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DOE OSTI2024

Designing Ta C Virtual Substrates for Vertical Al x Ga 1 − x N Power Electronics Devices

Power electronics are critical for a sustainable energy future, playing a key role in electrification and integration of renewable energy sources into the grid. Advances in ultrawide band gap materials are needed to handle higher powers in smaller form factors while reducing electrical and thermal losses. High Al content Al x Ga 1 − x N is theoretically capable of meeting these demands, but its impact in power electronics has been severely restricted by a lack of substrates that can satisfy conductivity, lattice matching, and/or thermal expansion requirements. We demonstrate that electrically conductive Ta C can be used as a virtual substrate for Al x Ga 1 − x N heteroepitaxy. Scaleably sputtered Ta C grown on Al 2 O 3 , followed by high-temperature face-to-face annealing, produces a thin film Ta C template with an effective hexagonal lattice constant matched to Al 0.70 Ga 0.30 N . Annealing of the Ta C promotes recrystallization, significantly improving crystallinity and reducing crystalline defects from as-deposited columnar grains to a step-and-terrace surface morphology, enabling the subsequent growth of high-quality Al 0.70 Ga 0.30 N by molecular beam epitaxy. X-ray diffraction and scanning transmission electron microscopy confirm that the Al x Ga 1 − x N layer is heteroepitaxially aligned, strain-free, and lattice-matched, transitioning abruptly from Ta C to Al x Ga 1 − x N without intermediate phases. These results demonstrate Ta C virtual substrates as electrically conductive, lattice-matched, and thermally compatible templates for vertical Al x Ga 1 − x N devices that can meet the growing power needs of a sustainable energy future. Published by the American Physical Society 2024

36 MATERIALS SCIENCE↗

DOE OSTI2023

Vertical β -Ga2O3 metal–insulator–semiconductor diodes with an ultrathin boron nitride interlayer

In this work, we demonstrate the high performance of β-Ga2O3 metal–insulator–semiconductor (MIS) diodes. An ultrathin boron nitride (BN) interlayer is directly grown on the Ga2O3 substrate by pulsed laser deposition. X-ray photoelectron spectroscopy, Raman spectroscopy, and high-resolution transmission electron microscopy confirm the existence of a 2.8 nm BN interlayer. Remarkably, with the insertion of the ultrathin BN layer, the breakdown voltage is improved from 732 V for Ga2O3 Schottky barrier diodes to 1035 V for Ga2O3 MIS diodes owing to the passivated surface-related defects and reduced reverse leakage currents. Our approach shows a promising way to improve the breakdown performance of Ga2O3-based devices for next-generation high-power electronics.

Physics↗

DOE OSTI2021

Measuring a Low Horizontal Hydraulic Gradient in a High Transmissivity Aquifer

Abstract High transmissivity aquifers typically have low hydraulic gradients (i.e., a flat water table). Measuring low gradients using water levels can be problematic because measurement error may be greater than the true difference in water levels (i.e., a low signal‐to‐noise ratio). In this study, the feasibility of measuring a hydraulic gradient in the range of 10 −6 to 10 −5 m/m was demonstrated. The study was performed at a site where the depth to water from land surface ranged from 40.1 to 94.2 m and the aquifer transmissivity was estimated at 41,300 m 2 /d (hydraulic conductivity of 18,800 m/d). The goals of the study were to reduce measurement error as much as practicable and assess the importance of factors affecting water level measurement accuracy. Well verticality was the largest source of error (0.000 to 0.168 m; median of 0.014 m), and geodetic survey of casing elevations was the next most important source of error (0.002 to 0.013 m; median of 0.005 m). Variability due to barometric pressure fluctuations was not an important factor at the site. Hydraulic heads were measured to an accuracy of ±0.0065 m, and the average hydraulic gradient was estimated to be 8.0 × 10 −6 (±0.9 × 10 −6 ) m/m. The improvement in accuracy allowed for two reversals in the groundwater flow direction to be identified, after which the gradient averaged 2.5 × 10 −5 (±0.4 × 10 −5 ) m/m. This study showed it is possible to sufficiently control sources of error to measure hydraulic gradients in the 10 −6 to 10 −5 m/m range.

McDonald, John P.↗

NASA NTRS1974

Auditory display for the blind

A system for providing an auditory display of two-dimensional patterns as an aid to the blind is described. It includes a scanning device for producing first and second voltages respectively indicative of the vertical and horizontal positions of the scan and a further voltage indicative of the intensity at each point of the scan and hence of the presence or absence of the pattern at that point. The voltage related to scan intensity controls transmission of the sounds to the subject so that the subject knows that a portion of the pattern is being encountered by the scan when a tone is heard, the subject determining the position of this portion of the pattern in space by the frequency and interaural difference information contained in the tone.

Fish, R. M.↗

DOE OSTI2023

Light detection with power and signal transmission over fiber

The Deep Underground Neutrino Experiment is a next generation long baseline (1300 km) neutrino oscillation experiment. The neutrino beam measurements will be performed by a near detector and far detector. The far detector will consist of four modules, installed 1.5 km deep underground, based on Liquid Argon Time Projection Chamber (LArTPC) technology to detect particles. The Vertical Drift (VD) LArTPC is a recent technology proposed by the DUNE collaboration for the second FD module. In VD, light collection will be optimized by embedding photon detectors within the LArTPC cathode, which is biased at −300 kV. As a result, power must arrive to the Photon Detection System and signal must be transmitted via non-conductive material. The proposed solution is to use Power-over-Fiber and Signal-over-Fiber. An intense validation of the system is being performed by the collaboration at the CERN Neutrino Platform. The design of the system and the results of the validation collected over the first half of 2022 are presented here.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

NASA NTRS1973

Investigation of vibration characteristics of electric motors

The vibration characteristics of electric motors were analyzed using mathematical statistics methods. The equipment used and the method of conducting the test are described. Curves are developed to show the visualization of the electric motor vibrations in the vertical direction. Additional curves are included to show the amplitude-phase frequency characteristic of dynamic rotor-housing vibrations at the first lug and the same data for the second lug of the electric motor. Mathematical models were created to show the transmission function of the dynamic rotor housing system.

Bakshis, A. K.↗

DOE OSTI2020

Surface Passivation by Excess Sulfur for Controlled Synthesis of Large, Thin SnS Flakes

Tin sulfide (SnS) is part of the group IV chalcogenides (SnX, GeX; X: S, Se), a family of anisotropic layered materials considered for thin film photovoltaics, optoelectronics, and valleytronics, and predicted narrow bandgap multiferroic materials. Large ultrathin SnS flakes, suitable for a variety of applications, are challenging to synthesize because of the enhanced surface reactivity due to the open layer structure of SnS which gives rise to a competition between lateral and vertical growth. Here we investigate the effects of added sulfur on passivating the surface and modifying the balance between lateral expansion and thickening of SnS flakes in chemical vapor transport from a SnS precursor. In addition, we investigate the growth of SnS flakes and compare the results of synthesis from a pure SnS precursor with growth, in which a slight excess of sulfur is supplied in different ways. Our results demonstrate that small amounts of excess sulfur can profoundly affect the size and thickness distributions of SnS flakes. The largest and thinnest flakes are obtained if (i) traces of sulfur are added and (ii) the sulfur source consists either of small Sx fragments released at high temperatures from the reactor walls, or atomic S supplied by sublimation from SnS 2 . The likely mechanism for the observed growth modifications is a transient surface passivation of SnS flakes during growth, which reduces the reactivity of the top facet of the flakes, limits vertical growth, and thus gives rise to ensembles with increased lateral size and reduced thickness.

36 MATERIALS SCIENCE↗

DOE OSTI2021

Gouge formation and dilation impacts to flow during fracture shearing

We report flow in fractures is of critical importance to fluid flow in low-permeability shales, particularly when they restrict vertical migration from reservoirs. The Mt. Simon Sandstone is a target for geologic CO 2 sequestration and the overlying Eau Claire Formation is the sealing formation capping this reservoir. The lower Eau Claire, a primary barrier to upward migration of CO 2 from the Mt. Simon, is lithologically heterogenous with a mixture of sandstone and shale. We use a series of flow-through experiments on fractured samples from the Eau Claire to document the morphological changes taking place in the fracture and surrounding rock as it is sheared in a stepwise fashion. The samples were imaged using computed tomography after each shearing episode and flow resistance was calculated based on the pressure differential across each core. We found that gouge accumulations in the fracture plane led to specific instances of self-sealing behavior despite the fact that most samples increased in average fracture aperture and transmissivity. Gouge limited the increase or, in some cases, decreased flow through these samples. Fractures adjacent to shale-rich zones and concordant with bedding were more likely to show evidence of self-sealing, while increased sandstone content and fracture orientation perpendicular to bedding planes was more likely to result in fracture dilation and fracture permeability increases. Reactivation and shearing of vertical fractures in lithologically heterogenous caprocks is more likely to pose risks to long term CO 2 storage scenarios.

58 GEOSCIENCES↗

NASA NTRS2010

A Principal Component-Based Radiative Transfer Forward Model (PCRTM) for Vertically in Homogeneous Cloud

A principal-component based radiative transfer model (PCRTM) is developed for simulating the infrared spectral radiance at the top of the atmosphere (TOA). The PCRTM approach removes the redundancy in radiative transfer calculation in high resolution infrared spectra, and saves significant amount of computational time with great accuracy. In PCRTM, both ice and water clouds are treated as effective transmissivity and reflectivity stored in a pre-calculated lookup tables. These quantities are calculated using cloud single scattering properties such as cloud optical depth, cloud particle size, cloud phase, etc. The cloud can be inserted into any pressure layer in the PCRTM model (up to 100 layers). The effective temperature of each cloud layer is treated as a function of its optical depth. To test the accuracy of this approximation, the results are compared with the more rigorous DISORT model, which treats cloud as a plane parallel layer. The root-mean-square error of PCRTM, with respect to DISORT results, is generally less than 0.5 K in brightness temperature. However, the CPU time required by PCRTM was approximately two orders of magnitude less than that required by DISORT.

Li, Hui↗

DOE OSTI2021

The R-matrix bootstrap for the 2d O( N ) bosonic model with a boundary

The S-matrix bootstrap is extended to a 1+1d theory with O(N) symmetry and a boundary in what we call the R-matrix bootstrap since the quantity of interest is the reflection matrix (R-matrix). Given a bulk S-matrix, the space of allowed R-matrices is an infinite dimensional convex space from which we plot a two dimensional section given by a convex domain on a 2d plane. In certain cases, at the boundary of the domain, we find vertices corresponding to integrable R-matrices with no free parameters. In other cases, when there is a one-parameter family of integrable R-matrices, the whole boundary represents integrable theories. We also consider R-matrices which are analytic in an extended region beyond the physical cuts, thus forbidding poles (resonances) in that region. In certain models, this drastically reduces the allowed space of R-matrices leading to new vertices that again correspond to integrable theories. We also work out the dual problem, in particular in the case of extended analyticity, the dual function has cuts on the physical line whenever unitarity is saturated. For the periodic Yang-Baxter solution that has zero transmission, we computed the R-matrix initially using the bootstrap and then derived its previously unknown analytic form.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

NASA NTRS1981

Improved simulation of aerosol, cloud, and density measurements by shuttle lidar

Data retrievals are simulated for a Nd:YAG lidar suitable for early flight on the space shuttle. Maximum assumed vertical and horizontal resolutions are 0.1 and 100 km, respectively, in the boundary layer, increasing to 2 and 2000 km in the mesosphere. Aerosol and cloud retrievals are simulated using 1.06 and 0.53 microns wavelengths independently. Error sources include signal measurement, conventional density information, atmospheric transmission, and lidar calibration. By day, tenuous clouds and Saharan and boundary layer aerosols are retrieved at both wavelengths. By night, these constituents are retrieved, plus upper tropospheric, stratospheric, and mesospheric aerosols and noctilucent clouds. Density, temperature, and improved aerosol and cloud retrievals are simulated by combining signals at 0.35, 1.06, and 0.53 microns. Particlate contamination limits the technique to the cloud free upper troposphere and above. Error bars automatically show effect of this contamination, as well as errors in absolute density nonmalization, reference temperature or pressure, and the sources listed above. For nonvolcanic conditions, relative density profiles have rms errors of 0.54 to 2% in the upper troposphere and stratosphere. Temperature profiles have rms errors of 1.2 to 2.5 K and can define the tropopause to 0.5 km and higher wave structures to 1 or 2 km.

Russell, P. B.↗

NASA NTRS1992

Lidar multiple scattering: Dependence on atmospheric parameters

Backscatter lidars are very useful tools in gaining information about the atmosphere. Inversion of backscatter signals can be used to retrieve the spatial distribution of clouds and aerosols, e.g., vertical extensions of clouds and aerosol layers, detection of 'subvisible' cirrus, etc., very accurately compared to passive radiometers. To retrieve extinction coefficient profiles, in general, the so-called lidar equation is solved. This equation describes a laser pulse which propagates through an atmosphere with transmission exp(- integral of sigma(z')dz'), which is scattered singly under 180 degrees towards a receiver, and which is attenuated on its way back again by exp(- integral of sigma(z')dz'). For inversion, further information on optical properties of the scatterers are required (extinction to backscatter ratio). However, it is evident that, at least for optically thick clouds and/or large receiver's field-of-views, this approach may be erroneous because of multiply scattered photons. Several studies were performed to simulate multiple scattering in case of collimated beams or pulses including Monte Carlo, transport, and diffusion theory. Unfortunately, most of the approaches require an enormous amount of computer time. Thus, it is meaningful to elaborate approximate methods, and one such method is discussed. Our method is based on Bissonnett (1988). We have improved the numerical simulation of limited field-of-view detectors, and compared the results to Monte Carlo calculations and an exact model of Altmann (1989).

Wiegner, Matthias↗

NASA NTRS1999

The LISA Mission Design

The proposed Laser Interferometer Space Antenna (LISA) is designed to observe gravitational radiation from galactic binaries and massive black holes in other galaxies. LISA will observe waves in the frequency range 0.1 mHz to 1 Hz, which can never be observed on Earth due to background noise. The three LISA spacecraft will be located at the vertices of an equilateral triangle with side length 5 million km. The orbits are chosen so that the triangle formation trails the Earth by 20 degrees. Each spacecraft will contain two independent instruments containing a proof mass, laser and 30 cm diameter telescope for the transmission and reception of laser signals. Two independent Michelson interferometers will be formed, allowing both polarizations of gravitational waves to be detected. The observed signals will yield unique information about the formation of massive black holes and the nature of gravity in the high-field limit.

Folkner, W. M.↗

NASA NTRS2010

Simulation of Earth-Moon-Mars Environments for the Assessment of Organ Doses

Space radiation environments for historically large solar particle events (SPE) and galactic cosmic rays (GCR) at solar minimum and solar maximum are simulated in order to characterize exposures to radio-sensitive organs for missions to low-Earth orbit (LEO), moon, and Mars. Primary and secondary particles for SPE and GCR are transported through the respective atmosphere of Earth or Mars, space vehicle, and astronaut s body tissues using the HZETRN/QMSFRG computer code. In LEO, exposures are reduced compared to deep space because particles are deflected by the Earth s magnetic field and absorbed by the solid body of the Earth. Geomagnetic transmission function as a function of altitude was applied for the particle flux of charged particles, and the shift or the organ exposures to higher velocity or lower stopping powers compared to those in deep space were analyzed. In the transport through Mars atmosphere, a vertical distribution of atmospheric thickness was calculated from the temperature and pressure data of Mars Global Surveyor, and the directional cosine distribution was implemented to describe the spherically distributed atmospheric distance along the slant path at each altitude. The resultant directional shielding by Mars atmosphere at solar minimum and solar maximum was used for the particle flux simulation at various altitudes on the Martian surface. Finally, atmospheric shielding was coupled with vehicle and body shielding for organ dose estimates. We made predictions of radiation dose equivalents and evaluated acute symptoms at LEO, moon, and Mars at solar minimum and solar maximum.

Kim, Myung-Hee↗

DOE OSTI2023

Overview of Potential Hazards in Electric Aircraft Charging Infrastructure

With increasing efforts in electrification of Advanced Air Mobility and electric aircraft, there is a growing need to install new infrastructure to support them. This report highlights potential hazards (non exhaustive) that the installation must be aware of and be prepared to mitigate with increased electrical equipment on site. The hazards can be due to natural causes as well as non natural causes. The report aims to provide starting guidelines for awareness of these hazards and to help plan for mitigation of the same.

24 POWER TRANSMISSION AND DISTRIBUTION↗

NASA NTRS1980

Anti-reflection coatings on large area glass sheets

Antireflective coatings which may be suitable for use on the covers of photovoltaic solar modules can be easily produced by a dipping process. The coatings are applied to glass by drawing sheets of glass vertically out of dilute aqueous sodium silicate solutions at a constant speed, allowing the adherent liquid film to dry, then exposing the dried film to concentrated sulfuric acid, followed by a water rinse and dry. The process produces coatings of good optical performance (96.7 percent peak transmission at 0.540 mu M wavelength) combined with excellent stain and soil resistance, and good resistance to abrasion. The process is reproduceable and easily controlled.

Pastirik, E.↗

DOE OSTI2021

Disaggregating Future Retail Electricity Rate Growth [Slides]

Recent Berkeley Lab research found that modest retail rate increases over the past 10 years were mostly driven by large increases in capital expenditures (CapEx) that were offset in part by substantial wholesale price reductions. Decision-makers are increasingly concerned about the potential future rate impacts of a number of policies and industry trends that support rapid decarbonization, electrification, and grid modernization. Using historical FERC Form 1 data and the existing literature on policies and industry trends that are likely to affect utility-incurred costs and retail sales, Berkeley Lab researchers developed ranges of forecasted growth rates for cost-related rate drivers (i.e., fuel and purchased power; transmission, distribution, generation, and other categories of both non-fuel operations & maintenance and CapEx) and non-cost related rate drivers (i.e., retail sales, peak demand, and customers). These were then used as inputs to a pro-forma utility financial model (FINDER) that estimated the growth in retail electric rates between 2020 and 2030 for a prototypical vertically-integrated investor-owned utility in the United States. The analysis produced the following results: 1. Assuming average growth rates in all rate drivers, future retail rate growth is driven by sizable increases in all CapEx costs, where fuel and purchased power costs are replaced by generation CapEx as the largest rate component between 2020 and 2030. 2. Growth in sales/peak demand/customers, generation CapEx costs, and fuel and purchased power (FPP) costs, in isolation, produce the most uncertainty in rate growth. Specifically, a 1% increase in the compound annual growth rate (CAGR) of retail sales, coincident peak demand (CP), and customers (Sales-CP-Cust) results in a 0.88-0.93% decrease in the CAGR of rates, in isolation. However, a 1% increase in the CAGR of generation CapEx budgets results in a 0.07-0.14% increase in the CAGR of rates, while a 1% increase in the CAGR of FPP costs causes a 0.10-0.14% increase in the CAGR of rates, all else being equal. 3. Taking into account the correlation and variability of the growth in all rate drivers jointly, generation CapEx is expected to be both the largest and most uncertain rate component by 2030 (20-25% share of the retail rate). Transmission and distribution CapEx, along with fuel and purchased power costs are each expected to comprise between 12% and 17% of retail rates.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

NASA NTRS2012

Optical Frequency Optimization of a High Intensity Laser Power Beaming System Utilizing VMJ Photovoltaic Cells

An effective form of wireless power transmission (WPT) has been developed to enable extended mission durations, increased coverage and added capabilities for both space and terrestrial applications that may benefit from optically delivered electrical energy. The high intensity laser power beaming (HILPB) system enables long range optical 'refueling" of electric platforms such as micro unmanned aerial vehicles (MUAV), airships, robotic exploration missions and spacecraft platforms. To further advance the HILPB technology, the focus of this investigation is to determine the optimal laser wavelength to be used with the HILPB receiver, which utilizes vertical multi-junction (VMJ) photovoltaic cells. Frequency optimization of the laser system is necessary in order to maximize the conversion efficiency at continuous high intensities, and thus increase the delivered power density of the HILPB system. Initial spectral characterizations of the device performed at the NASA Glenn Research Center (GRC) indicate the approximate range of peak optical-to-electrical conversion efficiencies, but these data sets represent transient conditions under lower levels of illumination. Extending these results to high levels of steady state illumination, with attention given to the compatibility of available commercial off-the-shelf semiconductor laser sources and atmospheric transmission constraints is the primary focus of this paper. Experimental hardware results utilizing high power continuous wave (CW) semiconductor lasers at four different operational frequencies near the indicated band gap of the photovoltaic VMJ cells are presented and discussed. In addition, the highest receiver power density achieved to date is demonstrated using a single photovoltaic VMJ cell, which provided an exceptionally high electrical output of 13.6 W/sq cm at an optical-to-electrical conversion efficiency of 24 percent. These results are very promising and scalable, as a potential 1.0 sq m HILPB receiver of similar construction would be able to generate 136 kW of electrical power under similar conditions.

Raible, Daniel E.↗