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Component Characterization of an eVTOL Reference Model for Crashworthiness Studies

Researchers at the National Aeronautics and Space Administration (NASA) Langley Research Center (LaRC) have conducted a series of structural component and seat level tests to improve finite element model (FEM) characterization of a representative vertical take-off and landing (eVTOL) test article developed by NASA. A full-scale dynamic test was conducted on the representative eVTOL test article in November of 2022. The test article represented a high wing, six passenger eVTOL design concept and is referred to as the lift plus cruise (LPC) test article. The full-scale test identified limitations in the analytical models used to predict aircraft structural response, in particular the composite material models did not effectively capture brittle failure of the structure which were measured during dynamic loading. To better understand the mechanism behind the composite material failure mechanisms observed and to improve the FEM, intact sample specimens of the composite airframe structure were recovered from the test article post-test and used in material characterization testing. In addition, the seat configurations used in the LPC test article were further studied using isolated seat and anthropomorphic test device (ATD) drop tower testing. Dynamic compression tests and three-point bend tests, conducted at varied impact speeds, were performed on the recovered frame section specimens. Additional testing was conducted to characterize the material properties of the forming foam, which remained in the frames after fabrication. These tests were used to improve characterization of the damage and failure parameters of the composite material model used in the FE model of the LPC test article. Seat level tests were conducted on the seats used in the LPC test article using acceleration pulses inclusive of current general aviation and rotorcraft certification load levels as well as conditions representative of those measured at the seat base during the LPC test. The structural material models and seat environment models of the LPC test article FEM were calibrated using the generated component test data. The updates made to these models were then integrated into the LPC FEM and simulated in the full-scale test condition. Results demonstrated the effectiveness of component testing to improve predictive capability of composite aerospace structural models within the crash and dynamic loading environments. Demonstration of the LPC FEM response across an accumulation of coupon, component, seat environment, and full-scale test levels provides confidence in the predictive capability of this model for future use in the study of occupant safety within eVTOL relevant crash environments.

Craswhorthiness↗

The Effects of Experimentally Induced Zircon Annealing on Melt Inclusion-Zircon Geochemistry: A Case Study of Archean Zircon From the Barberton Complex

Crystalline melt inclusions (MIs) in Archean zircons can potentially constrain the evolution of magmatic processes. However, to obtain a homogeneous glassy MI representative of the parent melt, devitrified MIs must be heated at temperatures above the liquidus. Although, it is well known that radiation damaged domains in MI-host zircon undergo temperature-time dependent annealing, the effects of annealing on zircon stable isotope and trace element compositions has received less attention. In this study, we heated multiple aliquots of low-magnetism zircons with relatively low levels of radiation damage (Deff<9.6x1014 α-events/mg) from a 3.304 Ga tonalite gneiss xenolith from the Barberton greenstone belt (sample B87-18; Kamo and Davis, 1994) in an internally-heated pressure vessel at 0.4GPa and 1000–1200°C. Zircons were imaged by SEM (CL, BSE) to determine the zoning patterns around the MIs. The radiation damage preserved in the heated and unheated zircons was determined by measuring broadening of the 3(SiO4) Raman stretching band of zircon (FWHM). Oxygen isotope ratios (δ18O), OH/O ratios, and trace and rare earth element (TREE) concentrations were measured in the zircons and MIs using SIMS. The FWHM and Raman shift of the zircon 3(SiO4) band show a systematic increase of zircon crystallinity with increasing experimental temperature. Despite increasing crystallinity, the 3(SiO4) FWHM is not correlated with δ18O(Zrn) values in the heated or unheated zircons, suggesting that δ18O was not altered by laboratory heating in these low initial radiation damage zircons. FWHM and OH/O are positively correlated in both heated and unheated zircons. The unheated zircons have the largest FWHM and OH/O (OH/OMAX=3.5×10-4) suggesting that H2O was lost during experimental heating due to the progressive annealing of radiation-damaged domains in the zircons. Zircon TREE concentrations and FWHM values are not correlated despite the presence of TREE altered domains in both the heated and unheated zircons. Our results demonstrate that pre-experimental zircon TREE concentrations and δ18O(Zrn) remain intact during laboratory heating of crystalline MIs in zircon, while secondary H2O hosted in radiation damaged domains is partially lost. Thus, MIs in low initial radiation damage Archean zircon are a potentially viable tool for constraining melt compositions.

Joseph P. Gonzalez↗

Madidrop for Passive Silver Dosing

Madidrop is a rectangular ceramic tablet originally designed to dose a 10-20-liter volume of water with silver to act as a biocide for remote communities with unreliable water sources. Silver as a biocide is a proposed method to control bacteria on the International Space Station or future Artemis missions. This would replace iodine currently used due to issues with a dual biocide system in place between Russian and US segments and the extra cost of iodine removal required before consumption. NASA has been reviewing this Madidrop technology and its potential application with a water reclamation system on orbit to dose silver after purifying the water. While there are a couple alternative methods to dosing silver on station, this method is like the existing passive dosing method used currently to dose iodine. Tests conducted characterize the manufacturer’s original intent to leave the tablet in a tank for a specified amount of time before removing and testing alternative passive flow-through methods. Passive flow testing involved two options: keeping the tablet intact or crushing the tablet into smaller particle sizes to increase the surface area while varying particle sizes. The results of these tests revealed a large amount of silver output at first that quickly reduced to a constant lower output within a reasonable dosing concentration range. The initial high concentration peaks after a couple days of quiescence and could be useful for shocking the initial tank water contents. Madidrop used as a passive particle doser could act as a stand-in replacement for iodine in future spaceflight water reclamation systems.

Ryan Ogilvie↗

How Many Vesta-Like Bodies Existed in the Asteroid Belt?

Asteroid 4 Vesta is typically thought to be the parent body of the HED (howardite, eucrite, and diogenite) meteorites due to spectral similarities. The discovery of asteroids far from Vesta with HED-like spectra like (1459) Magnya and HED-like meteorites (e.g., NWA 011) with anomalous oxygen isotopic values compared to typical HEDs is evidence that other Vesta-like bodies formed. We broadly define a Vesta-like body as a differentiated object with a crust composed primarily of low-Ca pyroxene and plagioclase feldspar. We estimate the number of Vesta-like bodies that did form by looking at the astronomical evidence; the oxygen isotopic, chemical, and petrologic evidence; and the iron meteorite evidence. Assuming that fragments of Vesta were scattered from Vesta by giant planet migration, we conservatively estimate that at least two Vesta-like bodies (Vesta and the Magnya parent bodies) existed. From the oxygen isotopic, chemical, and petrologic evidence, we also conservatively estimate that seven Vesta-like bodies formed. Analyses of iron meteorites indicate that there may be as many as 23 Vesta-like bodies (Vesta, 10 magmatic iron groups, South Byron trio, Emsland/Mbosi duo, 10 ungrouped irons). This estimate from iron meteorites is most certainly an overestimation due to the existence of a number of non-HED crustal/mantle fragments that potentially originated from bodies with magmatic iron cores. Using our three estimates as a guide, we predict that there were ~10 Vesta-like bodies (including Vesta) that formed in the early solar system. Only Vesta remains intact with the others being disrupted early in solar system history.

T. H. Burbine↗

Madidrop for Passive Silver Dosing

Madidrop is a rectangular ceramic tablet originally designed to dose a 10-20-liter volume of water with silver to act as a biocide for remote communities with unreliable water sources. Silver as a biocide is a proposed method to control bacteria on the International Space Station or future Artemis missions. This would replace iodine currently used due to issues with a dual biocide system in place between Russian and US segments and the extra cost of iodine removal required before consumption. NASA has been reviewing this Madidrop technology and its potential application with a water reclamation system on orbit to dose silver after purifying the water. While there are a couple alternative methods to dosing silver on station, this method is like the existing passive dosing method used currently to dose iodine. Tests conducted characterize the manufacturer’s original intent to leave the tablet in a tank for a specified amount of time before removing and testing alternative passive flow-through methods. Passive flow testing involved two options: keeping the tablet intact or crushing the tablet into smaller particle sizes to increase the surface area while varying particle sizes. The results of these tests revealed a large amount of silver output at first that quickly reduced to a constant lower output within a reasonable dosing concentration range. The initial high concentration peaks after a couple days of quiescence and could be useful for shocking the initial tank water contents. Madidrop used as a passive particle doser could act as a stand-in replacement for iodine in future spaceflight water reclamation systems.

Ryan Ogilvie↗

The Cognition Battery: Developing a Normative Database for Spaceflight and Examining the Impact of Prolonged Isolation and Confinement on Cognitive Performance

INTRODUCTION: Astronauts on future long duration space exploration will be required to execute complex tasks in which even minor errors could have devastating consequences. Intact cognition is critical to maintain exceptional performance standards and it is possible that variability even at the highest ends of the performance spectrum will impact operational tasks. Exposure to spaceflight hazards could compromise cognitive performance, and decrements have been documented under conditions of altered gravity and radiation exposure. The cognitive impacts of prolonged isolation and confinement remain relatively unknown. Traditional neuropsychological assessments cannot support earth independent monitoring, do not have normative comparisons for high functioning individuals, and most are not sensitive enough to detect small performance decrements. The Cognition Battery was developed to address these limitations but currently lacks comprehensive normative data. In this project, we aimed to 1) develop a preliminary normative database for astronauts and astronaut surrogates using the Cognition Battery, and 2) characterize differences in cognitive performance after short and long duration analog missions. PARTICIPANTS & METHODS: We assessed baseline cognitive performance by administering the Cognition Battery to 97 astronaut and astronaut surrogates recruited to approximate astronaut demographics (mean age: 39.38, SD=7.62; 35.1% female; 91.7% advanced degrees). For aim 1, we calculated speed and accuracy outcomes for each subtest and summarized the data with descriptive statistics. We examined the relationship between age and performance with Pearsons’s correlations and the relationship between gender and performance with independent samples t-tests. A subset of individuals on short duration (n=48; mean age: 38.18, SD=7.14; 37.5% female; 91.7% advanced degrees) missions of 45 days and long duration (n=34; mean age: 42.12, SD=8.39; 38.2% female; 94.1% advanced degrees) missions ranging from 4-8 months were administered the Cognition Battery during and after their respective missions. For aim 2, we accounted for practice effects using published corrections, and z-transformed post-mission scores using the full sample’s baseline scores. One-way analysis of covariance tests determined the main effect of analog duration on post-mission performance, after accounting for age and gender. The False Discovery Rate method was applied to adjust for multiple comparisons. RESULTS: In the full normative sample, older age was associated with slower reaction times on a processing speed task (r=.39, p=.02), and men were more accurate on processing speed (t=-2.19, p=.03) and faster on sustained attention (t=2.02, p=.049) and risk-taking tasks (t=2.49, p=.02). We observed a main effect of duration on performance on tasks of visual memory (f(1)=5.62, p=.04), processing speed (f(1)=5.48, p=.03), and sensorimotor functioning (f(1)=39.52, p < .001), such that slower performance was observed after long duration missions relative to short. Only sensorimotor functioning was significant after adjustments for multiple comparisons (adjusted p<.001). DISCUSSION: The full sample represents the largest dataset of cognitive performance assessed by the Cognition Battery available and can be used for further research in spaceflight and high-performance populations. Relationships between performance and key demographic variables suggest future research that include age and gender stratification is needed. Our results also show minimal changes in cognitive performance between longer and shorter periods of isolation and confinement.

S I Dev↗

Development of Cryogenic Phase Change Materials for Lunar Sample Return

One of the scientific goals of NASA’s Artemis missions is to return regolith samples from the lunar surface. To maintain scientific integrity of these samples, including any volatiles that may exist, cryogenic stowage is desired. FROSTE (Frozen Return Of Samples To Earth) is the element of the Moon to Mars architecture that is tasked with developing and advancing concepts related to this goal. Both active and passive solutions are being considered, but active solutions (cryo-coolers) have high mass and cost penalties. Phase change materials (PCMs) are commonly used as passive thermal management solutions, particularly for sensitive scientific samples. However, there are currently no PCMs capable of providing cooling at the cryogenic temperatures needed to enable lunar sample return with volatiles intact (<120 K). FROSTE has identified two possible candidate materials that could fill this gap. Testing is required to verify the thermal performance of these materials, as well as gain experience with their handling characteristics. We are conducting this testing at the Marshall Space Flight Center’s Space Environmental Effects laboratory, in vacuum, with liquid nitrogen providing cooling ability below the freezing point of the materials. In this talk, we will present an overview of the FROSTE program element and share results from the initial development testing of two cryogenic phase change materials.

phase change material↗

Investigating Low-Altitude Constellations of Ad-Hoc Lunar PNT System for Distributed Spacecraft Autonomy

In this study, we examine a low-altitude Lunar Position, Navigation, and Timing (LPNT) constellations and the localization performance of Centralized Extended Kalman Filter (CEKF) and Decentralized Extended Kalman Filter (DEKF) algorithms. The primary investigation involves a 100-node swarm operating at a 100 km altitude, in contrast to previous studies that examined a 21-node asset in a frozen-orbit at 5,500 km. The autonomous operation of large-scale swarm is based on two-way Inter-Satellite Link (ISL) measurements, which involve pseudoranges and relative velocities among swarm nodes. We perform a numerical assessment of the two filtering approaches, utilizing ‘fully sampled’ measurements from all available assets as well as ‘two ISL’ measurements where each spacecraft is restricted to only two antennas. This research includes an analysis of CEKF under 2-ISL constraints and evaluates the performance of DEKF in a 100-node swarm, which has not been explored in previous studies. In addition, we examine the impact of increasing the sampling frequency for DEKF, showing that the update cycle can be shortened from a 10-minute interval. A novel approach for ‘2-ISL limited’ DEKF will also be introduced, using a matching formulation that exhaustively enumerates all potential matches. This study provides valuable insights into large-scale distributed swarm operations, considering various filter configurations, sampling frequencies, matching strategies, and scalability of CEKF and DEKF for low-altitude LPNT applications. The Lunar PNT technology plays a key role in providing reliable and robust navigation services on the Moon's surface and the South pole, where the primary Lunar missions are planned. To support upcoming Lunar missions, including small satellites from NASA's Commercial Lunar Payload Services program, the Lunar PNT system must be adaptable to smaller platforms like CubeSats. Driven by the growing involvement of public and private exploration partnerships, the traditional low Earth orbit missions are shifting to beyond geosynchronous orbit [1]. These upcoming missions aim to foster a sustainable and innovative exploration program, in collaboration with commercial and international partners, to facilitate human expansion throughout the solar system and return new knowledge and opportunities to Earth [2]. As part of this trend, there are increasing efforts to utilize science missions in Lunar orbit to develop a non-dedicated and ad-hoc PNT network system. Two traditional approaches, the Deep Space Network (DSN) and the weak signal Global Positioning System (GPS), are established deep-space navigation technologies for missions beyond the geosynchronous orbit. Beginning in 1958, the DSN was developed to communicate with the Explorer 1 spacecraft based on the use of radiometric tracking in spacecraft navigation [3]. The DSN is capable of providing nearly unfettered coverage to spacecraft beyond low-Earth orbit (LEO), however, increased space mission volume has created concerns about future expectations of DSN usage for spacecraft navigation [4]. For cislunar mission applications, the position accuracy using DSN achieves 100 m (3σ) with at least three geometrically diverse ground stations when using radiometric tracking alone [5]. The DSN's dependence on Earth-based ground stations restricts its operational capabilities to periods of Earth visibility. This limitation, coupled with its poor localization performance, renders the DSN unsuitable for future lunar missions that demand continuous tracking and precise positioning. To satisfy the increasing requirements of DSN in Lunar applications, spacecrafts are also required to improve their onboard antenna power and efficiency of the transmission. However, there is an important aggregate cost trade between adding capabilities to every spacecraft and adding to a capacity on the ground that serves multiple spacecraft [6]. A weak GPS system can provide PNT service while the user spacecraft is bound to the Moon, leveraging a single, steerable high gain antenna with the relatively narrow beam which includes all the sources in its field of view [7]. However, the higher the altitude the receiver is above the GPS constellations, the poorer and the weaker are the relative geometry and the received signal powers, respectively, leading to a significant navigation accuracy reduction [8]. The transmitted power becomes weaker with increasing distance from the Earth as well as signals tracked from one of the side lobes of the GPS antenna pattern. As a results, the number of visible satellites and relative geometric condition of the GPS satellites at very high altitude drops dramatically and reduces the navigation solution accuracy. Therefore, the weak GPS system is also not an ideal way to provide PNT service to upcoming Lunar missions when considering its limited geometric condition and the recued navigation accuracy. Another navigation approach on the Moon is being developed, similar to the Global Navigation Satellite System (GNSS) on Earth, aiming to offer navigation service with continuous 24/7 coverage across the entire Lunar surface. For example, lunar communications relay and navigation systems (LCRNS) by NASA and Lunar navigation satellite systems (LNSS) by JAXA are designed to serve as dedicated Position, Navigation, and Timing (PNT) systems for the Moon. However, designing a dedicated LNSS and PNT service involves additional challenges, which are unique to the lunar environment, including limited payload capacity for the CubeSat platform, i.e., the size, weight, and power (SWaP) of the onboard clock, limited lunar ground monitoring stations, and limited financial investment as compared to the legacy Earth-GPS [9]. NASA’s focus on utilizing CubeSat platforms on the Moon leads to an alternative Lunar navigation platform that leverages the existing Lunar science and exploration assets. The small satellites used in Lunar missions can be used to create a low-cost, autonomous, ad-hoc, and on-demand mission-centric Lunar PNT swarm capable of providing PNT services to these low-cost lunar missions [10]. As upcoming Lunar missions will often operate at low-altitude about 30 km to 100 km for scientific observations and mapping purposes, the low-altitude orbital constellations could be employed to create an ad-hoc Lunar PNT system. However, several issues must be addressed, such as the instability of these orbits, which often require maintenance or are only suitable for short-duration missions, operating for fewer than 90 days. Additionally, at an altitude of 100 km, the satellites have a limited period during which they are above the horizon and capable of providing PNT service to users. The implementation of a non-dedicated, ad-hoc Lunar navigation constellation facilitates on-demand PNT services. A preliminary study of ad-hoc Lunar PNT system was conducted using 21 spacecraft in 5,5000 km altitude frozen orbits to test its feasibility and a basic performance of orbital asset localization among ad-hoc Lunar constellations in small satellites format [10]. These swarm assets are designed for autonomous localization with minimal Earth interaction, reducing dependency on bandwidth and ground resources. The design in [10] demonstrated the feasibility of a decentralized PNT approach, specifically employing a DEKF approach for state estimation, which helps minimize onboard operating costs. The DEKF method distributes computation across individual satellites, which lightens the computational load while maintaining accuracy in orbit ephemeris and clock offsets, similar to centralized systems [11]. In a follow-on study [12], each spacecraft was limited to 2 communications antennae, forcing the selection of measurements and scheduling spacecraft activities to perform the measurements. A matching algorithm is implemented to select the best measurements and schedule position estimation updates. The decentralized localization performance is also investigated with increasing levels of network degradation for swarm assets considering the impact of intermittent and permanent communication failure, to demonstrate the robustness and fidelity of the decentralized Lunar PNT service [13]. This study confirmed that the ad-hoc PNT constellations in frozen orbit are highly robust and resilient to communication failures. However, unlike frozen orbit swarm assets, the low-altitude satellites have a limited ground view at an altitude of 100 km, where the ad-hoc Lunar constellation consists of 98 low-altitude satellites, evenly distributed across seven circular polar orbital planes, alongside two satellites in a frozen orbit at an altitude of 5,500 km (Figure 1). Therefore, the number of satellites visible to ground users is significantly limited in low-altitude orbit constellations. As each visibility of a spacecraft remains intact for only a few ticks before it moves out of the field of view, the ground user encounters challenges in maintaining continuous navigation service, resulting in sparse availability and provision of Lunar PNT system. Consequently, service availability is primarily restricted to the Lunar South Pole region (Figure 2). Given these limitations and concerns, the localization performance of low-altitude swarm assets will be assessed in this study. We focus on the investigation of the localization performance of low-altitude swarm assets and ground users near the Lunar South Pole. The overall flow of the Lunar PNT simulation incorporates the DEKF approach of asset localization and the weighted least-squares approach in user localization (Figure 3). The autonomous Lunar PNT simulation is primarily implemented in MATLAB, where the DEKF based on the matching scheduler is implemented with Google’s OR-tools as a model builder and Gurobi optimization tool as a backend solver. The General Mission Analysis Tool (GMAT) is utilized to generate ephemeris data for swarm assets, and accounts for satellite orbital details, mass, and perturbations like solar radiation pressure and drag coefficients. Each ephemeris dataset is produced in the Moon International Celestial Reference Frame (ICRF) inertial coordinate system. For state estimation, the distributed swarm assets rely on two-way Inter-Satellite Link (ISL) measurements, which involve tracking pseudoranges and relative velocities between visible satellites and anchor nodes during each observation. Numerical evaluations of the decentralized localization process are conducted to demonstrate the feasibility of the low-altitude PNT system in providing reliable navigation services. The main approach involves using DEKF and CEKF to localize 100 satellites in low-altitude constellations, where the CEKF is implemented to serve as a baseline for comparing the performance of distributed algorithms. In both cases, we evaluate ‘fully sampled’ measurements from all available assets, and ‘two ISL’ measurements when spacecraft are constrained to have only two antennas. We test four estimation techniques: CEKF fully sampled, CEKF two ISL, DEKF fully sampled, and DEKF two ISL filters. As the DEKF update cycle is comprised of network setup, communication, and computations, a global broadcast network and 2-way ISL network setup will take from 4 to 6 minutes as maximum [12]. In this simulation, the DEKF update cycle is set to 10 minutes, including a 4-minute latency for obtaining and computing the actual measurement updates. We experiment an increased update cycle to demonstrate the feasibility and evaluate the impact on localization performance using various tuning values for measurement noise covariances (Figures 4 and 5). By comparing centralized and decentralized approaches using a matching algorithm, we analyze the influence of cross-correlation factors in the covariance matrix, assuming 100% reliability of all assets and measurements. The increased frequency and the adjustments of tuning parameters reveal distinct error patterns between the two scenarios. The localization accuracy of the swarm assets and ground users is assessed by taking the median error across 100 assets and one ground user (84.9°S, 137.5°E) over 7-day simulation period (Table 1). Since the user localization accuracy is significantly affected by the performance of the swarm assets, it is crucial to maintain high localization accuracy within the swarm. This study will continue to explore decentralized filtering for autonomous LPNT operations, with further investigation of an 'iterative' matching approach which enumerates every valid matching pair, planned for the following month.

Yeji Kim↗

Ribosomal targets for antibiotic drug discovery

The present invention relates to methods to identify molecules that binds in the neomycin binding pocket of a bacterial ribosome using structures of an intact bacterial ribosome that reveal how the ribosome binds tRNA in two functionally distinct states, determined by x-ray crystallography. One state positions tRNA in the peptidyl-tRNA binding site. The second, a fully rotated state, is stabilized by ribosome recycling factor (RRF) and binds tRNA in a highly bent conformation in a hybrid peptidyl/exit (P/E) site. Additionally, the invention relates to various assays, including single-molecule assay for ribosome recycling, and methods to identify compounds that interfere with ribosomal function by detecting newly identified intermediate FRET states using known and novel FRET pairs on the ribosome. The invention also provides vectors and compositions with an N-terminally tagged S13 protein.

59 BASIC BIOLOGICAL SCIENCES↗

MICRO/NANO-STRUCTURAL EXAMINATION AND FISSION PRODUCT IDENTIFICATION IN NEUTRON IRRADIATED AGR-1 TRISO FUEL

Advanced microscopic and microanalysis techniques were developed and applied to study irradiation effects and fission product behavior in selected low-enriched uranium oxide/uranium carbide TRISO-coated particles from fuel compacts in six capsules irradiated to burnups of 11.2 to 19.6% FIMA. Although no TRISO coating failures were detected during the irradiation, the fraction of Ag-110m retained in individual particles often varied considerably within a single compact and at the capsule level. At the capsule level Ag-110m release fractions ranged from 1.2 to 38% and within a single compact, silver release from individual particles often spanned a range that extended from 100% retention to nearly 100% release. In this paper, selected irradiated particles from Baseline, Variant 1 and Variant 3 type fueled TRISO coated particles were examined using Scanning Electron Microscopy, Atom Probe Tomography; Electron Energy Loss Spectroscopy; Precession Electron Diffraction, Transmission Electron Microscopy, Scanning Transmission Electron Microscopy (STEM), High Resolution Electron Microscopy (HRTEM) examinations and Electron Probe Micro-Analyzer. Particle selection in this study allowed for comparison of the fission product distribution with Ag retention, fuel type and irradiation level. Nano sized Ag-containing features were predominantly identified in SiC grain boundaries and/or triple points in contrast with only two sitings of Ag inside a SiC grain in two different compacts (Baseline and Variant 3 fueled compacts). STEM and HRTEM analysis showed evidence of Ag and Pd co-existence in some cases and it was found that fission product precipitates can consist of multiple or single phases. STEM analysis also showed differences in precipitate compositions between Baseline and Variant 3 fuels. A higher density of fission product precipitate clusters were identified in the SiC layer in particles from the Variant 3 compact compared with the Variant 1 compact. Trend analysis shows precipitates were randomly distributed along the perimeter of the IPyC-SiC interlayer but only weakly associated with kernel protrusion and buffer fractures. There has been no evidence that the general release of silver is related to cracks or significant degradation of the microstructure. The results presented in this paper provide new insights to Ag transport mechanism(s) in intact SiC layer of TRISO coated particles.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Exclusive and semi-exclusive pi+pi- production in proton-proton collisions at sqrt(s) = 7 TeV

A measurement is presented of the exclusive and semi-exclusive production of charged pion pairs in proton-proton collisions, pp to p(p*) + pi+pi- + p(p*) here the pi+pi- pair is emitted at central rapidities, and the scattered protons stay intact (p) or diffractively dissociate (p*) without detection. The measurement is performed with the CMS detector at the LHC, using a data sample corresponding to an integrated luminosity of 450 inverse microbarns collected at a center-of-mass energy of 7 TeV. The dipion cross section, measured for single-pion transverse momentum pt >0.2 GeV and rapidity abs(y)<2, is 26.5 +/- 0.3 (stat) +/- 5.0 (syst) +/- 1.1 (lumi) microbarns. The differential cross sections measured as a function of the invariant mass, pt, and y of the pion pair, and as a function of single-pion pt, are compared to phenomenological predictions.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

An Integrated Design Approach for Infill Patterning of Fused Deposition Modeling and its Application to an Airfoil

We present a new approach to incorporate an internal stress distribution into the design of infill via fused deposition modeling of additive manufacturing (AM). This design approach differs from topology optimization, since the topology optimization of AM focuses on changing the overall shape of the product, whereas the approach we propose in this research focuses on the porous infill and remains the overall shape of the product intact. The approach presented here is effective if the overall shape is an important functioning aspect of a product and the stress is applied to the entire body, not to given localized points. As an application, we demonstrate an airfoil with its infill densities optimized based on the pressure applied during operation. Specifically, the stress of an airfoil is analyzed with operational loading conditions. The local density of the infill pattern is determined based on the computational stress analysis. The infill geometry is mathematically generated using a circle packing algorithm. Test results show that the airfoil with the optimized infill outperforms the same shape with the traditional uniform infill pattern of an airfoil having the same weight.

Kim, Pum↗

Method for delivery of small molecules and proteins across the cell wall of algae using molecular transporters

The introduction of tools to study, control or expand the inner-workings of algae has been slow to develop. Provided are embodiments of a molecular method based on guanidinium-rich molecular transporters (GR-MoTrs) for bringing molecular cargos into algal cells. The methods of the disclosure have been shown to work in wild-type algae that have an intact cell wall. Developed using Chlamydomonas reinhardtii, this method is also successful with less studied algae, including Neochloris oleoabundans and Scenedesmus dimorphus, thus providing a new and versatile tool for algal research and modification. The method of delivering a cargo compound to an algal cell comprises contacting an algal cell with a guanidinium-rich delivery vehicle comprising a guanidinium-rich molecular transporter (GR-MoTr) linked to a cargo compound desired to be delivered to the algal cell, whereby the guanidinium-rich molecular transporter can traverse the algal cell wall, thereby delivering the cargo compound to the algal cell.

59 BASIC BIOLOGICAL SCIENCES↗

Black Carbon Aerosol Deposition Study (BCADS) Field Campaign Report

Black carbon (BC) absorbs incident solar radiation, perturbs temperature gradients in the atmosphere, and indirectly impacts cloud formation and optical properties (Koch and Del Genio 2010). Deposition of BC to snow and ice surfaces alters albedo and enhances snow melt (Hansen and Nazarenko 2004; Flanner et al., 2007). The impact of BC on regional and global climates through these processes depends on its atmospheric concentration, and thus on the relative rates of emission and loss. Combustion of fossil fuels and biofuel, biomass burning, and wildfires are major sources of BC (Bond et al., 2004). Significant sinks include wet and dry deposition. Wet deposition occurs through scavenging by cloud droplets, ice crystals, and precipitation, while dry deposition refers to the direct removal of particles in the atmosphere to planetary surfaces (e.g., plant, soil, ocean, ice surfaces). Bond et al. (2013) and references therein have focused on the source, aging, and optical properties of BC, while deposition components of the BC lifecycle remain poorly constrained. This is predominantly due to the lack of observations of both total aerosol and BC deposition. Removal rates of refractory and non-refractory sub-micron aerosol by wet and dry deposition are one of the most uncertain aspects of modelling cloud condensation nuclei (CCN; Lee et al., [2013]). BC is an ideal tracer for particle deposition because it is non-volatile and effectively chemically inert, though it can become mixed with other species in the atmosphere. Unlike other aerosol species, BC remains ‘intact’ in water and has no confounding gas-phase contribution to precipitation measurements, and can thus be used to examine the relative importance of wet and dry deposition. Thus, measurements of BC deposition are not only essential for constraining BC sinks and atmospheric lifetime, but also useful for investigating aerosol deposition more broadly.

Southern Great Plains, black carbon, aerosols, sin↗

Evaluation of Stimulation by Shear Slip in Fractured Rock Using a 3D Coupled Thermo-Poro-Mechanical FEM

This paper presents a 3D finite element model for simulating shear slip on fractures in rock in response to coupled thermo-poro-mechanical processes. The modeling is part of a broader effort to investigate the role of pore pressure and cooling by cold water injection on shear slip and permeability increase in granitic rock using laboratory shearing experiments under triaxial conditions. In particular, 3D thermo-poro-mechanical finite element modeling and analysis of injection experiment in fractured rock has been carried out to analyze the role of pore pressure, temperature, fracture deformation and their interactions. 4-noded tetrahedral elements are employed for intact rock deformation and transport processes within the matrix. To represent the mechanical response of a fracture surface, zero thickness contact interface element is developed based on recently developed element partitioning algorithm and procedures for applying hydraulic pressure on the fracture surfaces. A Mohr-Coulomb type criterion is adapted to capture the slip on the fracture and to quantify its reversible and irreversible deformation. The numerical model has been calibrated using results from well controlled, advanced laboratory experiments. Excellent agreement between modeling and experimental observations is achieved. Simulation results illustrate that pore pressure increase and rock matrix/fracture surface cooling cause the fracture system to deform and slip. Fracture slip is promoted due to its normal stress reduction associated with cooling effect of cold fluid injection. The numerical model provides a physics-based understanding of the role of coupled processes on shear stimulation phenomenon and the resulting permeability enhancement.

58 GEOSCIENCES↗

Development of High Temperature Out-of-Pile Experiments for Testing Nuclear Thermal Propulsion Fuel Surrogates

Nuclear thermal propulsion (NTP) technology is designed to provide “in-space” vehicle propulsion by deriving thrust from a hydrogen working fluid that is heated from a nuclear reaction. Initial NTP fuel structures (primarily carbon/carbide based materials) developed by the Rover/NERVA program were designed to withstand temperatures exceeding 2400 K and remain intact after tens of firing cycles. Current programs responsible for development of this technology expect the fuels to withstand temperatures in excess of 2550K under a similar duty cycle. Experiments that subject fuels to these conditions are being developed to provide data and performance information for optimization and potential down-selection of the candidate materials. Initial tests will be designed for laboratory benchtop operation and will not expose surrogate specimens to the hydrogen working fluid or irradiation fields. The primary focus of these out-of-pile experiments will be to study thermal performance and thermal failure limits of the candidate specimen materials.

Howard, Richard↗

Graded Infill Structure of Wind Turbine Blade Accounting for Internal Stress in Big Area Additive Manufacturing

In additively manufactured (AM) components, infill structure significantly affects the mechanical performance of the final printed part. However, mechanical stress induced by operation loads has been so far neglected for infill patterning. Most slicers currently available in the market provide infill patterns that are uniform in shape and size regardless of the operational loading. We develop a design approach for infill patterns that accounts for the induced stress. This approach differs from topology optimization as it focuses on the porous infill, which allows the external shape of the printed part to remain intact. The proposed approach uses a computational stress analysis to control the distribution of the local density of the infill pattern. We have applied the approach to a wind turbine blade core with infill densities optimized based on the structural loads. The blade core is fabricated in our big area additive manufacturing (BAAM) system. To ensure less warpage and better inter-layer bonding, fast layer deposition is critical in BAAM system. We have optimized the tool path sequences to minimize the deposition time via the solution to the Chinese Postman Problem (CPP). For the application of wind turbine infill, the deposition from the CPP method is twice faster than the deposition from conventional slicing.

Kim, Pum↗

Post-irradiation Examinations of High Burnup PWR Rods

The High Burnup Spent Fuel Data Project (herein referred to as the “project”), sponsored by the US Department of Energy (DOE) Office of Nuclear Energy (NE), is focused on experimentally evaluating the effects of long-term storage and transportation on high burnup (HBU) (defined as >45 gigawatt days per metric ton uranium) pressurized water reactor (PWR) spent nuclear fuel (SNF) [1]. To support this project, in the fall of 2017, an instrumented bolted-lid cask (project cask) at the North Anna reactor site was loaded with intact, HBU PWR fuel assemblies (project assemblies) having four different kinds of cladding and will be reopened in approximately 10-years for inspection. To support pre- and post-storage SNF rod characterization, 25 “sister rods” that are similar to the rods being stored in the project cask were extracted from seven different fuel assemblies at the North Anna nuclear power plant for post-irradiation examination (PIE).The sister rod testing program has multiple objectives, including: 1) Baseline testing to provide essential information on the physical condition and properties of the cladding and the fuel in the cladding prior to the loading, drying, and long-term dry storage process (analogous to an experiment control group). Similar tests are expected to be performed at the end of the 10-year storage period on rods extracted from the cask to identify any changes in the properties of the fuel rods that may have occurred during the dry storage period; and 2) Tests to provide material property and physical data using accelerated separate effects tests (SETs) and small-scale tests (SSTs) to explore a wide range of conditions that may occur for other dry storage systems and/or while the fuel is being transported after aging.Testing will be focused on understanding overall SNF rod strength and durability, and be comprised of both composite fuel and defueled clad testing with a focus on measuring cladding material and mechanical properties. Nondestructive testing is currently underway and plans are being updated to support the initial set of destructive tests that are expected to begin by early 2018. While the data generated can be used for multiple purposes, a primary goal of the sister rod PIE data and associated measured mechanical properties are expected to support existing fuel storage licensing and relicensing activities by addressing identified knowledge gaps, and enhance the technical bases for post-storage transportation, handling, and consolidation activities [1]. This paper presents results obtained from the sister rod testing to date, and describes some of the planned measurements, equipment, and procedures that will be implemented for the initial set of destructive examinations.

Montgomery, Rose↗

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