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NASA NTRS1998

Reflectance Spectroscopy and Lunar Sample Science: Finally a Marriage After Far Too Long an Engagement

Inferences about the igneous and impact evolution of planetary bodies are based upon spectral remote sensing of their surfaces. However, it is not the rocks of a body that are seen by the remote sensing, but rather the regolith, that may contain small pieces of rock but also many other phases as well. Indeed, recent flybys of objects even as small as asteroid Ida have shown that these objects are covered by a regolith. Thus, spectral properties cannot be directly converted into information about the igneous history of the object. It is imperative to fully understand the nature of the regolith, particularly its finer fraction termed "soil," to appreciate the possible effects of "space weathering" on the reflectance spectra. We have initiated a study of our nearest, regolith-bearing body, the Moon, as "ground truth" for further probes of planetary and asteroidal surfaces. the foundation for remote chemical and mineralogical analyses lies in the physics underlying optical absorption and the linking of spectral properties of materials measured in the laboratory to well understood mineral species and their mixtures. From this statement, it is obvious that there should be a thorough integration of the material science of lunar rocks and soils with the remote-sensing observations. That is, the lunar samples returned by the Apollo missions provide a direct means for evaluation of spectral characteristics of the Moon. However, this marriage of the remote-sensing and lunar sample communities has suffered from a prolonged unconsummated betrothal, nurtured by an obvious complacency by both parties. To make more direct and quantitative links between soil chemistry/mineralogy and spectral properties, we have initiated a program to (1) obtain accurate characterization of the petrography of lunar soils (in terms relevant to remote analyses), coupled with (2) measurement of precise reflectance spectra, with testing and use of appropriate analytical tools that identify and characterize individual mineral and glass components. It is the finest-sized fractions of the bulk lunar soil that dominate the observed spectral signatures.

Taylor, Lawrence A.↗
NASA NTRS1977

An Evaluation of Total Solar Reflectance and Spectral Band Ratioing Techniques for Estimating Soil Water Content

For several days in March of 1975, reflected solar radiation measurements were obtained from smooth and rough surfaces of wet, drying, and continually dry Avondale loam at Phoenix, Arizona, with pyranometers located 50 cm above the ground surface and a multispectral scanner flown at a 300-m height. The simple summation of the different band radiances measured by the multispectral scanner proved equally as good as the pyranometer data for estimating surface soil water content if the multispectral scanner data were standardized with respect to the intensity of incoming solar radiation or the reflected radiance from a reference surface, such as the continually dry soil. Without this means of standardization, multispectral scanner data are most useful in a spectral band ratioing context. Our results indicated that, for the bands used, no significant information on soil water content could be obtained by band ratioing. Thus the variability in soil water content should insignificantly affect soil-type discrimination based on identification of type-specific spectral signatures. Therefore remote sensing, conducted in the 0.4- to 1.0-micron wavelength region of the solar spectrum, would seem to be much More suited to identifying crop and soil types than to estimating of soil water content.

Reginato, R. J.↗
NASA NTRS1998

Characterization of Clouds and the Anisotropy of Emitted and Reflected Radiances for the Purpose of Obtaining the Radiative Heating of the Atmosphere

The goal of the work supported through this grant was to assess the validity of the assumptions underlying the CERES Strategy for determining radiative fluxes. Specifically, the work focused on the determination of scene type and the use of anisotropic factors to derive radiative fluxes from observed broadband radiances. The work revealed a dependence of the anisotropy of reflected and emitted broadband radiances on the spatial resolution of the observations that had been overlooked in the formulation of the CERES strategy. This dependence on spatial resolution coupled with errors in scene identification led to view zenith angle dependent biases in the ERBE derived radiative fluxes. Scene identification will be greatly improved in CERES thereby alleviating somewhat the biases arising from the dependence of the anisotropy of the radiances on spatial resolution. Attention was then focused on the validity of plane-parallel radiative transfer theory which is relied on to characterize the scene types viewed by the CERES scanner. Again, viewing geometry dependent biases were found even for single-layered, overcast cloud systems. Such systems are taken to be the closest examples of plane-parallel clouds. At least some of the departures from plane-parallel behavior were evidently due to relatively small bumps on the tops of extensive stratus layers. The bumps cannot be resolved in the imagery that will be used to characterize the scenes viewed by the CERES scanner. As part of this investigation, the ice sheets of Greenland and Antarctica were shown to provide radiometrically stable targets for determining the visible and near infrared calibrations of radiometers. These targets were used to calibrate the reflected sunlight at visible wavelengths used in this study. Finally, the limitations of plane-parallel theory notwithstanding, the common practice of ignoring fractional cloud cover within the fields of view of imaging radiometers was shown to lead to biases in the retrieved cloud properties. The development of retrievals for pixel-scale cloud cover fraction is an attempt to reduce such bases. Work on these retrievals continues.

Coakley, James A., Jr.↗
NASA NTRS1999

Variability and Spectral Studies of Luminous Seyfert 1 Galaxy Fairall 9. Search for the Reflection Component is a Quasar: RXTE and ASCA Observation of a Nearby Radio-Quiet Quasar MR 2251-178

Monitoring observations with interval of 3 days using RXTE (X Ray Timing Explorer) of the luminous Seyfert 1 galaxy Fairall 9 were performed for one year. The purpose of the observations were to study the variability of Fairall 9 and compare the results with those from the radio-loud object 3C 390.3. The data has been received and analysis is underway, using the new background model. An observation of the quasar MR 2251-178 was made in order to determine whether or not it has a reflection component. Older background models gave an unacceptable subtraction and analysis is underway using the new background model. The observation of NGC 6300 showed that the X-ray spectrum from this Seyfert 2 galaxy appears to be dominated by Compton reflection.

Leighly, Karen M.↗
NASA NTRS1999

Seasonal Characteristics of Non-Meteorological Radar Reflectivity Returns in Central Florida and Their Impact on TRMM Ground Validation

Radar data quality control is a major component to the Tropical Rainfall Measuring Mission (TRMM) Ground Validation (GV) effort. The quality control algorithm utilizes several adjustable height and reflectivity threshold parameters to remove non-precipitation echoes from ground-based radar data. Spurious radar reflectivity returns not removed during the quality control process may create biases in ground validation rainfall products used to evaluate rainfall measurements retrieved from aboard the TRMM satellite. To better evaluate the performance of the quality control algorithm, WSR-88D radar data from one primary GV site, Melbourne, Florida, are used to determine the seasonal characteristics of non-meteorological radar echoes in cast central Florida during the first year of the TRMM mission. It is demonstrated that unique spurious echo regimes develop throughout the year, leading to different levels of successful non-meteorological echo removal by the quality control algorithm. In addition to the type of non- precipitation echoes present, the success of the algorithm is also greatly dependent upon the amount of precipitation present. Less aggressive attempts to remove non-meteorological echoes must be employed when rain is observed so as not to remove these echoes as well. Therefore, precipitation statistics from ground validation monthly rainfall products will be utilized to further document the quality control algorithm performance. Moreover, these precipitation statistics will be used to demonstrate the relationship between dominant spurious echo regimes and rainfall amount. Finally, monthly statistics of contaminated ground validation radar data will be calculated and the effect on rainfall accumulation products will be discussed.

Robinson, Michael↗
NASA NTRS1971

Water Pollution Detection by Reflectance Measurements

Measurement of the intensity of light reflected from various planar liquid surfaces has been performed. The results of this brief study show that the presence of a film of foreign material floating on a reference substrate is easily detected by reflectance measurement if the two liquids possess significantly different refractive indices, for example, oil (n = 1.40) and water (n = 1.33). Additional study of various optical configurations, and the building and testing of a prototype monitoring device revealed that the method is sufficiently practical for application to continuous water quality monitoring.

Goolsby, A. D.↗
NASA NTRS1990

Exploring the Relationship Between Reflectance Red Edge and Chlorophyll Content in Slash Pine

Chlorophyll is a key indicator of the physiological status of a forest canopy. However, its distribution may vary greatly in time and space, so that the estimation of chlorophyll content of canopies or branches by extrapolation from leaf values obtained by destructive sampling is labor intensive and potentially inaccurate. Chlorophy11 content is related positively to the point of maximum slope in vegetation reflectance spectra which occurs at wavelengths between 690-740 nm and is known as the "red edge." The red edge of needles on individual slash pine (Piniis elliottii Engelm.) branches and in whole forest canopies was measured with a spectroradiometer. Branches were measured on the ground against a spectrally flat reflectance target and canopies were measured from observation towers against a spectrally variable understory and forest floor. There was a linear relationship between red edge and chlorophyll content of branches (R(exp 2) = 0.91). Measurements of the red edge and this relationship were used to estimate the chlorophyll content of other branches with an error that was lower than that associated with the colorimetric (laboratory) method. There was no relationship between the red edge and the chlorophyll content of whole canopies. This can be explained by the overriding influence of the understory and forest floor, an influence that was illustrated by spectral mixture modeling. The results suggest that the red edge could be used to estimate the chlorophyll content in branches but it is unlikely to be of value for the estimation of chlorophyll content in canopies unless the canopy cover is high.

Curran, Paul J.↗
NASA NTRS1999

Apollo 17 Soil Characterization for Reflectance Spectroscopy

It is the fine fractions that dominate the observed spectral signatures of bulk lunar soil, and the next to the smallest size fractions are the most similar to the overall properties of the bulk soil. Thus, our Lunar Soil Characterization Consortium has concentrated on understanding the inter-relations of compositional, mineralogical, and optical properties of the <45-micron size fraction and its component sizes (20-44 micron, 10-20 micron, and <10 micron size fractions). To be able to generalize our results beyond the particular sample set studied, it is necessary to quantitatively identify the observed effects of space weathering and evaluate the processes involved. For this, it is necessary to know the chemistry of each size fraction, modal abundances of each phase, average compositions of the minerals and glasses, I(sub s)/FeO values, reflectance spectra, and the physical makeup of the individual particles and their patinas. This characterization includes the important dissection of the pyroxene minerals into four separate populations, with data on both modes and average chemical compositions. Armed with such data, it should be possible to effectively isolate spectral effects of space weathering from spectral properties related to mineral and glass chemistry. Four mare soils from the Apollo 17 site were selected for characterization based upon similarities in bulk composition and their contrasting maturities, ranging from immature to submature to mature. The methodology of our characterization has been discussed previously. Results of the Apollo 17 mare soils, outlined herein, are being prepared for publication in MAPS. As shown, with decreasing grain size, the agglutinitic (impact) glass content profoundly increases. This is the most impressive change for the mare soils. In several soils we have examined, there is an over two-fold increase in the agglutinitic glass contents between the 90-150- micron and the 10-20-micron size fractions. Accompanying this increase in agglutinitic glass is a definite decrease in pyroxenes and to lesser extents, the oxides (ilmenite), volcanic glass, and olivine. Unexpectedly, however, the absolute plagioclase abundances stay relatively constant throughout the different grain sizes, although the abundance of plagioclase relative to the mafic minerals increases with decreasing particle size. These soils were chosen for study based upon their similarities in FeO and Ti02 content, allowing for direct comparisons between evolutions of chemistry between size fractions and among different maturities of soils. The bulk chemistry of these fractions was determined by EMP analyses of fused glass beads. In contrast to the systematic variations in bulk chemistry discussed below, the relatively uniform composition of agglutinitic glass with grain size and soil maturity is illustrated. The composition of the bulk fraction of each size fraction becomes more feldspathic with increasing maturity, with the effect being most pronounced for the finest fractions. The composition of the agglutinitic glass, however, is relatively invariant and more feldspathic (i.e., rich in Al2O3) than even the <10-micron fraction. This relation not only strengthens the "fusion of the finest fraction" (F(sup 3)) hypothesis, but also highlights the important role of plagioclase in the formation of agglutinitic glass. With decreasing grain size, FeO, MgO, and TiO2 contents decrease, whereas CaO, Na2O, and Al2O3 (plag components) increase for all soils. These chemical variations would appear to be coupled with the significant increase in agglutinitic glass and decrease in oxide (ilmenite),pyroxene, and volcanic glass. These changes in chemistry do not appear to be due to distinct changes in the compositions of individual phases but to their abundances. Values of I(sub s)/FeO increase with decreasing grain size, even though the bulk FeO contents decrease. That is, the percentage of the total Fe that is present as nanophase Fe(sup O) has increased substantially in the smaller size fraction. Note that the increase in nanophase FeO in smaller size fractions is significantly greater than the increase in agglutinitic glass content, with its single-domain FeO component. This would seem to indicate that at least some of the FeO is surface correlated. To illustrate this effect, if it is assumed that the nanophase FeO is entirely surface correlated, then equal masses of 15-micron and 6-micron spheres should have about 3x as much FeO in the finer fraction. The recent findings of Kelleret al. of the major role of vapor-deposited, nanophase FeO-containing patinas on most soil particles is a major breakthrough in our understanding of the distribution of FeO within agglutinitic glass and upon grain surfaces. Bidirectional reflectance spectra for a representative Apollo 17 soil (70181) are shown. The size separates all have similar albedo in the blue and follow a regular sequence in which the continuum slope increases, ferrous bands weaken, and albedo, increases with decreasing particle size. The bulk <45-micron soil is typically close to the 10-20 micron spectrum. It is important to note that although the finest fraction (<10 micron) is close in composition to the abundant agglutinitic glass in each size fraction, this size fraction is relatively featureless and does not dominate the spectrum of the bulk <45-micron soil. It has long been suspected that agglutinitic glass, to a large extent, is the product of melting of the finest fraction of the soils, with a dominance of plagioclase. Given the low abundance of pyroxene in the finest fractions of each soil the source of the FeO in these Apollo 17 agglutinitic glasses is not fully identified. We suspect the abundant volcanic glass in these samples may be a significant contributor and this hypothesis will be tested with the suite under study from other Apollo sites.

Taylor, L. A.↗
NASA NTRS2000

Reflective Silvered Polyimide Films Via In Situ Thermal Reduction Silver (I) Complexes

Self-metallizing. flexible polyimide films with highly reflective surfaces are prepared by an in situ self-metallization procedure involving thermally initiated reduction of polymer-soluble silver(I) complexes. Polyamic acid solutions are doped with silver(I) acetate and solubilizing agents. Thermally curing the silver(I) doped resins leads to flexible. metallized films which have reflectivities as high as 100%. abrasion-resistant surfaces. thermal stability and, in some cases, electrical conductivity, rendering them useful for space applications.

Southward, Robin E.↗
NASA NTRS1998

Apparent Surface Reflectance of the DOE ARM SGP CART Central Site Derived from AVIRIS Spectral Images

The primary objective of the Department of Energy (DOE) Atmospheric Radiation Measurement (ARM) Program at the Southern Great Plains (SGP) Cloud and Radiation Testbed (CART) is to acquire in situ and remote sensing data to improve cloud and atmospheric radiative models and parameterizations. As a consequence of this program, a large number of atmosphere and surface measurements are being acquired at the ARM SGP CART central site. NASA's Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) overflew this site on August 1, 1997. AVIRIS measures the upwelling spectral solar radiance from 400 to 2500 nm at 10-nm intervals. From 20 km altitude, these calibrated spectra are acquired as images of 11 by up to 800 km with 20-by-20 m spatial resolution. These data were acquired at the ARM SGP CART Central Site to first investigate derivation of atmospheric parameters from the measured spectra, second study the variation of these parameters, and third demonstrate the inversion of the calibrated radiance spectra to apparent surface reflectance. These objectives have been pursued with AVIRIS data at other sites for atmospheric water vapor and derivation of apparent surface reflectance.

Green, Robert O.↗
NASA NTRS1998

Diurnal Reflectance Changes in Vegetation Observed with AVIRIS

Among the most important short-term dynamic biological processes are diurnal changes in canopy water relations. Plant regulation of water transport through stomatal openings affects other gaseous transport processes, often dramatically decreasing photosynthetic fixation of carbon dioxide during periods of water stress. Water stress reduces stomatal conductance of water vapor through the leaf surface and alters the diurnal timing of stomatal opening. Under non-water stressed conditions, stomates typically open soon after dawn and transpire water vapor throughout the daylight period. During stress periods, stomates may close for part of the day, generally near mid-day. Under prolonged stress conditions, stomatal closure shifts to earlier times during the day; stomates may close by mid-morning and remain closed until the following morning - or remain closed entirely. Under these conditions the relationship between canopy greenness (e.g., measured with a vegetation index or by spectral mixture analysis) and photosynthetic fixation of carbon is lost and the remotely sensed vegetation metric is a poor predictor of gas exchange. Prediction of stomatal regulation and exchange of water and trace gases is critical for ecosystem and climate models to correctly estimate budgets of these gases and understand or predict other processes like gross and net ecosystem primary production. Plant gas exchange has been extensively studied by physiologists at the leaf and whole plant level and by biometeorologists at somewhat larger scales. While these energy driven processes follow a predictable if somewhat asymmetric diurnal cycle dependent on soil water availability and the constraints imposed by the solar energy budget, they are nonetheless difficult to measure at the tree and stand levels using conventional methods. Ecologists have long been interested in the potential of remote sensing for monitoring physiological changes using multi-temporal images. Much of this research has focused on day-to-day changes in water use, especially for agricultural applications. Ustin et al. showed seasonal changes in canopy water content in chaparral shrub could be estimated using optical methods. Vanderbilt et al. followed asymmetric diurnal changes in the reflectance of a walnut orchard, but could not attribute specific reflectance changes to specific changes in canopy architecture or physiology. Forests and shrub lands in California experience prolonged periods of drought, sometimes extending six months without precipitation. The conifer and evergreen chaparral communities common to the foothill region around the central valley of California retain their foliage throughout the summer and have low transpiration rates despite high net radiation and temperature conditions. In contrast, grasslands and drought resistant deciduous species in the same habitat are seasonally dormant in summer. Because of differences in the mechanisms of drought tolerance, rooting depth and physiology between different plant communities in the region, it is likely that they display differences in diurnal water relations. The presence of diverse plant communities provides an opportunity to investigate possible diurnal landscape patterns in water relations that could be observed by an airborne hyperspectral scanner. This investigation of AVIRIS data collected over forest and shrub land represents the continuation of a prior investigation involving spectral mixture analysis of diurnal effects in the same AVIRIS data set.

Vanderbilt, V. C.↗
NASA NTRS2000

Relativistically Skewed Iron Emission and Disk Reflection in Galactic Microquasar XTE J1748-288

We report evidence for an Fe K-alpha fluorescence line feature in the Very High, High, and Low state X-ray spectra of the galactic microquasar XTE JI748-288 during its June 1998 outburst. Spectral analyses were made on observations spread across the outburst, gathered with the Rossi X-ray Timing Explorer. Gaussian line. disk emission line, relativistic disk emission line, and disk reflection models are fit to the data. In the Very High State, the line profile is strongly redshifted and consistent with emission from the innermost radius of a maximally rotating Kerr black hole, 1.235 R(sub g). The line profile is less redshifted in the High State, but increasingly prominent. In the Low State, the line profile is very strong and centered af approx. 6.7 keV; disk line emission models constrain the inner edge of the disk to fluctuate between approx.20 and approx.59 R(sub g). We trace the disk reflection fraction across the full outburst of this source, and find well-constrained fractions below those observed in AGN in the Very High and High States, but consistent with other galactic sources in the Low State. We discuss the possible implications for black hole X-ray binary system dynamics and accretion flow geometry.

Miller, J. M.↗
NASA NTRS2000

Comparison Between Sea Surface Wind Speed Estimates From Reflected GPS Signals and Buoy Measurements

Reflected signals from the Global Positioning System (GPS) have been collected from an aircraft at approximately 3.7 km altitude on 5 different days. Estimation of surface wind speed by matching the shape of the reflected signal correlation function against analytical models was demonstrated. Wind speed obtained from this method agreed with that recorded from buoys to with a bias of less than 0.1 m/s, and with a standard derivation of 1.3 meters per second.

Garrison, James L.↗
NASA NTRS2000

Technical Report Series on the Boreal Ecosystem-Atmosphere Study (BOREAS) RSS-19 1994 CASI At-Sensor Radiance and Reflectance Images

The Remote Sensing Science (RSS)-19 team collected Compact Airborne Spectrographic Imager (CASI) images from the Chieftain Navaho aircraft in order to observe the seasonal change in the radiometric reflectance properties of the boreal forest landscape. CASI was deployed as a site-specific optical sensor during Boreal Ecosystem-Atmosphere Study (BOREAS) field campaigns. Image data were collected with CASI on 36 days during five field campaigns between February and September 1994, primarily at flux tower sites located at study sites near Thompson, Manitoba, and Prince Albert, Saskatchewan. A variety of CASI data collection strategies were used to meet the following scientific objectives: 1) canopy bidirectional reflectance, 2) canopy biochemistry, 3) spatial variability, and 4) estimates of up and downwelling Photosynthetically Active Radiation (PAR) and spectral albedo, as well as changes along transects across lakes and transects the Northern Study Area (NSA) and Southern Study Area (SSA). The images are stored as binary image files. A subset of the 1994 CASI acquisitions have been compressed and included on the BOREAS CD-ROM set. This subset includes three images for the NSA-OBS (Old Black Spruce) site on 06 Jun 94, 08 Aug 94, and 06 Sep 94, one image for the SSA-OBS site on 24 Jul 94; and one image for the NSA-Fen site on 08 Aug 94. The CASI imagery on the BOREAS CD-ROMs have been compressed using the Gzip program. The rest of the 1994 BOREAS CASI archive are not contained on the BOREAS CD-ROM set. Inventory listing files are supplied on the CD-ROM to inform users of the data that were collected. The RSS-19 1994 CASI images are available from the Earth Observing System Data and Information System (EOSDIS) Oak Ridge National Laboratory (ORNL) Distributed Active Archive Center (DAAC). The data files are available on a CD-ROM (see document number 20010000884).

Miller, John↗
NASA NTRS2000

BOREAS TE-8 Aspen Bark Spectral Reflectance Data

The BOREAS TE-08 team collected in-lab spectral reflectance data for aspen bark and leaves from three sites within the BOREAS SSA from 24-May-1994 to 16-Jun-1994 (IFC 1), 19-Jul-1994 to 08-Aug-1994 (IFC 2), and 30-Aug-1994 to 19-Sep-1994 (IFC 3). One to nine trees from each site were sampled during the three IFCs. Each tree was sampled in five different locations for bark spectral properties: BS, US, BR, BT, and BO. Additionally, a limited number of LV were collected. Bark samples were removed from the stem of the tree and placed in ziplock bags for transport to UNH, where they were scanned with a spectroradiometer in a controlled environment. Each sample was scanned twice: the first set of measurements was made with the bark surface moistened, and the second set was made with the bark surface air-dried for a period of 30 minutes. These data represent continuous spectra of bark reflectance. Each sample was scanned three times, rotating the sample when possible. The reported values for each sample are an average over the three scans. The data are provided in tabular ASCII files. The data files are available on a CD-ROM (see document number 20010000884), or from the Oak Ridge National Laboratory (ORNL) Distributed Active Archive Center (DAAC).

Hall, Forrest G.↗
NASA NTRS2000

BOREAS RSS-1 PARABOLA SSA Surface Reflectance and Transmittance Data

The BOREAS RSS-1 team collected surface reflectance and transmittance data from three forested sites in the SSA. This data set contains averaged reflectance factors and transmitted radiances measured by the PARABOLA instrument at selected sites in the BOREAS SSA at different view angles and at three wavelength bands throughout the day. PARABOLA measurements were made during each of the three BOREAS IFCs during the growing season of 1994 at three SSA tower flux sites as well as during the FFC-T. Additional measurements were made in early and mid-1996 during the FFC-W and during IFC-2. The data are stored in tabular ASCII files.

Hall, Forrest G.↗
NASA NTRS2000

Small Engine Technology (SET) Task 23 ANOPP Noise Prediction for Small Engines, Wing Reflection Code

The work performed under Task 23 consisted of the development and demonstration of improvements for the NASA Aircraft Noise Prediction Program (ANOPP), specifically targeted to the modeling of engine noise enhancement due to wing reflection. This report focuses on development of the model and procedure to predict the effects of wing reflection, and the demonstration of the procedure, using a representative wing/engine configuration.

Lieber, Lysbeth↗

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