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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 181 records · Page 10

Fine-scale motion in NGC 6514 and NGC 6523

Velocity maps of the inner regions of the bright H II regions NGC 6514 and NGC 6523 were made with unprecedented spatial and spectral resolution in the 5007 A line of forbidden O III. In addition to the advantages of an instrumental full width at half-maximum intensity of only 5.4 km/s, the small thermal width of the heavy oxygen ion also allows determination of accurate line widths and velocities. The CCD spectra were numerically fitted to Gaussian line profiles and revealed two separate velocity systems in NGC 6523. The data sets of radial velocities were used to derive the dependence of the most probable turbulent velocities upon the sample sizes, and the spatial dependence of the structure function. These relationships are the basic functions for comparison with the predictions of the models for turbulence in H II regions.

O'Dell, C. R.↗

The velocity structure and turbulence at the center of the Orion Nebula

Using the Coude Feed System of the Kitt Peak National Observatory at its highest possible dispersion and a CCD detector with wide dynamic range it was possible to examine in detail the radial and turbulent velocities of the Orion Nebula at the seeing limit. For the first time, multiple components of the spectral lines were resolved and the Gaussian profiles fit to them. Using four different observing runs, two circular areas 2 minutes in diameter were observed, the first centered on the theta sup 1 Orionis and the second centered on theta sup 2 Orionis. The velocity resolution of 1 km/s combined with the angular resolution of 2 seconds allowed observation in detail at line splitting as well as the location and measurement of high internal motions, about -50 km/s with respect to the bulk of ionized matter. Because over 900 different positions were measured, modern statistical techniques were used for the analysis of turbulence, so that the dispersion relation and the structure function could be calculated and compared with predictions of the Kolmogorov theory. The random motions showed correlation with spatial separation, as expected for turbulence; but comparison with predictions of the classical theory for nebular turbulence showed poor agreement. If Kolmogorov theory applies, then the energy must be input at many scales.

Castaneda, Hector O.↗

Turbulent small-scale neutral and ion density fluctuations as measured during MAC/Epsilon

During the MAC/Epsilon campaign (Fall 1987, from Andoya, Northern Norway, 69 N, 16 E) a total of four altitude profiles of neutral gas number densities and six profiles of ion number densities were measured with high spatial resolution in the height range from 60 to 120 km. First results of these rocket-borne experiments are presented with emphasis on small scale turbulent density variations and related turbulent parameter as structure function constants and energy dissipation rates.

Luebken, F.-J.↗

Space Station flight telerobotic servicer functional requirements development

The Space Station flight telerobotic servicer (FTS), a flight robotic system for use on the first Space Station launch, is described. The objectives of the FTS program include: (1) the provision of an alternative crew EVA by supporting the crew in assembly, maintenance, and servicing activities, and (2) the improvement of crew safety by performing hazardous tasks such as spacecraft refueling or thermal and power system maintenance. The NASA/NBS Standard Reference Model provides the generic, hierarchical, structured functional control definition for the system. It is capable of accommodating additional degrees of machine intelligence in the future.

Oberright, John↗

Spatial and temporal variability of VAS radiance measurements by structure and correlation analysis

The statistical structure function analysis presently applied to VISSR Atmospheric Sounder (VAS) measurements has been extended to include time, and yields structure plots in either two spatial dimensions or one spatial dimension and time that indicate three-dimensional measurement variability. The analyses that include time as a coordinate also yield an indication of the mean speed and direction of the analyzed data. Results for three-hourly VAS data indicate that sampling at a high, approximately 1-hour, frequency is required in order to correctly monitor VAS measurements' temporal variability in a way equivalent to high spatial resolution.

Hillger, Donald W.↗

Enhanced image products by limb-correction and smoothing of VAS radiance measurements

Limb darkening and brightening affect the GOES satellite's VISSR Atmospheric Sounder instrument's imagery with varying satellite viewing angles and instrument noise; limb effects are also associated with a vertical shift of a wavelength's characteristic weighting function. The radiances in an image can be normalized to a reference zenith angle by limb-correcting the image. An additional undesirable effect is that of instrument noise, which varies as a function of channel characteristics and is greatest for channels sensitive to the upper atmosphere. The statistical structure function analysis method of Hillger et al. (1987) is used to obtain noise levels and optimal spatial averaging distances; the averaging domain size from the analysis is used to produce smoothed images, via a running average technique.

Jones, Andrew S.↗

Simulation of microwave brightness temperatures of an evolving hailstorm at SSM/I frequencies

A simulation of the appearance of an intense hailstorm in the passive microwave spectrum is used to characterize the vertical sources of radiation contributing to the microwave brightness temperatures at the top of the atmosphere. The four frequencies studied correspond to those used on the USAF Special Sensor Microwave Imager. The origin and movement of the radiation are described by two vertically resolved radiative structure functions. Consideration is given to problems relating to precipitation retrieval through passive remote sensing.

Mugnai, Alberto↗

Multifrequency observations of BL Lacertae

Optical, IR, and radio monitoring data covering 20 years are presented for BL Lac. Also, four simultaneous multifrequency spectra are given, covering the range 10 to the 9th - 10 to the 18th Hz. These spectra include ground-based observations and data from the Einstein, Exosat, IUE, and IRAS satellites. From the monitoring data, the character of emission variability is determined using structure functions. The multifrequency spectra are used to study the origin of X-ray emission and to determine the physical parameters of emitting regions. The data show that the emitting region is inhomogeneous, with a small inner region of high density and magnetic field that eventually becomes a large, partially opaque radio emitting region with a low density and magnetic fields. Also, the two simple predictions of the synchrotron self-Compton model are reproduced by the multifrequency spectra.

Bregman, Joel N.↗

Intermittent turbulence in the solar wind

This paper demonstrates the existence of intermittent turbulence in the solar wind at 8.5 AU. The pth-order velocity structure functions show scaling behavior in the range of periods from 0.85 hour to 13.6 hours for p of less than 20. The exponent of the scaling law s(p) is a quadratic function of p. These observations of s(p) for compressible MHD turbulence on a scale of the order of about 1 AU are consistent with laboratory measurements of s(p) for gasdynamic turbulence on a scale of the order of 1 m, indicating the universal character of intermittent turbulence. The observations are not described by the 'constant beta' model of intermittent turbulence. They are marginally consistent with the lognormal model. The observations are consistent with a random beta model prediction which assumes that the turbulence is a mixture of sheets and space-filling eddies.

Burlaga, L. F.↗

Simulations of sonic boom ray tube area fluctuations for propagation through atmospheric turbulence including caustics via a Monte Carlo method

A theory which gives statistical predictions for how often sonic booms propagating through the earth's turbulent boundary layer will encounter caustics, given the spectral properties of the atmospheric turbulence, is outlined. The theory is simple but approximately accounts for the variation of ray tube areas along ray paths. This theory predicts that the variation of ray tube areas is determined by the product of two similar area factors, psi (x) and phi (x), each satisfying a generic harmonic oscillator equation. If an area factor increases the peak acoustic pressure decreases, and if the factor decreases the peak acoustic pressure increases. Additionally, if an area factor decreases to zero and becomes negative, the ray has propagated through a caustic, which contributes a phase change of 90 degrees to the wave. Thus, it is clear that the number of times that a sonic boom wave passes through a caustic should be related to the distorted boom waveform received on the ground. Examples are given based on a characterization of atmospheric turbulence due to the structure function of Tatarski as modified by Crow.

Sparrow, Victor W.↗

High resolution atmospheric and surface variability from combined MAMS and VAS radiances

Measuring of the variation of atmospheric and surface quantities such as moisture and stability at small scales is an important step to monitoring, understanding and forecasting mesoscale processes. For instance, moisture and stability products from the geostationary platform VISSR Atmospheric Sounder (VAS) exhibit interesting detail at the meso B (20-200 km) level (Chesters et al., 1986; Smith et al., 1985). However, variations at the meso C scale (2-20 km) and at the lower end of the meso B scale (20-100 km) suffer from the effects of noise. Noise can be greatly reduced by using a high resolution data collection system. The Multispectral Atmospheric Mapping Sensor (MAMS), with its 100-m resolution over a 36km swath, is well suited to provide high resolution mesoscale information about the atmosphere and surface of the earth. A more complete depiction of the atmospheric state at the smaller scales is possible through the combination of the high horizontal resolution MAMS data with the vertical sounding data of the VAS. This paper demonstrates a procedure for combining MAMS and VAS data in a physical retrieval to produce high resolution derived products of precipitable water (PW), lifted index (LI), and skin temperature (TS). The variability of these products is evaluated in a structure function analysis similar to that of Hillger and Vonder Haar (1979). Results for 19 June 1986 from the Cooperative Hunstville Meteorological Experiment (COHMEX) are presented.

Moeller, Christopher C.↗

Use of wind data in global modelling

The European Centre for Medium Range Weather Forecasts (ECMWF) is producing operational global analyses every 6 hours and operational global forecasts every day from the 12Z analysis. How the wind data are used in the ECMWF golbal analysis is described. For each current wind observing system, its ability to provide initial conditions for the forecast model is discussed as well as its weaknesses. An assessment of the impact of each individual system on the quality of the analysis and the forecast is given each time it is possible. Sometimes the deficiencies which are pointed out are related not only to the observing system itself but also to the optimum interpolation (OI) analysis scheme; then some improvements are generally possible through ad hoc modifications of the analysis scheme and especially tunings of the structure functions. Examples are given. The future observing network over the North Atlantic is examined. Several countries, coordinated by WMO, are working to set up an 'Operational WWW System Evaluation' (OWSE), in order to evaluate the operational aspects of the deployment of new systems (ASDAR, ASAP). Most of the new systems are expected to be deployed before January 1987, and in order to make the best use of the available resources during the deployment phase, some network studies are carried out at the present time, by using simulated data for ASDAR and ASAP systems. They are summarized.

Pailleux, J.↗

Adaptation and Response in Drylands (ARID): A Dryland Research Agenda and Campaign Strategy

Dryland ecosystems cover 41% of Earth’s land surfaces, account for 44% of cultivated lands and 60% of food sources, and make large contributions to the global water and carbon cycles. However, these ecosystems are experiencing unprecedented extremes including heatwaves, floods, and droughts as well as hotter temperatures and often declining water resource availability. These ecosystems are some of the most challenging to monitor given their high temporal variability with rapid response to their environment as well as vast spatial variability with intermixing of different plant species and life forms amongst bare soil coverage. The Adaptation and Response in Drylands (ARID) campaign was selected by National Aeronautics and Space Administration (NASA) as a scoping study to develop a research agenda for a dryland field campaign. Here, we detail our ARID science research agenda and implementation plan that were developed based on an extensive community engagement effort in over 160 events with over a thousand scientists, land managers, and Tribal communities between 2023 and 2024. The selected science themes cover drought and climate variability, ecosystem structure, function, and biodiversity, carbon cycle interannual variability and trends, and social ecological systems (land management and adaptation). We then detail our remote sensing, modeling, and field-based strategies to capture high temporal and high spatial resolution processes. Finally, our implementation strategy is presented which includes focus area selections in a core intensive western U.S. domain and distributed international domains. This strategy includes our overarching guiding principles of using multi-temporal airborne acquisitions and super sites as well as enhancing land management in co-development with end-user partners. While originally developed for NASA, our ARID report creates a blueprint for any future dryland field campaign, at any scale, that can be implemented widely for foundational and applied science objectives.

drylands↗

Exploring the Nucleon Structure via Deep Electroproduction Processes

Understanding the internal structure of the nucleon is a fundamental goal of modern physics, which aims at a comprehensive framework describing the internal dynamics of quarks and gluons. Among other structure functions, Generalized Parton Distributions (GPDs) offer a powerful framework for describing the nucleon dynamics by correlating the longitudinal momentum and the transverse position of its internal partons. Such a correlation provides a three-dimensional picture of the nucleon and enables access to fundamental properties, including the internal pressure distributions and the parton’s angular momentum contribution to the nucleon's total spin, thereby playing a central role in resolving the nucleon spin puzzle. At the Thomas Jefferson National Facility (JLab), polarized electron beam experiments allow for probing GPDs through the measurement of hard exclusive processes. Among the cleanest experimental channels, we find the electro-production of a real photon through the Deeply Virtual Compton Scattering (DVCS) mechanism. The first data-taking period of the CLAS12 program, taking place in 2018, allowed for unique DVCS Beam Spin Asymmetry (BSA) measurements in the phase space covered by a 10.6 GeV polarized electron beam impinging on an unpolarized liquid hydrogen target. Although detecting all final-state particles ensures exclusivity of the process, conservation laws indicate that it is not mandatory. I adopt an approach omitting the direct detection of the recoil proton, providing a simplified yet effective event selection strategy that boosts statistics and gives access to a larger phase space sensitive to the underlying GPD dynamics through BSA and cross section measurements. The Double DVCS (DDVCS) process promises a dedicated mapping of GPDs. Contributing to the electro-production of a lepton pair cross-section, the DDVCS reaction extends DVCS by allowing the final-state photon to be virtual, enriching the kinematic phase space and providing unique access to the internal correlations encoded by GPDs. A feasibility study is conducted to assess the potential of future DDVCS measurements at Jefferson Lab and the future Electron-Ion Collider (EIC). While Jefferson Lab will provide DDVCS measurements in the valence region through the SoLID$\mu$ and $\mu$CLAS12 experimental projects, in the long term, the EIC will provide complementary measurements in the sea region, both accessing unprecedented information about GPDs in a phase space region otherwise inaccessible. Taken together, these investigations demonstrate both the current capabilities and future opportunities for probing GPDs through exclusive processes. The experimental analysis of DVCS at CLAS12 provides precise measurements within an established framework, while the phenomenological study of DDVCS opens the door to richer and more comprehensive explorations with future detectors and facilities.

Alvarado, Juan [Université Paris-Saclay: Gif-sur-Y↗

Chemical changes from N-doped graphene and Metal-Organic Frameworks to N-G/MOF composites for improved electrocatalytic activity

Integrating N doped graphene (N G) with Metal Organic Frameworks (MOFs) enhances catalytic activity for oxygen reduction reaction (ORR), often exceeding both the performances of their precursors and, in some cases, even PGM based catalysts. However, the factors driving this improved catalytic activity in N G/MOF composites remain unexplored, particularly from the perspective of the chemical changes. To investigate the chemical changes in N G and MOF upon their integration and the implications of these changes on ORR catalytic activity, an N G/MOF was synthesized from N G with a MOF (ZIF 8) following a mechanochemical wet ball milling process. The N G, ZIF 8, and N G/MOF samples were examined for changes in elemental composition, chemical state of carbon, different nitrogen and carbon bonds, and other chemical interactions. In the N G/MOF catalyst, compared to its N G and ZIF 8 precursors, the relative oxygen content increased, indicating the formation of additional oxygen containing groups. The C 1s peak shifted to a lower binding energy in N G/MOF, suggesting changes in the overall chemical or oxidation state of the carbon atoms. Besides, the increase in pyridinic N functional groups in N G/MOF points to the formation of additional active sites. Furthermore, the formation of C Zn bonds in N G/MOF suggests the probable emergence of single atom Zn sites, while the increase in C=O bonds points to the formation of carboxyl or carbonyl groups. These chemical changes could be linked to the enhanced electrocatalytic activity of the N G/MOF composite for ORR. In conclusion, this study may also be beneficial for other research focused on developing composite catalysts involving various N G and MOF materials.

25 ENERGY STORAGE↗

Current understanding of Oxidative Coupling of Methane (OCM) reaction over supported Mn-Na 2 WO 4 catalysts

This perspective reviews the current understanding of the Oxidative Coupling of Methane (OCM) reaction over the supported Mn-Na 2 WO 4 /SiO 2 catalyst, with a focus on recent insights gained from state-of-the-art in-situ and operando spectroscopic characterization and chemical probe experiments under controlled environments. The supported Mn-Na 2 WO 4 /SiO 2 catalyst exhibits dynamic structural changes during the OCM reaction, involving multiple reactive lattice and adsorbed oxygen species, each associated with different oxide phases. These oxygen species play distinct roles in various steps of the OCM mechanism. The catalytic active sites for activation of CH 4 are associated with isolated surface Na-WO x sites on the SiO 2 support and the role of surface MnO x sites on SiO 2 is to oxidatively dehydrogenate C 2 H 6 to C 2 H 4 . Furthermore, this paper provides a detailed discussion of these roles and also introduces new experimental data from Temporal Analysis of Products (TAP) studies to clarify the ongoing debate in the literature regarding the contributions of lattice versus adsorbed oxygen species in OCM reaction product formation. Additionally, recommendations are offered for optimizing the performance of supported Mn-Na 2 WO 4 /SiO 2 catalysts to enhance CH 4 activation and C 2 product selectivity.

03 - NATURAL GAS↗

Rubisco kinetic acclimation at the holoenzyme level

Kinetic acclimation enables proteins to adjust their activity in response to environmental perturbations. For the CO 2 -fixing enzyme Rubisco, kinetic acclimation may be conferred by its small subunits. Plants express multiple small subunits and vary their expression with temperature. Here, we demonstrate that different small subunits can bind to the same Rubisco to form a heterogeneous holoenzyme. These small subunits had distinct kinetic effects which aligned with changes in holoenzyme structure and stability. Our findings indicate that small subunits enable Rubisco kinetic acclimation via manipulation of flexibility. By assembling a more rigid active site in higher temperatures and a more flexible one in lower temperatures, plants maximize the efficiency of their Rubisco, and thus photosynthesis, over a wide range of temperatures.

CO2 fixation↗