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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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All sourcesNASA NTRSDOE OSTI
NASA NTRS2021

Measuring Small- and Medium-Scale TEC Variations and Irregularities from Ground-Based GNSS Observations

This paper describes approaches to measuring small- and medium-scale spatial rate of vertical TEC from GNSS observations. The horizontal scale size measured by small-scale TEC spatial rate (STSR, in TECU/km), including its latitude and longitude components, ranges from about 1.8 km to 15 km at 450 km altitude. The medium-scale TEC gradient components can be derived from global ionospheric map (GIM) based TEC gradient (GBTG) over about 110 km horizontally at low and middle latitudes, with smaller scale lengths in the longitude component in the polar region. Our analyses of GPS data show that the latitude component of STSR and GBTG is much larger than the longitude component. The spatial rates in most regions of the globe are relatively small, and their absolute mean values are mostly under 0.03 TECU/km. However, STSR is substantially larger, often greater than 0.05 TECU/km, in the equatorial ionospheric anomaly (EIA) region than in other regions, or when ionospheric disturbances occur. The disturbances include ionospheric irregularities, significant changes of regional ionospheric state during space weather events, and traveling ionospheric disturbances. Combined global TEC gradient (CGTG) with STSR and GBTG is also shown in this paper as snapshots using data from networks of more than three thousand GNSS receivers. The comparisons between STSR and GBTG indicate that their regional variation patterns are consistent though STSR is often larger than GBTG in the equatorial anomaly region or during ionospheric disturbances particularly during space weather events. The difference is attributed to the fact that the global TEC mapping technique may smooth the gradient in regions where spatial variations are large at small- and medium scales.

Akopian, Vardan↗
DOE OSTI2019

A hardware-based heat pump water heater design model for quasi-steady-state simulation

A storage heat pump water heater (HPWH) comprises a vapor compression system and a hot water tank. It can lead to more than 70% energy saving, compared to electric resistance heating. HPWH usually uses a wrapped-tank coil as the water heater. The wrapped coil has a strong interaction with the water tank and impose a new challenge for the engineering design and simulation study. Based on the US DOE/ORNL Heat Pump Design Model (HPDM), a component-based thermal system modelling platform, a segment-to-segment wrapped-tank coil model and a one-dimensional stratified water tank model were developed, which facilitates modeling and design HPWHs having various configurations and components. In the paper, the new HPWH system design model was used to investigate effects of compressor size, refrigerant charge, water draw pattern, and refrigerant type, etc., for predicting 24-hour energy factors and first-hour rating. The HPWH system model was proved to be an effective equipment design tool.

Shen, Bo↗
DOE OSTI2020

CITRC Cable Info

Working on a DOE project with university sub-contractors to build power grid simulations. We need the cable size and spacing to build accurate models. Other related documents on the physical set up and electrical components have been released, INL/MIS-20-59900 and INL/MIS-20-60003.

24 POWER TRANSMISSION AND DISTRIBUTION↗
DOE OSTI2021

Experience with Inner Reflector Plug exchange in SNS

The Inner Reflector Plug (IRP) is a central component of the Spallation Neutron Source target monolith, which houses the mercury target and four liter-sized neutron moderator units. It is exposed to high-level radiation fields during routine operation and builds up significant activity. The IRP needs to be replaced due to moderator neutron poison and decoupler burn-out, which is used for shaping neutron pulses. The first IRP exchange took place in March 2018. The old IRP was extracted from the target monolith, providing space for the new one. It was split into three segments, each of which was handled separately. The lowest section of the IRP is the largest segment in size and in activity and is temporarily stored on-site for cool down before conduction post irradiation examination. In support of planning the replacement activities, a wide range of activation and transport analyses were performed. This included calculating isotope inventories and the radiation fields for each segment as it is extracted in storage casks, and the radiation field from the empty IRP pit in the target monolith. While the replacement was taking place, measurements were performed and later on compared to the calculations. During these studies, it was discovered that a significant contributor to the radiation field from the lower IRP segment is from photo-neutrons. Photo-nuclear physics was added to the analyses and calculated results compared well with measured dose rates.

Popova, Irina I.↗
DOE OSTI2024

Anode Upcycling via Tailored Solvent Treatment

To achieve a truly closed-loop direct recycling process for lithium-ion batteries, all component materials must be recovered. To date, direct recycling method development has primarily focused on the high-value transition-metal cathode materials, while the inherently lower-value graphite has been challenging to recover in a cost-effective manner. However, end-of-life graphite contains a unique engineered value due to the presence of the solid electrolyte interphase (SEI). Growth of the SEI during the cell's active lifetime stabilizes the electronically reactive graphite surface through an irreversible consumption of Li, and thus necessitates both excess lithiation of the cathode and a costly and time-intensive formation procedure during manufacturing. An optimized pre-formed SEI that capitalizes on existing SEI components from end-of-life batteries has the potential to significantly reduce cathode lithiation requirements and eliminate the critical bottleneck of formation cycling during cell remanufacturing. Further, retaining Li at the anode obviates the need for a separate Li leaching and recovery step, improving the overall efficiency of the direct recycling line. In this work, we present a novel approach to "upcycling" spent graphite through use of tailored chemical treatment to remove adverse (i.e., highly resistive and/or poorly passivating) SEI species while retaining beneficially passivating components. We have explored a rational set of solvents spanning a range of polarity, proticity, and molecular size to evaluate structure-property-performance relationships between applied solvent(s), removed and remaining SEI species, and electrochemical response of the resulting graphite product. Further, we have developed and optimized a robust and holistic analysis procedure that couples symmetric-cell electrochemical testing, multi-modal materials characterization, and advanced electrochemical modeling. These analysis results inform a set of correlative metrics for graphite performance relative to both solvent properties and upcycled SEI composition. We demonstrate effective tunability in the residual SEI composition by varying solvent identity and concentration, and report on several promising solvent systems that achieve comparable or performance to pristine graphite.

anode recycling↗
NASA NTRS1990

Improved evaluation of optical depth components from Langley plot data

A simple, iterative procedure to determine the optical depth components of the extinction optical depth measured by a solar radiometer is presented. Simulated data show that the iterative procedure improves the determination of the exponent of a Junge law particle size distribution. The determination of the optical depth due to aerosol scattering is improved as compared to a method which uses only two points from the extinction data. The iterative method was used to determine spectral optical depth components for June 11-13, 1988 during the MAC III experiment.

Biggar, S. F.↗
DOE OSTI2017

Investigation of the Interaction between Nafion Ionomer and Surface Functionalized Carbon Black Using Both Ultrasmall Angle X-ray Scattering and Cryo-TEM

In making a catalyst ink, the interaction between Nafion ionomer and catalyst support are the key factors that directly affect both ionic conductivity and electronic conductivity of the catalyst layer in a membrane electrode assembly (MEA). One of the major aims of this investigation is to understand the behavior of the catalyst support, Vulcan XC-72 (XC-72) aggregates, in the existence of the Nafion ionomer in a catalyst ink to fill the knowledge gap of the interaction of these components. The dispersion of catalyst ink not only depends on the solvent, but also depends on the interaction of Nafion and carbon particles in the ink. The interaction of Nafion ionomer particles and XC-72 catalyst aggregates in liquid media was studied using ultra small angle x-ray scattering (USAXS) and cryogenic TEM techniques. Carbon black XC-72) and functionalized carbon black systems were introduced to study the interaction behaviors. A multiple curve fitting was used to extract the particle size and size distribution from scattering data. The results suggest that the particle size and size distribution of each system changed significantly in Nafion + XC-72 system, Nafion + NH2-XC72 system, and Nafion + SO3H-XC-72 system, which indicates that an interaction among these components (i.e. ionomer particles and XC-72 aggregates) exists. The cryogenic TEM, which allows for the observation the size of particles in a liquid, was used to validate the scattering results and shows excellent agreement.

Catalyst Ink↗
NASA NTRS2006

Relationships Among Intrinsic Properties of Ordinary Chondrites: Oxidation State, Bulk Chemistry, Oxygen-isotopic Composition, Petrologic Type, and Chondrule Size

The properties of ordinary chondrites (OC) reflect both nebular and asteroidal processes. OC are modeled here as having acquired nebular water, probably contained within phyllosilicates, during agglomeration. This component had high Ai70 and acted like an oxidizing agent during thermal metamorphism. The nebular origin of this component is consistent with negative correlations in H, L, and LL chondrites between oxidation state (represented by olivine Fa) and bulk concentration ratios of elements involved in the metal-silicate fractionation (e.g., NdSi, Ir/Si, Ir/Mn, Ir/Cr, Ir/Mg, Ni/Mg, As/Mg, Ga/Mg). LL chondrites acquired the greatest abundance of phyllosilicates with high (delta)O-17 among OC (and thus became the most oxidized group and the one with the heaviest O isotopes); H chondrites acquired the lowest abundance, becoming the most reduced OC group with the lightest O isotopes. Chondrule precursors may have grown larger and more ferroan with time in each OC agglomeration zone. Nebular turbulence may have controlled the sizes of chondrule precursors. H-chondrite chondrules (which are the smallest among OC) formed from the smallest precursors. In each OC region, low-FeO chondrules formed before high-FeO chondrules during repeated episodes of chondrule formation. During thermal metamorphism, phyllosilicates were dehydrated; the liberated water oxidized metallic Fe-Ni. This caused correlated changes with petrologic type including decreases in the modal abundance of metal, increases in olivine Fa and low-Ca pyroxene Fs, increases in the olivine/pyroxene ratio, and increases in the kamacite Co and Ni contents. As water (with its heavy 0 isotopes) was lost during metamorphism, inverse correlations between bulk (delta)O-18 and bulk (delta)O-17 with petrologic type were produced. The H5 chondrites that were ejected from their parent body approx.7.5 Ma ago during a major impact event probably had been within a few kilometers of each other since they accreted approx.4.5 Ga ago. There are significant differences in the olivine compositional distributions among these rocks; these reflect stochastic nebular sampling of the oxidant (Le., phyllosilicates with high (delta)O-17) on a 0.1-1 km scale during agglomeration.

Rubin, Alan E.↗
DOE OSTI2021

Dynamic self-assembly of compartmentalized DNA nanotubes

Abstract Bottom-up synthetic biology aims to engineer artificial cells capable of responsive behaviors by using a minimal set of molecular components. An important challenge toward this goal is the development of programmable biomaterials that can provide active spatial organization in cell-sized compartments. Here, we demonstrate the dynamic self-assembly of nucleic acid (NA) nanotubes inside water-in-oil droplets. We develop methods to encapsulate and assemble different types of DNA nanotubes from programmable DNA monomers, and demonstrate temporal control of assembly via designed pathways of RNA production and degradation. We examine the dynamic response of encapsulated nanotube assembly and disassembly with the support of statistical analysis of droplet images. Our study provides a toolkit of methods and components to build increasingly complex and functional NA materials to mimic life-like functions in synthetic cells.

59 BASIC BIOLOGICAL SCIENCES↗
NASA NTRS1978

Development of structural dynamic test environments for subsystems and components

Structural dynamic environmental test levels were developed for the thematic mapper instrument, components of the Tandberg-Hanssen instrument, and components of the International Ultraviolet Explorer spacecraft using NASTRAN structural models and test data. Both static and dynamic NASTRAN analyses were used. The model size required could be as small as 300 degrees of freedom for the static analysis and as large as 4000 degrees of freedom or more for the high frequency dynamic analysis. An important step in the development of the levels is model verification by test. The launch environments that generally dictate many important features of the design of an instrument or component are steady state acceleration, sinusoidal vibration, and random vibration.

Coladonato, R. J.↗
NASA NTRS2002

Dynamic Modeling of ALS Systems

The purpose of dynamic modeling and simulation of Advanced Life Support (ALS) systems is to help design them. Static steady state systems analysis provides basic information and is necessary to guide dynamic modeling, but static analysis is not sufficient to design and compare systems. ALS systems must respond to external input variations and internal off-nominal behavior. Buffer sizing, resupply scheduling, failure response, and control system design are aspects of dynamic system design. We develop two dynamic mass flow models and use them in simulations to evaluate systems issues, optimize designs, and make system design trades. One model is of nitrogen leakage in the space station, the other is of a waste processor failure in a regenerative life support system. Most systems analyses are concerned with optimizing the cost/benefit of a system at its nominal steady-state operating point. ALS analysis must go beyond the static steady state to include dynamic system design. All life support systems exhibit behavior that varies over time. ALS systems must respond to equipment operating cycles, repair schedules, and occasional off-nominal behavior or malfunctions. Biological components, such as bioreactors, composters, and food plant growth chambers, usually have operating cycles or other complex time behavior. Buffer sizes, material stocks, and resupply rates determine dynamic system behavior and directly affect system mass and cost. Dynamic simulation is needed to avoid the extremes of costly over-design of buffers and material reserves or system failure due to insufficient buffers and lack of stored material.

Jones, Harry↗
NASA NTRS2019

Micro-meteoroid and orbital debris radar from Goldstone Radar observations

Micro-meteoroid and orbital debris (MMOD) refers to millions of micrometeoroids and orbital debris orbiting the Earth, which can come from remaining parts of spacecraft from previous missions. These debris objects keep colliding and creating new pieces of debris, with very different sizes ranging from millimeters to meters. About 99.3% of the debris objects have a size < 1 cm. These debris objects, traveling at speeds of 10 km/s, can cause significant damage to spacecraft, satellites, and astronauts. Despite the historic use of shielding to protect vital spacecraft components, MMOD still present a potential hazard for future missions and operations involving humans in space. Goldstone’s orbital debris radar (ODR) enhances the NASA orbital debris model with radar observation data, providing vital information on orbital debris detections: size, Doppler, range, and orbit inclination angle. These observations currently provide the only access to information about this size class (2 mm to 10 mm) of orbital debris. Goldstone’s ODR experiments operate as a bistatic radar, with overlapping beams providing a wide distribution of ranges. From 2004 to early 2018, Goldstone’s ODR has been collecting orbital debris data from altitudes covering 280 km to 3000 km. Since the decommissioning of the receive antenna in early 2018, Goldstone’s range coverage is reduced to a 300 km window within a 600 km to 1000 km potential range coverage, depending on the pointing geometry and antenna station used. We are investigating alternative transmit receive configurations at Goldstone to recover our previous wide range coverage.

Rodriguez-Alvarez, Nereida↗
DOE OSTI2016

Development of a beam ion velocity detector for the heavy ion beam probe

In an axisymmetric plasma, the conservation of canonical angular momentum constrains heavy ion beam probe (HIBP) trajectories such that measurement of the toroidal velocity component of secondary ions provides a localized determination of the poloidal flux at the volume where they originated. We have developed a prototype detector which is designed to determine the beam angle in one dimension through the detection of ion current landing on two parallel planes of detecting elements. A set of apertures creates a pattern of ion current on wires in the first plane and solid metal plates behind them; the relative amounts detected by the wires and plates determine the angle which beam ions enter the detector, which is used to infer the toroidal velocity component. The design evolved from a series of simulations within which we modeled ion beam velocity changes due to equilibrium and fluctuating magnetic fields, along with the ion beam profile and velocity dispersion, and studied how these and characteristics such as the size, cross section, and spacing of the detector elements affect performance.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2016

Lower molar shape and size in prosimian and platyrrhine primates

Abstract The goal of this research is to evaluate the relative strength of the influences of diet, size, and phylogenetic signal on dental geometric shape. Accurate comprehension of these factors and their interaction is important for reconstructing diet and deriving characters for a cladistic analysis in fossil primates. Geometric morphometric analysis is used to identify axes of shape variation in the lower second molars of (a) prosimian primates and (b) platyrrhines. Landmarks were placed on µCT‐generated surface renderings. Landmark configurations were aligned using generalized Procrustes analysis. Principal components analysis and phylogenetic principal components analysis (pPCA) were performed on species average landmark co‐ordinates. pPCs were examined with phylogenetic generalized least squares analysis for association with size and with diet. PCs from both phylogenetic and non‐phylogenetic analyses were sufficient to separate species by broad dietary categories, including insectivores and folivores. In neither analysis was pPC1 correlated with tooth size, but some other pPCs were significantly correlated with size. The pattern of association between pPCs and size altered when centroid size and dietary variables were combined in the model; effects of diet factors typically exceeded effects of size. These results indicate a dominant phylogenetic and dietary signal in molar shape but also show some shape change correlated with size in the absence of obvious dietary associations. Geometric morphometric analysis appears to be useful for tracking functional traits in molars, particularly in tracking differences between folivorous and insectivorous species.

St. Clair, Elizabeth M.↗
NASA NTRS1982

Dustsonde measurements of the Mount St. Helens volcanic dust cloud over Wyoming

Numerous balloon soundings of the aerosol and condensation nuclei (CN) concentrations were made over Laramie, Wyoming following the eruption of Mount St. Helens in May of 1980. On several occasions the volatility of the particles was tested. In addition, special instrumentation was used to observe the evolution of particle size after the eruption. The particles in the initial cloud were relatively large and nonvolatile. In a relatively short time, however, the aerosol began showing a dominant volatile component. Although there were probably no CN in the original cloud due to the expected very short coagulation life time, high concentrations of unusually small CN particles were observed about a month after the eruption. By the end of September the CN profiles and associated particle size were practically back to normal. At present the aerosol particles show about a three times larger concentration than before the eruption, most of the new material being in a layer centered around 19 km. The net effect of the more recent series of eruptions during the last half of October 1980 seems to be negligible.

Rosen, J. M.↗
NASA NTRS1993

Impact comminution of glasses: Implications for lunar regolith evolution

Glasses are important parts of every lunar regolith sample, whether in the form of indigenous melts such as mesostasis or pyroclastics, or as quenched impact melts. The modal proportions of agglutinitic impact melts alone can exceed 50 percent for some mature regoliths, and glasses are commonly the most dominant single component of lunar soils. They therefore participate in and possibly affect all evolutionary processes to which regoliths are subjected, such as comminution and attendant chemical fractionation as a function of grain size, the retention of solar-wind products, the production of superparamagnetic iron, and others. Because they are such an integral part of lunar regoliths, a more complete understanding of regolith evolution must include the role played by these vitreous components. This contribution examines the comminution behavior of a variety of glasses and a fine-grained basalt under conditions of repetitive impact, and compares this behavior to those of crystalline components, such as lithic fragments and major rock-forming minerals.

Cintala, Mark J.↗
DOE OSTI2025

Dust Direct Radiative Effect Including Large Particles and Component Minerals

The direct radiative effect (DRE) of dust aerosols in Earth system models (ESMs) remains highly uncertain, largely due to inadequate representations of particle size distribution (PSD) and mineral composition. Using NASA's Earth Surface Mineral Dust Source Investigation (EMIT) soil mineralogy data and observed PSD in an ESM that resolves dust mineral composition and emitted diameters from 0.1 to 70 μm, we find a near-neutral global dust net DRE (−0.057 W m −2 ), weaker than most previous estimates. Large dust (diameter >10 μm) contributes 30% of the global longwave dust optical depth, providing observational constraints on large-particle abundance, and offsets 20% of the dust shortwave cooling over major source regions. Incorporation of EMIT mineralogy reduces shortwave uncertainty by more than 50%. The remaining uncertainty mainly exists in processes controlling dust abundance, particularly the poorly understood transport of large dust, and longwave optical properties, which require additional observational constraints to more accurately quantify the dust DRE.

Li, Longlei [Cornell Univ., Ithaca, NY (United Sta↗
NASA NTRS1975

Heat conduction in metal-filled polymers - The role of particle size, shape, and orientation

This paper presents a new type of analysis for predicting the thermal conductivity of disperse composites from the properties of the component phases and elementary characterizations of particle shapes and orientation. This analysis successfully predicted the sensitivity to particle shape which was confirmed by experiments also reported in this paper. These results suggest that highly elongated particles may be used to achieve dramatic modifications of thermal conductivity and the analysis presented here may be a useful tool in the design or development of disperse composites of specific thermal conductivity. The analysis may also apply to other properties such as electrical conductivity or magnetic permeability.

Hansen, D.↗

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