl analog' was purified using thin-layer chromatography and the biotransformation of this compound (at 27 ug/ml bacterial culture) was monitored. After a seven-day incubation, approximately 40% of the organic compound was biotransformed. These results demonstrate the biotransformation of the prepreg resin and indicate that biological remediation of the prepreg wastes is feasible.

Welsh, Clement J.↗

Electrochemical Orbital Energy Storage (ECOES) technology program

The versatility and flexibility of a regenerative fuel cell power and energy storage system is considered. The principal elements of a Regenerative Fuel Cell System combine the fuel cell and electrolysis cell with a photovoltaic solar cell array, along with fluid storage and transfer equipment. The power output of the array (for LEO) must be roughly triple the load requirements of the vehicle since the electrolyzers must receive about double the fuel cell output power in order to regenerate the reactants (2/3 of the array power) while 1/3 of the array power supplies the vehicle base load. The working fluids are essentially recycled indefinitely. Any resupply requirements necessitated by leakage or inefficient reclamation is water - an ideal material to handle and transport. Any variation in energy storage capacity impacts only the fluid storage portion, and the system is insensitive to use of reserve reactant capacity.

Mcbryar, H.↗

Closed-ecology life support systems /CELSS/ for long-duration, manned missions

Studies were conducted to scope the principal areas of technology that can contribute to the development of closed-ecology life support systems (CELSS). Such systems may be required for future space activities, such as space stations, manufacturing facilities, or colonies. A major feature of CELSS is the regeneration of food from carbon in waste materials. Several processes, using biological and/or physico-chemical components, have been postulated for closing the recycle loop. At the present time, limits of available technical information preclude the specification of an optimum scheme. Nevertheless, the most significant technical requirements can be determined by way of an iterative procedure of formulating, evaluating and comparing various closed-system scenario. The functions features and applications of this systems engineering procedure are discussed.

Modell, M.↗

Electrochemical incineration of wastes

The novel technology of waste removal in space vehicles by electrochemical methods is presented to convert wastes into chemicals that can be eventually recycled. The important consideration for waste oxidation is to select a right kind of electrode (anode) material that should be stable under anodic conditions and also a poor electrocatalyst for oxygen and chlorine evolution. On the basis of long term electrolysis experiments on seven different electrodes and on the basis of total organic carbon reduced, two best electrodes were identified. The effect of redox ions on the electrolyte was studied. Though most of the experiments were done in mixtures of urine and waste, the experiments with redox couples involved 2.5 M sulfuric acid in order to avoid the precipitation of redox ions by urea. Two methods for long term electrolysis of waste were investigated: (1) the oxidation on Pt and lead dioxide electrodes using the galvanostatic methods; and (2) potentiostatic method on other electrodes. The advantage of the first method is the faster rate of oxidation. The chlorine evolution in the second method is ten times less then in the first. The accomplished research has shown that urine/feces mixtures can be oxidized to carbon dioxide and water, but current densities are low and must be improved. The perovskite and Ti4O7 coated with RuO2 are the best electrode materials found. Recent experiment with the redox agent improves the current density, however, sulphuric acid is required to keep the redox agent in solution to enhance oxidation effectively. It is desirable to reduce the use of acid and/or find substitutes.

Bhardwaj, R. C.↗

Scenarios for optimizing potato productivity in a lunar CELSS

The use of controlled ecological life support system (CELSS) in the development and growth of large-scale bases on the Moon will reduce the expense of supplying life support materials from Earth. Such systems would use plants to produce food and oxygen, remove carbon dioxide, and recycle water and minerals. In a lunar CELSS, several factors are likely to be limiting to plant productivity, including the availability of growing area, electrical power, and lamp/ballast weight for lighting systems. Several management scenarios are outlined in this discussion for the production of potatoes based on their response to irradiance, photoperiod, and carbon dioxide concentration. Management scenarios that use 12-hr photoperiods, high carbon dioxide concentrations, and movable lamp banks to alternately irradiate halves of the growing area appear to be the most efficient in terms of growing area, electrical power, and lamp weights. However, the optimal scenario will be dependent upon the relative 'costs' of each factor.

Wheeler, R. M.↗

Mechanisms for lithospheric heat transport on Venus Implications for tectonic style and volcanism

The mechanisms of plate recycling, lithospheric conduction, and hot spot volcanism are each evaluated to determine which is the dominant mode of lithospheric heat transfer on Venus, with attention given to the implications of each mechanism for the interpretation of Venus surface features. It is thought that plate recycling on Venus cannot be excluded on the basis of either theoretical arguments or present observations on topography and radar backscatter. Landforms caused by plate convergence and divergence on Venus, it is noted, would differ substantially from those on the earth owing to the high surface temperature and the absence of oceans on Venus, the lack of free or hydrated water in subducted material, the possibility that subduction would more commonly be accompanied by lithospheric delamination, and the rapid spreading rates that would be required if plate recycling removed a significant fraction of the internal heat. The possibility that the dominant mechanism early in the history of the planet was different from the one at work now is thought to merit consideration.

Solomon, S. C.↗

The Space Station Freedom - International cooperation and innovation in space safety

The Space Station Freedom (SSF) being developed by the United States, European Space Agency (ESA), Japan, and Canada poses novel safety challenges in design, operations, logistics, and program management. A brief overview discloses many features that make SSF a radical departure from earlier low earth orbit (LEO) space stations relative to safety management: size and power levels; multiphase manned assembly; 30-year planned lifetime, with embedded 'hooks and scars' forevolution; crew size and skill-mix variability; sustained logistical dependence; use of man, robotics and telepresence for on-orbit maintenance of station and free-flyer systems; closed-environment recycling; use of automation and expert systems; long-term operation of collocated life-sciences and materials-science experiments, requiring control and segregation of hazardous and chemically incompatible materials; and materials aging in space.

Rodney, George A.↗

Influence of Transport on Two-Dimensional Model Simulation. Tracer Sensitivity to 2-D Model Transport: Long Lived Tracers - 1

In this study, we examine the sensitivity of long lived tracers to changes in the base transport components in our 2-D model. Changes to the strength of the residual circulation in the upper troposphere and stratosphere and changes to the lower stratospheric K(sub zz) had similar effects in that increasing the transport rates decreased the overall stratospheric mean age, and increased the rate of removal of material from the stratosphere. Increasing the stratospheric K(sub yy) increased the mean age due to the greater recycling of air parcels through the middle atmosphere, via the residual circulation, before returning to the troposphere. However, increasing K(sub yy) along with self-consistent increases in the corresponding planetary wave drive, which leads to a stronger residual circulation, more than compensates for the K(sub yy)-effect, and produces significantly younger ages throughout the stratosphere. Simulations with very small tropical stratospheric K(sub yy) decreased the globally averaged age of air by as much as 25% in the middle and upper stratosphere, and resulted in substantially weaker vertical age gradients above 20 km in the extratropics. We found only very small stratospheric tracer sensitivity to the magnitude of the horizontal mixing across the tropopause, and to the strength of the mesospheric gravity wave drag and diffusion used in the model. We also investigated the transport influence on chemically active tracers and found a strong age-tracer correlation, both in concentration and calculated lifetimes. The base model transport gives the most favorable overall comparison with a variety of inert tracer observations, and provides a significant improvement over our previous 1995 model transport. Moderate changes to the base transport were found to provide modest agreement with some of the measurements. Transport scenarios with residence times ranging from moderately shorter to slightly longer relative to the base case simulated N2O lifetimes that were within the observational estimates of Volk et al. [1997]. However, only scenarios with rather fast transport rates were comparable with the Volk et al. estimates of CFCl3 lifetimes. This is inconsistent with model-measurement comparisons of mean age in which the base model or slightly slower transport rates compared the most favorably with balloon SF6 data. For all comparisons shown, large transport changes away from the base case resulted in simulations that were outside the range of measurements, and in many cases, far outside this range.

Fleming, Eric L.↗

Advances in Thermoplastic Composites Over Three Decades – A Literature Review

Recently, there has been a renewed interest in thermoplastic composites driven mainly by advances in automation which can lead to significant cost reductions by increasing manufacturing rates while simultaneously reducing the part count and energy consumption relative to the manufacturing of thermoset composites. At the same time, new material systems have been developed and the thermoplastic composites prepreg material quality has improved over time. Additionally, thermoplastic composites have nearly infinite room-temperature shelf life and production scraps can be reused and retired parts can be recycled, providing opportunities for more sustainable operations and downstream markets. These factors have contributed to a strong interest in advancing thermoplastic composites for aerospace, automotive, and other industrial applications. The objective of the present study is to assess the state of the art regarding the maturity and performance of thermoplastic composite materials and to document the advances made in manufacturing and assembly of thermoplastic composite structures. Therefore, more than 200 NASA reports, conference proceedings and journal papers spanning three and a half decades (1986-2022) were reviewed and the findings summarized. The current study, however, is limited in scope with a focus on the application of thermoplastic composites to aircraft structures. Further, the study does not provide a comprehensive assessment of the available literature but rather offers an overview of past and present research being conducted in the field of thermoplastic composites. The information provided may be used to identify gaps and help guide future research and development. In this report, the opportunities offered by the use of thermoplastic composites in general and challenges encountered in particular are presented first. Second, an overview of thermoplastic materials is presented, manufacturing methods are discussed, and new methods for fastener-less assembly such as welding are introduced. Third, tests that have been performed on different levels of the building block, ranging from coupon to structural level, are presented. In particular, fracture toughness results for different thermoplastic composite materials are used to demonstrate their performance compared to state-of-the-art thermoset composites. Fourth, several examples of analyses are discussed including process modelling and progressive damage analysis (PDA). An extensive list of references and appendices with tables support the narrative. Lastly, a brief summary with outlook and recommendations for future research is provided.

composites↗

Human life support for advanced space exploration

The requirements for a human life support system for long-duration space missions are reviewed. The system design of a controlled ecological life support system is briefly described, followed by a more detailed account of the study of the conceptual design of a Lunar Based CELSS. The latter is to provide a safe, reliable, recycling lunar base life support system based on a hybrid physicochemical/biological representative technology. The most important conclusion reached by this study is that implementation of a completely recycling CELSS approach for a lunar base is not only feasible, but eminently practical. On a cumulative launch mass basis, a 4-person Lunar Base CELSS would pay for itself in approximately 2.6 years relative to a physicochemical air/water recycling system with resupply of food from the Earth. For crew sizes of 30 and 100, the breakeven point would come even sooner, after 2.1 and 1.7 years, respectively, due to the increased mass savings that can be realized with the larger plant growth units. Two other conclusions are particularly important with regard to the orientation of future research and technology development. First, the mass estimates of the Lunar Base CELSS indicate that a primary design objective in implementing this kind of system must be to minimized the mass and power requirement of the food production plant growth units, which greatly surpass those of the other air and water recycling systems. Consequently, substantial research must be directed at identifying ways to produce food more efficiently. On the other hand, detailed studies to identify the best technology options for the other subsystems should not be expected to produce dramatic reductions in either mass or power requirement of a Lunar Base CELSS. The most crucial evaluation criterion must, therefore, be the capability for functional integration of these technologies into the ultimate design of the system. Secondly, this study illustrates that existing or near-term technologies are adequate to implement a Lunar Base CELSS. There are no apparent "show-stoppers" which require the development of new technologies. However, there are several areas in which new materials and technologies could be used for a more efficient implementation of the system, e.g., by decreasing mass or power requirement and increasing recycling efficiency. These areas must be further addressed through research and development. Finally, although this study focused on the development of a Lunar Base CELSS, the same technologies and a nearly identical design would be appropriate for a Mars base. Actually, except for the distance of transportation, the implementation of a CELSS on Mars would even be easier than it would be on the Moon. The presence of atmospheric CO2 on Mars, although in low concentration, coupled with the fact that the day/night cycle on Mars is very similar to that on Earth, makes the use of light-weight, greenhouse-like structures for growing food plants even more feasible than on the Moon. There are some environmental problems, which would have to be dealt with, like dust storms and the large amount of the ultraviolet radiation incident on the planet's surface. However, the materials and methods are largely available today to develop such a life support system for a Mars base.

Review, Tutorial↗

The relation between the age of the subconducting slab and the recycling of sediments into the mantle

The recycling of sediments into the mantle has become an important issue because recent papers have suggested that the geochemical inverse models of the evolution of radiogenic isotope abundances over the history of the Earth have nonunique solutions. Both the recycling of continent-derived sediments into the mantle and mixing in the mantle could produce similar geochemical effects in the mean isotopic ratios of new igneous material emplaced in continents. Recent models of Archaean heat flow and of plate tectonics during early Earth history have demonstrated that higher internal heat production of the early Earth was mainly dissipated through a higher creation rate of oceanic lithosphere. If the seafloor creation rate was higher on the early Earth, then the residence time of any one piece of oceanic lithosphere on the surface would have been shorter. It is possible that a higher rate of recycling of oceanic lithosphere into the mantle could have resulted in some transport of sediment into the mantle.

Abbott, D.↗

Solving a product safety problem using a recycled high density polyethylene container

The objectives are to introduce basic problem-solving techniques for product safety including problem identification, definition, solution criteria, test process and design, and data analysis. The students are given a recycled milk jug made of high density polyethylene (HDPE) by blow molding. The objectives are to design and perform proper material test(s) so they can evaluate the product safety if the milk jug is used in a certain way which is specified in the description of the procedure for this investigation.

Liu, Ping↗

Hybrid Suitcase Demonstrator

The need for a small, transportable hybrid motor used to demonstrate and test various hybrid propulsion concepts was identified. Demonstrations would be for public audiences to explain basic hybrid rocket concepts. Tests would be for scientific purposes and hands-on training of engineers. Funded by Technical Excellence and NESC, the system as a whole has served as a learning tool for the NASA project cycle. Coming out of the Preliminary Design Review (PDR), the project was split into two separate configurations, one for demonstrations and one for tests; each would have its own oxidizer feed system. The Demonstration system will be a simple, low pressure system with the ability to recycle for multiple motor firings. The grain design will be a fixed configuration for all firings and utilize a clear material such that the combustion process is visible. The Test Readiness Review has been held and final actions are being pursued before the initial firing.

hybrid rocket↗

NiTi Alloys: New Materials that enable Shockproof, Corrosion Immune Bearings

Though steel is the dominant material of choice for mechanical components (bearings and gears) it has intrinsic limitations related to corrosion and plastic deformation. In contrast, dimensionally stable nickel-rich Ni-Ti alloys, such as Nitinol 60, are intrinsically rustproof and can withstand high contact loads without damage (denting). Over the last decade, focused RD to exploit these alloys for new applications has revealed the science behind NiTi's remarkable properties. In this presentation, the state-of-the-art of nickel-rich NiTi alloys will be introduced along with a discussion of how NASA is adopting this new technology inside the space station water recycling system as a pathfinder for more down-to-earth tribological challenges.

bearings↗