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At least 181 records · Page 10

Force Measurement on the GLAST Delta II Flight

This viewgraph presentation reviews the interface force measurement at spacecraft separation of GLAST Delta II. The contents include: 1) Flight Force Measurement (FFM) Background; 2) Team Members; 3) GLAST Mission Overview; 4) Methodology Development; 5) Ground Test Validation; 6) Flight Data; 7) Coupled Loads Simulation (VCLA & Reconstruction); 8) Basedrive Simulation; 9) Findings; and 10) Summary and Conclusions.

Gordon, Scott↗

Nucleation in aqueous NaCl solutions shifts from 1-step to 2-step mechanism on crossing the spinodal

Here, we use large-scale molecular dynamics simulations coupled to free energy calculations to identify for the first time a limit of stability (spinodal) and a change in the nucleation mechanism in aqueous NaCl solutions. This is a system of considerable atmospheric, geological, and technical significance. We find that the supersaturated metastable NaCl solution reaches its limit of stability at sufficiently high salt concentrations, as indicated by the composition dependence of the salt chemical potential, indicating the transition to a phase separation by spinodal decomposition. However, the metastability limit of the NaCl solution does not correspond to spinodal decomposition with respect to crystallization. We find that beyond this spinodal, a liquid/amorphous separation occurs in the aqueous solution, whereby the ions first form disordered clusters. We term these clusters as “amorphous salt.” We also identify a transition from one- to two-step crystallization mechanism driven by a spinodal. In particular, crystallization from aqueous NaCl solution beyond the spinodal is a two-step process, in which the ions first phase-separate into disordered amorphous salt clusters, followed by the crystallization of ions in the amorphous salt phase. By contrast, in the aqueous NaCl solution at concentrations lower than the spinodal, crystallization occurs via a one-step process as the ions aggregate directly into crystalline nuclei. The change of mechanism with increasing supersaturation underscores the importance of an accurate determination of the driving force for phase separation. The study has broader implications on the mechanism for nucleation of crystals from solutions at high supersaturations.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Flow processes in overexpanded chemical rocket nozzles. Part 2: Side loads due to asymmetric separation

Methods for measuring the lateral forces, occurring as a result of asymmetric nozzle flow separation, are discussed. The effect of some parameters on the side load is explained. A new method was developed for calculation of the side load. The values calculated are compared with side load data of the J-2 engine. Results are used for predicting side loads of the space shuttle main engine.

Schmucker, R. H.↗

Velocity-Field Measurements of an Axisymmetric Separated Flow Subjected to Amplitude-Modulated Excitation

Active flow control was applied at the point of separation of an axisymmetric, backward-facing-step flow. The control was implemented by employing a Helmholtz resonator that was externally driven by an amplitude-modulated, acoustic disturbance from a speaker located upstream of the wind tunnel. The velocity field of the separating/reattaching flow region downstream of the step was characterized using hotwire velocity measurements with and without flow control. Conventional statistics of the data reveal that the separating/reattaching flow is affected by the imposed forcing. Triple decomposition along with conditional averaging was used to distinguish periodic disturbances from random turbulence in the fluctuating velocity component. A significant outcome of the present study is that it demonstrates that amplitude-modulated forcing of the separated flow alters the flow in the same manner as the more conventional method of periodic excitation.

Trosin, Barry James↗

Attribution of Historical Whole-atmosphere Ozone Forcing to Emissions

Anthropogenic ozone radiative forcing is traditionally separately attributed to tropospheric and stratospheric changes assuming these have distinct causes. Using the interactive composition-climate model GISS-E2-R we find that this assumption is not justified. Our simulations show that changes in emissions of tropospheric ozone precursors have substantial effects on ozone in both regions, as do anthropogenic halocarbon emissions. Based on our results, additional simulations with the NCARCAM3.5 model, and published studies, we estimate industrial era (1850 to 2005) whole-atmosphere ozone forcing of 0.5 W/sq m due to anthropogenic tropospheric precursors and about -0.2 W/sq m due to halocarbons. The net troposphere plus stratosphere forcing is similar to the net halocarbon plus precursor ozone forcing, but the latter provides a more useful perspective. The halocarbon-induced ozone forcing is roughly two-thirds the magnitude of the halocarbon direct forcing but opposite in sign, yielding a net forcing of only 0.1 W/sq m. Thus the net effect of halocarbons has been smaller, while the effect of tropospheric ozone precursors has been greater, than generally recognized.

Shindell, Drew↗

Simulations of vertical displacement oscillatory modes and global Alfvén Eigenmodes in JET geometry

Vertical Displacement Oscillatory Modes (VDOM), with frequency in the Alfvén range, are natural modes of oscillation of magnetically confined laboratory plasmas with elongated cross-section. These axisymmetric modes arise from the interaction between the plasma current, which is in equilibrium with currents flowing in external coils, and perturbed currents induced on a nearby conducting wall. The restoring force exerted by these perturbed currents on the vertical motion of the plasma column leads to its oscillatory behavior. An analytic model for VDOM was proposed based on an idealized 'straight tokamak' equilibrium with uniform equilibrium current density. This article introduces the first numerical simulations of VDOM in a realistic JET tokamak configuration, using the extended-MHD code NIMROD and drawing comparisons with Global Alfvén Eigenmodes (GAE). The results show qualitative agreement with analytic predictions regarding mode frequency and radial structure, supporting the identification of VDOM as a fundamental oscillation mode in tokamak plasmas. VDOM and GAE are modeled in a representative JET discharge, where axisymmetric perturbations with toroidal mode number n = 0 driven unstable by fast ions were observed. The two modes are examined separately using a forced oscillator within the NIMROD code, which enables a comparison of their characteristics and helps identify the experimentally observed mode possibly as a GAE.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Some aspects of unsteady separation

Unsteady separation can be forced in a variety of ways and in this presentation two fundamental means will be considered: (1) the introduction of convected vorticular disturbances into the flow; and (2) the influence of a specific type of three-dimensional geometry. In both situations a response of the viscous flow near the wall is provoked wherein the fluid near the surface abruptly focuses into a narrow region that erupts from the surface into the mainstream. In two-dimensional flows, the eruption takes the form of a narrow, explosively-growing spike, while in three-dimensional situations, examples are presented which indicate that the eruption is along a narrow zone in the shape of a crescent-shaped plume. The nature of the three-dimensional flow near a circular cylinder, which is mounted normal to a flat plate, is also examined in this study. Here the three-dimensional geometry induces complex three-dimensional separations periodically. The dynamics of the generation process is studied experimentally in a water channel using hydrogen bubble wires and a laser sheet, and the main features of the laminar regime through to transition are documented.

Smith, C. R.↗

Unexpected Intermediate State Photoinduced in the Metal-Insulator Transition of Submicrometer Phase-Separated Manganites

At ultrafast timescales, the initial and final states of a first-order metal-insulator transition often coexist forming clusters of the two phases. In this work, we report an unexpected third long-lived intermediate state emerging at the photoinduced first-order metal-insulator transition of La 0.325 Pr 0.3 Ca 0.375 MnO 3 , known to display submicrometer length-scale phase separation. Using magnetic force microscopy and time-dependent magneto-optical Kerr effect, we determined that the third state is a nanoscale mixture of the competing ferromagnetic metallic and charge-ordered insulating phases, with its own physical properties. This discovery bridges the two different families of colossal magnetoresistant manganites known experimentally and shows for the first time that the associated states predicted by theory can coexist in a single sample.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Process for CO2 Capture Using Ionic Liquid That Exhibits Phase Change

A novel process for capturing carbon dioxide from the flue gas of a coal-fired power plant has been shown to reduce parasitic power consumption substantially. The process employs an ionic liquid created at the University of Notre Dame that has a high capacity for absorbing CO2 by chemical reaction. A distinguishing property of this ionic liquid is that it changes phase from solid to liquid upon reaction with CO2. The process uses heat generated by this phase transition to lower parasitic power consumption. The driving force for CO2 separation is a combination of temperature and pressure differences; the process could even work without the addition of heat. A realistic process was created to capture CO2 efficiently. Computer simulation of the process enabled calculation of viable process conditions and power usage. The main concepts of the process were shown to work using a lab-scale apparatus. Parasitic power consumes 23% of net power generation, 55% lower than that of the monoethanolamine (MEA) process. However, capital cost is higher. The cost of electricity (COE) is 28% lower than that of the MEA process.

Eisinger, RS↗

Photovoltaic effect in an indium-tin-oxide/ZnO/BiFeO{sub 3}/Pt heterostructure

We have studied the photovoltaic effect in a metal/semiconductor/ferroelectric/metal heterostructure of In{sub 2}O{sub 3}-SnO{sub 2}/ZnO/BiFeO{sub 3}/Pt (ITO/ZnO/BFO/Pt) multilayer thin films. The heterolayered structure shows a short-circuit current density (J{sub sc}) of 340 μA/cm{sup 2} and an energy conversion efficiency of up to 0.33% under blue monochromatic illumination. The photovoltaic mechanism, specifically in terms of the major generation site of photo-excited electron-hole (e-h) pairs and the driving forces for the separation of e-h pairs, is clarified. The significant increase in photocurrent of the ITO/ZnO/BFO/Pt compared to that of ITO/BFO/Pt is attributed to the abundant e-h pairs generated from ZnO. Ultraviolet photoelectron spectroscopy reveals the energy band alignment of ITO/ZnO/BFO/Pt, where a Schottky barrier and an n{sup +}-n junction are formed at the BFO/Pt and ZnO/BFO interfaces, respectively. Therefore, two built-in fields developed at the two interfaces are constructively responsible for the separation and transport of photo-excited e-h pairs.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Non-pairwise additivity of the leading-order dispersion energy

The leading-order (i.e., dipole-dipole) dispersion energy is calculated for one-dimensional (1D) and two-dimensional (2D) infinite lattices, and an infinite 1D array of infinitely long lines, of doubly occupied locally harmonic wells. The dispersion energy is decomposed into pairwise and non-pairwise additive components. By varying the force constant and separation of the wells, the non-pairwise additive contribution to the dispersion energy is shown to depend on the overlap of density between neighboring wells. As well separation is increased, the non-pairwise additivity of the dispersion energy decays. The different rates of decay for 1D and 2D lattices of wells is explained in terms of a Jacobian effect that influences the number of nearest neighbors. For an array of infinitely long lines of wells spaced 5 bohrs apart, and an inter-well spacing of 3 bohrs within a line, the non-pairwise additive component of the leading-order dispersion energy is −0.11 kJ mol{sup −1} well{sup −1}, which is 7% of the total. The polarizability of the wells and the density overlap between them are small in comparison to that of the atomic densities that arise from the molecular density partitioning used in post-density-functional theory (DFT) damped dispersion corrections, or DFT-D methods. Therefore, the nonadditivity of the leading-order dispersion observed here is a conservative estimate of that in molecular clusters.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Quaternary MgSiN 2 -GaN alloy semiconductors for deep UV applications

Ultrawide direct band gap semiconductors hold great promise for deep ultraviolet optoelectronic applications. Here we evaluate the potential of MgSiN 2 -GaN alloys for this purpose. Although MgSiN 2 itself has an indirect gap ~0.4 eV below its direct gap of ~6.5 eV, its different sign lattice mismatch from GaN in two different basal plane directions could avoid the tensile strain which limits Al x Ga 1–x N on GaN for high x. Two octet-rule-preserving structures (with space groups Pmn2 1 and P1n1) of a 50% alloy of MgSiN 2 and GaN are investigated and are both found to have gaps larger than 4.75 eV using quasiparticle self-consistent GW calculations. Both are nearly direct gap in the sense that the indirect gap is less than 0.1 eV lower than the direct gap. Furthermore, their mixing energies are positive yet small, with values of 8 (31) meV/atom for Pmn2 1 (P1n1), indicating only a small driving force toward phase separation.

36 MATERIALS SCIENCE↗

Aerodynamic Drag Reduction Technologies Testing of Heavy-Duty Vocational Vehicles and a Dry Van Trailer

This study focused on two accepted methods for quantifying the benefit of aerodynamic improvement technologies on vocational vehicles: the coastdown technique, and on-road constant speed fuel economy measurements. Both techniques have their advantages. Coastdown tests are conducted over a wide range in speed and allow the rolling resistance and aerodynamic components of road load force to be separated. This in turn allows for the change in road load and fuel economy to be estimated at any speed, as well as over transient cycles. The on-road fuel economy measurements only supply one lumped result, applicable at the specific test speed, but are a direct measurement of fuel usage and are therefore used in this study as a check on the observed coastdown results. Resulting coefficients were then used to populate a vehicle model and simulate expected annual fuel savings over real-world vocational drive cycles.

30 DIRECT ENERGY CONVERSION↗

Electron observations in the solar wind and magnetosheath.

Electron temperature measurements taken by a triaxial electron analyzer on Ogo 5 in the solar wind and in the magnetosheath are interpreted. In the interplanetary medium, observations made on the bow shock connected lines of magnetic force have been separated from those made on non-bow-shock connected lines. The dependence of electron thermal properties on the local field geometry is discussed together with features of electron temperature and density discontinuities across the bow shock. The velocity distribution function is characterized together with temperature and density variations in a part of the dawn magnetosheath.

Scudder, J. D.↗

Special Perturbations Using Back-Correction Methods of Numerical Integration

A new class of linear multistep methods for numerical integration of differential equations is reported that permits satellite computation solutions to be corrected at certain points in the past as the integration advances in time. Algorithms have been developed for the solution of both first- and second-order differential equations. The back correction method appears to be more efficient than classical methods when dominant and perturbing forces can be separated.

Feagin, T.↗

Transient excitation and mechanical admittance test techniques for prediction of payload vibration environments

Transient excitation forces were applied separately to simple beam-and-mass launch vehicle and payload models to develop complex admittance functions for the interface and other appropriate points on the structures. These measured admittances were then analytically combined by a matrix representation to obtain a description of the coupled system dynamic characteristics. Response of the payload model to excitation of the launch vehicle model was predicted and compared with results measured on the combined models. These results are also compared with results of earlier work in which a similar procedure was employed except that steady-state sinusoidal excitation techniques were included. It is found that the method employing transient tests produces results that are better overall than the steady state methods. Furthermore, the transient method requires far less time to implement, and provides far better resolution in the data. However, the data acquisition and handling problem is more complex for this method. It is concluded that the transient test and admittance matrix prediction method can be a valuable tool for development of payload vibration tests.

Kana, D. D.↗