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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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NASA NTRS2016

Space Launch System: Building the Future of Space Exploration

NASA has begun a new era of human space exploration, with the goal of landing humans on Mars. To carry out that mission, NASA is building the Space Launch System, the world's most powerful rocket. Space Launch System is currently under construction, with substantial amounts of hardware already created and testing well underway. Because of its unrivaled power, SLS can perform missions no other rocket can, like game-changing science and human landings on Mars. The Journey to Mars has begun; NASA has begun a series of missions that will result in astronauts taking the first steps on the Red Planet.

Morgan, Markeeva↗
NASA NTRS2016

The NANOGrav Nine-Year Data Set: Limits on the Isotropic Stochastic Gravitational Wave Background

We compute upper limits on the nanohertz-frequency isotropic stochastic gravitational wave background (GWB) using the 9 year data set from the North American Nanohertz Observatory for Gravitational Waves (NANOGrav) collaboration. Well-tested Bayesian techniques are used to set upper limits on the dimensionless strain amplitude (at a frequency of 1 yr(exp -1) for a GWB from supermassive black hole binaries of A(sub gw) less than 1.5 x 10(exp -15). We also parameterize the GWB spectrum with a broken power-law model by placing priors on the strain amplitude derived from simulations of Sesana and McWilliams et al. Using Bayesian model selection we find that the data favor a broken power law to a pure power law with odds ratios of 2.2 and 22 to one for the Sesana and McWilliams prior models, respectively. Using the broken power-law analysis we construct posterior distributions on environmental factors that drive the binary to the GW-driven regime including the stellar mass density for stellar-scattering, mass accretion rate for circumbinary disk interaction, and orbital eccentricity for eccentric binaries, marking the first time that the shape of the GWB spectrum has been used to make astrophysical inferences. Returning to a power-law model, we place stringent limits on the energy density of relic GWs, OMEGA(sub gw) (f) h squared less than 4.2 x 10(exp -10). Our limit on the cosmic string GWB, OMEGA(sub gw) (f) h squared less than 2.2 x 10(exp -10), translates to a conservative limit on the cosmic string tension with G mu less than 3.3 x 10(exp -8), a factor of four better than the joint Planck and high-l‚ cosmic microwave background data from other experiments.

Arzoumanian, Z.↗
NASA NTRS2016

We Can't Count on Repairing All Failures Going to Mars

Reliability analysis often assumes that a complex system can be kept operating indefinitely with scheduled maintenance and emergency repair using a stock of spare parts, as long as the spare parts are not depleted. This assumption seems justified for well-tested, widely used, long operational systems with a multigenerational history of failure, redesign, and reliability growth. It seems doubtful that newer, relatively untried, high technology space systems can always be repaired. We cannot assume space systems will have a low rate of random failures that can all be repaired with a few identical spares. New untried systems usually have a high initial failure rate, called infant mortality, due to errors in requirements, design, parts, materials, and operations planning. These problems can cause groups of related failures called Common Cause Failures (CCFs). The practical definition of a CCF is any failure mode that cannot be cured using identical redundant systems or spare parts. Systems with CCFs may fail repeatedly for the same reason. Can a life support system be kept operating on the way to Mars using only redundant systems and spare parts? The failure history of International Space Station (ISS) life support systems suggests that CCFs are likely to occur and will probably require design changes rather than being reparable with spare parts.

Mars↗
NASA NTRS2014

TPSAS-NF1676L-18357-DND

High-spectral resolution measurements (in the IR region) from space born infrared sensors can provide sufficient spectral information about cloud properties like cloud top pressure, cloud particle size and cloud optical thickness. Empirical orthogonal function (EOF) based regression scheme was used to retrieve cloud properties along with atmospheric state profiles. A channel based physical inversion scheme was also tried on cloud-contaminated radiances to improve retrieval accuracy achieved by regression scheme. Recently developed principle component (PC) based physical retrieval algorithm utilized the EOF transformation to compress both hyperspectral radiance spectra and atmospherical profiles into PC scores to greatly boost the computational speed while maintaining the information content. The accuracy of the (PC) based radiation transfer model (PCRTM) to simulate top-of the atmosphere(TOA) high-spectral resolution radiance spectra for both clear and cloudy sky conditions has been well tested by comparing with the other line-by-line radiation transfer model and using the observation data. The application of the PCRTM based physical inversion method on simulated IASI radiance under 'cloudy' conditions will be a good integrity test for the new algorithm.

X Liu↗
NASA NTRS2021

T0TEM - T0 Test Evaluation Module Development and Verification

Transition temperature testing of ferritic steels evaluates the ductile to brittle transition temperature, where the behavior of the steel changes from controlled ductile tearing to uncontrollable brittle fracture. This testing is governed by ASTM (American Society of Testing and Materials) E1921 standard. The calculations and plots required by this standard are iterative in nature and require significant effort to produce by standard hand calculations. In addition to analysis of a complete data set, intermediate analysis during testing is beneficial to determine optimal test temperatures. Given the exhaustive nature of calculating the transition temperature, being able to quickly update target temperatures is a significant benefit to not only the quality of tests, but the number of required tests as well. T0 Test Evaluation Module (T0TEM) v1.5 is a software application created under the Layered Pressure Vessel (LPV) certification effort. To reduce the analysis time of transition temperature test data sets producedfor this effort, T0TEM was created to calculate the E1921 Master Curve along with all required data and validity checks. By creating this program, hundreds of hours of analysis time were saved. In addition, the creation of a standard program provided a significant improvement in the consistency with which results were reported. T0TEM also calculates the results and plots required for the E1921 inhomogeneity annex to determine whether a material behaves in a homogenous manner. This program was created by Levi Shelton and Cameron Bosley at NASA, with input and review from the E1921 committee. The results generated by T0TEM were compared to the validation data sets provided by ASTM with good concurrence. ASTM committee members have reviewed and applied T0TEM to other data sets with satisfactory results. T0TEM was originally released to the NASA Software Repository and publicly via SourceForge in May of 2020. Version 1.5 was released in April of 2021 with minor functionality updates and additional statistical analysis methods.

Levi Shelton↗
NASA NTRSDate not supplied

Comparative Analysis of Thermal Conversion Technologies for Deep Space Missions

Radioisotope power systems (RPS) utilizing Plutonium-238 as a heat source for thermal-to-electric energy conversion have been used as a reliable power source for NASA’s deep space missions for sixty years. Recent innovations and improvements to thermal energy technologies show potential increases to radioisotope system efficiencies from current measurements of ~5-7% to efficiencies upwards of 20%. This report surveys and ranks recent, innovative thermal-to-electric energy conversion research technologies. Technologies being developed at universities and industry are compared with respect to thermal conversion method and relevant key performance parameters. Key performance parameters are identified as system specific power per kg, efficiency, power output, technology readiness level, and system mass. Analytical Hierarchy Process (AHP) was utilized to create weighted values for each evaluation criterion. The AHP tables combined with decision matrices create table scores for past, present, and potential future systems. The table score was combined with a conversion method score in an adjustable system to add value to flight-proven or well-tested thermal conversion technologies such as thermoelectrics. While the three highest-ranking systems reviewed are currently being developed by NASA’s RPS Program, the additional highest-ranking systems not under-development by RPS could warrant further research.

Radioisotope Power System↗
NASA NTRSDate not supplied

Quantum Mechanical Simulations of Dynamics of Electronic Excitations in Low-Dimensional Photovoltaics Materials

Dynamics of electronically excited states including exciton generation and relaxation, exciton-exciton interaction, and charge/energy transfer and transport, are critical to understanding and optimizing photovoltaic materials. Although considerable progress has been made, accurate experimental characterization of such crucial dynamics remains extremely challenging, especially in low-dimensional materials. In this talk, I will discuss how the advancement of quantum mechanical simulations of the dynamics of electronic excitations can reveal the physical mechanisms hindering or improving solar energy harvest. Specifically, we find that surface dangling-bond defects on silicon quantum dots cause rapid charge recombination and low carrier mobility in the inorganic-organic PV cells. Although small quantum dots are essentially free of defects, their optical gaps are too large. To solve this issue, a full-spectrum-light-absorption scheme is computationally designed, taking advantage of complexity and flexibility of low-dimensional materials consisting of different characteristics and dimensions. In this scheme the multifunctional ligands are used to (1) passivate against oxidation, (2) facilitate interfacial charge transfer, and (3) improve both charge transport and optical absorption. A joint theoretical and experimental study has demonstrated the feasibility of this approach. Finally, I will briefly talk about how this scheme and the well-tested quantum mechanical simulations can be employed to help improve energy-conversion efficiency in perovskite photovoltaics including perovskite-based tandem cells.

Zhigang Wu↗
NASA NTRSDate not supplied

Autonomous In-space Construction, Maintenance, and Reconfiguration Using Programmable Meta-Material

NASA ARC's Coded Structures Laboratory (CSL) is developing autonomous construction, maintenance, and reconfiguration technologies to meet long-duration and deep space infrastructure needs, in accordance with long-term NASA goals of "in-space reliance" and "mass-less exploration." We seek to achieve these capabilities by utilizing a "programmable meta-material" approach that integrates emerging advances in materials (mechanical meta-materials), manufacturing (cooperative mobile robotics), and autonomy (multi-agent planning algorithms). Through the ARMADAS project, we have shown assembly of high-performance engineered cellular materials using multiple cooperating mobile robotic assemblers. In this paper, we describe how such a programmable meta-material architecture may shift the paradigm of how we design, build, manufacture, and operate future space infrastructure and assets. The core of a programmable meta-material architecture consists of 3 main technology sub-areas: the structure, the assembly agents, and the assembly algorithms. We co-design these systems to ensure an adaptable system that can create and reconfigure structures from a base set of building block components. From this core technology, we can branch out and expand the capability of the system through additional secondary component types and robotic agents to perform activities such as inspections, maintenance, repair, payload installation, or perform power and communications interconnect. As these technologies mature, future designers will be able to utilize the system to rapidly integrate and operate assets in space or on planetary surfaces from a set of well-tested part library, or create their own modules to integrate into the system. A core trait to the development of this system is the automation approach. Because of the modular and functional discrete (pixel-like) nature of the structural system, a diverse set of powerful algorithms for analysis, planning, and simulation can be adapted and leveraged to optimize construction, maintenance, and dynamic reorganization (as hardware with programmable form and function). With an ability to free the design space from launch vehicle constraints and fundamentally shift how a mission is designed and conducted, we discuss the influence of a programmable meta-material architecture on mission design, build, and operations. For the "design phase", we discuss project lifecycle effects, costs, time, and performance. For the "build phase", we discuss reusability, ISRU, manufacturing, material logistics, and scalability. And for "operations", we discuss autonomy, maintenance and upgrades, reliability, and reconfiguration. Autonomy and modularity are the primary enabling traits of this system. Engineering systems that utilize a modular and reconfiguration building block approach such as digital communication and computation systems, currently lead all other areas of technology in size and complexity scalability. NASA is extending the benefits and flexibility of digital systems to hardware systems, to optimize materials lifecycle management and expand our space exploration mission capabilities.

in space assembly↗
NASA NTRS2022

The Psyche Planning Software Subsystem: Creating a Robust Toolset for a Discovery-class Mission

Psyche is a Discovery-class mission to the small metal-rich asteroid (16) Psyche, and is slated to launch in 2022. Psyche, like many missions, requires low-cost activity planning and sequence generation that serves as the backbone to overall uplink design. Such tools must be maintainable over long periods of operations, and powerful enough to solve complex issues that deep-space one-off missions encounter. In this paper we introduce cost-effective solutions that leverage inner- and open-source principles to meet a variety of common and novel use cases.The uplink process that was designed to meet these challenges is presented, as well as the data-flow through the high-level architecture of the planning software subsystem. The user-facing planning tools are described, particularly the Science Opportunity Analyzer, the Plan Editor, Psyche’s planning automation in the Blackbird framework, and Psyche Simulation Reports. All these applications are either new or have been substantially revamped to meet Psyche’s concept of operations. In particular, ensuring the entire toolchain can correctly process epoch-relative activities is discussed. Underlying the main applications are a common set of dependencies developed and maintained by a new cross-mission association of planning developers. In this way, Psyche can inherit well-tested functionality which saves effort and ensures its developers can focus on solving domain challenges. Quality control of the applications and libraries is ensured with a code-review and unit-test based novel ‘CM lite’ process. Collaboration with international industry and academia using the open-source modules is already occurring.The planning and scheduling software is designed to maximize operator awareness of the integrated plan at every step of the process and use common interfaces and file formats to easily transfer information. Design choices plus the team’s test-driven development process enables more expansive capabilities compared to the decentralized planning and sequence generation functions typical of Discovery-class orbiters without significant development cost increases. Benefits and drawbacks of Psyche’s approach are discussed, including comparison to other missions and tools where appropriate.

Ramanathan, Keshav↗
NASA NTRS2023

AgMIP-Wheat Multi-Model Simulations on Climate Change Impact and Adaptation for Global Wheat

The climate change impact and adaptation simulations from the Agricultural Model Intercomparison and Improvement Project (AgMIP) for wheat provide a unique dataset of multi-model ensemble simulations for 60 representative global locations covering all global wheat mega environments. The multi-model ensemble reported here has been thoroughly benchmarked against a large number of experimental data, including different locations, growing season temperatures, atmospheric CO2 concentration, heat stress scenarios, and their interactions. In this paper, we describe the main characteristics of this global simulation dataset. Detailed cultivar, crop management, and soil datasets were compiled for all locations to drive 32 wheat growth models. The dataset consists of 30-year simulated data including 25 output variables for nine climate scenarios, including Baseline (1980-2010) with 360 or 550 ppm CO2, Baseline +2oC or +4oC with 360 or 550 ppm CO2, a mid-century climate change scenario (RCP8.5, 571 ppm CO2), and 1.5°C (423 ppm CO2) and 2.0oC (487 ppm CO2) warming above the pre-industrial period (HAPPI). This global simulation dataset can be used as a benchmark from a well-tested multi-model ensemble in future analyses of global wheat. Also, resource use efficiency (e.g., for radiation, water, and nitrogen use) and uncertainty analyses under different climate scenarios can be explored at different scales. The DOI for the dataset is 10.5281/zenodo.4027033 (AgMIP-Wheat, 2020), and all the data are available on the data repository of Zenodo (http://doi.org/10.5281/zenodo.4027033). Two scientific publications have been published based on some of these data here.

Agricultural Model Intercomparison and Improvement↗
DOE OSTI2020

Evaluating turbulence models at high energy densities

The RESHOCK campaign at Lawrence Livermore National Laboratory has been working on increasing our understanding of the evolution of turbulent, unstable plasma interfaces which are applicable in various HED applications including ICF implosions. A common approach to model such interfaces involves the use of Renolds-Averaged-Navier-Stokes (RANS) models whose parameters have been constrained by theory and experiments. These parameter sets are not unique and the applicability of one set of tuned model parameters to systems with differing shock strengths or material densities has not been well tested. Our new NIF experiments, along with related studies of turbulent shear flows, provide data and model validation for plasma interfaces in the HED regime. Our experiments measure mixing-layer width at an unstable interface in the plasma regime and are specifically designed to challenge mix models of the Reynolds-Averaged-Navier-Stokes (RANS) type where turbulence is assumed to be fully developed, i.e. the flow exhibits a broad spectrum of length scales without memory of the initial condition.4 We utilize precise control of the initial interface conditions (densities on both sides of the interface, an initial rippled perturbation pattern consisting of equally weighted wavelengths between 10 and 20 microns, and initial material compositions) along with a repeatable drive history

36 MATERIALS SCIENCE↗
DOE OSTI2022

Snowmass2021 Cosmic Frontier White Paper: Cosmological Simulations for Dark Matter Physics

Over the past several decades, unexpected astronomical discoveries have been fueling a new wave of particle model building and are inspiring the next generation of ever-more-sophisticated simulations to reveal the nature of Dark Matter (DM). This coincides with the advent of new observing facilities coming online, including JWST, the Rubin Observatory, the Nancy Grace Roman Space Telescope, and CMB-S4. The time is now to build a novel simulation program to interpret observations so that we can identify novel signatures of DM microphysics across a large dynamic range of length scales and cosmic time. This white paper identifies the key elements that are needed for such a simulation program. We identify areas of growth on both the particle theory side as well as the simulation algorithm and implementation side, so that we can robustly simulate the cosmic evolution of DM for well-motivated models. We recommend that simulations include a fully calibrated and well-tested treatment of baryonic physics, and that outputs should connect with observations in the space of observables. We identify the tools and methods currently available to make predictions and the path forward for building more of these tools. A strong cosmic DM simulation program is key to translating cosmological observations to robust constraints on DM fundamental physics, and provides a connection to lab-based probes of DM physics.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2022

Geothermal Reserve Pits: Considerations for Installation on BLM-Administered Lands

Reserve pits, also known as sumps, are a common aspect of geothermal drilling operations. This paper describes the Bureau of Land Management's regulatory authorities and key environmental considerations associated with geothermal reserve pits. Reserve pit design, the need for environmental compliance measures, and reclamation approaches will vary depending on site-specific conditions. Groundwater and wildlife impacts are the most common environmental considerations related to reserve pits. In some cases, regulations or groundwater or soil conditions necessitate the use of a synthetic liner. However, the chemical composition of most geothermal drilling fluids and muds, completion fluids, and produced fluids that are discharged to reserve pits does not warrant pit liners. The potential for hazardous fluids, high water temperatures, and entrapment are concerns for wildlife. Common wildlife impact avoidance and mitigation measures include fencing, netting, and escape ramps. The need for these measures depends on localized site and environmental conditions. There are requirements to reclaim reserve pits following geothermal drilling operations. Reserve pits often remain in place to accommodate multiple phases of drilling and well testing. They are eventually backfilled and decommissioned.

BLM↗
DOE OSTI2022

Single–Well Injection–Drift Test to Estimate Groundwater Velocity

A simple algebraic equation is presented here to estimate the magnitude of groundwater velocity based on data from a single-well injection-drift test thereby eliminating the time-consuming and costly extraction phase. A volume of tracer-amended water was injected by forced-gradient into a single well followed by monitoring of the conservative solute tracers under natural-gradient conditions as their upgradient portions drifted back through the well. The breakthrough curve data from the single well during the drift phase was analyzed to determine the mean travel times of the tracers. The estimated mean upgradient travel distance back through the single well and the mean travel times of the tracers were used in a simple algebraic equation to estimate groundwater velocity. The groundwater velocity based on the single-well injection-drift test was estimated to be approximately 0.64 ft per day. Two transects of observation wells were used to monitor the natural-gradient tracer transport downgradient of the injection well. The one-dimensional, or dual-well, transport of the tracer from the injection well to the nearest downgradient observation well indicated that the groundwater velocity was 0.55 ft per day. The two-dimensional, or multi-well, transport of the center of mass of the tracers indicated that the groundwater velocity was 0.60 ft per day; the dual- and multi-well results were in excellent agreement with those from the single-well and validated the simple algebraic equation. In conclusion, the new single-well method presented here is relatively simple, rapid, and does not require an extraction phase.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS2007

Joint Test Report For Validation of Alternatives to Aliphatic Isocyanate Polyurethanes

National Aeronautics and Space Administration (NASA) and Air Force Space Command (AFSPC) have similar missions and therefore similar facilities and structures in similar environments. The standard practice for protecting metallic substrates in atmospheric environments is the application of an applied coating system. The most common topcoats used in coating systems are polyurethanes that contain isocyanates. Isocyanates are classified as potential human carcinogens and are known to cause cancer in animals. The primary objective of this effort was to demonstrate and validate alternatives to aliphatic isocyanate polyurethanes resulting in one or more isocyanate-free coatings qualified for use at AFSPC and NASA installations participating in this project. This joint Test Report (JTR) documents the results of the laboratory and field testing as well as any test modifications made during the execution of the testing. The technical stakeholders agreed upon test procedure modifications documented in this document. This JTR is made available as a reference for future pollution prevention endeavors by other NASA centers, the Department of Defense and commercial users to minimize duplication of effort. All coating system candidates were tested using approved NASA and AFSPC standard coating systems as experimental controls. This study looked at eight alternative coating systems and two control coating systems and was divided into Phase I Screening Tests, Phase II Tests, and Field Testing. The Phase I Screening Tests were preliminary tests performed on all the selected candidate coating systems. Candidate coating systems that did not meet the acceptance criteria of the screening tests were eliminated from further testing. Phase I Screening Tests included: Ease of Application, Surface Appearance, Dry-To-Touch (Sanding), Accelerated Storage Stability, Pot Life (Viscosity), Cure Time (Solvent Rubs), Cleanability, Knife Test, Tensile (pull-off) Adhesion, and X-Cut Adhesion by Wet Tape After a review of the Phase I test results, four of the alternative coating systems showed substandard performance in relation to the Control Systems and were eliminated from the Phase II testing. Due to the interest of stakeholders and time constraints, however, all eight alternatives were subjected to the following Phase II tests, along with field testing at Stennis Space Center (SSC), Mississippi: Hypergol Compatibility, Liquid Oxygen Compatibility, 18-Month Marine Exposure (Gloss Retention, Color Retention, Blistering, Visual Corrosion, Creepage from Scribe, Heat Adhesion), and Field Exposure (6- and 12-month Evaluation for Coating Condition, Color Retention, Gloss Retention). The remaining four alternative coating systems determined to be the best viable alternatives were carried on to Phase II testing that included: Removability, Repairability, Abrasion Resistance, Gravelometer, Fungus Resistance, Accelerated Weathering, Mandrel Bend Flexibility, and Cyclic Corrosion Resistance. Of the systems that continued to Phase II, three (3) alternative coating systems meet the performance requirements as identified by stakeholders. Two (2) other systems, that were not included in Phase II testing, performed well enough on the 18-Month Marine Exposure, the primary requirement for NASA technical standard NASA-STD-5008, Protective Coating of Carbon Steel, Stainless Steel, and Aluminum on Launch Structures, Facilities, and Ground Support Equipment, that they were also considered to be successful candidates. In total, five (5) alternative coating systems were approved for inclusion in the NASA-STD- 5008 Qualified Products List (QPL). The standard is intended to provide a common framework for consistent practices across NASA and is often used by other entities. The standard's QPL does not connote endorsement of the products by NASA, but lists those products that have been tested and meet the requirements as specified.

Lewis, Pattie↗
DOE OSTI2022

Tundra SGS – Critical Importance of Site-Specific Injectivity Testing for Carbon Dioxide Injection Well Simulation Calibration

Paper presented at 16th International Conference on Greenhouse Gas Control Technologies (GHGT-16), October 23–27, 2022, Lyon, France. Brine injectivity tests were conducted on both the Broom Creek (BC) and Deadwood (DW) storage formations in one of the cored stratigraphic test wells prior to finalized simulations. The injectivity tests entailed injection of brine into the formations, followed by shutting in the wells. The shut-in duration represents the fall-off period which was used to carry out pressure transient analyses of the tests. The analysis of injectivity tests indicated that core-indicated and modeled permeability distributions should be conservatively multiplied by 2.5× and 5× in the BC and DW geologic models, respectively, prior to numerical simulations of CO 2 injection using Computer Modelling Group’s (CMG’s) GEM equation-of-state reservoir simulator. The scaler permeability multipliers allowed the fluid flow simulations to fully represent well test-measured injection well rates in the respective formations.

20 FOSSIL-FUELED POWER PLANTS↗
DOE OSTI2024

Applying colloidal silica suspensions injection and sequential gelation to block vertical water flow in well annulus: laboratory testing on rheology, gelation, and injection

We evaluated the application of silica suspension injection and sequential gelation to block vertical water flow in the annuli of long-screened wells. First, we studied the viscosity, rheological behavior, and gelation performance of colloidal silica suspensions in batch tests. Then, we tested the injection of silica suspensions and the water flow blocking efficiency of the later formed silica gel in column and bench-scale sandbox experiments. Micron-sized fumed powder silica suspensions and nanosized silica suspensions recovered from geothermal fluids were tested in this work. Fumed silica suspensions showed shear thinning, while nanosized silica suspensions exhibited Newtonian flow behavior. During the gelation process, the nanosized silica suspension changed from a Newtonian fluid to a shear thinning fluid while increasing its overall viscosity. At comparable concentrations, the nanosized silica suspensions have much lower viscosity than that of the fumed silica suspensions. Increases in the Na + concentration and silica particle concentration in these suspensions shortened the gelation time. Silica suspension gelation in sand columns completely blocked the water flow and sustained the injection pressure up to 50 psig (344.7 kPa). A silica suspension was successfully injected into the target zone in the annulus of a bench-scale sandbox mimicking long-screened wells in the field. The silica gel formed in the annulus effectively blocked chemical transport through the gelled zone. Our research reveals that a process using silica suspension injection and sequential gelation technology is promising for blocking the vertical water flow and chemical transport through the filter pack in targeted zones within the annulus of long-screened well systems.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2020

Research three-dimensional hierarchical graphite architectures for anodes for fast charging

With current lithium ion batteries optimized for performance under relatively low charge rate conditions, implementation of XFC has been hindered by drawbacks including Li plating, kinetic polarization, and heat dissipation. This project will utilize model-informed design of 3-D hierarchical electrodes to tune key XFCrelated variables like 1) bulk porosity/tortuosity 2) vertical pore diameter, spacing, and lattice 3) crystallographic orientation of graphite particles relative to exposed surfaces 4) interfacial chemistry of the graphite surfaces through "artificial sEr' formation using ALD 5) current collector surface roughness (aspect ratio, roughness factor, etc.). A key aspect of implementing novel electrodes is characterizing them in relevant settings. For this project, ultimately led out of University of Michigan by Neil Dasgupta, that includes both coin cell and 2+ Ah pouch cell testing, as well as comparison testing against baselines. Sandia National Labs will be conducting detailed cell characterization on iterative versions/improvements of the model-based hierarchical electrodes, as well as COTS cells for baseline comparisons. Key metrics include performance under fast charge conditions, as well as the absence or degree of lithium plating. Sandia will use their unique high precision cycling and rapid EIS capabilities to accurately characterize performance and any lithium plating during 6C charging and beyond, coupling electrochemical observations with cell teardown. Sandia will also design custom fixturing to cool cells during rapid charge, to decouple any kinetic effects brought about by cell heating and allow comparisons between different cells and charge rates. Using these techniques, Sandia will assess HOH electrodes from the University of Michigan, as well as aiding in iterative model and electrode design.

25 ENERGY STORAGE↗