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At least 181 records · Page 10

Time lag effects in the nucleation of particles in stellar atmospheres

When a system goes from a saturated state to a supersaturated one, the classical nucleation-rate formula is not instantly valid; rather, the nucleation rate relaxes exponentially (with a characteristic time - the time lag) to the value given by the steady-state formula. Under some circumstances, particularly those found in some cool stellar atmospheres, the time lag can be quite long and a decisve factor in determining the possibility of particle formation. Carbon condensation in the atmospheres of Mira variables is considered and found to be unlikely on the basis of classical nucleation theory because of the long time lags involved, unless the parameters describing the physical conditions in these atmospheres are significantly different from current estimates.

Walker, G. H.↗

The distribution of ammonia and its photochemical products on Jupiter

Altitude profiles of ammonia and its photochemical products are generated in the light of measurements of the Jovian temperature structure, eddy transport coefficient, improved chemical scheme, and rate constants. Realistic limits are placed on the concentration of hydrazine which may participate in the recycling of ammonia on Jupiter. The maximum hydrazine-ice production rate is calculated to be about 1.3 mg/sq m per Jovian day. The distribution of nitrogen gas is presented with and without supersaturation of hydrazine. The nitrogen mixing ratio near the ammonia cloud top is estimated to be in the range between 10 to the -9th and 10 to the -11th power. An appreciable latitudinal variation in the ammonia concentration is expected.

Atreya, S. K.↗

Contributions of experimental protobiogenesis to the theory of evolution

Inferences from experiments in protobiogenesis are examined as a forward extension of the theory of evolutionary biology. A nondiscontinuous, intraconsistent theory of general evolution embracing both protobiology and biology is outlined. This overview emphasizes Darwinian selection in the later stages of evolution, and stereochemical molecular selection in some of its earlier stages. It incorporates the concept of limitation of the scope of evolution by internal constraints on variation, based on the argument that internally limiting constraints observed in experiments with molecules are operative in organisms, if chemical processes occur within biological processes and biological processes are assumed to be exponentializations of chemical processes. Major evolutionary events might have occurred by rapid self-assembly processes analogous to those observed in the formation of phase-separated microspheres from amorphous powder or supersaturated solutions.

Fox, S. W.↗

Grain formation in astronomical systems: A critical review of condensation processes

An analysis is presented of the assumption and the applicability of the three theoretical methods for calculating condensations in cosmic clouds where no pre-existing nuclei exist. The three procedures are: thermodynamic equilibrium calculations, nucleation theory, and a kinetic treatment which would take into account the characteristics of each individual collision. Thermodynamics provide detailed results on the composition temperature and composition of the condensate provided the system attains equilibrium. Because of the cosmic abundance mixture of elements, large supersaturations in some cases and low pressures, equilibrium is not expected in astronomical clouds. Nucleation theory, a combination of thermodynamics and kinetics, has the limitations of each scheme. Kinetics, not requiring equilibrium, avoids nearly all the thermodynamics difficulties but requires detailed knowledge of many reactions which thermodynamics avoids. It appears to be the only valid way to treat grain formation in space. A review of experimental studies is given.

Donn, B.↗

Floating substrate process: Large-area silicon sheet task low-cost solar array project

Supercooling of silicon-tin alloy melts was studied. Values as high as 78 C at 1100 C and 39 C at 1200 C were observed, corresponding to supersaturation parameter values 0.025 and 0.053 at 1050 C and 1150 C, respectively. The interaction of tin with silane gas streams was investigated over the temperature range 1000 to 1200 C. Single-pass conversion efficiencies exceeding 30% were obtained. The growth habit of spontaneously-nucleated surface growth was determined to be consistent with dendritic and web growth from singly-twinned triangular nucleii. Surface growth of interlocking silicon crystals, thin enough to follow the surface of the liquid and with growth velocity as high as 5 mm/min, was obtained. Large area single-crystal growth along the melt surface was not achieved. Small single-crystal surface growth was obtained which did not propagate beyond a few millimeters.

Garfinkel, M.↗

Chemical whitings and chlorophyll distributions in the Great Lakes as viewed by Landsat

A chemical precipitation of calcium carbonate, or whiting, was first observed by satellite in Lake Michigan during August 1973. Since that initial observation similar events have been noted in Lakes Michigan, Erie, and Ontario with imagery from Landsat, Skylab, and NOAA satellites. By the use of Landsat multispectral data together with NOAA thermal infrared data, it has been observed that whitings occur several meters below the lake surface in relatively warm water. They are most vividly displayed during and after periods of upwelling. As the epilimnetic waters become supersaturated with Ca(+2) ions during summer, a triggering mechanism (presumably biological or physical) initiates the whiting, which may continue for several months. The effects on the biota of the euphotic zone when this milky cloud is present in the upper layers are poorly understood. However, Great Lakes circulation studies are taking advantage of these natural dye tracers.

Strong, A. E.↗

Some effects of 8-12 micron radiant energy transfer on the mass and heat budgets of cloud droplets

In standard treatments of the mass and energy budget of cloud droplets, radiant energy transfer is neglected on the grounds that the temperature difference between the droplet and its surroundings is small. This paper includes the effect of radiant heating and cooling of droplets by using the Eddington approximation for the solution of the radiative transfer equation. Although the calculation assumes that the cloud is isothermal and has a constant size spectrum with altitude, the heating or cooling of droplets by radiation changes the growth rate of the droplets very significantly. At the top of a cloud with a base at 2500 m and a top at 3000 m, a droplet will grow from 9.5 to 10.5 microns in about 4 min, assuming a supersaturation ratio of 1.0013. Such a growth rate is more than 20 times the growth rate for condensation alone, and may be expected to have a significant impact on estimates of precipitation formation as well as on droplet spectrum calculations.

Barkstrom, B. R.↗

Water system microbial check valve development

A residual iodine microbial check valve (RIMCV) assembly was developed and tested. The assembly is designed to be used in the space shuttle potable water system. The RIMCV is based on an anion exchange resin that is supersaturated with an iodine solution. This system causes a residual to be present in the effluent water which provides continuing bactericidal action. A flight prototype design was finalized and five units were manufactured and delivered.

Colombo, G. V.↗

Temperature structure and emergent flux of the Jovian planets

Long path, low temperature, moderate resolution spectra of methane and ammonia, broadened by hydrogen and helium, are used to calculate non-gray model atmospheres for the four Jovian planets. The fundamental and first overtone of hydrogen contributes enough absorption to create a thermal inversion for each of the planets. The suite of emergent spectral fluxes and representative limb darkenings and brightenings are calculated for comparison with the Voyager infrared spectra. The temperature differences between Jovian belts and zones corresponds to a difference in the ammonia cirrus particle radii (1 to 3 micron in zones; 10 micron in belts). The Jovian tropopause is approximately at the 0.1 bar level. A thin ammonia cirrus haze should be distributed throughout the Saturnian troposphere; and NH3 gas must be slightly supersaturated or ammonia ice particles are carried upwards convectively in the upper troposphere of Saturn. Substantial methane clouds exist on both Uranus and Neptune. There is some evidence for almost isothermal structures in the deep atmospheres of these two planets.

Silvaggio, P.↗

Hygroscopic chemicals and the formation of advection warm fog: A numerical simulation

The formation of advection fog is closely associated with the characteristics of the aerosol particles, including the chemical composition, mass of the nuclei, particle size, and concentration. Both macrophysical and microphysical processes are considered. In the macrophysical model, the evolution of wind components, water vapor content, liquid water content and potential temperature under the influences of vertical turbulent diffusion, turbulent momentum, and turbulent energy transfers are taken into account. In the microphysical model, the supersaturation effect is incorporated with the surface tension and hygroscopic material solution.

Hung, R. J.↗

Growth of silicon carbide crystals on a seed while pulling silicon crystals from a melt

A saturated solution of silicon and an element such as carbon having a segregation coefficient less than unity is formed by placing a solid piece of carbon in a body of molten silicon having a temperature differential decreasing toward the surface. A silicon carbide seed crystal is disposed on a holder beneath the surface of the molten silicon. As a rod or ribbon of silicon is slowly pulled from the melt, a supersaturated solution of carbon in silicon is formed in the vicinity of the seed crystal. Excess carbon is emitted from the solution in the form of silicon carbide which crystallizes on the seed crystal held in the cool region of the melt.

Ciszek, T. F.↗

Shock tube and shock wave research; Proceedings of the Eleventh International Symposium, University of Washington, Seattle, Wash., July 11-14, 1977

Papers are presented on the applications of shock-wave technology to the study of hydrodynamics, the use of the pressure-wave machine for charging diesel engines, and measurements of the heat-transfer rate in gas-turbine components. Consideration is given to shock propagation along 90-degree bends, the explosive dissemination of liquids, and rotational and vibrational relaxation behind weak shock waves in water vapor. Shock phenomena associated with expansion flows are described and stratospheric-related research using the shock tube is outlined. Attention is given to shock-wave ignition of magnesium powders, Mach reflection and boundary layers, and transition in the shock-induced unsteady boundary layer on a flat plate. Shock-tube measurements of induction and post-induction rates for low-Btu gas mixtures are presented and shock-initiated ignition in COS-N2O-Ar mixtures is described. Cluster growth rates in supersaturated lead vapor are presented and a study of laser-induced plasma motion in a solenoidal magnetic field is reviewed.

Ahlborn, B.↗

The mean Jovian temperature structure derived from spectral observations from 105 to 630 cm kaysers

Far infrared observations of the thermal emission of Jupiter are used to determine the temperature at 1 bar. High-altitude observations of the whole-disk brightness temperature of Jupiter in the range of 100 to 347 kaysers were inverted to obtain a P-T profile between 1.5 and 0.06 atm, assuming as opacity sources the H2 collisionally induced continuum and the rotation inversion bands of ammonia. The P-T profile derived from the spectrum reproduces the main features of the observed spectrum, with a slightly improved fit if the effects of ammonia haze opacity or NH3 supersaturation in the saturated region are taken into account. The Jovian temperature is found to be 160 + or - 7 K at 1 bar, and 105 + or - 3 K at the inversion level at 0.15 bar. The 1-bar temperature is shown to be consistent with Jovian interior models which match the observed gravitational moment.

Goorvitch, D.↗

Airborne measurements of cloud-forming nuclei and aerosol particles in stabilized ground clouds produced by solid rocket booster firings

Airborne measurements of cloud volumes, ice nuclei and cloud condensation nuclei, liquid particles, and aerosol particles were obtained from stabilized ground clouds (SGCs) produced by Titan 3 launches at Kennedy Space Center, 20 August and 5 September 1977. The SGCs were bright, white, cumulus clouds early in their life and contained up to 3.5 g/m3 of liquid in micron to millimeter size droplets. The measured cloud volumes were 40 to 60 cu km five hours after launch. The SGCs contained high concentrations of cloud condensation nuclei active at 0.2%, 0.5%, and 1.0% supersaturation for periods of three to five hours. The SGCs also contained high concentrations of submicron particles. Three modes existed in the particle population: a 0.05 to 0.1 micron mode composed of aluminum-containing particles, a 0.2 to 0.8 micron mode, and a 2.0 to 10 micron mode composed of particles that contained primarily aluminum.

Hindman, E. E., II↗

Aerosol particles and the formation of advection fog

A study of numerical simulation of the effects of concentration, particle size, mass of nuclei, and chemical composition on the dynamics of warm fog formation, particularly the formation of advection fog, is presented. This formation is associated with the aerosol particle characteristics, and both macrophysical and microphysical processes are considered. In the macrophysical model, the evolution of wind components, water vapor content, liquid water content, and potential temperature under the influences of vertical turbulent diffusion, turbulent momentum, and turbulent energy transfers are taken into account. In the microphysical model, the supersaturation effect is incorporated with the surface tension and hygroscopic material solution. It is shown that the aerosol particles with the higher number density, larger size nuclei, the heavier nuclei mass, and the higher ratio of the Van't Hoff factor to the molecular weight favor the formation of the lower visibility advection fogs with stronger vertical energy transfer during the nucleation and condensation time period.

Hung, R. J.↗

Nitrous oxide measurements in the eastern tropical Pacific Ocean

The paper considers nitrous oxide measurements in the eastern tropical Pacific Ocean. The concentration of N2O in the marine air showed a direct relationship to the N2O in the surface sea water, with the highest N2O mixing ratios over highly supersaturated regions; water samples were also collected down to depths of 300 m at seven hydrocast stations. The stations showed two distribution patterns for N2O concentration vs depth for the region between the surface and 300 m; two stations in the oxygen deficient region off the coast of Peru showed considerable N2O super-saturation at all depths, and results indicate that the role of N2O in the nitrogen cycle of the ocean may be more complex than previously suggested.

Pierotti, D.↗

Saturn - Tropospheric ammonia and nitrogen

Photochemical calculations based on recent data on the Saturn temperature structure and Lyman-alpha albedo indicate that detectable amounts of gaseous ammonia may exist between 20 and 35 km above the cloud tops. An instrument that might be able to observe this gas is the spectrometer on board the International Ultraviolet Explorer satellite. The calculations also yield a maximum nitrogen mixing ratio at the cloud tops between 1.8 x 10 to the -10th to 6 x 10 to the -8th by volume, depending upon the degree of supersaturation of ammonia and hydrazine. Even the lower limit could produce intense emissions if electrical discharges such as those observed on Jupiter by Voyager are also present on Saturn, or if high energy particles penetrate to the Saturnian troposphere.

Atreya, S. K.↗

Monitoring Crystal Growth From Solution

Experimental system for monitoring growth of triglycine sulfate (TGS) crystals from solution is being studied. System consists of outer cell containing distilled water heated and stirred to maintain constant temperature to within plus or minus 0.1 degrees C, inner (growth) cell containing supersaturated solution of TGS, and seed crystal mounted in plastic-covered stainless-steel sting equiped with controlled cooling mechanism and temperature sensors.

Lal, R. B.↗