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At least 181 records · Page 10

Experimental and Calculational Studies of the Interactions of BF3 with Fluoroethers

BF3 was co-condensed with (C2H5)2O, (CF3CH2)2O and (C2F5)2O in excess argon at 15 K. Infrared spectra of the matrices showed a definite Lewis acid-base interaction between BF3 and diethyl ether; a weak but definite interaction with bis(2,2,2,-trifluorodiethyl)ether, and no observable interaction with perfluorodiethyl ether. Molecular orbital (MO) calculations complemented the experimental observations by revealing that fluorine atoms on the ethers decreased electron localization about the oxygen atom. Thus, the experimental data and MO calculations indicated a clear trend between strength of interaction with BF3 and the degree of ether F substitution. The implications of the results for commercial perfluoro ether lubricant/metal oxide surface interactions are discussed.

Zehe, Michael J.↗

Shock enhancement and control of hypersonic mixing and combustion

Experimental and computational analyses of the possibility that shock-enhanced mixing can substantially increase the rate of mixing between coflowing streams of hydrogen and air are discussed. Numerical computations indicate that the steady interaction between a weak shock in air with a coflowing hydrogen jet can be approximated by the two-dimensional time-dependent interaction between a weak shock and an initially circular region filled with hydrogen imbedded in air. Experimental results obtained in a shock tube and contoured wall injector are presented. It is shown that the shock impinging process causes the light gas cylinder to split into two parts; one of these mixes rapidly with air and the other forms a stably stratified vortex pair which mixes more slowly. The geometry of the flow field and the mixing process and scaling parameters are assessed.

Marble, Frank E.↗

Shocks in the outer helisphere: Voyager 2 observations from 18.9 AU to 30.2 AU (1986-1989)

A search for shocks observed by Voyager 2 from 1986.0 to day 233, 1989, in the region between 18.9 AU and 30.2 AU revealed only five candidate fast forward shocks and no reverse shocks. No shock was observed during 1987 (near solar minimum). Only one candidate shock was observed during 1986, when the heliospheric current sheet (HCS) was still close to the equator. This, the weakest of the shocks, was associated with a weak corotating merged interaction region (CMIR). Only two shocks were observed during 1988, when solar activity and the inclination of the HCS were increasing. One of these shocks was associated with a CMIR, the other with a local merged interaction region (MIR) (a transient MIR localized in space). The shocks observed between 18.9 AU and 28.2 AU from 1986 through 1988 were relatively weak, the estimated magnetoacoustic Mach number being less than or equal to 1.5 for each of the three shocks. Since the shocks observed between 20 AU and 29 AU during the 3-year period centered around solar minimum were weak and few in number, shocks were not important in determining the structure, dynamics, and thermodynamics of the equatorial solar wind. The strongest shock in this study was observed during 1989 at the front of a global merged interaction region (GMIR) (a MIR that extends around the Sun and is presumably formed by the coalescence of several transient ejecta and other interaction regions). A weak shock was also observed inside this GMIR.

Burlaga, L. F.↗

On the dynamics of a shock-bubble interaction

We present a detailed numerical study of the interaction of a weak shock wave with an isolated cylindrical gas inhomogenity. Such interactions have been studied experimentally in an attempt to elucidate the mechanisms whereby shock waves propagating through random media enhance mixing. Our study concentrates on the early phases of the interaction process which are dominated by repeated refractions of acoustic fronts at the bubble interface. Specifically, we have reproduced two of the experiments performed by Haas and Sturtevant : M(sub s) = 1.22 planar shock wave, moving through air, impinges on a cylindrical bubble which contains either helium or Refrigerant 22. These flows are modelled using the two-dimensional, compressible Euler equations for a two component fluid (air-helium or air-Refrigerant 22). Although simulations of shock wave phenomena are now fairly commonplace, they are mostly restricted to single component flows. Unfortunately, multi-component extensions of successful single component schemes often suffer from spurious oscillations which are generated at material interfaces. Here we avoid such problems by employing a novel, nonconservative shock-capturing scheme. In addition, we have utilized a sophisticated adaptive mesh refinement algorithm which enables extremely high resolution simulations to be performed relatively cheaply. Thus we have been able to reproduce numerically all the intricate mechanisms that were observed experimentally (e.g., transitions from regular to irregular refraction, cusp formation and shock wave focusing, multi-shock and Mach shock structures, jet formation, etc.), and we can now present an updated description for the dynamics of a shock-bubble interaction.

Quirk, James J.↗

Numerical simulations - Some results for the 2- and 3-D Hubbard models and a 2-D electron phonon model

Numerical simulations on the half-filled three-dimensional Hubbard model clearly show the onset of Neel order. Simulations of the two-dimensional electron-phonon Holstein model show the competition between the formation of a Peierls-CDW state and a superconducting state. However, the behavior of the partly filled two-dimensional Hubbard model is more difficult to determine. At half-filling, the antiferromagnetic correlations grow as T is reduced. Doping away from half-filling suppresses these correlations, and it is found that there is a weak attractive pairing interaction in the d-wave channel. However, the strength of the pair field susceptibility is weak at the temperatures and lattice sizes that have been simulated, and the nature of the low-temperature state of the nearly half-filled Hubbard model remains open.

Scalapino, D. J.↗

An experimental study of fluctuating pressure loads beneath swept shock/boundary-layer interactions

A database is established on the fluctuating pressure loads produced on aerodynamic surfaces beneath 3-D shock wave/boundary layer interactions. Such loads constitute a fundamental problem of critical concern to future supersonic and hypersonic flight vehicles. A turbulent boundary layer on a flat plate is subjected to interactions with swept planar shock waves generated by sharp fins. Fin angles from 5 to 25 deg at freestream Mach numbers between 2.5 and 4 produce a variety of interaction strengths from weak to very strong. Miniature Kulite pressure transducers mounted in the flat plate were used to measure interaction-induced wall pressure fluctuations. These data will be correlated with proposed new optical data on the fluctuations of the interaction structure, especially that of the lambda-shock system and its associated high-speed jet impingement.

Settles, Gary S.↗

An experimental study of the sources of fluctuating pressure loads beneath swept shock/boundary-layer interactions

An experimental research program providing basic knowledge and establishing a database on the fluctuating pressure loads produced on aerodynamic surfaces beneath three dimensional shock wave/boundary layer interactions is described. Such loads constitute a fundamental problem of critical concern to future supersonic and hypersonic flight vehicles. A turbulent boundary layer on a flat plate is subjected to interactions with swept planar shock waves generated by sharp fins at angle of attack. Fin angles from 10 to 20 deg at freestream Mach numbers of 3 and 4 produce a variety of interaction strengths from weak to very strong. Miniature Kulite pressure transducers flush-mounted in the flat plate are used to measure interaction-induced wall pressure fluctuations. The distributions of properties of the pressure fluctuations, such as their ring levels, amplitude distributions, and power spectra, are also determined. Measurements were made for the first time in the aft regions of these interactions, revealing fluctuating pressure levels as high as 160 dB. These fluctuations are dominated by low frequency (0-5 kHz) signals. The maximum ring levels in the interactions show an increasing trend with increasing interaction strength. On the other hand, the maximum ring levels in the forward portion of the interactions decrease linearly with increasing interaction sweep back. These ring pressure distributions and spectra are correlated with the features of the interaction flowfield. The unsteadiness of the off-surface flowfield is studied using a new, non-intrusive technique based on the shadow graph method. The results indicate that the entire lambda-shock structure generated by the interaction undergoes relatively low-frequency oscillations. Some regions where particularly strong fluctuations are generated were identified. Fluctuating pressure measurements are also made along the line of symmetry of an axisymmetric jet impinging upon a flat plate at an angle. This flow was chosen as a simple analog to the impinging jet region found in the rear portion of the shock wave/boundary layer interactions under study. It is found that a sharp peak in ring pressure level exists at or near the mean stagnation point. It is suggested that the phenomena responsible for this peak may be active in the swept interactions as well, and may cause the extremely high fluctuating pressures observed in the impinging jet region in the present experimental program.

Settles, G. S.↗

Inception length to a fully-developed fin-generated shock wave boundary-layer interaction

An experimental study of fin-generated shock wave turbulent boundary-layer interactions confirmed previous observations that, sufficiently far from the fin apex, such interactions become conical. The inception length to conical symmetry was found to increase weakly with Mach number for Mach numbers from 2.5 to 4 and fin angles from 4 to 22 deg. For the range of interactions examined, the inception length was found to depend primarily upon the inviscid shock angle, this angle ranging from 21 to 40 deg. The behavior of the inception length with shock angle can be broadly divided into two categories. For 'weak' interactions with shock angles less than about 35 deg, the inception length decreased as the shock angle increased. For 'strong' interactions with shock angles greater than about 35 deg, the inception region was small and was approximately constant at three boundary-layer thicknesses in length. In the latter, strong interaction case, the inception length was an order of magnitude smaller than that found in the weakest interactions examined, to the extent that strong interactions were practically fully-developed from the apex.

Lu, Frank K.↗

Verification of theory on weak turbulence relating to the sequence of diffuse plasma resonances in space.

An interpretation of the sequence of diffuse plasma resonances observed by space probes (Alouette 2 and ISIS-1 satellites) is developed in terms of wave-particle nonlinear interaction in a weakly turbulent plasma including the electrostatic electron cyclotron harmonic wave instability. The longest time duration of the center frequency of the diffuse plasma resonance is found to coincide with the most favorable condition for the electrostatic electron cyclotron harmonic wave instability which is obtained by solving the dispersion equation obtained for a linear approximation of the kinetic wave equation for the warm magnetoactive plasma. The electrostatic field due to the transmission of the intense rf pulse produces plasma turbulence involving nonlinear wave-wave interaction and temperature anisotropy which leads to instability. This instability supplies energy to the turbulence. The process can be thought of as a feedback system.

Oya, H.↗

Phase Diagram of the Two-Chain Hubbard Model

We have calculated the charge gap and spin gap for the two-chain Hubbard model as a function of the on-site Coulomb interaction and the interchain hopping amplitude. We used the density matrix renormalization group method and developed a method to calculate separately the gaps numerically for the symmetric and antisymmetric modes with respect to the exchange of the chain indices. We have found very different behaviors for the weak and strong interaction cases. Our calculated phase diagram is compared to the one obtained by Balents and Fisher using the weak coupling renormalization group technique.

Park, Youngho↗

Emergence of Complex Modes in Lightly Damped Structural Systems

In this short presentation format, we will provide a set of useful equations, relationships, and physical interpretations direct from the damped two-mode interaction problem. We will demonstrate that the results from the two-mode interaction problem are in direct agreement with observed test data. Practical methods for estimating the parameters driving the relations direct from modal test data are provided. We finalize with two examples demonstrating weak and strong interactions.

spaceflight hardware↗

Linear and weakly nonlinear aspects of free shear layer instability, roll-up, subharmonic interaction and wall influence

The growth of the momentum thickness and the modal disturbance energies are examined to study the nature and onset of nonlinearity in a temporally growing free shear layer. A shooting technique is used to find solutions to the linearized eigenvalue problem, and pseudospectral weakly nonlinear simulations of this flow are obtained for comparison. The roll-up of a fundamental disturbance follows linear theory predictions even with a 20 percent disturbance amplitude. A weak nonlinear interaction of the disturbance creates a finite-amplitude mean shear stress which dominates the growth of the layer momentum thickness, and the disturbance growth rate changes until the fundamental disturbance dominates. The fundamental then becomes an energy source for the harmonic, resulting in an increase in the growth rate of the subharmonic over the linear prediction even when the fundamental has no energy to give. Also considered are phase relations and the wall influence.

Cain, A. B.↗

Hybrid approach to steady transonic normal-shock compressible laminar boundary-layer interactions over airfoils

A simulation of steady transonic viscous-inviscid interactions through a combination of zonal solution methods (involving different equation sets and numerical regions for various flow regions) is used in an investigation of a fluid mechanics problem in which the pressure distribution is determined by the interaction between transonic inviscid flow and an inner laminar viscous layer. The results obtained are in good agreement with laminar experimental data. Both attached and separated boundary layer flows are considered for either weak or strong interactions.

Ram, R. B.↗

A numerical investigation of supersonic strut/endwall interactions in annular flow with varying strut thickness

A full 3D Navier-Stokes numerical investigation has been conducted of the shock-wave/boundary-layer flow interactions caused by four diamond-shaped struts, of varying thickness, in an annular duct with Mach 3 core flow and turbulent boundary-layers on both walls. Secondary flows caused by weak-to-strong interactions are examined in the vicinity of a strut which is bounded by curved endwalls. The duct endwall boundary-layer separated for the strongest interaction. The struts studied had maximum thickness-to-chord ratios of 0.125, 0.188, 0.250, and 0.500. The duct gap height is 0.7 strut chords, the duct inner-to-outer wall radius ratio is 0.7, and the Reynolds number is 3 x 10 exp 5 based on the strut chord length which was held constant for all interactions considered. The effects of strut thickness on the secondary flows are discussed, including: trajectories for the leading and trailing edge horseshoe vortices, strut/endwall corner vortices, and boundary-layer separation. The line of coalescence discussed in the literature, previously ascribed to boundary-layer separation, is shown to be caused by the leading edge horseshoe vortex convecting along the shock front.

Williams, K. E.↗

TS - Dean interactions in curved channel flow

A weakly nonlinear theory is developed to study the interaction of TS waves and Dean vortices in curved channel flow. The prediction obtained from the theory agree well with results obtained from direct numerical simulations of curved channel flow, especially for low amplitude disturbances. At low Reynolds numbers the wave interaction is generally stabilizing to both disturbances, though as the Reynolds number increases, many linearly unstable TS waves are further destabilized by the presence of Dean vortices.

Singer, Bart A.↗

Investigations related to the inviscid-viscous interaction in transonic flows about finite 3-D wings

Inviscid small-disturbance theory has been shown to predict three-dimensional transonic flows about finite wings reasonably well as long as viscous effects are negligible. In order to include these effects, the inviscid small-disturbance solution of Bailey and Ballhaus (1975) has been combined with a finite-difference solution for Prandtl's boundary-layer equations. This solution employs the conditionally stable Krause (1968) scheme, implicit in the direction normal to the wall, to cope with the domain-of-dependence problem that arises for reverse cross flow. To be consistent with the inviscid-flow solution, the boundary layer is computed in the representative wing planform plane which is transformed into rectangular shape in the computational domain. The flow has been assumed turbulent, and a scalar eddy-viscosity model is adopted. The interaction between inviscid and viscous flow is modeled with the help of the displacement surface which is added to the geometric wing shape. Sample distributions of displacement thickness for swept wings are presented for weak and strong interaction cases.

Kordulla, W.↗

Water as a matrix for life

Life is based on non-covalent interactions. They might be either specific (enzyme-substrate interactions, selective ion transport) or nonspecific (lipid-lipid and lipid-protein interactions needed for membrane integrity, fusion and division). Their strength needs to be properly tuned, and this is mediated by the solvent. If interactions are too weak, there might be undesired response to natural fluctuations of physical and chemical parameters. If they are too strong it could impede kinetics and energetics of cellular processes. Thus, the solvent must allow for balancing these interactions. Physical and chemical properties of solvent provide strong constraints for life. Water exhibits a remarkable trait that it promotes both solvophobic and solvophilic interactions. Solvophobic interactions; related to high dielectric constant of the solvent) are necessary for self-organization of matter whereas solvophilic interactions are needed to ensure solubility of polar species. Water offers a large temperature domain of stable liquid and the characteristics hydrophobic effects are a consequence of the temperature in sensitivity of essential properties of its liquid state. Water, however, is not the only liquid with these favorable properties. I will compare in detail properties of water and other pure liquids or their mixtures that have a high dielectric constant and simultaneously support self-organization. I will also discuss properties of water that are unfavorable to life (e.g. its chemical activity against polymerization reactions) and close with summarizing what are alternatives to water as a matrix of life in space.

Pohorille, Andrew↗