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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 181 records · Page 10

Effect of coherent edge-localized mode on transition to high-performance hybrid scenarios in KSTAR

This paper deals with one of the origins and trigger mechanisms responsible for the observed performance enhancements in the hybrid scenario experiments conducted in Korea Superconducting Tokamak Advanced Research (KSTAR). The major contribution to the performance improvement comes from a broader and higher pedestal formation. The increase of fast ion pressure due to a plasma density decrease also contributes substantially to the global beta. Although the reduced core plasma volume resulting from the pedestal expansion has a negative effect on the core thermal energy, a considerable confinement improvement observed in the inner core region limits the degradation. The one significant characteristic of high-performance discharges is the presence of Coherent Edge-localized Mode (CEM) activity. CEM is triggered during the pedestal recovery phase between typical ELM crashes and has been found to be related to the increase of particle and heat transport. It appears to underlie two commonly observed phenomena in high-performance hybrid scenario discharges in KSTAR; pedestal broadening and continuous density decrease. Despite the associated transport increase, CEM activities can induce performance enhancement. With the pedestal broadening, ELM crashes become delayed and weakened, which, in turn, allows for a higher pedestal. Moreover, the density decrease directly increases fast ion pressure by extending the beam-slowing-down time. The linear gyrokinetic analysis reveals that the increase of fast ions could initiate positive feedback loops, leading to the stabilization of Ion Temperature Gradient mode in the inner core region.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Phytoplankton in the Beaufort and Chukchi Seas: Distributions, Dynamics and Environmental Forcing

Time-series of remotely sensed distributions of phytoplankton, sea ice, surface temperature, albedo, and clouds were examined to evaluate the impact of the variability of environmental conditions and physical forcing on the phytoplankton distribution in the Beaufort and Chukchi Seas. Large-scale distributions of these parameters were studied for the first time using weekly and monthly composites from April 1998 through September 2002. The basic data set used in this study are phytoplankton pigment concentration derived from the Sea-viewing Wide Field-of-view Sensor (SeaWiFS), ice concentration obtained from the Special Sensor Microwave Imager (SSM/I) and surface temperature, cloud cover, and albedo derived from the Advanced Very High Resolution Radiometer (AVHRR). Seasonal variations of the sea ice cover was observed to be the dominant environmental factor as the ice edge blooms followed the retreating marginal ice zones northward. Blooms were most prominent in the southwestern Chukchi Sea, and were especially persistent immediately north of the Bering Strait in nutrient- rich Anadyr water and in some fronts. Chlorophyll concentrations are shown to increase from a nominal value during onset of melt in April to a maximum value in mid-spring or summer depending on location. Large interannual variability of ice cover and phytoplankton distributions was observed with the year 1998 being uniquely associated with an early season occurrence of a massive bloom. This is postulated to be caused in part by a rapid response of phytoplankton to an early retreat of the sea ice cover in the Beaufort Sea region. Correlation analyses showed relatively high negative correlation between chlorophyll and ice concentration with the correlation being highest in May, the correlation coefficient being -0.45. 1998 was also the warmest among the five years globally and the sea ice cover was least extensive in the Beaufort-Khukchi Sea region, partly because of the 1997-98 El Nino. Strong correlations were noted between ice extent and surface temperature, the correlation coefficient being highest at - 0.79 in April, during the onset of the bloom period

Wang, Jian↗

Sulfur speciation in Sphagnum peat moss modified by mutualistic interactions with cyanobacteria

Peat moss ( Sphagnum spp.) develops mutualistic interactions with cyanobacteria by providing carbohydrates and S compounds in exchange for N-rich compounds, potentially facilitating N inputs into peatlands. Here, we evaluate how colonization of Sphagnum angustifolium hyaline cells by Nostoc muscorum modifies S abundance and speciation at the scales of individual cells and across whole leaves. For the first time, S K-edge X-ray Absorption Spectroscopy was used to identify bulk and micron-scale S speciation across isolated cyanobacteria colonies, and in colonized and uncolonized leaves. Uncolonized leaves contained primarily reduced organic S and oxidized sulfonate- and sulfate-containing compounds. Increasing Nostoc colonization resulted in an enrichment of S and changes in speciation, with increases in sulfate relative to reduced S and sulfonate. Further, at the scale of individual hyaline cells, colonized cells exhibited localized enrichment of reduced S surrounded by diffuse sulfonate, similar to observations of cyanobacteria colonies cultured in the absence of leaves. We infer that colonization stimulates plant S uptake and the production of sulfate-containing metabolites that are concentrated in stem tissues. Sulfate compounds that are produced in response to colonization become depleted in colonized cells where they may be converted into reduced S metabolites by cyanobacteria.

59 BASIC BIOLOGICAL SCIENCES↗

Humidity sensitivity of large area silicon sensors: Study and implications

The production of large area sensors is one of the main challenges that the ATLAS collaboration faces for the new Inner-Tracker full-silicon detector. During the prototype fabrication phase for the High Luminosity Large Hadron Collider upgrade, several ATLAS institutes observed indications of humidity sensitivity of large area sensors, even at relative humidities well below the dew point. Specifically, prototype Barrel and End-Cap silicon strip sensors fabricated in 6-inch wafers manifest a prompt decrease of the breakdown voltage when operating under high relative humidity, adversely affecting the performance of the sensors. In addition to the investigation of these prototype sensors, a specific fabrication batch with special passivation is also studied, allowing for a deeper understanding of the responsible mechanisms. Here we present an extensive study of this behaviour on large area sensors. The locations of the hotspots at the breakdown voltage at high humidity are revealed using different infrared thermography techniques. Several palliative treatments are attempted, proving the influence of sensor cleaning methods, as well as baking, on the device performance, but no improvement on the humidity sensitivity was achieved. Furthermore, a study of the incidence of the sensitivity in different batches is also presented, introducing a hypothesis of the origins of the humidity sensitivity associated to the sensor edge design, together with passivation thickness and conformity. Several actions to be taken during sensor production and assembly are extracted from this study, in order to minimize the impact of humidity sensitivity on the performance of large area silicon sensors for High Energy Physics experiments.

47 OTHER INSTRUMENTATION↗

Revealing the frequency-dependent oscillations in the nonlinear terahertz response induced by the Josephson current

ABSTRACT Nonlinear responses of superconductors to intense terahertz radiation has been an active research frontier. Using terahertz pump-terahertz probe spectroscopy, we investigate the c-axis nonlinear optical response of a high-temperature superconducting cuprate. After excitation by a single-cycle terahertz pump pulse, the reflectivity of the probe pulse oscillates as the pump-probe delay is varied. Interestingly, the oscillatory central frequency scales linearly with the probe frequency, a fact widely overlooked in pump-probe experiments. By theoretically solving the nonlinear optical reflection problem on the interface, we show that our observation is well explained by the Josephson-type third-order nonlinear electrodynamics, together with the emission coefficient from inside the material into free space. The latter results in a strong enhancement of the emitted signal whose physical frequency is around the Josephson plasma edge. Our result offers a benchmark for and new insights into strong-field terahertz spectroscopy of related quantum materials.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Spectral characterization of the Landsat Thematic Mapper sensors

Relative spectral response data for the Landsat-4 and Landsat-4 backup multispectral scanner subsystems (MSS), the protoflight and flight models, are presented and compared to similar data for the Landsat 1, 2 and 3 scanners. Channel (six channels per band) outputs for soil and soybean targets were simulated and compared within each band and between scanners.The principal differences between the spectral responses of the Landsat-4 scanners and previous scanners are discussed. The simulated Landsat-4 scanner outputs were 3 to 10 percent lower in the red band and 3 to 11 percent higher in the first near-IR band than previous scanners for the soybeans targets. The Landsat-4 scanners were generally more uniform from channel to channel within bands than previous scanners. In the upper-band edge of the red band of the protoflight scanner, one channel was markedly different (12 nm) from the rest. For a soybeans target, this nonuniformity resulted in a within-band difference of 6.2 percent in simulated outputs between channels.

Markham, B. L.↗

Ionospheric Convection in the Postnoon Auroral Oval: SuperDARN and Polar UVI Observations

Super Dual Auroral Radar Network (SuperDARN) observations, ultraviolet imaging from the Polar satellite (UVI), and particle precipitation data from DMSP satellites have been used to investigate the electrodynamics of the postnoon auroral oval in the Northern hemisphere. We show that: (1) For negative IMF By, the convection reversal (CR) was co-located with the maximum of auroral luminosity, but during positive IMF By the convection reversal was poleward of the auroral oval up to several degrees in latitude; (2) Postnoon auroral oval was associated with a large-scale upward field-aligned current (FAC) of the order of 6x10(exp -7). A m(exp -2) in magnitude (the FAC was inferred from the SuperDARN and UVI data). For negative IMF By, maximum of the auroral intensity coincides in latitude with the maximum of the upward field-aligned current. However, for positive IMF By. the maximum of the upward FAC was shifted to the poleward edge of the auroral oval; (3) In response to the IMF By turning from positive to negative, the maximum of the auroral luminosity did not change its position noticeably, but the position of the convection reversal changed considerably from 80-81 degs to about 76 degs MLAT, and the maximum of FAC moved from 77-78 degs to about 76 degs MLAT. Thus, after IMF By turns negative, both the FAC maximum and CR tend to coincide with the auroral maximum; (4) The IMF Bz positive deflection was followed by a decrease in both field-aligned current intensity and auroral luminosity. However, the decrease in the auroral luminosity lags behind the FAC decrease by about 12 min. Firstly, these observations allow us to suggest that the IMF By-related electric field can penetrate into the closed magnetosphere and produce convection and FAC changes in the region of the postnoon auroral oval. Secondly, we suggest that the interchange instability is a promising mechanism for the postnoon auroras.

Kozlovsky, A.↗

Spectral Characterization of the LANDSAT-4 MSS Sensors

Relative spectral response data for the LANDSAT-4 and LANDSAT-4 backup multispectral scanner subsystems (MSS), the protoflight and flight models are presented and compared to similar data for the LANDSAT 1, 2 and 3 scanners. Channel (six channels per band) outputs for soil and soybean targets were simulated and compared within each band and between scanners. The principal differences between the spectral responses of the LANDSAT-4 scanners and previous scanners are discussed. The simulated LANDSAT-4 scanner outputs were 3 to 10 percent lower in the red band and 3 to 11 percent higher in the first near-IR band than previous scanners for the soybeans targets. The LANDSAT-4 scanners were generally more uniform from channel to channel within bands than previous scanners. In the upper-band edge of the red band of the protoflight scanner, one channel was markedly different (12 nm) from the rest. For a soybeans target, this nonuniformity resulted in a within-band difference of 6.2 percent in simulated outputs between channels.

Markham, B. L.↗

Challenges in Modeling the Sun-Earth System

The transfer of mass, energy and momentum through the coupled Sun-Earth system spans a wide range of scales in time and space. While profound advances have been made in modeling isolated regions of the Sun-Earth system, minimal progress has been achieved in modeling the end-to-end system. Currently, end-to-end modeling of the Sun-Earth system is a major goal of the National Space Weather and NASA Living With a Star (LWS) programs. The uncertainty in the underlying physics responsible for coupling contiguous regions of the Sun-Earth system is recognized as a significant barrier to progress. Our limited understanding of the underlying coupling physics is illustrated by the following example questions: how does the propagation of a typical CME/solar flare influence the measured properties of the solar wind at 1 AU? How does the solar wind compel the dynamic response of the Earth's magnetosphere? How is variability in the ionosphere-thermosphere system coupled to magnetospheric variations? Why do these and related important questions remain unanswered? What are the primary problems that need to be resolved to enable significant progress in comprehensive modeling of the Sun-Earth system? Which model/technique improvements are required and what new data coverage is required to enable full model advances? This poster opens the discussion for how these and other important questions can be addressed. A workshop scheduled for October 8-22, 2004 in Huntsville, Alabama, will be a forum for identifying ana exploring promising new directions and approaches for characterizing and understanding the system. To focus the discussion, the workshop will emphasize the genesis, evolution, propagation and interaction of high-speed solar wind streamers or CME/flares with geospace and the subsequent response of geospace from its outer reaches in the magnetosphere to the lower edge of the ionosphere-mesosphere-thermosphere. Particular emphasis will be placed on modeling the coupling aspects of these phenomena across boundaries between regions and on data analysis that guides and constrains model results. Specific topics to be addressed are: Corotating interaction regions, Coronal mass ejections, Energetic particles, System preconditioning, Extreme events and super storms, End-to-End modeling efforts.

Spann, James↗

Extremely Slow Trap-Mediated Hole Relaxation in Room-Temperature InP/ZnSe/ZnS Quantum Dots

Time-resolved photoluminescence (PL) and transient absorption (TA) spectroscopy have been used to elucidate the hole relaxation dynamics in high-quality InP/ZnSe/ZnS quantum dots (QDs) at room temperature. In QDs having an In/P ratio close to 1:1, hole cooling is fast compared to the ~40 ps time-correlated photon-counting instrument response. However, in QDs that luminesce at wavelengths greater than around 600 nm and have excess indium, a significant fraction of the PL exhibits a slower rise time. In this case, the PL rises over a range of timescales varying from close to the instrument response to approximately 300–400 ps. The time constant of the slowest component increases with increasing InP core size and the fraction of the PL that has the slow rise time increases with excess indium in the particle. In all cases, a slow rise time and any spectral evolution on that timescale are absent in the TA results, indicating that the slow dynamics may be assigned to relaxation in the valence band. QDs emitting at wavelengths below 560 nm show very different dynamics, exhibiting a barely detectable <50 ps rise time. Based on these results and measured elemental compositions, the slow hole relaxation is assigned to the transient population of indium-based traps in the ZnSe shell that are above the valence band edge only for the larger, red-emitting QDs. Here, the relative trap to band edge relaxation rates can be understood in terms of effective mass approximation hole wave function calculations, which show that the relaxation rate is largely determined by the extent to which the hole wave function in the lowest exciton penetrates into the ZnSe shell, overlapping the trapped-hole wave functions.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

The separation between gas and dust filaments at the edge of the expanding shell in Eridanus

Observations obtained from IRAS for a 120 sq deg region at the boundary of a large expanding shell in Eridanus are presented. It is found that the separation between the structures in the H I and IR emission is not due to a transition of the gas into molecular hydrogen at the location of the IR filaments. The molecular hydrogen column density of these filaments is at least two orders of magnitude below what is typically seen in high-latitude molecular clouds. As the H I and dust in this region are associated with a large expanding shell (or superbubble), the action of shocks and radiation fields may be responsible for the separations of gas and dust. Unless the gas and dust structures are resolved and lie in a favorable viewing geometry, the effect tends to be hidden. The results indicate that it is not always evident, from observations with spatial resolutions coarser than a few arcminutes, how interstellar gas and dust are related.

Verschuur, G. L.↗

Experimental and Theoretical Studies of the Surface Oxidation Process of Rare–Earth Tritellurides

Recent studies have established Van der Waals (vdW) layered and 2D rare-earth tritellurides (RTe 3 ) as superconductors and near room-temperature charge density wave (CDW) materials. Their environmental stability raises natural concern owing to aging/stability effects observed in other tellurium-based layered crystals. Here, the results establish the stability and environmental aging characteristics of these RTe 3 systems involving a variety of metals such as La, Nd, Sm, Gd, Dy, and Ho. The atomic force microscopy (AFM) and scanning electron microscopy (SEM) results show that all the RTe 3 sheets oxidize to form thin TeO x layers that are primarily confined to the surface, edges, and grain boundaries. Time-resolved in situ Raman spectroscopy measurements are used to understand the kinetics of the oxidization process for different lanthanide metal cations and establish their relative stability/resilience to oxidization. Overall results indicate that the vdW layers show higher air stability as the 4f electron number decreases going from Ho to La, resulting in the most stable LaTe 3 compared to the least stable HoTe 3 . Comprehensive quantum mechanical simulations reveal that environmental degradation originates from a strong oxidizing reaction with O 2 molecules, while humidity (H 2 O) plays a negligible role unless Te vacancies are present. Moreover, the simulations explain the effects of 4f electrons on the work function and Te vacancies formation, which directly impact the aging characteristics of RTe 3 layers. Interestingly, optical and electrical measurements show that the CDW response is still observed in aged RTe 3 layers owing to the presence of underlying pristine/nonoxidized RTe 3 layers, except CDW transition temperatures increase due to the thickness effect. Overall results offer the first in-depth environmental aging studies on these materials, which can be applied to engineer and design their chemical stability, surface properties, and overall CDW characteristics.

36 MATERIALS SCIENCE↗

A study of degradation of plates for nickel-cadmium spacecraft cells

The relative merits of coining and not coining of sintered nickel-oxide and cadmium plates was investigated. A survey of the industry including cell manufactures and users was made and results summarized. Sample plate materials from most commercial cell suppliers were obtained and characterized for properties that may correlate with the tendency toward physical disintegration during handling and over long periods of time in the cell. Special test methods were developed to obtain comparative data in a short time. A wide range of physical properties and coining thicknesses was observed, resulting in a range of responses. The stronger, less brittle materials resisted loss of sinter better than weaker materials whether or not coined. Coining improved handling and resistance to electrochemical cycling in all materials tested. An apparent exception was found to be due to improper coining of a tapered edge.

Scott, W. R.↗

Effects of Elastic Edge Restraints and Initial Prestress on the Buckling Response of Compression-Loaded Composite Panels

A parametric study of the effects of test-fixture-induced initial prestress and elastic edge restraints on the prebuckling and buckling responses of a compression-loaded, quasi-isotropic curved panel is presented. The numerical results were obtained by using a geometrically nonlinear finite element analysis code with high-fidelity models. The results presented show that a wide range of prebuckling and buckling behavior can be obtained by varying parameters that represent circumferential loaded-edge restraint and rotational unloaded-edge restraint provided by a test fixture and that represent the mismatch in specimen and test-fixture radii of curvature. For a certain range of parameters, the panels exhibit substantial nonlinear prebuckling deformations that yield buckling loads nearly twice the corresponding buckling load predicted by a traditional linear bifurcation buckling analysis for shallow curved panels. In contrast, the results show another range of parameters exist for which the nonlinear prebuckling deformations either do not exist or are relatively benign, and the panels exhibit buckling loads that are nearly equal to the corresponding linear bifurcation buckling load. Overall, the results should also be of particular interest to scientists, engineers, and designers involved in simulating flight-hardware boundary conditions in structural verification and certification tests, involved in validating structural analysis tools, and interested in tailoring buckling performance.

Hilburger, Mark W.↗

Compression-Loaded Composite Panels With Elastic Edge Restraints and Initial Prestress

A parametric study of the effects of test-fixture-induced initial prestress and elastic edge restraints on the prebuckling and buckling responses of a compression-loaded, quasi-isotropic curved panel is presented. The numerical results were obtained by using a geometrically nonlinear finite element analysis code with high-fidelity models. The results presented show that a wide range of prebuckling and buckling behavior can be obtained by varying parameters that represent circumferential loaded-edge restraint and rotational unloaded-edge restraint provided by a test fixture and that represent the mismatch in specimen and test-fixture radii of curvature. For a certain range of parameters, the panels exhibit substantial nonlinear prebuckling deformations that yield buckling loads nearly twice the corresponding buckling load predicted by a traditional linear bifurcation buckling analysis for shallow curved panels. In contrast, the results show another range of parameters exist for which the nonlinear prebuckling deformations either do not exist or are relatively benign, and the panels exhibit buckling loads that are nearly equal to the corresponding linear bifurcation buckling load. Overall, the results should be of particular interest to scientists, engineers, and designers involved in simulating flight-hardware boundary conditions in structural verification and certification tests, involved in validating structural analysis tools, and interested in tailoring buckling performance.

Hilburger, Mark W.↗

Spreadsheets in Team X: Preserving Order in an Inherently Chaotic Environment

JPL is NASA's prime center for deep space missions. In response to the need to reduce the cost and time to complete early concept studies and proposals JPL created the first concurrent engineering team in the aerospace industry: Team X. Started in 1995, Team X has carried out over 800 studies, dramatically reducing the time and cost involved, and has been the model for other concurrent engineering teams both within NASA and throughout the larger aerospace community. Since its inception, the software backbone of this highly successful design team - engaged in examining some of NASA's cutting edge concepts - has been the unassuming spreadsheet. Over the years the Team X spreadsheet-based tools have evolved from simple standalone engineering models into a networked spreadsheet intensive system with real time parameter updating. Recent new capabilities include stochastic cost estimation and a graphical drag and drop block diagram that automatically populates the related spreadsheet parameters of cost, mass and power. This paper describes how the spreadsheet functions within Team X: its history, architecture, current capabilities, enabling strengths and persistent weaknesses. In addition, the verification methods and institutional oversight that have evolved as the Team X products became increasingly critical to Laboratory success are also discussed.

concurrent engineering↗

Using Explainable Artificial Intelligence to Predict Perovskite Solar Cell Electrical Metastability from Operando Photoluminescence Images in Accelerated Stress Testing

Metal halide perovskite (MHP) solar cells exhibit a metastable response to bias governed by coupled ionic–electronic processes, complicating the conventional reciprocity relation between luminescence intensity and device open-circuit voltage (V oc ). This limits the use of luminescence as a diagnostic for device screening or accelerated stress testing, motivating new approaches that can interpret photoluminescence (PL) signals under nonequilibrium conditions. From the artificial intelligence perspective, we develop an explainable deep learning framework that integrates convolutional neural networks (CNN), long short-term memory (LSTM) layers, and an attention mechanism to learn spatiotemporal features from operando photoluminescence PL image sequences. The model achieves a mean absolute error of ±0.027 V in predicting open-circuit voltage transients and reduces extreme-tail errors by up to 78% compared to physics-based reciprocity calculations. Gradient-weighted Class Activation Mapping (Grad-CAM) provides interpretability by highlighting physically meaningful regions such as electrode edges and emergent defect features. From the engineering application perspective, this framework enables accurate, contactless prediction of device V oc and identification of degradation-relevant features during accelerated aging of perovskite solar cells. This approach demonstrates how explainable AI can enhance operando diagnostics and reliability analysis in photovoltaic devices under nonequilibrium conditions.

14 SOLAR ENERGY↗

Optimization of Second Fault Detection Thresholds to Maximize Mission POS

In order to support manned spaceflight safety requirements, the Space Launch System (SLS) has defined program-level requirements for key systems to ensure successful operation under single fault conditions. To accommodate this with regards to Navigation, the SLS utilizes an internally redundant Inertial Navigation System (INS) with built-in capability to detect, isolate, and recover from first failure conditions and still maintain adherence to performance requirements. The unit utilizes multiple hardware- and software-level techniques to enable detection, isolation, and recovery from these events in terms of its built-in Fault Detection, Isolation, and Recovery (FDIR) algorithms. Successful operation is defined in terms of sufficient navigation accuracy at insertion while operating under worst case single sensor outages (gyroscope and accelerometer faults at launch). In addition to first fault detection and recovery, the SLS program has also levied requirements relating to the capability of the INS to detect a second fault, tracking any unacceptable uncertainty in knowledge of the vehicle's state. This detection functionality is required in order to feed abort analysis and ensure crew safety. Increases in navigation state error and sensor faults can drive the vehicle outside of its operational as-designed environments and outside of its performance envelope causing loss of mission, or worse, loss of crew. The criteria for operation under second faults allows for a larger set of achievable missions in terms of potential fault conditions, due to the INS operating at the edge of its capability. As this performance is defined and controlled at the vehicle level, it allows for the use of system level margins to increase probability of mission success on the operational edges of the design space. Due to the implications of the vehicle response to abort conditions (such as a potentially failed INS), it is important to consider a wide range of failure scenarios in terms of both magnitude and time. As such, the Navigation team is taking advantage of the INS's capability to schedule and change fault detection thresholds in flight. These values are optimized along a nominal trajectory in order to maximize probability of mission success, and reducing the probability of false positives (defined as when the INS would report a second fault condition resulting in loss of mission, but the vehicle would still meet insertion requirements within system-level margins). This paper will describe an optimization approach using Genetic Algorithms to tune the threshold parameters to maximize vehicle resilience to second fault events as a function of potential fault magnitude and time of fault over an ascent mission profile. The analysis approach, and performance assessment of the results will be presented to demonstrate the applicability of this process to second fault detection to maximize mission probability of success.

Anzalone, Evan↗