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Chemical and physical studies of type 3 chondrites. II Thermoluminescence of sixteen type 3 ordinary chondrites and relationships with oxygen isotopes

Thermoluminescence (TL) sensitivity values for sixteen type 3 ordinary chondrites, fourteen of them from Antarctica, have been measured. The values obtained (normalized to the TL sensitivity of the Dhajala meteorite) range from 1.6 (Allan Hills A77216) to 0.010 (Allan Hills A77176), and include two (Reckling Peak A80207 and Allan Hills A77176) that are particularly low. They fill a hiatus in the TL distribution that previously existed between St. Mary's County and Bishunpur, the latter being a meteorite with one of the lowest TL sensitivities known. The histogram of TL sensitivity values now shows a single distribution with higher values preferred; it resembles the histogram for L chondrites occupying the petrologic types 3, 4, 5, and 6. There is a tendency for the TL sensitivity of meteorites to decrease as delta O-18 increases. Theoretically, it is possible that the range of delta O-18 values observed may reflect progressive loss of O in the form of CO at very low temperatures, but very restrictive physical conditions and a complex history seem to be required.

Sears, D. W. G.↗

Pyroxene thermobarometry in LL-group chondrites and implications for parent body metamorphism

Geothermometry based on the compositions of clinopyroxenes in type 6 and 7 LL chondrites gives coherent results, but the estimated temperatures from coexisting orthopyroxenes are consistently lower than for clinopyroxenes. Orthopyroxene thermometry is suspect because of compositional effects of polymorphic inversions and/or unknown kinetic factors. Lack of clinopyroxene equilibration precludes accurate estimation of peak metamorphic temperatures for type 4 and 5 chondrites. There is no apparent correlation between Al content (a pressure-dependent variable) and equilibration temperature in chondritic pyroxenes. This finding, which is at variance with a previously published conclusion that temperature and pressure are correlated in metamorphosed chondrites, may have important implications for asteroid thermal models.

Mcsween, Harry Y., Jr.↗

M-H characteristics and demagnetization resistance of samarium-cobalt permanent magnets to 300 C

The influence of temperature on the M-H demagnetization characteristics of permanent magnets is important information for the full utilization of the capabilities of samarium-cobalt magnets at high temperatures in demagnetization-resistant permanent magnet devices. In high temperature space power converters, such as free-piston Stirling engine driven linear alternators, magnet demagnetization can occur as a long-term consequence of thermal agitation of domains and of metallurgical change, and also as an immediate consequence of too large an applied field. Investigated here is the short-term demagnetization resistance to applied fields derived from basic M-H data. This quasistatic demagnetization data was obtained for commercial, high-intrinsic-coercivity, Sm2Co17-type magnets from 5 sources, in the temperature range 23 to 300 C. An electromagnet driven, electronic hysteresigraph was used to test the 1-cm cubic samples. The observed variation of the 2nd quadrant M-H characteristics was a typical rapid loss of M-coercivity and a relatively lesser loss of remanence with increasing temperature. The 2nd quadrant M-H curve knee point is used to define the limits of operation safe against irreversible demagnetization due to an excessive bucking field for a given flux density swing at temperature. Such safe operating area plots are shown to differentiate the high temperature capabilities of the samples from different sources. For most of the samples, their 2nd quadrant M-H loop squareness increased with temperature, reaching a peak or a plateau above 250 C.

Niedra, Janis M.↗

M-H characteristics and demagnetization resistance of samarium-cobalt permanent magnets to 300 C

The influence of temperature on the M-H demagnetization characteristics of permanent magnets is important information for the full utilization of the capabilities of samarium-cobalt magnets at high temperatures in demagnetization-resistant permanent magnet devices. In high temperature space power converters, such as free-piston Stirling engine driven linear alternators, magnet demagnetization can occur as long-term consequence of thermal agitation of domains and of metallurgical change, and also as an immediate consequence of too large an applied field. Investigated here is the short-term demagnetization resistance to applied fields derived from basic M-H data. These quasistatic demagnetization data were obtained for commercial, high-intrinsic-coercivity, Sm2Co17-type magnets from 5 sources, in the temperature range 23 to 300 C. An electromagnet driven, electronic hysteresigraph was used to test the 1-cm cubic samples. The observed variation of the 2nd quadrant M-H characteristics was a typical rapid loss of M-coercivity and a relatively lesser loss of remanence with increasing temperature.

Niedra, J. M.↗

Evolutionary history of the mesosiderite asteroid - A chronologic and petrologic synthesis

The evolutionary history of the mesosiderite parent body is composed of six principal epochs. (1) Accretion occurred about 4.56 Ga ago, and (2) initial melting occurred less than about 26 Ma after accretion. (3) Significant crustal remelting occurred more than 4.47 Ga ago, possibly during metal-silicate mixing caused by the accretion of a large metallic Fe-Ni core fragment with some overlying mantle to the MPB regolith. (4) Localized impact melting 4.5-3.9 Ga ago produced quench-textured clasts and caused mesosiderite metamorphism and the extensive melting of type-4 mesosiderites. (5) Collisional disruption and gravitational reassembly occurred about 3.9 Ga ago, causing extensive degassing of Ar and resetting the metallographic cooling rates to about 1 C/Ma. (6) Impact excavitation and ejection of deeply buried breccias occurred much less than 3.9 Ga.

Rubin, Alan E.↗

Chondrite thermal histories from Low-CA pyroxene microstructures: Autometamorphism versus prograde metamorphism revisited

In order to constrain the thermal histories of chondritic meteorites, a detailed study of the microstructures of low-Ca pyroxenes produced experimentally and in types 4 and 5 ordinary chondrites was carried out. Cooling experiments on synthetic MgSiO3 at cooling rates between 2 and 10000 C/hr from the protopyroxene stability field into that of orthopyroxene (OPX) were performed and the products of these experiments were annealed for a variety of annealing times. There are clear microstructural differences between samples which were cooled and those which were subsequently annealed. A comparison of the microstructures observed in the experimental samples with those in H4-5 ordinary chondrites shows that they cannot have experienced a single stage cooling history, as proposed for the autometamorphism model.

Brearley, Adrian J.↗

Observation of Kilohertz Quasiperiodic Oscillations from the Atoll Source 4U 1702-429 by RXTE

We present results of Rossi X-Ray Timing Explorer (RXTE) observations of the atoll source 4U 1702-429 in the middle of its luminosity range. Kilohertz-range quasiperiodic oscillations (QPOS) were observed first as a narrow (FWHM approximately 7 Hz) peak near 900 Hz, and later as a pair consisting of a narrow peak in the range 625 825 Hz and a faint broad (FWHM 91 Hz) peak. When the two peaks appeared simultaneously the separation was 333 +/- 5 Hz. Six type I thermonuclear bursts were detected, of which five exhibited almost coherent oscillations near 330 Hz, which makes 4U 1702-429 only the second source to show burst oscillations very close to the kilohertz QPO separation frequency. The energy spectrum and color-color diagram indicate that the source executed variations in the range between the "island" and "lower banana" atoll states. In addition to the kilohertz variability, oscillations at approximately 10, approximately 35, and 80 Hz were also detected at various times, superimposed on a red noise continuum. The centroid of the approximately 35 Hz QPO tracks the frequency of the kilohertz oscillation when they were both present. A Lense-Thirring gravitomagnetic precession interpretation appears more plausible in this case, compared to other atoll sources with low frequency QPOs.

Markwardt, C. B.↗

Observations of Herbig Ae/Be Stars with Herschel/PACS: The Atomic and Molecular Contents of Their Protoplanetary Discs

We observed a sample of 20 representative Herbig Ae/Be stars and 5 A-type debris discs with PACS onboard Herschel, as part of the GAS in Protoplanetary Systems (GASPS) project. The observations were done in spectroscopic mode, and cover the far-infrared lines of [OI], [CII], CO, CH+, H20, and OH. We have a [OI]63 micro/ detection rate of 100% for the Herbig Ae/Be and 0% for the debris discs. The [OI] 145 micron line is only detected in 25% and CO J = 18-17 in 45% (and fewer cases for higher J transitions) of the Herbig Ae/Be stars, while for [CII] 157 micron, we often find spatially variable background contamination. We show the first detection of water in a Herbig Ae disc, HD 163296, which has a settled disc. Hydroxyl is detected as well in this disc. First seen in HD 100546, CH+ emission is now detected for the second time in a Herbig Ae star, HD 97048. We report fluxes for each line and use the observations as line diagnostics of the gas properties. Furthermore, we look for correlations between the strength of the emission lines and either the stellar or disc parameters, such as stellar luminosity, ultraviolet and X-ray flux. accretion rate, polycyclic aromatic hydrocarbon (PAH) band strength, and flaring. We find that the stellar ultraviolet flux is the dominant excitation mechanism of [OI] 63 micron, with the highest line fluxes being found in objects with a large amount of flaring and among the largest PAH strengths. Neither the amount of accretion nor the X-ray luminosity has an influence on the line strength. We find correlations between the line flux of [OI]63 micron and [OI] 145 micron, CO J = IS-17 and [OI] 6300 A, and between the continuum flux at 63 micron and at 1.3 mm, while we find weak correlations between the line flux. of [OI] 63 micron and the PAH luminosity, the line flux of CO J = 3-2, the continuum flux at 63 pm, the stellar effective temperature, and the Br-gamma luminosity. Finally, we use a combination of the [OI] 63 micron and C(12)O J = 2-1 line fluxes to obtain order of magnitude estimates of the disc gas masses, in agreement with the values that we find from detailed modelling of two Herbig Ae/Be stars, HD 163296 and HD 169142.

Meeus, G.↗

The Dark Energy Survey supernova program: a reanalysis of cosmology results and evidence for evolving dark energy with an updated Type Ia supernova calibration

We present improved cosmological constraints from a re-analysis of the Dark Energy Survey (DES) 5-year sample of Type Ia supernovae (DES-SN5YR). This re-analysis includes an improved photometric cross-calibration, recent white dwarf observations to cross-calibrate between DES and low-redshift surveys, retraining the salt3 light-curve model and fixing a numerical approximation in the host-galaxy colour law. Our fully recalibrated sample, which we call DES-Dovekie, comprises ~1600 likely Type Ia SNe from DES and ~200 low-redshift SNe from other surveys. With DES-Dovekie, we obtain Ω m = 0.330 ± 0.015 in flat Lambda-cold dark matter (⁠ΛCDM) which changes Ω m by –0.022 compared to DES-SN5YR. Combining DES-Dovekie with cosmic microwave background data from Planck, Atacama Cosmology Telescope, and South Pole Telescope and the DESI DR2 measurements in a flat CDM cosmology, we find ω 0 = –0.803 ± 0.054 and ω a = –0.72 ± 0.21⁠. Our results hold a significance of 3.2σ, reduced from 4.2σ for DES-SN5YR, to reject the null hypothesis that the data are compatible with the cosmological constant. This significance is equivalent to a Bayesian model preference odds of approximately 5:1 in favour of the flat ω 0 ω a CDM model. Using generally accepted thresholds for model preference, our updated data exhibits only a weak preference for evolving dark energy.

dark energy↗

Understanding the Role of Borohydride Doping in Electrochemical Stability of Argyrodite Li 6 PS 5 Cl Solid‐State Electrolyte

This work elucidates the mechanism by which lithium borohydride (LiBH 4 ) doping into argyrodite-type Li 6 PS 5 Cl (LBH-LPSCl) solid-state electrolyte (SSE) enhances electrochemical stability. State-of-the-art electrochemical performance is achieved with 5 wt% borohydride. Symmetric cells achieve critical current density (CCD) of 7.3 mA cm −2 , versus 2.6 mA cm −2 for baseline-LPSCl. All solid-state batteries (ASSBs) employing lithium metal and NMC811 cathode are stable over 400 cycles at 0.5C, with capacity retention of 83%. An anode-free ASSB (AF-ASSB) is stable over 600 cycles, with capacity loss of 0.04% per cycle. 5LBH-LPSCl allows for enhanced low temperature operation, down to −14 °C. Yet the difference in electrolytes’ bulk microstructures and hardnesses are minimal, while ionic conductivity is incrementally improved (≈50%). Theoretical modeling indicates limited effect of substitution on thermodynamic stability of PS 4 3- units, which decompose when contacting Li. Instead, enhanced electrochemical stability is site-specific kinetic effect: In situ electrodeposition experiments using X-ray photoelectron spectroscopy (XPS) and time-of-flight secondary ion mass spectrometry (TOF-SIMS) reveal tri-layer SEI based predominately on Li 3 P/LiBH 4 /Li 2 S that blocks electrons while facilitating ion transport. This SEI manifests reduced interface resistance and accelerated nucleation and growth of metallic Li. With baseline-LPSCl the SEI based on Li 3 P/Li 2 S is substantially thicker, generating localized stresses that promote interfacial cracking while cycling.

argyrodite↗

CasDinG is a 5′-3′ dsDNA and RNA/DNA helicase with three accessory domains essential for type IV CRISPR immunity

Abstract CRISPR-associated DinG protein (CasDinG) is essential to type IV-A CRISPR function. Here, we demonstrate that CasDinG from Pseudomonas aeruginosa strain 83 is an ATP-dependent 5′-3′ DNA translocase that unwinds double-stranded (ds)DNA and RNA/DNA hybrids. The crystal structure of CasDinG reveals a superfamily 2 helicase core of two RecA-like domains with three accessory domains (N-terminal, arch, and vestigial FeS). To examine the in vivo function of these domains, we identified the preferred PAM sequence for the type IV-A system (5′-GNAWN-3′ on the 5′-side of the target) with a plasmid library and performed plasmid clearance assays with domain deletion mutants. Plasmid clearance assays demonstrated that all three domains are essential for type IV-A immunity. Protein expression and biochemical assays suggested the vFeS domain is needed for protein stability and the arch for helicase activity. However, deletion of the N-terminal domain did not impair ATPase, ssDNA binding, or helicase activities, indicating a role distinct from canonical helicase activities that structure prediction tools suggest involves interaction with dsDNA. This work demonstrates CasDinG helicase activity is essential for type IV-A CRISPR immunity as well as the yet undetermined activity of the CasDinG N-terminal domain.

59 BASIC BIOLOGICAL SCIENCES↗

High-resolution measurements and analysis of (N-14)(O-16)2 in the (001)-(000) and (011)-(010) bands

High-resolution spectra of NO2 were recorded with a Fourier-transform spectrometer, covering transitions in the (001)-(000) and (011)-(010) bands from 1540 to 1662/cm. The measured line frequencies were used with additional data taken from studies at microwave and far-IR frequencies in an analysis to obtain spin-rotation constants and rotational energies of levels in the (001) and (011) states. Line strengths of these two bands were also measured and analyzed. The analyses included spin-rotation levels of the (001) state for Ka up to and including 13 and N to 73 and those of the (001) state for Ka up to and including 7 and N to 55. The study included observed and enhanced Ka = 5 - 6 transitions in the (020)-(000) band that interact, by means of a Coriolis-type interaction, with Ka = 5 transitions in the (011)-(000) band. Also observed and analyzed were the results of spin-rotation resonance interactions between two levels of the same state. These perturbations affected one or more levels of a given Ka and state and were observed for Ka = 0 with Ka = 2 and Ka = 1 with Ka = 3 for the (001) and (000) states and for Ka = 0 with Ka = 2 for the (011) and (001) states.

Toth, Robert A.↗

Minority carrier lifetime in indium phosphide

Transient photoluminescence is used to measure the minority carrier lifetime on n-type and p-type InP wafers. The measurements show that unprocessed InP wafers have very high minority carrier lifetimes. Lifetimes of 200 ns and 700 ns were observed for lightly-doped p- and n-type material respectively. Lifetimes over 5 ns were found in heavily doped n-type material.

Jenkins, Phillip↗

Tailoring a Human Reliability Analysis to Your Industry Needs

Companies at risk of accidents caused by human error that result in catastrophic consequences include: airline industry mishaps, medical malpractice, medication mistakes, aerospace failures, major oil spills, transportation mishaps, power production failures and manufacturing facility incidents. Human Reliability Assessment (HRA) is used to analyze the inherent risk of human behavior or actions introducing errors into the operation of a system or process. These assessments can be used to identify where errors are most likely to arise and the potential risks involved if they do occur. Using the basic concepts of HRA, an evolving group of methodologies are used to meet various industry needs. Determining which methodology or combination of techniques will provide a quality human reliability assessment is a key element to developing effective strategies for understanding and dealing with risks caused by human errors. There are a number of concerns and difficulties in "tailoring" a Human Reliability Assessment (HRA) for different industries. Although a variety of HRA methodologies are available to analyze human error events, determining the most appropriate tools to provide the most useful results can depend on industry specific cultures and requirements. Methodology selection may be based on a variety of factors that include: 1) how people act and react in different industries, 2) expectations based on industry standards, 3) factors that influence how the human errors could occur such as tasks, tools, environment, workplace, support, training and procedure, 4) type and availability of data, 5) how the industry views risk & reliability, and 6) types of emergencies, contingencies and routine tasks. Other considerations for methodology selection should be based on what information is needed from the assessment. If the principal concern is determination of the primary risk factors contributing to the potential human error, a more detailed analysis method may be employed versus a requirement to provide a numerical value as part of a probabilistic risk assessment. Industries involved with humans operating large equipment or transport systems (ex. railroads or airlines) would have more need to address the man machine interface than medical workers administering medications. Human error occurs in every industry; in most cases the consequences are relatively benign and occasionally beneficial. In cases where the results can have disastrous consequences, the use of Human Reliability techniques to identify and classify the risk of human errors allows a company more opportunities to mitigate or eliminate these types of risks and prevent costly tragedies.

DeMott, D. L.↗

Prototypes of Nonrelativistic Spin Splitting and Polarization in Symmetry Broken Antiferromagnets

Antiferromagnets that break both space-time reversal and translation-spin-rotation symmetries were recently predicted [L.-D. Yuan, Z. Wang, J.-W. Luo, E. I. Rashba, and A. Zunger, Phys. Rev. B 102, 014422 (2020)] to possess splitting between the otherwise spin-degenerate energy bands even without the relativistic spin-orbit coupling (SOC). Here, we point out that such nonrelativistic spin splitting (NRSS)—in particular, “spin splitting type 4” (SST-4) symmetry-broken antiferromagnets—can be divided into subgroups having distinct patterns of spin splitting and spin textures, depending on additional auxiliary symmetries of spin interconversion and polarity. These SST-4 subgroups include the 𝛼-type (no spin-interconverting symmetry) having spin splitting at the Brillouin zone center, as well as the 𝛽 subgroup in which a rotation symmetry is applied and determines the alternating spin texture and the 𝛾 subgroup having exclusively reflection spin-interconverting symmetry. Unlike ferrimagnets, the 𝛼-type compounds are shown to have tiny net magnetization at finite temperature and thus avoid the adverse effect of the stray field. The 𝛼 and 𝛽 subgroups can be either polar or nonpolar, whereas the 𝛾 subgroup is polar only, providing a basis for possible switching by external fields. The combination of NRSS-enabling and auxiliary symmetries is used here as a filter for identifying previously synthesized compounds as specific prototypes. Their characteristic splitting and spin polarization are calculated by density functional theory to the benefit of potential future experimental testing. Interesting results are as follows: (i) SOC-independent NRSS can exceed the magnitude of the SOC-induced Rashba and Dresselhaus spin splitting in semiconductors. (ii) Examples of predicted 𝛼-type insulating compounds include BiCrO 3 (nonpolar) and Mn 2 ⁢ScSbO 6 (polar), the latter having spin splitting of 158 meV and 160 meV in the valence and conduction bands, respectively. (iii) The 𝛽-type (Cu 2 ⁢Y 2 ⁢O 5 and FeF 2 ) and 𝛾-type compounds (Mn 4 ⁢Nb 2 ⁢O 9 and FeScO 3 ) are distinguished both by their auxiliary symmetries and polarity. The spin textures of 𝛾-type compounds are mirror reflected with spin degeneracy of the wave vectors on that mirror. These observations will likely broaden the experimental playing field of NRSS physics significantly.

antiferromagnets↗

Differential Pressures on a Pitot-venturi and a Pitot-static Nozzle over 360 Degrees Pitch and Yaw

Measurements of the differential pressures on two navy air-speed nozzles, consisting of a Zahm type Pitot-Venturi tube and a SQ-16 two-pronged Pitot-static tube, in a tunnel air stream of fixed speed at various angles of pitch and yaw between 0 degrees and plus or minus 180 degrees. This shows for a range over -20 degrees to +20 degrees pitch and yaw, indicated air speeds varying very slightly over 2 per cent for the Zahm type and a maximum of about 5 per cent for the SQ-16 type from the calibrated speed at 0 degree. For both types of air-speed nozzle the indicated air speed increases slightly as the tubes are pitched or yawed several degrees from their normal 0 degrees altitude, attains a maximum around plus or minus 15 degrees to 25 degrees, declines rapidly therefrom as plus or minus 40 degrees is passed, to zero in the vicinity of plus or minus 70 degrees to 100 degrees, and thence fluctuates irregular from thereabouts to plus or minus 180 degrees. The complete variation in indicated air speed for the two tubes over 360 degree pitch and yaw is graphically portrayed in figures 9 and 10. For the same air speed and 0 degree pitch and yaw the differential pressure of the Zahm type Pitot-Venturi nozzle is about seven times that of the SQ-16 type two-prolonged Pitot-static nozzle.

Bear, R M↗

Integration of polyurethane meniscus scaffold during ACL revision is not reliable at 5 years despite favourable clinical outcome

Abstract Purpose The aim of this study was to evaluate the clinical outcome at 5‐year follow‐up of a one‐step procedure combining anterior cruciate ligament (ACL) reconstruction and partial meniscus replacement using a polyurethane scaffold for the treatment of symptomatic patients with previously failed ACL reconstruction and partial medial meniscectomy. Moreover, the implanted scaffolds have been evaluated by MRI protocol in terms of morphology, volume, and signal intensity. Methods Twenty patients with symptomatic knee laxity after failed ACL reconstruction and partial medial meniscectomy underwent ACL revision combined with polyurethane‐based meniscal scaffold implant. Clinical assessment at 2‐ and 5‐year follow‐ups included VAS, Tegner Activity Score, International Knee Documentation Committee (IKDC), Western Ontario and McMaster Universities Osteoarthritis Index (WOMAC), and the Lysholm Score. MRI evaluation of the scaffold was performed according to the Genovese scale with quantification of the scaffold’s volume at 1‐ and 5‐year follow‐ups. Results All scores revealed clinical improvement as compared with the preoperative values at the 2‐ and 5‐year follow‐ups. However, a slight, but significant reduction of scores was observed between 2 and 5 years. Concerning the MRI assessment, a significant reduction of the scaffold’s volume was observed between 1 and 5 years. Genovese Morphology classification at 5 years included two complete resorptions (Type 3) and all the remaining patients had irregular morphology (Type 2). With regard to the Genovese Signal at the 5‐year follow‐up, three were classified as markedly hyperintense (Type 1), 15 as slightly hyperintense (Type 2), and two as isointense (Type 1). Conclusion Simultaneous ACL reconstruction and partial meniscus replacement using a polyurethane scaffold provides favourable clinical outcomes in the treatment of symptomatic patients with previously failed ACL reconstruction and partial medial meniscectomy at 5 years. However, MRI evaluation suggests that integration of the scaffold is not consistent. Level of evidence Level IV.

Pereira, Hélder↗